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31.
In climate modeling studies, there is a need to choose a suitable land surface model (LSM) while adhering to available resources. In this study, the viability of three LSM options (Community Land Model version 4.0 [CLM4.0], Noah-MP, and the five-layer thermal diffusion [Bucket] scheme) in the Weather Research and Forecasting model version 3.6 (WRF3.6) was examined for the warm season in a domain centered on the central USA. Model output was compared to Parameter-elevation Relationships on Independent Slopes Model (PRISM) data, a gridded observational dataset including mean monthly temperature and total monthly precipitation. Model output temperature, precipitation, latent heat (LH) flux, sensible heat (SH) flux, and soil water content (SWC) were compared to observations from sites in the Central and Southern Great Plains region. An overall warm bias was found in CLM4.0 and Noah-MP, with a cool bias of larger magnitude in the Bucket model. These three LSMs produced similar patterns of wet and dry biases. Model output of SWC and LH/SH fluxes were compared to observations, and did not show a consistent bias. Both sophisticated LSMs appear to be viable options for simulating the effects of land use change in the central USA.  相似文献   
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Clay-rich mine tailings from phosphate mine operations in Florida are a major environmental and economic problem. Options for reclamation and restoration for these tailings are very limited and are fundamentally restricted by poor physical properties such as low mechanical strength, low hydraulic conductivity, and heavy metal content. The major control on these bulk physical properties is the mineralogy of the materials. Eight continuous push borings were obtained to investigate stratigraphy, mineralogy, aspects of geochemistry, and bulk properties of a deposit of clay-rich mine tailings from a phosphate mine near Bartow, Florida that ceased operations in the early 1970s. Stratigraphy is dominated by laminated clay-rich sediment with minor units of silt and sand. An intact kaolinite liner occurs near the impoundment walls and the impoundment floor has approximately 4 m of relief. Moisture content varies from 4.35 to 57.40 wt% and organic content varies from 0.41 to 9.53 wt%. Bulk XRF investigation indicates that the P2O5 concentrations vary from approximately 4 to 21 wt%. A very strong correlation (r 2 = 0.92) between CaO and P2O5 indicates that apatite is a major control on the phosphate. The strong correlation (r 2 = 0.77) of Al2O3 and TiO2 suggests that the source materials for this deposit are comparatively uniform. A number of heavy metal elements and trace elements occur. Cr, V, Ni, Cu are interpreted to be in phosphate minerals, largely apatite. Sr and Pb are interpreted to be in both phyllosilicates and phosphate minerals. Two populations of apatite were observed in the clay-sized fraction, one that was Fe and Si- bearing and another that was only Si-bearing. Fe-bearing apatite had Fe2O3 contents that varied from 0.38 to 5.32 wt% and SiO2 contents that varied from 0.90 to 3.32 wt%. The other apatite population had a wider range of SiO2 contents that varied from 0.77 to 8.80 wt%. TEM imaging shows that apatite grains are dominantly single crystals with lesser amounts of aggregates. Wavellite commonly occurs as individual or clusters of lath-like crystals and the chemical composition differs from the pure aluminium phosphate end member with average concentrations of components being that of CaO (1.57 wt%), Fe2O3 (1.98 wt%), SiO2 (5.94 wt%). In the clay-sized phosphate minerals investigated no fluorine was found above detection limit (approximately 0.15 wt%), nor was any uranium, radium, heavy metal, or REE element detected. The phyllosilicate mineralogy of the deposit is dominated by smectite (montmorillonite with lesser amounts of nontronite), palygorskite, illite and kaolinite. No systematic variation in the relative proportions of phyllosilicates was observed in the clay deposit. Energy dispersive spectroscopy EDS analysis indicates that chemical compositions of phyllosilicates are somewhat typical but overall are enriched with respect to Fe compared to theoretical end members. The relative enrichment of Fe is interpreted to be a primary sedimentary feature. Ca content in smectite minerals is high and may inhibit stabilization using lime or similar methods. The high percentages of montmorillonite and palygorskite explain the high bulk water contents observed. This investigation provides fundamentally new details regarding clay tailing deposits from closed phosphate mines in central Florida which can be used in restoration and reclamation efforts.  相似文献   
33.
