Geochemical modelling of basalts from DSDP Leg 65, East Pacific Rise,Gulf of California     

A.M. Kudo  S.E. Barker  K. Keil  Marvin H. Beeson 《Geochimica et cosmochimica acta》1982,46(12):2427-2434

Major and rare earth element (REE) data for basalts from Holes 483, 483B, and 485A of DSDP Leg 65, East Pacific Rise, mouth of the Gulf of California, support a simple fractional crystallization model for the genesis of rocks from this suite. The petrography and mineral chemistry (presented in detail elsewhere) provide no evidence for magma mixing, but rather a simple multistage cooling process. Based on its lowest TiO₂ content (0.88%), $\text{FeO}{}^1\text{MgO}$ ratio (0.95 with total Fe as FeO), and Mg# (100 $\text{Mg}\text{Mg + Fe}\text{″ = 70}$), sample 483-17-2-(78–83) has been selected as the most primitive primary magma of the samples analyzed. This is supported by the REE data which show this sample has the lowest total REE content, a $\text{La}\text{Sm}{}_{\mathrm{cn}}$ (chondrite-normalized) = 0.36, and $\text{Eu}\text{Sm}{}_{\mathrm{cn}}$ = 1.05. Because other samples analyzed have higher SiO₂, lower Mg#, and a negative Eu anomaly ($\text{Eu}\text{Sm}{}_{\mathrm{cn}}$ as low as 0.89), they are most likely derivative magmas. Wright-Doherty and trace element modelling support fractional crystallization of 14.1% plagioclase (An₈₈), 6.7% olivine (Fo₈₆), and 4.7% clinopyroxene (Wo₄₁En₄₉Fs₁₀) from 483-17-2-(78–83) to form the least differentiated sample with Mg# = 63. The $\text{La}\text{Sm}{}_{\mathrm{cn}}$ of this derivative magma is almost identical to the parent magma (0.35 to 0.36), but the other samples have higher $\text{La}\text{Sm}{}_{\mathrm{cn}}$ (0.45 to 0.51), more total REE, and lower Mg# (60 to 56). Both Wright-Doherty and trace element modelling indicate that the primary magma chosen cannot produce these more evolved samples. For the major elements, the TiO₂ and P₂O₅ are too low in the calculated versus the observed (1.38 to 1.90; 0.11 to 0.17, respectively, for example). Rayleigh fractionation calculates a lower $\text{La}\text{Sm}{}_{\mathrm{cn}}$ and requires about 60% crystal removal versus 40% for the Wright-Doherty. These more evolved samples must be derived from a parent magma different from the one selected here and, unfortunately, not sampled in this study. A magma formed by a smaller degree of partial melting with slightly more residual clinopyroxene left in the mantle than for sample 483-17-2-(78–83) is required.  相似文献   

Thermal expansion of fayalite,Fe2SiO4     

Isao Suzuki  Kiyoshi Seya  Humihiko Takei  Yoshio Sumino 《Physics and Chemistry of Minerals》1981,7(2):60-63

Thermal expansion of single-crystal fayalite has been measured by a dilatometric method at temperatures between 25 °C and 850 °C. The results show the presence of anomalous expansion in the b axis, which is correlated to the anomalous variation of elastic moduli with temperature. Grüneisen's parameter is 1.10 and the thermal Debye temperature is 565 K, which is close to the acoustic Debye temperature of 511 K.  相似文献   

The isotopic composition of strontium in Central American ignimbrites     

P. Pushkar  A. R. McBirney  A. M. Kudo 《Bulletin of Volcanology》1971,35(2):265-294

Voluminous sheets of rhyolitic ignimbrites were crupted during Miocene time in a region of Central America that is underlain by a thick sequence of middle Paleozoic and older metamorphic and plutonic rocks. Strontium isotopic ratios of fifteen ignimbrites range from 0.7035 to as high as 0.7175. These values are markedly higher than those measured for cale-alkaline lavas of the same province, but overlap the range found in basement rocks that may have served as source rocks for anateetic magmas. This relationship is in contrast to that found in the western United States where siliceous ignimbrites are not significantly richer in radiogenic strontium than are the basalt erupted through the same basement series. Several possible models for the origin of the large volumes of siliceous magma are examined in terms of major-element and isotopic relations, experimental studies of phase relations, and the thermal requirements of melting or assimilating basement rocks. A mathematical model for the effects of assimilation in open and closed systems permits a comparison of predicted chemical and isotopic compositions with those observed and places limits on the plausibility of various schemes of contamination with or without concurrent crystal fractionation. None of the models is without its flaws. Recent suggestions that large volumes of siliceous magma may be derived from the mantle or lower crust explain certain aspects of the Central American ignimbrites very well if one postulates that the high strontium ratios resulted from contamination of the magma with radiogenic strontium released by the break-down of mieas in basement rocks through which the magmas rose. Such a model fails to explain the apparent restriction of large rhyolitic ignimbrite cruptions to areas underlain by thick continental crust.  相似文献   

