Origin,organic geochemistry,and estimation of the generation potential of Neogene lacustrine sediments from the Valjevo-Mionica Basin,Serbia     

A. Sajnović  K. Stojanović  G. S. Pevneva  A. K. Golovko  B. Jovančičević 《Geochemistry International》2010,48(7):678-694

This paper reports an investigation of 60 samples of lacustrine sedimentary rocks of Neogene age lying at depths of 0–400 m in the Valjevo-Mionica Basin, Serbia. The goal of the study was to determine the origin and type of primary organic matter (OM), the degree of thermal alteration, the generation potential of OM from the rocks of this basin, and conditions in the sedimentation environment during the formation of the rocks. The potential of OM of the rocks was estimated on the basis of the thermolysis of a representative sample after its preliminary debituminization.  相似文献   

Occurrence and geochemistry of arsenic in the groundwater of Eastern Croatia     

M. Ujević  Ž. Duić  C. Casiot  L. Sipos  V. Santo  Ž. Dadić  J. Halamić 《Applied Geochemistry》2010

In order to examine the extent of the As enrichment and the factors influencing this enrichment in the groundwater of Eastern Croatia, groundwater samples were collected from 56 production wells in two counties, Osijek-Baranja and Vukovar-Srijem, suspected to be more affected. Hydrochemical analyses were performed at all locations including in situ As speciation at 32 locations. Arsenic was detected in 46 out of 56 groundwater samples with total As concentrations up to 491 μg/L. Thirty-six of the studied wells yielded groundwater with total As concentrations that exceeded the WHO Maximum Contaminant Level for arsenic in drinking water of 10 μg/L. Only inorganic As species were detected with arsenite As(III) as the predominant form. The spatial distribution of As in the groundwater was significantly linked with geological, geomorphological and hydrogeological development of the alluvial basin of the Drava and Sava rivers. The most probable groundwater As sources are deeper sediments from the Middle and Upper Pleistocene. The results obtained suggest that biogeochemical processes controlling As concentration in the groundwater are complex and location-specific. Reductive dissolution of Fe oxides, desorption of As from Fe oxides and/or clay minerals as well as competition for the sorption sites with organic matter and phosphate could be the principal mechanisms that control As mobilization. The extent of those processes vary in the different parts of the Drava and Sava depressions and could be linked to different site related parameters, such as lithology, mineralogy, local hydrology and hydrogeology; thus different processes of As mobilization have been proposed for the different types of water in relation to groundwater evolution.  相似文献   

Radiometric mapping of the Berg River estuary     

Ivan Henrico  Susan Henrico  Rikus le Roux  Jacques Bezuidenhout 《Transactions in GIS》2023,27(1):105-114

Geographic Information Systems (GIS) consists of various tools to perform spatial analyses in a wide variety of disciplines, including radiometric analysis to characterize the distribution of natural radionuclide concentrations. Recently, open-source GIS has become popular among geospatial users because it can be freely used, and powerful tools are constantly developed to enhance software capabilities. Gamma-ray spectroscopy was used to measure the concentrations of these natural radionuclides by dragging a Delta Underwater Gamma System (DUGS) among the sediment in the Berg River estuary located in Velddrif, South Africa. In this study, QGIS was used to visually illustrate and interpret the distribution of natural radionuclides, that is, potassium (K⁴⁰), thorium (Th²³²), and uranium (U²³⁸). These concentrations can be used to investigate various geographical and geological phenomena, which include sediment processes. The data were then interpreted to derive sediment characteristics. Various features of tidal estuaries were demonstrated by the results.  相似文献   

Estimating present day extreme water level exceedance probabilities around the coastline of Australia: tropical cyclone-induced storm surges   总被引：2，自引：0，他引：2  

Ivan D. Haigh  Leigh R. MacPherson  Matthew S. Mason  E. M. S. Wijeratne  Charitha B. Pattiaratchi  Ryan P. Crompton  Steve George 《Climate Dynamics》2014,42(1-2):139-157

The incidence of major storm surges in the last decade have dramatically emphasized the immense destructive capabilities of extreme water level events, particularly when driven by severe tropical cyclones. Given this risk, it is vitally important that the exceedance probabilities of extreme water levels are accurately evaluated to inform risk-based flood and erosion management, engineering and for future land-use planning and to ensure the risk of catastrophic structural failures due to under-design or expensive wastes due to over-design are minimised. Australia has a long history of coastal flooding from tropical cyclones. Using a novel integration of two modeling techniques, this paper provides the first estimates of present day extreme water level exceedance probabilities around the whole coastline of Australia, and the first estimates that combine the influence of astronomical tides, storm surges generated by both extra-tropical and tropical cyclones, and seasonal and inter-annual variations in mean sea level. Initially, an analysis of tide gauge records has been used to assess the characteristics of tropical cyclone-induced surges around Australia. However, given the dearth (temporal and spatial) of information around much of the coastline, and therefore the inability of these gauge records to adequately describe the regional climatology, an observationally based stochastic tropical cyclone model has been developed to synthetically extend the tropical cyclone record to 10,000 years. Wind and pressure fields derived for these synthetically generated events have then been used to drive a hydrodynamic model of the Australian continental shelf region with annual maximum water levels extracted to estimate exceedance probabilities around the coastline. To validate this methodology, selected historic storm surge events have been simulated and resultant storm surges compared with gauge records. Tropical cyclone induced exceedance probabilities have been combined with estimates derived from a 61-year water level hindcast described in a companion paper to give a single estimate of present day extreme water level probabilities around the whole coastline of Australia. Results of this work are freely available to coastal engineers, managers and researchers via a web-based tool (www.sealevelrise.info). The described methodology could be applied to other regions of the world, like the US east coast, that are subject to both extra-tropical and tropical cyclones.  相似文献   

