Effects of Lime‐Based Waste Materials on Immobilization and Phytoavailability of Cadmium and Lead in Contaminated Soil     

Jung Eun Lim  Mahtab Ahmad  Sang Soo Lee  Christopher L. Shope  Yohey Hashimoto  Kwon‐Rae Kim  Adel R. A. Usman  Jae E. Yang  Yong Sik Ok 《洁净——土壤、空气、水》2013,41(12):1235-1241

Low cost lime‐based waste materials have recently been used to immobilize metals in contaminated soils. This study was conducted to evaluate the effects of oyster shells and eggshells as lime‐based waste materials on immobilization of cadmium (Cd) and lead (Pb) in contaminated soil, as well as their effects on metal availability to maize plants (Zea mays L.). Oyster shells and eggshells were applied to soils at 1 and 5% w/w, after which they were subject to 420 days of incubation. The toxicity characteristic leaching procedure (TCLP) test was employed to determine the mobility of Cd and Pb in soils. The results showed that the addition of waste materials effectively reduced the metal mobility as indicated by the decrease in the concentration of TCLP‐extractable Cd and Pb, and this was mainly due to significant increases in soil pH (from 6.74 in untreated soil to 7.85–8.13 in treated soil). A sequential extraction indicated that the addition of such alkaline wastes induced a significant decline in the concentration of Cd in the exchangeable fraction (from 23.64% in untreated soil to 1.90–3.81% in treated soil), but it increased the concentration of Cd in the carbonate fraction (from 19.59% in untreated soil to 36.66–46.36% in treated soil). In the case of Pb, the exchangeable fraction was also reduced (from 0.67% in untreated soil to 0.00–0.01% in treated soil), and the fraction of Pb bound to carbonate was slightly increased (from 16.61% in untreated soil to 16.41–18.25% in treated soil). Phytoavailability tests indicated that the metal concentrations in the shoots of maize plant were reduced by 63.39–77.29% for Cd and by 47.34–75.95% for Pb in the amended soils, with no significant differences being observed for the amendment types and the application rates. Overall, these results indicate that oyster shells and eggshells can be used as low cost lime‐based amendments for immobilizing Cd and Pb in contaminated soils.  相似文献   

Convection in a rotating cylinder with its sidewall having a finite thermal conductance     

Jae Min Hyun 《地球物理与天体物理流体动力学》2013,107(1-4):83-98

Abstract

An investigation is made of steady thermal convection of a Boussinesq fluid confined in a vertically-mounted rotating cylinder. The top and bottom endwall disks are thermal conductors at temperatures T_t and T_b with δT = T_t ? T_b >0. The vertical sidewall has a finite thermal conductance. A Newtonian heat flux condition is adopted at the sidewall. The Rayleigh number of the fluid system is large to render a boundary layer-type flow. Finite-difference numerical solutions to the full Navier-Stokes equations are obtained. The vertical motions within the buoyancy layer along the sidewall induce weak meridional flows in the interior. Because of the Coriolis acceleration, the meridional flows give rise to azimuthal flows relative to the rotating container. Strong vertical gradients of azimuthal flows exist in the regions near the endwalls. As the stratification effect increases, concentration of flow gradients in thin endwall boundary layers becomes more pronounced. The azimuthal flow field exhibits considerable horizontal gradients. The temperature field develops horizontal variations superposed on the dominant vertical distribution. As either the sidewall thermal conductance or the stratification effect decreases, the temperature distribution tends to the profile varying linearly with height. Comparisons of the sizes of the dynamic effects demonstrate that, in the bulk of flow field, the vertical shear of azimuthal velocity is supported by the horizontal temperature gradient, resulting in a thermal-wind relation.  相似文献   

Historical record of metal accumulation and lead source in the southeastern coastal region of Korea     

Dhong-il Lim  Seung Woon Jung  Man Sik Choi  Sun Mee Kang  Hoi Soo Jung  Jin Yong Choi 《Marine pollution bulletin》2013

