Chronology of early Archaean granite-greenstone evolution in the Barberton Mountain Land, South Africa, based on precise dating by single zircon evaporation   总被引：2，自引：0，他引：2  

Krüner A  Byerly GR  Lowe DR 《Earth and Planetary Science Letters》1991,103(1-4):41-54

We report precise 207Pb/206Pb single zircon evaporation ages for low-grade felsic metavolcanic rocks within the Onverwacht and Fig Tree Groups of the Barberton Greenstone Belt (BGB), South Africa, and from granitoid plutons bordering the belt. Dacitic tuffs of the Hooggenoeg Formation in the upper part of the Onverwacht Group yield ages between 3445 +/- 3 and 3416 +/- 5 Ma and contain older crustal components represented by a 3504 +/- 4 Ma old zircon xenocryst. Fig Tree dacitic tuffs and agglomerates have euhedral zircons between 3259 +/- 5 and 3225 +/- 3 Ma in age which we interpret to reflect the time of crystallization. A surprisingly complex xenocryst population in one sample documents ages from 3323 +/- 4 to 3522 +/- 4 Ma. We suspect that these xenocrysts were inherited, during the passage of the felsic melts to the surface, from various sources such as greenstones and granitoid rocks now exposed in the form of tonalite-trondhjemite plutons along the southern and western margins of the BGB, and units predating any of the exposed greenstone or intrusive rocks. Several of the granitoids along the southern margin of the belt have zircon populations with ages between 3490 and 3440 Ma. coeval with or slightly older than Onverwacht felsic volcanism, while the Kaap Valley pluton along the northwestern margin of the belt is coeval with Fig Tree dacitic volcanism. These results emphasize the comagmatic relationships between greenstone felsic volcanic units and the surrounding plutonic suites. Some of the volcanic plutonic units contain zircon xenocrysts older than any exposed rocks. These indicate the existence of still older units, possibly stratigraphically lower and older portions of the greenstone sequence itself, older granitoid intrusive rocks, or bodies of older, unrelated crustal material. Our data show that the Onverwacht and Fig Tree felsic units have distinctly different ages and therefore do not represent a single, tectonically repeated unit as proposed by others. Unlike the late Archaean Abitibi greenstone belt in Canada, which formed over about 30 Ma. exposed rocks in the BGB formed over a period of at least 220 Ma. The complex zircon populations encountered in this study imply that conventional multigrain zircon dating may not accurately identify the time of felsic volcanic activity in ancient greenstones. A surprising similarity in rock types, tectonic evolution, and ages of the BGB in the Kaapvaal craton of southern Africa and greenstones in the Pilbara Block of Western Australia suggests that these two terrains may have been part of a larger crustal unit in early Archaean times.  相似文献   

Partnerships in forest governance     

Ingrid J. Visseren-Hamakers  Pieter Glasbergen   《Global Environmental Change》2007,17(3-4):408-419

One of the major current global environmental challenges is the conservation of forest biodiversity. Deforestation and forest degradation continue despite international governmental agreements on forest conservation. In recent years private regulation in the international forest governance system has increased. Numerous partnerships between governments, business and/or civil society have been developed. Most of them focus on a single threat to forest biodiversity. This private regulation has had a limited positive impact. The most valuable contribution has been filling the gap of lack of implementation by governments. The forest governance system can become more effective if metagovernance is strengthened.  相似文献   

Adsorption mechanisms of trivalent gold on iron- and aluminum-(oxy)hydroxides. Part 1: X-ray absorption and Raman scattering spectroscopic studies of Au(III) adsorbed on ferrihydrite, goethite, and boehmite     

Ingrid Berrodier  François Farges  Marc Benedetti  Gordon E. Brown Jr  Michel Deveughèle 《Geochimica et cosmochimica acta》2004,68(14):3019-3042