Nicol Morton 《《幕》》2008,31(4):420-422
The Jurassic is traditionally famous for shallow marine sediments that are often very fossiliferous, notably in Europe, where the standard chronostratigraphic subdivisions were established and defined. However, widespread marginal and non-marine Jurassic sediments are also known, and are of great importance for the wellpreserved terrestrial biotas they contain, as well as for their hydrocarbon and coal reserves. IGCP Project 506 is directed towards finding means of correlation between marine and non-marine Jurassic rocks, as a foundation for a better understanding of the evolution of the Earth during the Jurassic Period.  相似文献   
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Flow-through seagrass core microcosms were used to examine responses of species and processes to a logarithmic gradient of dosing with14C-labeled tributyltin-chloride (TBT-CI). Experiments involved delivery of TBT-CI to the water column of replicate cores of a treatment (n=16) once per week; one-half of the cores were sacrificed after 3 wk of dosing, the others were dosed for 6 wk. Initial water column concentrations for the three treatments averaged 0.205, 2.23, and 22.21 μg I?1, expressed as the TBT+ cation, but these concentrations dropped rapidly. Retained14C tracer, an estimate of total organotin species, was distributed to sediments, plants, and other biological tissues, all of whose tracer concentrations increased with time. Measures to indicate responses of both autotrophic and heterotrophic organisms were made; in general, treatment effects were demonstrable statistically only at the highest dose level. Accumulation of chlorophyll and biomass on glass slides was highest when suspended for the entire experiment in the water of the highest treatment; this unexpected result was perhaps an indirect effect related to reduced grazing activity in the microcosms. The highest dose of TBT-CI resulted in virtual population mortality of a few macrobenthic species and decreased loss of plant material in litter bags, both demonstrated within the first 3 wk of dosing. Reduced litter loss was coincident with mortality of an amphipod (Cymadusa compta) capable of shredding plant material, and a causal relation between the two effects is plausible. Thus, if concentrated to similar levels in aThalassia bed, TBT+ may have direct species-level effects and process-level effects, potentially causing ecosystem change via disruption of a species-process linkage influential in seagrass detrital food web dynamics.  相似文献   
36.
A sand-prone Middle Eocene sequence is recognized in three cored boreholes on the East Shetland Platform. Three lithostratigraphic divisions are recognized: Lower Sand Unit, Main Sand Unit and Upper Claystone Unit. The Lower Sand Unit is of fluvio-deltaic origin, occurring on the southern part of the East Shetland Platform. The Main Sand Unit represents the subsequent transgression of the delta. The unit comprises a set of highstand shelf systems tracts separated by glauconitic bands and reflected by palynological assemblage breaks. The presence of reworked palynofloras in sediments of late Middle Eocene age implies derivation of sediment from the north-west part of the East Shetland Platform. Although it is tempting to ascribe sea level changes to the sediment pattern, a tentative correlation with the Hampshire Basin only highlights the difficulties involved.  相似文献   
37.
Extreme value analysis in a multivariate offshore environment   总被引:8,自引:0,他引:8  
Floating offshore systems are exposed to a multivariate environment with wind, waves and current all making a significant contribution to the mooring forces. The design of such systems requires an appreciation of the extreme conditions but the concept of the return period value has to be extended to reflect multiple environmental variables. This study examines the practicalities of employing a multivariate point process model in extreme value analyses, using a moored semi-submersible and its responses to the wind and waves as an example. The output from this illustrative bivariate analysis includes both estimates of the 50-year mooring force and also return period contours which indicate the likely combinations of wind and wave which might give rise to the 50-year condition.  相似文献   
38.