Concentrations of heavy metals and Pb isotopes were measured in the 1-M HCl leaching fraction of core sediments spanning the last 400 years. This sedimentary record of pollution history in metal concentrations shows a good correlation with the increases in industrialization, urbanization, and energy consumption since 1901s. Notably, the Pb concentration and the ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb ratios were constant before the 1910s (16.7 μg/g, 0.844, and 2.098, respectively), whereas they increased steadily up to 21.9 μg/g, 0.848, and 2.101 after the 1910s. The correlations between Pb isotope ratios (²⁰⁶Pb, ²⁰⁷Pb, and ²⁰⁸Pb) showed different linear regression trends for core sediments before and after the 1910s, indicating differences in Pb sources. Our interpretation suggests that the source of anthropogenic Pb in Korean coastal region and the Yellow Sea shelf was presumed to be Chinese coals or ores, which have also played a major role as sources of atmospheric particulate Pb.  相似文献   

Internal reflection pattern of Korea Strait shelf mud (Nakdong River subaqueous delta) off southeast Korea and implications for Holocene relative base-level change     

Gwang H.  Lee  Dae C.  Kim  Mi K.  Park  Soo C.  Park  Han J.  Kim  Hyeong T.  Jou  Boo K.  Khim 《Island Arc》2010,19(1):71-85

The Korea Strait shelf mud (KSSM) (Nakdong River subaqueous delta) is the most conspicuous Holocene sedimentary feature in the inner shelf off southeast Korea. Analysis of multi-channel sparker profiles and ¹⁴C ages of sediment cores reveals that the KSSM consists of three seismic units at the depocenter (>60 m thick): (i) the thin transgressive bottom (> ca 8000 cal bp ); (ii) thick (>40 m) obliquely progradational middle ( ca 8000– ca 2600 cal bp ); and (iii) thin transgressive top ( ca 2600 cal bp –present) units. The relative base level, predicted from the internal reflection pattern of the KSSM, remained significantly deeper (up to >70 m) than global sealevel during much of the Holocene. The apparent gradual drop (∼20 m) of the relative base level during the deposition of the middle unit, followed by a rise, further suggests that base level does not conform to sealevel and is more sensitive than the relative sealevel is to the local oceanographic regime and processes.  相似文献   

Detrital zircon geochronology of the Cretaceous Sindong Group,Southeast Korea: Implications for depositional age and Early Cretaceous igneous activity   总被引：1，自引：0，他引：1  

Yong Il Lee  Taejin Choi  Hyoun Soo Lim  Yuji Orihashi 《Island Arc》2010,19(4):647-658

The Sindong Group forms the lowermost basin‐fill of the Gyeongsang Basin, the largest Cretaceous nonmarine basin located in southeastern Korea, and comprises the Nakdong, Hasandong, and Jinju Formations with decreasing age. The depositional age of the Sindong Group has not yet been determined well and the reported age ranges from the Valanginian to Albian. Detrital zircons from the Sindong Group have been subjected to U–Pb dating using laser ablation inductively coupled plasma mass spectrometry. The Sindong Group contains noticeable amounts of detrital magmatic zircons of Cretaceous age (138–106 Ma), indicative of continuous magmatic activity prior to and during deposition of the Sindong Group. The youngest detrital zircon age of three formations becomes progressively younger stratigraphically: 118 Ma for the Nakdong Formation, 109 Ma for the Hasandong Formation, and 106 Ma for the Jinju Formation. Accordingly, the depositional age of the Sindong Group ranges from the late Aptian to late Albian, which is much younger than previously thought. Lower Cretaceous magmatic activity, which supplied detrital zircons to the Sindong Group, changed its location spatially through time; it occurred in the middle and northern source areas during the early stage, and then switched to the middle to southern source areas during the middle to late stages. This study reports first the Lower Cretaceous magmatic activity from the East Asian continental margin, which results in a narrower magmatic gap (ca 20 m.y.) than previously known.  相似文献   

Erosion of a high‐altitude,low‐relief area on the Korean Peninsula: implications for its development processes and evolution          下载免费PDF全文

Jongmin Byun  Arjun M. Heimsath  Yeong Bae Seong  Soo Yong Lee 《地球表面变化过程与地形》2015,40(13):1730-1745

