Oxygen and sulfur isotope systematics of sulfate produced by bacterial and abiotic oxidation of pyrite   总被引：4，自引：0，他引：4  

Nurgul Balci  Wayne C. Shanks III  Kevin W. Mandernack 《Geochimica et cosmochimica acta》2007,71(15):3796-3811

To better understand reaction pathways of pyrite oxidation and biogeochemical controls on δ¹⁸O and δ³⁴S values of the generated sulfate in acid mine drainage (AMD) and other natural environments, we conducted a series of pyrite oxidation experiments in the laboratory. Our biological and abiotic experiments were conducted under aerobic conditions by using O₂ as an oxidizing agent and under anaerobic conditions by using dissolved Fe(III)_aq as an oxidant with varying δ¹⁸O_H2O values in the presence and absence of Acidithiobacillus ferrooxidans. In addition, aerobic biological experiments were designed as short- and long-term experiments where the final pH was controlled at ∼2.7 and 2.2, respectively. Due to the slower kinetics of abiotic sulfide oxidation, the aerobic abiotic experiments were only conducted as long term with a final pH of ∼2.7. The δ³⁴S_SO4 values from both the biological and abiotic anaerobic experiments indicated a small but significant sulfur isotope fractionation (∼−0.7‰) in contrast to no significant fractionation observed from any of the aerobic experiments. Relative percentages of the incorporation of water-derived oxygen and dissolved oxygen (O₂) to sulfate were estimated, in addition to the oxygen isotope fractionation between sulfate and water, and dissolved oxygen. As expected, during the biological and abiotic anaerobic experiments all of the sulfate oxygen was derived from water. The percentage incorporation of water-derived oxygen into sulfate during the oxidation experiments by O₂ varied with longer incubation and lower pH, but not due to the presence or absence of bacteria. These percentages were estimated as 85%, 92% and 87% from the short-term biological, long-term biological and abiotic control experiments, respectively. An oxygen isotope fractionation effect between sulfate and water (ε¹⁸O_SO4-H2O) of ∼3.5‰ was determined for the anaerobic (biological and abiotic) experiments. This measured value was then used to estimate the oxygen isotope fractionation effects between sulfate and dissolved oxygen in the aerobic experiments which were −10.0‰, −10.8‰, and −9.8‰ for the short-term biological, long-term biological and abiotic control experiments, respectively. Based on the similarity between δ¹⁸O_SO4 values in the biological and abiotic experiments, it is suggested that δ¹⁸O_SO4 values cannot be used to distinguish biological and abiotic mechanisms of pyrite oxidation. The results presented here suggest that Fe(III)_aq is the primary oxidant for pyrite at pH < 3, even in the presence of dissolved oxygen, and that the main oxygen source of sulfate is water-oxygen under both aerobic and anaerobic conditions.  相似文献   

Mineralogy,petrology, chronology,and exposure history of the Chelyabinsk meteorite and parent body          下载免费PDF全文

K. Righter  P. Abell  D. Agresti  E. L. Berger  A. S. Burton  J. S. Delaney  M. D. Fries  E. K. Gibson  M. K. Haba  R. Harrington  G. F. Herzog  L. P. Keller  D. Locke  F. N. Lindsay  T. J. McCoy  R. V. Morris  K. Nagao  K. Nakamura‐Messenger  P. B. Niles  L. E. Nyquist  J. Park  Z. X. Peng  C.‐Y. Shih  J. I. Simon  C. C. Swisher III  M. J. Tappa  B. D. Turrin  R. A. Zeigler 《Meteoritics & planetary science》2015,50(10):1790-1819