Study of the relationship between non-dimensional roughness length and wave age, effected by wave directionality     

Naoya Suzuki  Naoto Ebuchi  Chaofang Zhao  Isao Watabe  Yasuhiro Sugimori 《Journal of Earth System Science》2002,111(3):305-313

Relationship between the non-dimensional roughness length and inverse of wave age has been discussed without consideration of wave directions, though wind wave field consists of various directional component waves. In this study we observe wave heights by an array of four wave gauges at the Hiratsuka Tower of (Independent Administrative Institution) National Research Institute for Earth Science and Disaster Prevention (NIED), Japan, and discuss the effect of wave directionality. As a result, the data sets were classified into two different groups according to the directional wave spectrum distribution. In case 1 only swell and wind waves exist and in case 2 there exist wave components from several directions. It is shown that the case of multiple-directional component waves (case 2) may affect the non-dimensional roughness length and friction velocity.  相似文献   

A 100 m laser strainmeter system installed in a 1 km deep tunnel at Kamioka, Gifu, Japan   总被引：1，自引：0，他引：1  

Shuzo Takemoto  Akito Araya  Junpei Akamatsu  Wataru Morii  Hideo Momose  Masatake Ohashi  Ichiro Kawasaki  Toshihiro Higashi  Yoichi Fukuda  Shinji Miyoki  Takashi Uchiyama  Daisuke Tatsumi  Hideo Hanada  Isao Naito  Souichi Telada  Nobuo Ichikawa  Kensuke Onoue  Yasuo Wada 《Journal of Geodynamics》2004,38(3-5):477

We have installed a laser strainmeter system in a deep tunnel about 1,000 m below the ground surface at Kamioka, Gifu, Japan. The system consists of three types of independent interferometers: (1) an EW linear strainmeter of the Michelson type with unequal arms, (2) an NS-EW differential strainmeter of the Michelson type with equal arms and (3) a NS absolute strainmeter of the Fabry–Perot type. These are configured in L-shaped vacuum pipes, each of which has a length of 100 m. (1) and (2) are highly sensitive (order of 10⁻¹³ strain) and have wide dynamical range (10⁻¹³–10⁻⁶). Observations with strainmeters (1) and (2) started on June 11, 2003. (3) is a new device for absolute-length measurements of the order of 10⁻⁹ of a long-baseline (100 m) Fabry–Perot cavity by the use of phase-modulated light. This third strainmeter will be ready for operation before the end of 2004. The laser source of strainmeters (1) and (2) is a frequency-doubled YAG laser with a wavelength of 532 nm. The laser frequency is locked onto an iodine absorption line and a stability of 2 × 10⁻¹³ is attained. The light paths of the laser strainmeter system are enclosed in SUS304 stainless steel pipes. The inside pressure is kept to be 10⁻⁴ Pa. Consequently, quantitative measurement of crustal strains of the order of 10⁻¹³ can be attained by employing the laser strainmeter system of (1) and (2) at Kamioka. This resolving power corresponds to that of a superconducting gravimeter. Using the laser strainmeter system, we expect to determine parameters related to fluid core resonance, core modes and core undertone as well as other geodynamic signals such as slow strain changes caused by silent earthquakes or slow earthquakes.  相似文献   

Xenoliths in recent basaltic andesite flows from Arenal Volcano,Costa Rica: inference on the composition of the lower crust     

Corrado Cigolini  Albert M. Kudo 《Contributions to Mineralogy and Petrology》1987,96(3):381-390

Basaltic andesite flows erupted between 1973 and 1980 from Arenal Volcano contain abundant inclusions of anorthosite, olivine gabbro, and pyroxenites, and megacrysts of olivine and anorthite. The anorthosites with large (20 mm) anorthite grains (An_96-92) exhibit deformation twinning and granulation between grain boundaries. Some olivine gabbros have angular clasts of anorthite with bent twins, pyroxene, and olivine in a finer-grained matrix which is distinctly foliated. These textural features suggest that these inclusions were deformed. An exotic (xenolithic) origin is supported in part by the mineral compositions and the estimated temperatures of equilibration: a temperature of about 975° C is obtained by two-pyroxene and Fe-Ti oxide geothermometers for the gabbros, but two-pyroxene temperatures are higher (1064 to 1120° C) for the basaltic andesite host. The olivine gabbro is thought to have crystallized at a pressure between 8.5 and 9.5 kb; whereas the lava phenocrysts crystallized at a much lower pressure of less than 5 kb. These xenoliths probably represent fragments of the lower crust below Arenal volcano. The lava flows show evidence for some contamination especially from fragments of anorthite broken apart from the larger megacrysts and xenoliths. A few phenocrysts of plagioclase in the lava samples have deformation twins. The unusually high Al₂O₃ content (19.4 to 23.2 wt%) of the lava samples can be attributed directly to the addition of anorthite; in fact the observed chemical variation in the lava flows (the increasing alumina and lime contents with decreasing silica) can be explained by this contamination.  相似文献   