The processes involved in the development of high‐altitude, low‐relief areas (HLAs) are still poorly understood. Although cosmogenic nuclides have provided insights into the evolution of HLAs interpreted as paleo‐surfaces, most studies focus on estimating how slowly they erode and thereby their relative stability. To understand actual development processes of HLAs, we applied several techniques of cosmogenic nuclides in the Daegwanryeong Plateau, a well‐known HLA in the Korean Peninsula. Our denudation data from strath terraces, riverine sediments, soils, and tors provide the following conclusions: (1) bedrock incision rate in the plateau (~127 m Myr^?1) is controlled by the incision rate of the western part of the Korean Peninsula, and is similar to the catchment‐wide denudation rate of the plateau (~93 m Myr^?1); (2) the soil production function we observed shows weak depth dependency that may result from highly weathered bedrock coupled with frequent frost action driven by alpine climate; (3) a discrepancy between the soil production and catchment‐wide denudation rates implies morphological disequilibrium in the plateau; (4) the tors once regarded as fossil landforms of the Tertiary do not reflect Tertiary processes; and (5) when compared with those of global paleo‐surfaces (<20 m Myr^?1), our rapid denudation rates suggest that the plateau cannot have maintained its probable initial paleo landscape, and thus is not a paleo‐surface. Our data contribute to understanding the surface processes of actively eroding upland landscapes as well as call into question conventional interpretations of supposed paleo‐surfaces around the world. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Comparison of the Bright Band Characteristics Measured by Micro Rain Radar （MRR） at a Mountain and a Coastal Site in South Korea   总被引：1，自引：0，他引：1  

Joo-Wan CHA  Ki-Ho CHANG  Seong Soo YUM  Young-Jean CHOI 《大气科学进展》2009,26(2):211-221

Data from a long term measurement of Micro Rain Radar (MRR) at a mountain site (Daegwallyeong,DG, one year period of 2005) and a coastal site (Haenam, HN, three years 2004–2006) in South Korea were analyzed to compare the MRR measured bright band characteristics of stratiform precipitation at the two sites. On average, the bright band was somewhat thicker and the sharpness (average gradient of reflectivity above and below the reflectivity peak) was slightly weaker at DG, compared to those values at HN. The ...  相似文献   

Local Meteorological and Synoptic Characteristics of Fogs Formed over Incheon International Airport in the West Coast of Korea   总被引：2，自引：0，他引：2  

Chang Ki KIM  Seong Soo YUM 《大气科学进展》2010,27(4):761-776

Fogs observed over Incheon international airport (IIA) in the west coast of Korea from January 2002 to August 2006 are classified into categories of coastal fog, cold sea fog, and warm sea fog based on the areal extent of the fogs and the difference between the air temperature (T) and the SST, i.e., cold sea fog if TSST = T-SST>0^oC and warm sea fog if TSST <0^oC. The numbers of coastal, cold, and warm sea fog cases are 64, 26, and 9. Coastal fogs form most frequently in winter, while cold sea fogs occur mostly in summer and warm sea fogs are observed from January to May but not in November and December. On average the air gets colder by 1.6^oC during the three hours leading up to the coastal fog formation, and an additional cooling of 1.1^oC occurs during the fog. The change in the dew point temperature (T_d) is minimal except during the fog (0.6^oC). Decreases in T for the cold and warm sea fogs are relatively smaller. The average T_d is higher than SST during the cold sea fog periods but this T_d is more than 4^oC higher than that for the corresponding non-fog days, suggesting that cold sea fogs be formed by the cooling of already humid air (i.e., T_d>SST). Increases of T_d are significant during the warm sea fog periods (1.4^oC), implying that efficient moisture supply is essential to warm sea fog formation. Four major synoptic patterns are identified in association with the observed fogs. The most frequent is a north Pacific high that accounts for 38% of cases. Surface or upper inversions are present in 77%, 69%, and 81% of the fog periods for coastal, cold, and warm sea fogs, respectively.  相似文献   