Three masses of the Chelyabinsk meteorite have been studied with a wide range of analytical techniques to understand the mineralogical variation and thermal history of the Chelyabinsk parent body. The samples exhibit little to no postentry oxidation via Mössbauer and Raman spectroscopy indicating their fresh character, but despite the rapid collection and care of handling some low levels of terrestrial contamination did nonetheless result. Detailed studies show three distinct lithologies, indicative of a genomict breccia. A light‐colored lithology is LL5 material that has experienced thermal metamorphism and subsequent shock at levels near S4. The second lithology is a shock‐darkened LL5 material in which the darkening is caused by melt and metal‐troilite veins along grain boundaries. The third lithology is an impact melt breccia that formed at high temperatures (~1600 °C), and it experienced rapid cooling and degassing of S₂ gas. Portions of light and dark lithologies from Chel‐101, and the impact melt breccias (Chel‐102 and Chel‐103) were prepared and analyzed for Rb‐Sr, Sm‐Nd, and Ar‐Ar dating. When combined with results from other studies and chronometers, at least eight impact events (e.g., ~4.53 Ga, ~4.45 Ga, ~3.73 Ga, ~2.81 Ga, ~1.46 Ga, ~852 Ma, ~312 Ma, and ~27 Ma) are clearly identified for Chelyabinsk, indicating a complex history of impacts and heating events. Finally, noble gases yield young cosmic ray exposure ages, near 1 Ma. These young ages, together with the absence of measurable cosmogenic derived Sm and Cr, indicate that Chelyabinsk may have been derived from a recent breakup event on an NEO of LL chondrite composition.  相似文献   

Improved reliability of ENSO hindcasts with multi-ocean analyses ensemble initialization     

Jieshun Zhu  Bohua Huang  Magdalena A. Balmaseda  James L. Kinter III  Peitao Peng  Zeng-Zhen Hu  Lawrence Marx 《Climate Dynamics》2013,41(9-10):2785-2795

Currently, ensemble seasonal forecasts using a single model with multiple perturbed initial conditions generally suffer from an “overconfidence” problem, i.e., the ensemble evolves such that the spread among members is small, compared to the magnitude of the mean error. This has motivated the use of a multi-model ensemble (MME), a technique that aims at sampling the structural uncertainty in the forecasting system. Here we investigate how the structural uncertainty in the ocean initial conditions impacts the reliability in seasonal forecasts, by using a new ensemble generation method to be referred to as the multiple-ocean analysis ensemble (MAE) initialization. In the MAE method, multiple ocean analyses are used to build an ensemble of ocean initial states, thus sampling structural uncertainties in oceanic initial conditions (OIC) originating from errors in the ocean model, the forcing flux, and the measurements, especially in areas and times of insufficient observations, as well as from the dependence on data assimilation methods. The merit of MAE initialization is demonstrated by the improved El Niño and the Southern Oscillation (ENSO) forecasting reliability. In particular, compared with the atmospheric perturbation or lagged ensemble approaches, the MAE initialization more effectively enhances ensemble dispersion in ENSO forecasting. A quantitative probabilistic measure of reliability also indicates that the MAE method performs better in forecasting all three (warm, neutral and cold) categories of ENSO events. In addition to improving seasonal forecasts, the MAE strategy may be used to identify the characteristics of the current structural uncertainty and as guidance for improving the observational network and assimilation strategy. Moreover, although the MAE method is not expected to totally correct the overconfidence of seasonal forecasts, our results demonstrate that OIC uncertainty is one of the major sources of forecast overconfidence, and suggest that the MAE is an essential component of an MME system.  相似文献   

Measurements of winds on Mars with Hubble Space Telescope images in 2003 opposition     

V.G. Kaydash  M.A. Kreslavsky  Yu.G. Shkuratov  J.F. Bell III 《Icarus》2006,185(1):97-101

The winds of Mars at the water cloud level are measured by tracking cloud features in sequential high-resolution Hubble Space Telescope UV images for 5 days during the perihelion season in 2003. Global circulation model (GCM) predictions are in general agreement with the observations for the zonal wind component, but reveal significant differences for the meridional component.  相似文献   

Humpback whale song or humpback whale sonar? A reply to Au et al     

Mercado  E.  III Frazer  L.N. 《Oceanic Engineering, IEEE Journal of》2001,26(3):406-415