Gold adsorption products on powdered ferrihydrite, goethite, and boehmite samples, prepared by reacting Au(III)-Cl solutions ([Au] = 4.2 × 10⁻⁵-9.0 × 10⁻³ M; [Cl] = 0.017-0.6 M) with these adsorbents at pH values of 4 to 9 and Au adsorption densities ranging from 0.046 to 1.53 μmol/m² were characterized using Au-L_III XAFS spectroscopy. The solutions (before and after uptake) were investigated by Raman scattering to determine speciation and by Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES) to determine solution composition. We present an analysis of several effects that are observed in the Au L_III-edge XAFS spectra, including X-ray beam-induced photo-reduction, multi-electronic excitations, disorder effects, and multiple scattering, that would complicate interpretation of the spectra if not accounted for. A combination of methods (spectral deconvolution, principal component analysis, spectral inversion, and wavelet analysis) was used to identify and quantify these effects, to characterize the nature of mixed ligands around gold, and to distinguish between multiple-scattering features and features due to next-nearest neighbors in the XAFS spectra.Analysis of the Au-L_III XAFS spectra showed that Au(III) is present as square-planar Au(III)(O,Cl)₄ complexes in the aqueous solutions and on the surfaces of the Al/Fe-(oxy)hydroxide adsorption samples with dominantly O ligands at pH > 6 and mixed O/Cl ligands at lower pH values. The EXAFS-derived Au-O and Au-Cl distances are 2.00(2) and 2.28(2) Å, respectively, and the magnitudes of the Debye-Waller factors and third cumulants from anharmonic analyses indicate very little thermal or positional disorder around Au(III) in the adsorption samples. Iron second neighbors are present around Au in the Au(III)/ferrihydrite and Au(III)/goethite adsorption samples, with Au-Fe distances of 3.1(1) and 3.3(1) Å. In boehmite, two sets of Au-Al distances were detected at 3.0(1) and 3.2(1) Å. A reverse Monte Carlo study of the XAFS spectroscopic data suggests the presence of a continuum of edge-shared AuO₄-FeO₆ distances, which cannot be described correctly by a classical model of these data in which only a mean distance (although severely under-estimated) is derived.  相似文献   

Answer to Rebuttal to "Unfilterable 'geoaerosols', their use in a search for thermal,mineral and mineralised waters and their possible influence on the origin of certain types of mineral waters" by R.F. Holub,P.K. Smrz,published in Environmental Geology (2002) 41:984–985     

B. Krčmář  T. Vylita 《Environmental Geology》2003,44(1):119-120

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The Erzincan (Turkey) Earthquake (Ms 6.8) of March 13, 1992 and its Aftershock Sequence     

H. Grosser  M. Baumbach  H. Berckhemer  B. Baier  A. Karahan  H. Schelle  F. Krüger  A. Paulat  G. Michel  R. Demirtas  S. Gencoglu  R. Yilmaz 《Pure and Applied Geophysics》1998,152(3):465-505

—The Erzincan strike-slip earthquake of March 13, 1992 ruptured a section of the North Anatolian fault (NAF) at the northern margin of the Erzincan basin. The focal depth of about 10 km was less than given by ISC and NEIC. Erzincan and the surrounding villages were considerably damaged. In the Erzincan basin and in the neighbouring mountains a seismic network of ten stations was installed. It was operating continuously from March 21 through June 16, 1992. More than 3,000 aftershocks were recorded of which 505 could be located. The spectral parameters of 394 and the fault-plane solutions of 53 aftershocks were determined. For the given region the frequency dependent coda Q was derived as Q _c = 122 f ^0.68. The aftershock area increased with time, reflecting the process of stress redistribution. Some events clustered in the immediate vicinity of the town of Erzincan close to the epicentre of the main event and seem to trace the NAF. Their source mechanism is similar to that of the main event (strike slip). About 150 aftershocks clustered in the southeastern part of the Erzincan basin where a concentration of the events in a small volume of 5 × 5 × 3 km³ was observed. The majority of fault-plane solutions available for these aftershocks showed a normal faulting mechanism with an east-west directed extension. Most of the aftershocks southeast of the basin clustered between two lineaments that were mapped by satellite images. The P-wave velocity below the Erzincan basin, derived from travel-time residual analysis, is lower compared to areas NE and SW of the basin. Three-dimen sional stress modelling of the Erzincan region qualitatively explains the occurrence of the aftershocks southeast of the basin. The calculated displacement distribution which exhibits the north-westward motion of the basin and tension at its southeastern margin, caused by the Erzincan earthquake, is in agreement with derived fault-plane solutions.  相似文献   

Time of formation and peak of Variscan HP-HT metamorphism of quartz-feldspar rocks in the central Erzgebirge,Saxony, Germany   总被引：3，自引：1，他引：2  

Kröner  A.  Willner  A. P. 《Contributions to Mineralogy and Petrology》1998,132(1):1-20

