Sediment-water interactions of thallium under simulated estuarine conditions   总被引：1，自引：0，他引：1  

Andrew Turner  Amelie Cabon  Andrew S. Fisher 《Geochimica et cosmochimica acta》2010,74(23):6779-6787

Thallium(I) has been added to estuarine sediment suspended in various natural and artificial aqueous samples in order to examine its reactivity under simulated estuarine conditions. In river water and sea water, adsorption of Tl to sediment was so rapid that a period of desorption-relaxation succeeded instantaneous adsorption. Entire time-courses could not be fitted with a conventional kinetic model, but pseudo-first-order forward and reverse rate constants of 0.0044 and 0.30 h⁻¹, respectively, were derived for river water by omitting measurements defining the adsorption “overshoot” observed at the onset of the experiment. The extent of adsorption after a 16 h equilibration period was considerably greater in river water than in sea water, and displayed a quasi-linear increase with increasing pH over the range 2-9 in the former but no clear dependence on pH in the latter. A logarithmic reduction in the sediment-water distribution coefficient, K_D, was observed on estuarine mixing from river water to sea water. Experiments conducted in electrolyte solutions coupled with inorganic equilibrium speciation modeling revealed that the effect was the combined result of a reduction in the activity of Tl⁺, an increase in the proportion of TlCl⁰ and increasing competition for adsorption sites from K⁺ with an increase in salinity. Overall, there was little experimental evidence for either the oxidation of Tl⁺ or its complexation by dissolved organic matter. The findings of the investigation are discussed in terms of the likely behavior of Tl in estuaries.  相似文献   

A search for evolutionary period variations of Cepheids using the Harvard plate stacks: FF Aql     

L. N. Berdnikov  D. G. Turner  A. A. Henden 《Astronomy Reports》2014,58(4):240-248

Photographic plates of the Harvard Observatory stacks have been used to obtain 1261 brightness estimates for the low-amplitude Cepheid FF Aql (P = 4.47 days). Combined with published visual, photoelectric, and CCD observations, these data enable the construction of an O-C diagram spanning 122 years. The resulting O-C diagram is parabola-shaped, enabling the determination of quadratic brightness elements for the first time. The evolutionary rate of increase of the period, dP/dt = 0.072 ± 0.011 s/year, is in agreement with theoretical computations for the third crossing of the instability strip. The available data, reduced using the technique of by Eddington and Plakidis, reveal the presence of small, random period fluctuations, ? = 0.0061^d ± 0.0044^d, that do not distort the evolutionary trend of the O-C residuals.  相似文献   

<Superscript>10</Superscript>Be, <Superscript>18</Superscript>O and radiogenic isotopic constraints on the origin of adakitic signatures: a case study from Solander and Little Solander Islands,New Zealand     

Fiona?V.?FoleyEmail author  Simon?Turner  Tracy?Rushmer  John?T.?Caulfield  Nathan?R.?Daczko  Paul?Bierman  Matthew?Robertson  Craig?D.?Barrie  Adrian?J.?Boyce 《Contributions to Mineralogy and Petrology》2014,168(3):1048

Subduction-related Quaternary volcanic rocks from Solander and Little Solander Islands, south of mainland New Zealand, are porphyritic trachyandesites and andesites (58.20–62.19 wt% SiO₂) with phenocrysts of amphibole, plagioclase and biotite. The Solander and Little Solander rocks are incompatible element enriched (e.g. Sr ~931–2,270 ppm, Ba ~619–798 ppm, Th ~8.7–21.4 ppm and La ~24.3–97.2 ppm) with MORB-like Sr and Nd isotopic signatures. Isotopically similar quench-textured enclaves reflect mixing with intermediate (basaltic-andesite) magmas. The Solander rocks have geochemical affinities with adakites (e.g. high Sr/Y and low Y), whose origin is often attributed to partial melting of subducted oceanic crust. Solander sits on isotopically distinct continental crust, thus excluding partial melting of the lower crust in the genesis of the magmas. Furthermore, the incompatible element enrichments of the Solander rocks are inconsistent with partial melting of newly underplated mafic lower crust; reproduction of their major element compositions would require unrealistically high degrees of partial melting. A similar argument precludes partial melting of the subducting oceanic crust and the inability to match the observed trace element patterns in the presence of residual garnet or plagioclase. Alternatively, an enriched end member of depleted MORB mantle source is inferred from Sr, Nd and Pb isotopic compositions, trace element enrichments and εHf ? 0 CHUR in detrital zircons, sourced from the volcanics. ¹⁰Be and Sr, Nd and Pb isotopic systematics are inconsistent with significant sediment involvement in the source region. The trace element enrichments and MORB-like Sr and Nd isotopic characteristics of the Solander rocks require a strong fractionation mechanism to impart the high incompatible element concentrations and subduction-related (e.g. high LILE/HFSE) geochemical signatures of the Solander magmas. Trace element modelling shows that this can be achieved by very low degrees of melting of a peridotitic source enriched by the addition of a slab-derived melt. Subsequent open-system fractionation, involving a key role for mafic magma recharge, resulted in the evolved andesitic adakites.  相似文献   

