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351.
Spatio-temporal variability of pollutants in the environment is a complex phenomenon that requires a combined approach for its analysis. Whereas data on measured levels of contaminants in various environmental compartments is essential, it is not always possible to monitor at the necessary frequency and with the adequate spatial sampling distribution to capture this variability. Therefore a modelling approach able to complement experimental data and close the gaps in the monitoring programs is useful for assessing the contaminant dynamics occurring at different time scales. In this work a 1D water column fate model has been developed and tested for Polycyclic Aromatic Hydrocarbons (PAHs). The model has been coupled with a simple ecological model that includes a bioaccumulation module. Afterwards, the model has been used to study the temporal variability of contaminant concentrations as well as the fluxes between compartments. The results evidence the complex coupling between spatio-temporal scales and its influence on environmental concentration levels.  相似文献   
352.
We have studied the temperature response to changes in the CO2 concentration in the middle and upper atmosphere using the Coupled Middle Atmosphere–Thermosphere Model 2 (CMAT2). We have performed simulations with a range of CO2 concentrations and three different ways of accounting for the effects of gravity waves, to allow for comparison with previous studies and sensitivity analyses. We initially find that the response of the model to the changes in CO2 concentration which took place between 1965 and 1995 (320–360 ppm) is strongly dependent on the gravity wave parameterization that is used, but this is to a large degree due to steps or kinks in an otherwise nearly linear curve describing the temperature as a function of CO2 concentration. We have not been able to identify the cause of these steps as part of the present study, which is a limitation and must be studied in future work. Here we treated the steps as model noise and rather focused on correcting for their effects by fitting straight lines to the temperature–CO2 curves to estimate the overall slope of the curves. From these slopes we were able to obtain more robust trend estimates than can be obtained by comparing only two model simulations, as is normally done in other, similar studies. The corrected temperature responses to a 40 ppm change in CO2 concentration still show up to 15–17% sensitivity to the gravity wave parameterization in the mesosphere and thermosphere. This remaining sensitivity is likely to be related to the fundamental differences in the way a change in temperature modifies the propagation and dissipation characteristics of gravity waves in each parameterization, which is particularly different for linear and non-linear schemes. The corrected trends we find are largely in agreement with other modelling studies, and therefore do not fully explain observed trends, which are typically larger than those predicted by modelling studies. However, modelling results could be similarly sensitive to other model parameters and settings, for example to gravity wave characteristics or solar activity level, and this should be further investigated as well.  相似文献   
353.
U–Pb and Pb–Pb zircon ages for metamorphic zircons from granulites in the Saxonian granulite complex are reported, using the SHRIMP ion microprobe, conventional multigrain and single-gain techniques and the evaporation method. This is complemented by a Pb–Pb evaporation age for a post-granulite granite emplaced into the schist mantle around the granulites during uplift of the complex. We also demonstrate that zircon ages are not reset during high-grade metamorphism, as commonly argued, but have a very high closure temperature and usually preserve the isotopic composition reflecting the time of their formation. Multifaceted zircons from four granulite samples that probably grew close to the peak of high-grade metamorphism yielded identical U–Pb and Pb–Pb ages of ~340?Ma which support previously published data and unambiguously show that the granulites formed during a lower Carboniferous event and not in the early Palaeozoic or Precambrian as previously suggested. Older cores in some of the metamorphic zircons reveal early Palaeozoic components at 470–485?Ma that we interpret as ages reflecting magmatic crystallization of the granulite precursors. One sample suggests an inherited component as old as ~1700?Ma. The post-granulite granite has a Pb–Pb evaporation age of 333.1±1.0?Ma, and the short time interval between granulite metamorphism and granite intrusion implies that uplift, crustal extension and cooling of the granulite complex occurred rapidly after peak metamorphic conditions.  相似文献   
354.
 Salt-water discharges from a fault system in the crystalline basement of the Black Forest into the gravel aquifer of the Kinzig River valley near Ohlsbach, upper Rhine River valley, southwestern Germany. The salt water (TDS, 16 g/kg) ascends from a reservoir at  1 3 km depth. Once discharged into the gravel aquifer, the saline deep water mixes with fresh groundwater and is carried along the groundwater flow path to the middle of the Rhine River valley. There, the natural geogene salt-water plume merges with a man-made chloride-rich infiltration zone along the Rhine River. The plume was mapped using (1) chloride data from groundwater observation wells, and (2) resistivity data from geoelectric sounding. Background chloride is about 7 mg/kg. In the central region of the plume, chloride concentration exceeds 200 mg/kg. A continuous area of Cl  1 50 mg/kg is distinguished from the discharge fault to the Rhine River over a distance of 12 km. Resistivities range from  1 50 Ω in uncontaminated regions to <7 Ω in the 700 m-long central region of the plume. A low resistivity plume (7–10 Ω) stretches for  1 7 km into the Rhine River valley. The two plume maps are in good agreement. Received, April 1998 / Revised, November 1998, January 1999 / Accepted, January 1999  相似文献   
355.
