Plasma processing of interstellar PAHs into solar system kerogen     

Wdowiak TJ  Lee W  Cronin J  Beegle LW  Robinson MS 《Planetary and Space Science》1995,43(10-11):1175-1182

Processes resulting in the formation of hydrocarbons of carbonaceous chondrites and the identity of the interstellar molecular precursors involved are an objective of investigations into the origin of the solar system and perhaps even life on earth. We have combined the resources and experience of an astronomer and physicists doing laboratory simulations with those of a chemical expert in the analysis of meteoritic hydrocarbons, in a project that investigated the conversion of polycyclic aromatic hydrocarbons (PAHs) formed in stellar atmospheres into alkanes found in meteorites. Plasma hydrogenation has been found in the University of Alabama at Birmingham Astrophysics Laboratory to produce from the precursor PAH naphthalene, a new material having an IR absorption spectrum (Lee, W. and Wdowiak, T.J., Astrophys. J. 417, L49-L51, 1993) remarkably similar to that obtained at Arizona State University of the benzene-methanol extract of the Murchison meteorite (Cronin, J.R. and Pizzarello, S., Geochim. Cosmochim. Acta 54, 2859-2868, 1990). There are astrophysical and meteoritic arguments for PAH species from extra-solar sources being incorporated into the solar nebula, where plasma hydrogenation is highly plausible. Conversion of PAHs into alkanes could also have occurred in the interstellar medium. The synthesis of laboratory analogs of meteoritic hydrocarbons through plasma hydrogenation of PAH species is underway, as is chemical analysis of those analogs. The objective is to clarify this heretofore uninvestigated process and to understand its role during the origin of the solar system as a mechanism of production of hydrocarbon species now found in meteorites. Results have been obtained in the form of time-of-flight spectroscopy and chemical analysis of the lab analog prepared from naphthalene.  相似文献   

On the astrometric detection of neighboring planetary systems,II     

George Gatewood  Lee Breakiron  Ronald Goebel  Steven Kipp  Jane Russell  John Stein 《Icarus》1980,41(2):205-231

Extensive testing suggests that astrometric techniques can be employed to detect and study virtually any planetary system that may exist within 40 light years (12.5 parsec) of the Sun. Following the conclusion of Paper I [G. Gatewood, Icarus27 (1976), 1–12], the astrometric group at the Allegheny Observatory began an intensive survey of 20 nearby stars to detect the nonlinear variations in their motion that planetary systems would induce. Several tests conducted to further our understanding of the limitations of this survey indicated that the photographic detector itself is responsible for the majority of the random error. A new photoelectric detector has been designed and a simplified prototype of it successfully tested. The new detector is expected to be able to utilize virtually all of the astrometric information transmitted through the Earth's atmosphere. This is sufficient to determine relative positions to within an accuracy of approximately 1 milliarcsec/hr. Such precisions exceed the design capabilities of the best existing astrometric telescopes, thus a feasibility study has been conducted for the design of an improved instrument. The study concludes that a new ground-based telescope and the new detector combined should be able to study stars as faint as the 17th magnitude with an annual accuracy of a few tenths of a milliarcsecond. However, to obtain the ultimate accuracy possible from current technology, we must place an astrometric system above the Earth's atmosphere. A space-borne instrument utilizing the new detector would in theory have sufficient accuracy to detect any Earth-like planet orbiting any of the several hundred stars nearest the Sun.  相似文献   

Coherent amplification and pulsar phenomena     

Lee W. Casperson 《Astrophysics and Space Science》1977,48(2):389-399

A modification of the rotating-star model has been developed to interpret the periodic energy bursts from pulsars. This new configuration involves -directed oscilltion modes in the stellar atmosphere or magnetosphere, and most aspects of the typical pulse characteristics are well accounted for. Gain is provided by resonant interactions with particles trapped in the stellar magnetic field. The most significant feature is the fact that highly directional beaming of the output energy results as a natural consequence of coherence between the radiation fields emerging from various locations about the pulsar; and a localized radiation origin is not required.  相似文献   

Observations of the Orion Nebula in Hα, [NII] and Hβ lines     

C. T. Hua  R. Louise 《Astrophysics and Space Science》1982,88(2):477-485

Monochromatic photographs of the Orion Nebula taken through narrow bandpass interference filters (Δλ=10 Å) centred on Hα, Hβ and [NII] lines are presented. Ratio contours of Hα/[NII] and Hα/Hβ are derived. They enable a detailed study of the point-to-point variation in ionization structure and temperature throughout the nebula. Dust located within the ionized gas is studied from the Hα/Hβ ratio which varies from point to point over the nebula. Its strongest concentration, apart in the obvious ‘dark bay’, occurs in a shell surrounding the exciting stars, with about 2′ of diameter. Close to Θ¹ Ori the Hα/Hβ ratio, corrected for interstellar reddening, is about 3.0 in good agreement with the predicted value (Brocklehurst, 1971). To account for these measures, the following arguments are proposed:

1. Dust grains are completely or partially destroyed in region close to the exciting stars.
2. Radiation pressure and stellar wind push the remaining dust up to some equilibrium distance outwards. The consequence of this action is obviously the formation of a ‘dust mantle’ which is seen as a ring in projection.