Summary The stable isotope geochemistry of native gold-bearing quartz veins contained within low-grade metasedimentary strata in the central Canadian Rocky Mountains, British Columbia is examined. The data augment previous geological and geochemical studies.Vein pyrite 34S values cluster between + 14.2 and + 16.3 (CDT). Coeval galenas exhibit 34S values between + 11.4 and 13.3. Pyrite-galena geothermometry reveals a mean temperature of mineralization of 300 ± 43°C. Comparison of 34S values for the vein pyrites, with values for pyrite porphyroblasts in country rocks suggests that vein sulfur was probably derived from the host rocks.18O(SMOW) values of host quartzites and pelites cluster between + 12.0 and + 13.5, and + 9.5 and + 10.5, respectively. Auriferous vein quartz exhibits 18O values between + 13.0 and + 15.0. Veins were likely deposited from fluids undergoing post-peak metamorphic cooling.Vein inclusion fluids exhibit values between –105 and –124 (SMOW). Combined O-H-isotope data are most compatible with a source fluid involving chemically- and isotopically-evolved meteoric waters.The critical role of H-isotope data in the evaluation of source fluids for such mesothermal gold lodes is stressed. The paucity of H-isotope data pertaining to the study of lode gold deposits in similar low-grade metasedimentary domains suggests that the involvement of meteoric waters may at times be overlooked.
Der Ursprung metamorphogener Gold-Ganglagerstätten: Bedeutung stabiler Isotopendaten aus den zentralen Rocky Mountains, Kanada
Zusammenfassung Die vorliegende Arbeit befaßt sich mit der Untersuchung der Geochemie stabiler Isotope goldführender Quarzgänge in schwach metamorphen Sedimenten der zentralen Rocky Mountains in Britisch Kolumbien, Kanada. Die Resultate ergänzen früher publizierte geologische und geochemische Daten.Die 34S-Werte von Gang-Pyrit liegen zwischen + 14.2 und + 16.3 (CDT); gleichzeitig gebildeter Bleiglanz hat 34S-Werte von + 11.4 bis + 13.3. Die Isotopengeothermo metrie des Pyrits und Bleiglanzes ergibt eine mittlere Mineralisationstemperatur von 300°C + 43° für diese beiden Minerale. Vergleiche der 8345-Werte des Gang-Pyrits mit denen von Pyrit-Porphyroblasten des Nebengesteins lassen für die Gang-Pyrite eine Herkunft des Schwefels aus dem Nebengestein als wahrscheinlich erscheinen.Die 18O-Werte von Quarziten und Peliten, die als Nebengesteine auftreten, streuen von + 12.0 bis + 13.5 (SMOW), beziehungweise von +9.5 bis + 10.5 Quarz goldführender Gänge hat 18O-Werte, die zwischen + 13.0 und + 15.0 (SMOW) liegen. Er wurde als Gangfüllung wahrscheinlich bei sinkenden Temperaturen aus post metamorphen wäßrigen Lösungen abgesetzt.Flüssigkeitseinschlüsse von Gangmineralien zeigen D-Werte von -105 bis -124 (SMOW). Die H-O-Isotope sind deshalb ein Hinweis dafür, daß als mineralisierende Lösungen isotopisch veränderte meteorische Wässer in Betracht zu ziehen sind. Bei der Deutung der Herkunft der mineralisierenden wäßrigen Lösungen von mesothermalen Goldgängen muß die Kenntnis der H-Isotope als kritisch betrachtet werden. Die Seltenheit mit der H-Isotopendaten dieses Lagerstättentyps in der Literatur diskutiert werden, dürfte ein wesentlicher Grund dafür sein, daß die Rolle meteorischer Wässer bei der Genese mesothermaler, in Metasedimenten liegender Goldgänge, vielfach übersehen wurde.


With 4 Figures  相似文献   
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