The Variscan Erzgebirge represents an antiform with a core of gneisses and mica schists, surrounded by a phyllitic mantle. The Gneiss-Eclogite Unit (GEU), in the central part, is a composite tectonometamorphic assemblage characterized by a HP-HT imprint and comprises migmatitic para- and orthogneisses, HT mylonites, HP granulites, eclogites and garnet peridotites. It is tectonically sandwiched between two major units with distinctly lower PT histories. The GEU experienced a characteristic “kinked” retrograde PT path after HP-HT equilibration with: (1) strong near-isothermal decompression at high temperatures; (2) extensive re-equilibration at medium pressures, followed (3) by rapid cooling during continued uplift. We dated zircons (Pb-Pb evaporation) from granitoid orthogneisses and metapelites of the GEU. The orthogneisses contain euhedral, long-prismatic zircons of igneous origin that provided protolith ages between 470 and 524 Ma. Metapelites retain well-preserved granulite-facies mineral assemblages and contain spherical, multifaceted metamorphic zircons that grew near the peak of HP/HT metamorphism. Inclusions of prograde HP phengite (∼15 kbar) and rutile are included in one such zircon. Metamorphic zircons of three samples from different localities yielded identical ²⁰⁷Pb/²⁰⁶Pb ages of 340.5 ± 0.7 Ma, 341.2 ± 0.5 Ma and 341.6 ± 0.5 Ma respectively. Consideration of these zircon ages with published ³⁹Ar/⁴⁰Ar white mica ages suggests fast cooling and uplift rates in excess of 50 °C/Ma and 4 km/Ma. This is typical for large-scale extensional tectonic unroofing of the ultra-deep part of a fossil, thickened Variscan continental crust (>60 km) during continuing continental collision and orogenic collapse. Received: 5 June 1997 / Accepted: 7 January 1998  相似文献   

Rb-Sr geochronology in favour of polymetamorphism in the Pan African Damara belt of Namibia (South West Africa)     

A. Kröner  M. Halpern  R. E. Jacob 《International Journal of Earth Sciences》1978,67(2):688-705

New Rb-Sr whole rock age data are reported from two metasedimentary sequences of the Damara Supergroup in the central Pan African Damara belt of Namibia (South West Africa).Calc-granofels rocks of the Karibib Formation (Swakop Group) near Usakos are dated at 665±34 Ma (⁸⁷Rb=1.39×10^–11 a^–1) which is interpreted as reflecting a high-grade metamorphic event predating widespread granite intrusion.Pyroxene-bearing feldspathic gneisses of the Khan Formation (Nosib Group) from the Khan-Swakop River area east of Swakopmund show incomplete homogenization at 474±16 Ma. In view of similar ages obtained on the nearby Rössing alaskite granite and on biotites from a variety of rock assemblages this age is interpreted as reflecting a second Damaran metamorphic event rather than a specific stage in a long cooling history as previously thought.It is probable that the new ages characterize two distinct Pan-African tectono-metamorphic events previously named Katangan and Damaran episodes respectively (Clifford, 1967). The younger of these has affected large areas of south western Africa both within orogenic zones and on the neighbouring Kalahari Craton and may reflect crustal processes of sub-continental proportion during the closing stages of the Pan-African tectogenesis.

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Zusammenfassung Neue Rb-Sr-Gesamtgesteins-Isochronenalter von zwei sedimentären Abfolgen der spätpräkambrischen Damara-Supergruppe in der Zentralzone des Pan-Afrikanischen Damara-Orogens von Namibia (Südwest-Afrika) deuten auf eine mehrphasige metamorphe Geschichte hin.Kalk-Granofels-Gesteine der Karibib-Formation (Swakop-Gruppe) südöstlich von Usakos ergaben ein Alter von 665±34 M. J. (⁸⁷Rb=1,39×10^–11 a^–1) und wir interpretieren dieses Alter als das Resultat isotoper Homogenisierung während einer intensiven Regionalmetamorphose, die vor dem Eindringen weitverbreiteter Granite stattfand.Pyroxenführende und feldspathaltige Gneise der Khan-Formation (Nosib-Gruppe) aus dem Gebiet der Khan- und Swakop-Flüsse östlich von Swakopmund zeigen unvollständige Homogenisierung ihrer Sr-Isotope um 474±16 M. J. In Anbetracht ähnlicher Alter für den benachbarten Rössing-Alaskitgranit und für Biotite verschiedener Gesteinstypen aus dem gesamten Zentralbereich des Orogens interpretieren wir obiges Alter eher als den Höhepunkt einer zweiten Regionalmetamorphose als ein bestimmtes Stadium in der post-orogenen Abkühlungsgeschichte.Es ist wahrscheinlich, daß unsere Altersbestimmungen zwei deutlich voneinander getrennte pan-afrikanische tektono-metamorphe Phasen charakterisieren, vor allem wenn man sie in Zusammenhang mit publizierten Daten betrachtet, und wir nehmen an, daß diese den vonClifford (1967) postulierten Katanga- und Damara-Episoden entsprechen. Die jüngere dieser Episoden hat nicht nur die pan-afrikanischen orogenen Bereiche im südwestlichen Afrika, sondern auch weite Teile des Kalahari-Kratons erfaßt und mag auf tektogenetische Prozesse von nahezu kontinentalen Ausmaßen in und unter der Kruste im frühen Paläozoikum zurückzuführen sein.