Au et al.'s arguments against the hypothesis that humpback whale songs function as long-range sonar are based on questionable assumptions rather than on empirical data. Like other echolocating mammals (e.g., bats), singing humpback whales: 1) localize targets in the absence of visual information; 2) possess a highly innervated peripheral auditory system; and 3) modulate the temporal and spectral features of their sounds based on environmental conditions. The sonar equation is inadequate for determining whether humpback whale songs generate detectable echoes from other whales because it does not account for temporal variables that can strongly affect the detectability of echoes. In particular, the sonar equation ignores the fact that much of the noise encountered by singing humpback whales is spectrally and temporally predictable, and that audition in mammals is a dynamic and plastic process. Experiments are needed to test the hypothesis that singing humpback whales listen for and respond to echoes generated by their songs  相似文献   

Radiating dike swarms on Venus: evidence for emplacement at zones of neutral buoyancy     

Eric B. Grosfils  James W. Head  III 《Planetary and Space Science》1995,43(12)

Theoretical calculations of extrusive volcanic degassing on Venus yield atmospheric pressure-related rock density profiles consistent with the formation of magma neutral buoyancy zones and magma reservoirs at different depths as a function of altitude (Head and Wilson, J. geophys. Res. 97, 3877, 1992). Global analysis of radiating dike swarms interpreted to originate at magma reservoirs show that their distribution matches these predictions across approximately 90% of the planet's surface; only those highland regions whose elevations exceed 6053 km appear anomalous. The distribution of the large volcano population (extrusive reservoir products) (Keddie and Head, Planet. Space Sci. 42, 455, 1994) has yielded similar results. Comparison between the dike swarm (intrusive) and large volcano (extrusive) populations suggests that neutral buoyancy plays an important role in governing volcanic processes near the venusian surface and that the depth to the level of neutral buoyancy increases systematically at altitudes above 6051 km.  相似文献   

A detailed study of the enigmatic cluster M82F     

N. Bastian  I. Konstantopoulos  L. J. Smith  G. Trancho  M. S. Westmoquette  J. S. Gallagher III 《Monthly notices of the Royal Astronomical Society》2007,379(4):1333-1342

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Spectral information from fourier analysis of digitized quartz grain profiles     

John D. Boon III  David A. Evans  Harold F. Hennigar 《Mathematical Geology》1982,14(6):589-605

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A New Interpretation of Centimetre-scale Variations in the Progress of Infiltration-driven Metamorphic Reactions: Case Study of Carbonated Metaperidotite, Val d'Efra, Central Alps, Switzerland   总被引：1，自引：0，他引：1  

FERRY  JOHN M.; RUMBLE  DOUGLAS  III; WING  BOSWELL A.; PENNISTON-DORLAND  SARAH C. 《Journal of Petrology》2005,46(8):1725-1746

Progress () of the infiltration-driven reaction, 4olivine +5CO₂ + H₂O = talc + 5magnesite, that occurred during Barrovianregional metamorphism, varies at the cm-scale by a factor of3·5 within an 3 m³ volume of rock. Mineral and stableisotope compositions record that X_CO2, ¹⁸O_fluid, and ¹³C_fluidwere uniform within error of measurement in the same rock volume.The conventional interpretation of small-scale variations in in terms of channelized fluid flow cannot explain the uniformityin fluid composition. Small-scale variations in resulted insteadbecause (a) reactant olivine was a solid solution, (b) initiallythere were small-scale variations in the amount and compositionof olivine, and (c) fluid composition was completely homogenizedover the same scale by diffusion–dispersion during infiltrationand subsequent reaction. Assuming isochemical reaction, spatialvariations in image variations in the (Mg + Fe)/Si of the parentrock rather than the geometry of metamorphic fluid flow. Ifinfiltration-driven reactions involve minerals fixed in composition,on the other hand, spatial variations in do directly imagefluid flow paths. The geometry of fluid flow can never be determinedfrom geochemical tracers over a distance smaller than the oneover which fluid composition is completely homogenized by diffusion–dispersion. KEY WORDS: Alpine Barrovian metamorphism; diffusion; metamorphic fluid composition; metamorphic fluid flow; reaction progress  相似文献   

A Simple Computer Program for the Determination of Aquifer Characteristics from Pump Test Data     

Joseph C. Holzschuh III 《Ground water》1976,14(5):283-285

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