New 1982 — 1990 photometry of λ Andromedae and its 11-year cycle     

Douglas S. Hall  Gregory W. Henry  Dietmar Böhme  Peter A. Brooks  Sandy Chang  Ales Dolzan  George L. Fortier  Robert E. Fried  Russell M. Genet  Bruce S. Grim  James Hannon  Darrel B. Hoff  Kevin Krisciunas  Howard J. Landis  Howard P. Louth  Larry P. Lovell  Paul Nielsen  Bobby E. Powell  Harry D. Powell  Don Pray  Thomas R. Renner  Charles W. Rogers  Stephen Shervais  Douglas M. Slauson  Samuel Slote  Harold J. Stelzer  Arthur J. Stokes  Jack C. Troeger  Louis C. Turner  Norman F. Wasson  Kenneth W. Zeigler 《Journal of Astrophysics and Astronomy》1991,12(4):281-287

We present photoelectric photometry of λ And never before published, obtained between February 1982 and December 1990 at 29 different observatories. Then we combine it with all other photometry available to us (previously published, contained in the I.A.U. Commission 27 Archives, and obtained with the Vanderbilt 16-inch automatic telescope but not yet published), to yield a 14.8-year data base. Analysis reveals a long-term cycle in mean brightness, with a full range of 0^m.15 and a period of 11.4 ± 0.4 years. Because most of our new photometry was concentrated in the 1983-84 observing season, we analyze that one well-defined light curve with a two-spot model. Spot A keeps a 0^m.04 amplitude throughout four rotation cycles whereas the amplitude of spot B diminishes from 0^m.09 down almost to 0^m.03. The spot rotation periods were 55^d.9 ± 0^d.6 and 520^d.8 ± 1^d.0, respectively.  相似文献   

A simple numerical model for inlet sedimentation at intermittently open–closed coastal lagoons     

M.A. Davidson  B.D. Morris  I.L. Turner 《Continental Shelf Research》2009,29(16):1975-1982

This contribution aims to model the dominant processes that control sedimentation within the ocean inlet to intermittently open–closed coastal lagoons; focussing on the role of infilling, backfilling and morphodynamic feedback. The key elements that have been included in the present model are: (1) the delivery of sediment to the mouth of the estuary by littoral processes; (2) sediment transport processes within the inlet due to non-linear tidal flow; and (3) the down-slope diffusion of sediment. The model discussed here includes a simple one-dimensional (1-D), non-linear flow parameterisation that predicts the spatial variability in the magnitude and non-linearity of the tidal flow. The predicted third and fourth velocity moments are used to drive a morphodynamic module. Down-slope diffusion of sediment is dealt with in a separate diffusion term in the bed-evolution equation. Feedback between the evolving morphology and the flow field are integral to the model. Numerical simulations are used to investigate different modes of evolution for this type of inlet system. Inlet closure due to infilling is critically controlled by the balance between sediment addition at the mouth due to littoral processes and the removal of sediment by non-linear tidal flow. Rapid widening or deepening of the inlet at its landward margin leads to the deposition of a flood shoal. Under conditions of high sedimentation (and low diffusion) the flood shoal can become sufficiently well developed to present a physical barrier to sediment entering the lagoon. Under these circumstances backfilling can become significant. The infilling and backfilling processes are ameliorated by efficient down-slope diffusion which is controlled in the present model by a diffusion parameter, D. High diffusion coefficients slow inlet closure and allow sediment to propagate further into the lagoon.  相似文献   