  相似文献   

M computed from strong motion accelerograms recorded in Yugoslavia     

V. Lee  M. Trifunac  M. Herak  M. iv i   D. Herak 《地震工程与结构动力学》1990,19(8):1167-1179

It is shown that the new definition¹ of strong motion local magnitude M leads to stable estimates of magnitudes for earthquakes in Yugoslavia, with epicentral distances R <100 km and for 2.5 < M < 6.5. Tables with magnitudes computed using this new procedure are presented for all earthquakes contributing to the strong motion accelerogram files in EQINFOS for Yugoslavia.² The similarity of our findings with the analogous analyses for California suggests new possibilities for relative calibration between various local magnitude scales, which are used in southeastern Europe, and M_L in California.  相似文献   

1980²000北京市农业土地生产性的变动分析   总被引：1，自引：0，他引：1  

王鹏飞  鲁奇  傅桦  李娟 《地理研究》2006,25(4):719-729

根据1980、1990、2000年的统计资料和实地走访观察,本文分析了北京市乡镇一级的粮食作物、蔬菜作物和果品作物的分布格局及农业土地生产性近20年的变化。研究认为:1980年北京农业生产分布格局与土地生产性为比较典型的杜能模式;随着农业经营的多样化,1990年和2000年北京农业土地生产性呈现出多样的分布格局;北京粮食作物、蔬菜作物、果品作物的分布格局及农业土地生产性近20年的变化与此阶段的农业生产政策、农业以外的社会经济活动变化有较强的关联性;对北京以上问题的研究为验证杜能、辛克利亚、布莱昂特城市周边农业地域研究经典理论的演变提供了实证案例。  相似文献   

Drying effects on sorption capacity of coastal sediment: The importance of architecture and polarity of organic matter     

Zhanfei Liu  Cindy Lee 《Geochimica et cosmochimica acta》2006,70(13):3313-3324

Investigations on how desiccation changes sorption of organic compounds by salt marsh sediments provide insight into the physical and chemical properties of these wide-spread coastal sediments. We measured sorption of compounds with different polarities (lysine, tyrosine, naphthalene and aniline) onto natural sediments and sediments that were dried and rewetted. Sorption of lysine by marsh sediment decreased significantly when the sediment was dried using a freeze-drier, oven, or desiccator, and sorption capacity was not restored when sediments were rewetted. In contrast to lysine, the sorption capacity of more hydrophobic compounds (tyrosine, aniline and naphthalene) increased significantly after salt marsh sediment was dried. These results suggest that drying greatly increased sediment hydrophobicity. Consistently, water drop penetration time, an index of hydrophobicity, was significantly lower for combusted sediments than for those that were simply dried. Sediments treated with EDTA, or boiled in seawater, exhibited a similar or even greater reduction in lysine sorption capacity compared with sediments that were dried. Water retention capacity of salt marsh sediment decreased 50% after sediment was dried. The effects of pH and salinity on lysine sorption in wet and dry sediments suggest that carboxyl groups play a major role in lysine sorption through cation ion exchange, and drying may reduce access to carboxyl groups. We hypothesize that the three-dimensional (3D) structure of organic matter, originating mainly from Spartina alterniflora, is an important factor controlling sorption capacity in salt marsh sediment. The drying process makes sedimentary organic matter change conformation, shrink in volume, and expose hydrophobic groups, thus becoming more hydrophobic. In environments with wet and dry cycles, the distribution of hydrophobic or hydrophilic compounds between solution and particulate phases could thus be influenced by the 3D structure and polarity of organic matter.  相似文献   

Some breakage characteristics of ultra-fine wet grinding with a centrifugal mill     

Heechan Cho  Hoon LeeYeongwoo Lee 《International Journal of Mineral Processing》2006

A centrifugal mill is a high-power intensity media mill that can be used for ultra-fine grinding, employing centrifugal forces generated by gyration of the axis of the mill tube in a circle. The mill charge motion is quite different depending on the ratio of the gyration diameter to the mill diameter (G / D ratio), varying from a motion similar to that of a conventional tumbling media mill to that of a vibration mill. In this study, a centrifugal mill was constructed with an arrangement where the gyration diameter could be readily adjusted. The batch grinding characteristics of three different minerals (limestone, talc and illite) in water with dispersing agent were investigated at various G / D ratios. It was found that the optimum G / D ratio in terms of the specific energy consumption to give a desired fineness of product was different for the three minerals. This was due to their different reactions to the breakage mechanisms provided by the mill charge motion at varying G / D ratios. The size distributions became progressively narrower at increased grinding times, and particles finer than about 0.1 μm were not detected even for prolonged grinding times. Measurement of specific surface areas indicated that this was not due to an artifact of the size measurements by laser diffractometry. This implies that there is a limitation in which particles finer than 0.1 μm are not produced under the conditions tested in this type of mill, but further investigation is needed for experimental verification of this limit of comminution.  相似文献   

Study on the kinetics of iron oxide leaching by oxalic acid   总被引：2，自引：0，他引：2  

Suong Oh Lee  Tam Tran  Yi Yong Park  Seong Jun Kim  Myong Jun Kim   《International Journal of Mineral Processing》2006,80(2-4):144-152

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.  相似文献   

Microbial resistance to the heavy metal pollution     

Jiang  Hua  Jing  Huxiao  Qing  Weixiao 《中国地球化学学报》2006,25(1):3-3

  相似文献