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Résumé Deux séquences métasédimentaires du supergroupe du Damara ont été datées par la méthode Rb/Sr.Des gneiss calciques («granofels») de la formation de Karibib (groupe de Swakop), récoltés près d'Usakos ont été datés à 665±34 Ma (avec⁸⁷Rb=1.39× 10^–11 a^–1). Cet âge est interprété comme le résultat d'un événement métamorphique de degré é levé antérieur à la mise en place des grandes masses de granite.Des gneiss feldspathiques à pryoxène de la Formation de Khan (Groupe de Nosib), échantillonnés dans la région de la Khan River — Swakop à l'Est de Swakopmund, montrent une homogénéisation isotopique incomplète à 474±16 Ma. Des âges voisins ayant été obtenus pour l'Alaskite de Rössing qui affleure dans la même zone et pour les biotites de différentes roches, cet âge est interprété comme le résultat d'un second métamorphisme damarien plutôt que comme un stade de la longue histoire de refroidissement comme cela avait été imaginé auparavant.Ces nouveaux âges caractériseraient les deux épisodes tectonométamorphiques distincts de l'orogénie Pan-Africaine, qui avaient été appelés respectivement épisode katangien et épisode demarien parClifford (1967). Le plus récent de ces événements a affecté une grande partie de l'Afrique du S.W. aussi bien dans les zones orogéniques que dans le craton voisin du Kalahari; il peut refléter une évolution crustale d'échelle subcontinentale se produisant pendant les derniers stades du tectogène Pan-Africain.

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Rb/Sr - , - ; , .- , , 665±34 (⁸⁷Rb=1,39 10^–1a^–1); , . , , , , 474 ± 16 . - ; , , . , - - , , . , 1967 , . - - , ; , , .

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Contribution No. 27 of the South African Geodynamics Project, presented at the 9th Colloquium on African Geology, Göttingen, April 1977.  相似文献   

Pre-Imbrian craters and basins: ages,compositions and excavation depths of Apollo 16 breccias     

P Maurer  P Eberhardt  J Geiss  N Grögler  A Stettler  G.M Brown  A Peckett  U Krähenbühl 《Geochimica et cosmochimica acta》1978,42(11):1687-1720