The soft X-ray absorption lines of the Seyfert 1 galaxy MCG–6-30-15     

A. K. Turner  A. C. Fabian  J. C. Lee  S. Vaughan 《Monthly notices of the Royal Astronomical Society》2004,353(1):319-328

  相似文献   

The origin of [Fe ii] emission in NGC 4151     

James E. H.Turner  JeremyAllington-Smith †  ScottChapman ‡  RobertContent  ChristineDone  RogerHaynes §  DavidLee ¶  SimonMorris &#; 《Monthly notices of the Royal Astronomical Society》2002,331(2):284-292

The centre of NGC 4151 has been observed in the J band with the SMIRFS integral field unit (IFU) on the UK Infrared Telescope. A map of [Fe  ii ] emission is derived, and compared with the distributions of the optical narrow-line region and radio jet. We conclude that, because the [Fe  ii ] emission is associated more closely with the visible narrow-line region than with the radio jet, it arises mainly through photoionization of gas by collimated X-rays from the Seyfert nucleus. The velocity field and strength with respect to Pa β are found to be consistent with this argument. The performance of the IFU is considered briefly, and techniques for observation and data analysis are discussed.  相似文献   

Comparative Analysis of a Transition Region Bright Point with a Blinker and Coronal Bright Point Using Multiple EIS Emission Lines     

N. Brice Orange  Hakeem M. Oluseyi  David L. Chesny  Maulik Patel  Katie Hesterly  Lauren Preuss  Chantale Neira  Niescja E. Turner 《Solar physics》2014,289(5):1557-1584

Since their discovery 20 year ago, transition region bright points have never been observed spectroscopically. Bright point properties have not been compared with similar transition region and coronal structures. In this work we have investigated three transient quiet Sun brightenings including a transition region bright point (TR BP), a coronal bright point (CBP) and a blinker. We use time-series observations of the extreme-ultraviolet emission lines of a wide range of temperature T (logT=5.3?–?6.4) from the EUV Imaging Spectrometer (EIS) onboard the Hinode satellite. We present the EIS temperature maps and Doppler maps, which are compared with magnetograms from the Michelson Doppler Imager (MDI) onboard the SOHO satellite. Doppler velocities of the TR BP and blinker are ≤?25 km?s^?1, which is typical of transient TR phenomena. The Doppler velocities of the CBP were found to be ≤?20 km?s^?1 with exception of those measured at logT=6.2 where a distinct bi-directional jet is observed. From an EM loci analysis we find evidence of single and double isothermal components in the TR BP and CBP, respectively. TR BP and CBP loci curves are characterized by broad distributions suggesting the existence of unresolved structure. By comparing and contrasting the physical characteristics of the events we find that the BP phenomena are an indication of multi-scaled self-similarity, given the similarities in both their underlying magnetic field configuration and evolution in relation to EUV flux changes. In contrast, the blinker phenomena and the TR BP are sufficiently dissimilar in their observed properties as to constitute different event classes. Our work is an indication that the measurement of similar characteristics across multiple event types holds class-predictive power, and is a significant step towards automated solar atmospheric multi-class classification of unresolved transient EUV sources. Finally, the analysis performed here establishes a connection between solar quiet region CBPs and jets.  相似文献   

Kinetics of phosphate adsorption by iron oxyhydroxides in aqueous systems     

S.A. Crosby  G.E. Millward  E.I. Butler  D.R. Turner  M. Whitfield 《Estuarine, Coastal and Shelf Science》1984,19(2):257-270

The rate of uptake of phosphate onto synthetic Fe(III)- and Fe(II)-derived oxyhydroxides has been studied using reaction conditions similar to those encountered in natural waters. Kinetic analyses were carried out on the adsorption profiles and both first-order and second-order conditional rate constants were obtained. The temperature dependence of some of the rate constants was investigated and corresponding apparent activation energies calculated. Similar experiments and analyses were undertaken using Fe from natural sources and in general the conditional rate constants obtained in seawater were in agreement with the synthetic ones. The results of this study are of value when comparing the time scales of adsorption processes in natural waters with the time scales of mixing and advection.  相似文献   

Folding of Viscous Plumes Impinging On A Density Or Viscosity Interface   总被引：1，自引：0，他引：1  

R. W. Griffiths  J. S. Turner 《Geophysical Journal International》1988,95(2):397-419

  相似文献