Elastic properties of a single-crystal forsterite Mg2SiO4, up to 1,200 K     

Isao Suzuki  Orson L. Anderson  Yoshio Sumino 《Physics and Chemistry of Minerals》1983,10(1):38-46

Elastic moduli of forsterite were measured between 300 and 1,200 K (? 1.6 times the Debye temperature) by the Rectangular Parallelepiped Resonance method. All the moduli decrease regularly with temperature. A summary of the results is as follows:

Elastic moduli C _ij in GPa  相似文献   

48.

High potential activity of extracellular alkaline phosphatase in deep waters of the central Pacific   总被引：1，自引：0，他引：1  

Isao Koike  Toshi Nagata 《Deep Sea Research Part II: Topical Studies in Oceanography》1997,44(9-10)

We found high potential activities of alkaline phosphatase associated with particles (0.2 μm or greater size fraction) in deep waters (1000–4000 m) of the central Pacific Ocean. The potential enzyme activity at depth (0.03 – 0.3 nM h⁻¹) was up to 50% of that at the surface (0–125 m). In contrast, activities of α- and β-d-glucosidase in the deep layer were low (generally less than 1 % of those in the upper layer), yielding up to two orders of magnitude difference in the ratio of alkaline phosphatase and α- and β-d-glucosidase activities with depth. It is unlikely that the phosphatase is actively produced by microorganisms inhabiting the deep-sea environment, where labile organic carbon supply is limited and phosphate concentration is high (2.4 – 3.0 AM). Instead, deep-water phosphatase is probably supplied by rapidly sinking particles and their subsequent fragmentation and dissolution. Different distributions of phosphatase and glucosidase indicate that sinking particles of phytoplankton origin are an important source of alkaline phosphatase enzymes in the deep sea.  相似文献   

49.

Fine scale distribution of nitrous oxide in marine sediments   总被引：1，自引：0，他引：1  

Isao Koike  Kazuki Terauchi 《Marine Chemistry》1996,52(3-4)

Vertical profiles of nitrous oxide and other inorganic nitrogen compounds in the sediments in Tokyo Bay and its vicinity were measured using the whole core squeezing method. Within the bay area, vertical profiles of nitrous oxide in the interstitial waters showed one or two distinctive peaks around the depth of 2–4 cm, which corresponded to the peaks of nitrite and nitrate. In situ formation of nitrous oxide through nitrification was suggested in those sediments, which was possibly activated by the presence of benthic animals. On the other hand, at the deep sediment off Tokyo Bay the profiles of nitrous oxide, nitrite and nitrate gave a monotonous single peak, indicating less bioturbated condition. Denitrification or dissimilatory nitrate reduction might be important for the formation of nitrous oxide peaks in the latter type of sediment.  相似文献   

50.

Silicate to Nitrate Ratio of the Upper Sub-Arctic Pacific and the Bering Sea Basin in Summer: Its Implication for Phytoplankton Dynamics   总被引：2，自引：0，他引：2  

Isao Koike  Hiroshi Ogawa  Toshi Nagata  Rumi Fukuda  Hideki Fukuda 《Journal of Oceanography》2001,57(3):253-260

Consumption of silicate and nitrate (Si:N molar ratio) in the upper layer of the pelagic subarctic Pacific in summer was evaluated by a regression analysis of silicate vs. nitrate concentrations at the upper 100 m depth. Based on data of three cruises, the pelagic subarctic Pacific can be classified into two groups. First group is characterized by roughly 1:1 consumption of silicate and nitrate, and occupies rather larger area of subarcfic Pacific, i.e., the Gulf of Alaska and the Western Subarctic gyre (averaged slope of Si:N linear regression: 1.21, n = 10 and 1.45, n = 9, respectively). Second group is the regions of the Bering Sea basin and the Oyashio region, and showed higher silicate consumption compared to that of nitrate (averaged slope of Si:N linear regression: 2.14, n = 9 and 2.36, n = 3, respectively). The Si:N difference observed is possibly attributed to relative contribution of diatoms production among the phytoplankton assemblages in the regions, i.e., dominance of diatoms production in the regions of the second group. Higher accumulation of ammonium at the bottom of euphotic layer in the summer Bering Sea basin would also contribute to increase consumption ratio of Si:N amounts.  相似文献   

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