The oribatid mite assemblages found in late-glacial and early-Holocene sediments in Kråkenes Lake, western Norway, consist of 38 species within 24 genera. In accordance with known present habitat distribution we distinguish 4 true aquatic species, 6 species associated with wetland, 2 with mesic grassland, 12 with dry grassland and heathland, 3 with saxicolous and arboricolous lichens, 7 widely distributed species, and 4 with uncertainly known habitat preferences. The sediments from the pioneer phase (12,300-11,700 14C BP) contain 7 species, among them the 2 typical pioneer species Limnozetes ciliatus and Tectocepheus velatus.The sediments of the warmer Allerød interstadial (11,700-10,900 BP) contain 18 species, the cold Younger Dryas (10,900-10,000 BP) 9 species, and the early Holocene (10,000-9,000 BP) 36 species.The oribatid fossils of the pioneer phase indicate habitats and climate similar to the mid-alpine zone in western Norway today, the Allerod interstadial that of the low- to mid-alpine zone. L. ciliatus is the aquatic pioneer species in the Allerod. In the Younger Dryas the climate was more arctic, 60-70% of the species had presumably disappeared, and no aquatic species were found. In the early Holocene, 4 true aquatic species colonised the lake and showed a high productivity. The terrestrial oribatid fauna in this period contained a high diversity of more boreal species, while the alpine species declined or became extinct.  相似文献   
356.
We present new concentration data for twenty four lithophile trace elements in NIST certified reference material glasses SRM 610-SRM 611 in support of their use in microanalytical techniques. The data were obtained by solution ICP-MS and isotope dilution TIMS analysis of two different sample wafers. An overall assessment of these new results, also taking into account ion probe studies that have been published in the literature, shows that these wafers can be considered to be homogeneous. Therefore, individually analysed wafers are believed to be representative of the entire batch of the SRM 610-611 glasses. Possible exceptions are the alkali metals (and a few volatile or non-lithophile trace elements). The analysed concentrations range between 370 μg g−1 (Cs) and 500 μg g−1 (Sr) and agree well with published values. On the basis of our new data and data recently published in the literature we propose "preferred average" values for the elements studied. These values are, within a few percent, identical to those proposed by other workers.  相似文献   
357.
This is a review paper on the fine structure of optical aurora. Spatial scales smaller than about 1 km and temporal scales shorter than about 1 s are considered. Fine structure is present in most types of aurora, but earlier much of it has not been possible to study properly due to instrument limitations. Recent advancements in optical instrumentation have provided considerable improvements of temporal and spatial resolution. Optical measurements are able to give higher resolution than any other types of ground-based instruments used in auroral studies. To interpret the information, both more advanced modelling and analysis methods are being developed. This gives access to new knowledge on the physical processes responsible for particle acceleration, precipitation, atmospheric ion chemistry, and auroral light production.  相似文献   
358.
Tree radial growth is influenced by individual tree abilities, climate, competition, disturbance regimes, as well as biogeomorphic processes – including biomechanical interactions between trees and soil. Trees are actively involved in hillslope dynamics, both responding to and affecting many (bio)geomorphic processes. Using dendrochronology, we studied feedbacks associated with tree–soil–landscape formation, specifically relationships between hillslope processes, biomechanical effects of trees in soils, tree microhabitat conditions and their morphological adaptations, in the flysch zone of the Carpathians. We visually evaluated stem shape, microhabitat conditions and the biomechanical effects of 1663 trees. Cores were taken in four growing directions from 224 individuals of European beech (Fagus sylvatica L.). In a set of 193 cross-dated beeches, average tree-ring widths and tree eccentricities in all directions were calculated and analysed in relation to the biogeomorphic impacts of trees. Some significant drivers of tree radial growth and sources of stem eccentricity were detected. The radial growth of trees on which deadwood was leaning was markedly limited. In contrast, trees with exposed roots expressed the highest growth rates. This clearly suggests that root exposure may not be an effect of ‘exogenous’ soil creep, but may rather result from individually intensifying tree growth due to fine-scale disturbance dynamics. The response of biomechanical tree–soil interactions in tree radial growth weakened with increasing stem diameter, reflecting the stabilizing role of larger trees. The significance of calendar year on radial growth suggests seasonality in the dynamic component of soil creep. Tree eccentricity was observed mainly in the downslope direction, which suggests a relatively complex effect of biomechanics on stem tilting. © 2020 John Wiley & Sons, Ltd.  相似文献   
359.
In this article we propose a method for combining geometric and real-aperture methods for monocular three-dimensional (3D) reconstruction of static scenes at absolute scale. Our algorithm relies on a sequence of images of the object acquired by a monocular camera of fixed focal setting from different viewpoints. Object features are tracked over a range of distances from the camera with a small depth of field, leading to a varying degree of defocus for each feature. Information on absolute depth is obtained based on a Depth-from-Defocus approach. The parameters of the point spread functions estimated by Depth-from-Defocus are used as a regularisation term for Structure-from-Motion. The reprojection error obtained from bundle adjustment and the absolute depth error obtained from Depth-from-Defocus are simultaneously minimised for all tracked object features. The proposed method yields absolutely scaled 3D coordinates of the scene points without any prior knowledge about scene structure and camera motion. We describe the implementation of the proposed method both as an offline and as an online algorithm. Evaluating the algorithm on real-world data, we demonstrate that it yields typical relative scale errors of a few per cent. We examine the influence of random effects, i.e. the noise of the pixel grey values, and systematic effects, caused by thermal expansion of the optical system or by inclusion of strongly blurred images, on the accuracy of the 3D reconstruction result. Possible applications of our approach are in the field of industrial quality inspection; in particular, it is preferable to stereo cameras in industrial vision systems with space limitations or where strong vibrations occur.  相似文献   
360.
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