Breccia fragments have been analyzed from the 2–4 mm sieve fraction of three Apollo 16 soils collected in the vicinity of North Ray Crater (63503,17 at Station 13; 67603,1 and 67703,14 at Station 11). Ar³⁹-Ar⁴⁰ ages, Ar³⁷-Ar³⁸ exposure ages, abundances of major and certain trace elements, and petrographie data relevant to thermal history have been obtained for up to 48 individual fragments.Among the samples. 30 gave Ar³⁹-Ar⁴⁰ release patterns that allowed the assignment of a high- or intermediate-temperature plateau age and the recognition of three age groups. Group I (10 fragments) are 4.12-4.21 AE, Group 2 (13 fragments) are 3.89-4.02 AE, and Group 3 (6 fragments) are <2.5 AE in age. Only one fragment (3.60 AE) falls outside this grouping and possibly represents Theophilus ejecta. The probability that the gap between 4.12 and 4.02 AE is a statistical fluctuation is only ～2%. The exposure ages cluster strongly around 50 × 10⁶y. the age of North Ray Crater.The oldest, Group 1 fragments are all anorthositic metamorphosed breccias of light-matrix type. The younger. Group 2 fragments are noritic anorthosite and anorthositic norite breccias with textures indicative of greater annealing (melted matrix), one totally melted sample being of KREEP-basalt texture. The very young. Group 3 fragments are chiefly of glass or devitrified glass. There is a marked distinction between Groups 1 and 2 in compositional as well as textural properties. The Group 2 breccias are generally enriched in Mg, K and REE relative to the aluminous Group I breccias (eg. K ≤ 400 ppm in Group 1 and mostly ≥ 600 ppm in Group 2). This difference is attributed to the introduction of KREEP and mafic ANT components during the formation of the Group 2 breccias.The results are interpreted as reflecting two magnitudes of cratering. The older craters (>4.1 AE) were of medium size (diameters up to a few hundred kilometers), large enough to reset the ages but not capable of excavating deeper than predominantly feldspathic (anorthositic) layers of the crust. The younger craters (～3.9-4.0 AE) were, in contrast, those ascribed to major basin-forming events and were therefore capable of excavating a deeper and wider spectrum of crustal lithologies. The latter resulted in admixture of KREEP and mafic ANT components with the feldspathic ANT, cover layer. KREEP was thus only excavated in abundance during the basin-forming events, from a sub-crustal layer formed initially at ～4.4 AE but incorporated in the breccias at ～4 AE.The KREEP-contaminated. Group 2 breccias have—except two fragments—ages between 3.95 and 4.02 AE. This group includes a crystallized melt (3.97 ± 0.04 AE), close in composition and texture to 14310 (3.87 ± 0.04 AE) which is generally attributed to the Imbrian basin-forming event (～3.88 AE). The pre-Imbrian. Group 2 breccias of Apollo 16 can best be attributed to the Nectaris basin-forming event, which according to the clustered ages probably occurred at ～3.98 AE. Our results support a multi-impact lunar cataclysm with the formation of Nectaris (3.98 AE). Humorum. South Serenitatis, Crisium and Imbrium (3.88 AE) within a 0.1 AE time interval.  相似文献   

The Precambrian geotectonic evolution of Africa: plate accretion versus plate destruction     

A. Kröner 《Precambrian Research》1977,4(2):163-213

The classical model of continental accretion and progressive cratonization, starting with an ancient nucleus onto which younger orogenic belts are welded (onion skin tectonics), has dominated geotectonic research for many years and has received new impetus with the general acceptance of the theory of plate tectonics. It has also been applied to the geotectonic evolution of large Precambrian crustal segments such as Africa.It is demonstrated, however, that new structural, geochronological and paleomagnetic data from Africa provide strong evidence for the existence of large cratonic continental plates since at least the Early Proterozoic which were later transected by linear mobile belts and thus partly destroyed. Crustal reworking and rejuvenation in these belts now gives the impression of younger orogens surrounding ancient “nuclei”.The geotectonic evolution of Africa is therefore characterized by plate destruction rather than by plate accretion with progressive cratonization, and only the “nuclei” have escaped this process.Many phenomena in the African mobile belts seem to indicate processes involving little or no relative motion of crustal plates or crustal shortening between them, and there is as yet no evidence of former oceanic plates to have been generated or consumed. It is therefore suggested that large-scale dispersive movements of major continental fragments were uncommon or absent in the Early and Middle Precambrian.Widespread drift may only have begun during the Late Precambrian/Early Paleozoic Pan African Tectogenesis, eventually leading to a crustal evolution as envisaged by the modern theory of global tectonics.  相似文献   

Meteoritic trace elements in lunar rock 14321, 184     

John W Morgan  R Ganapathy  Urs Krähenbühl 《Geochimica et cosmochimica acta》1975,39(3):261-264

The 16 trace elements (Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Rb, Re, Sb, Se, Te, Tl and Zn) were measured by radiochemical neutron activation analysis in six samples of 14321, 184: microbreccia-2 (15), microbreccia-3 (14A, 16A and 19A), basaltic clast (1A), and light matrix material (9A). The 14321 microbreccias typically contain a siderophile-rich ancient meteoritic component, poor in volatiles, which is characterized by low $\text{Ir}\text{Au}$ and $\text{Re}\text{Au}$ ratios (0.25-0.38 and 0.34-0.50, respectively, normalized to Cl). This component also occurs in Apollo 12 KREEP glasses, norite fractions of Apollo 14 1–2 mm soils, Apennine Front breccias, and Cayley Formation material, and may represent ejecta from the Imbrian basin.The basaltic clast 14321, 184-1A closely resembles 14053 in trace element content, and both are 5–10 times higher than mare basalts in volatile trace elements (Br, Cd, Tl). The light matrix material contains 9.2 ± 0.5 per cent of microbreccias, judging from its siderophile content.  相似文献