Pyrosequencing reveals specific associations of bacterial clades Roseobacter and Flavobacterium with the harmful dinoflagellate Cochlodinium polykrikoides growing in culture          下载免费PDF全文

Bum Soo Park  Ruoyu Guo  Weol‐Ae Lim  Jang‐Seu Ki 《Marine Ecology》2017,38(6)

Harmful algal blooms of the dinoflagellate Cochlodinium polykrikoides are of worldwide environmental concern. Previous field studies have demonstrated the association of such algal blooms with free‐living bacteria (FLB) and particle‐associated bacteria (PAB). In the present study, we report evidence for bacterial association with C. polykrikoides in laboratory culture. Sampling was performed at different growth stages (lag, exponential and stationary) and pyrosequencing was used to identify taxa. As a result, the community structures of FLB and PAB were elucidated and significant differences between FLB and PAB were identified by hierarchical cluster analysis and the similarity profiles test (p = .05). The relative abundances of bacterial operational taxonomic units distinctly changed in response to the different phases of C. polykrikoides growth. The Roseobacter genus Marivita and the Flavobacterium genus Winogradskyella were dominant in the FLB and PAB associated with C. polykrikoides, respectively. The Roseobacter clade, which has also exhibited associations with C. polykrikoides blooms in field samples, may influence host cell growth through the provision of vitamins.  相似文献   

Geology, tectonics, and the 2002-2003 eruption of the Semeru volcano, Indonesia: Interpreted from high-spatial resolution satellite imagery     

Akhmad SolikhinJean-Claude Thouret  Avijit GuptaAndy J.L. Harris  Soo Chin Liew 《Geomorphology》2012,138(1):364-379

The paper illustrates the application of high-spatial resolution satellite images in interpreting volcanic structures and eruption impacts in the Tengger-Semeru massif in east Java, Indonesia. We use high-spatial resolution images (IKONOS and SPOT 5) and aerial photos in order to analyze the structures of Semeru volcano and map the deposits. Geological and tectonic mapping is based on two DEMs and on the interpretation of aerial photos and four SPOT and IKONOS optical satellite images acquired between 1996 and 2002. We also compared two thermal Surface Kinetic Temperature ASTER images before and after the 2002-2003 eruption in order to delineate and evaluate the impacts of the pyroclastic density currents. Semeru's principal structural features are probably due to the tectonic setting of the volcano. A structural map of the Tengger-Semeru massif shows four groups of faults orientated N40, N160, N75, and N105 to N140. Conspicuous structures, such as the SE-trending horseshoe-shaped scar on Semeru's summit cone, coincide with the N160-trending faults. The direction of minor scars on the east flank parallels the first and second groups of faults. The Semeru composite cone hosts the currently active Jonggring-Seloko vent. This is located on, and buttressed against, the Mahameru edifice at the head of a large scar that may reflect a failure plane at shallow depth. Dipping 35° towards the SE, this failure plane may correspond to a weak basal layer of weathered volcaniclastic rocks of Tertiary age. We suggest that the deformation pattern of Semeru and its large scar may be induced by flank spreading over the weak basal layer of the volcano. It is therefore necessary to consider the potential for flank and summit collapse in the future. The last major eruption took place in December 2002-January 2003, and involved emplacement of block-and-ash flows. We have used the 2003 ASTER Surface Kinetic Temperature image to map the 2002-2003 pyroclastic density current deposits. We have also compared two 10 m-pixel images acquired before and after the event to describe the extent and impact of an estimated volume of 5.45 × 10⁶ m³ of block-and-ash flow deposits. An ash-rich pyroclastic surge escaped from one of the valley-confined block-and ash flows at 5 to 8 km distance from the crater and swept across the forest and tilled land on the SW side of the Bang River Valley. Downvalley, the temperature of the pyroclastic surge decreased and a mud-rich deposit coated the banks of the Bang River Valley. Thus, hazard mitigation at Semeru should combine: (1) continuous monitoring of the eruptive activity through an early-warning system, and (2) continuous remote sensing of the morphological changes in the drainage system due to the impact of frequent pyroclastic density currents and lahars.  相似文献