Annual and seasonal variability of precipitation in Vojvodina,Serbia     

Ivana Tošić  Ivana Hrnjak  Milivoj B. Gavrilov  Miroslava Unkašević  Slobodan B. Marković  Tin Lukić 《Theoretical and Applied Climatology》2014,117(1-2):331-341

Annual and seasonal variability of precipitation observed at 92 stations in Vojvodina (Serbia) were analyzed during the period 1946–2006. The rainfall series were examined by means of the empirical orthogonal functions (EOF). The first set of singular vectors explains from 68.8 % (in summer) to 81.8 % (in winter) of the total variance. The temporal variability of the time series associated with the main EOF configurations (the principal components, PCs) was examined using the Mann–Kendall test and the spectral analysis. The time series of PC1 revealed decreasing trend in the winter and spring precipitation and increasing trend in the autumn, summer, and annual precipitation. The relationships between the first PC and circulation patterns, such as the North Atlantic Oscillation (NAO), the East Atlantic (EA) pattern, and East Atlantic/West Russia pattern, were also investigated. The PC1, displaying temporal behavior of the first mode, demonstrated evident correspondence with the NAO index in analysis of the annual, winter, and autumn precipitation. Power spectra of the PC1 show statistically significant oscillations of about 3.3 years for the spring precipitation and about 8 and 15 years for the winter precipitation. Comparisons with spectral analysis of authors for some regions in Europe, most of them in the Mediterranean domain, show that similar periodicities are detected.  相似文献   

Sensitivity of the regional climate model RegCM4.2 to planetary boundary layer parameterisation     

Ivan Güttler  Čedo Branković  Travis A. O’Brien  Erika Coppola  Branko Grisogono  Filippo Giorgi 《Climate Dynamics》2014,43(7-8):1753-1772

This study investigates the performance of two planetary boundary layer (PBL) parameterisations in the regional climate model RegCM4.2 with specific focus on the recently implemented prognostic turbulent kinetic energy parameterisation scheme: the University of Washington (UW) scheme. When compared with the default Holtslag scheme, the UW scheme, in the 10-year experiments over the European domain, shows a substantial cooling. It reduces winter warm bias over the north-eastern Europe by 2 °C and reduces summer warm bias over central Europe by 3 °C. A part of the detected cooling is ascribed to a general reduction in lower tropospheric eddy heat diffusivity with the UW scheme. While differences in temperature tendency due to PBL schemes are mostly localized to the lower troposphere, the schemes show a much higher diversity in how vertical turbulent mixing of the water vapour mixing ratio is governed. Differences in the water vapour mixing ratio tendency due to the PBL scheme are present almost throughout the troposphere. However, they alone cannot explain the overall water vapour mixing ratio profiles, suggesting strong interaction between the PBL and other model parameterisations. An additional 18-member ensemble with the UW scheme is made, where two formulations of the master turbulent length scale in unstable conditions are tested and unconstrained parameters associated with (a) the evaporative enhancement of the cloud-top entrainment and (b) the formulation of the master turbulent length scale in stable conditions are systematically perturbed. These experiments suggest that the master turbulent length scale in the UW scheme could be further refined in the current implementation in the RegCM model. It was also found that the UW scheme is less sensitive to the variations of the other two selected unconstrained parameters, supporting the choice of these parameters in the default formulation of the UW scheme.  相似文献   

Coupling multipoint flux mixed finite element methodswith continuous Galerkin methods for poroelasticity     

Mary Wheeler  Guangri Xue  Ivan Yotov 《Computational Geosciences》2014,18(1):57-75

We study the numerical approximation on irregular domains with general grids of the system of poroelasticity, which describes fluid flow in deformable porous media. The flow equation is discretized by a multipoint flux mixed finite element method and the displacements are approximated by a continuous Galerkin finite element method. First-order convergence in space and time is established in appropriate norms for the pressure, velocity, and displacement. Numerical results are presented that illustrate the behavior of the method.  相似文献   

2D geological–geophysical model of the Timok Complex (Serbia,SE Europe): a new perspective from aeromagnetic and gravity data     

Snežana Ignjatović  Ivana Vasiljević  Milenko Burazer  Miodrag Banješević  Ivan Strmbanović  Vladica Cvetković 《Swiss Journal of Geoscience》2014,107(1):101-112

The study reports new aeromagnetic and gravity data for the northern part of the Timok Magmatic Complex (TMC), East Serbia. The TMC is part of the Tethyan Eurasian metallogenic zone well known for hosting large copper and gold deposits. The complex formed by continuous volcanic activity 90–78 Ma ago, that developed in roughly three phases: Turonian andesites, Santonian–Campanian andesites/basaltic andesites (both mostly volcanic) and Campanian latites/monzonites (mostly shallow intrusive). The aeromagnetic measurements included acquiring total magnetic intensity data that were corrected for diurnal variations, leveling, microleveling, calculated normal field values, calculated anomaly values of total magnetic field intensity and reduction to the pole. The gravity measurements were carried out in an irregular grid with relative gravity values obtained using a Worden gravity meter. 2D modeling reveals that the subsurface extension of the Campanian Valja Str? pluton is ten times larger than it is indicated by its surface outcrops. This implies that the area south and southeast from the pluton can be interesting in terms of finding new porphyry systems. The model indicates that this intrusive body should not be considered as a deeply dissected pluton. This sheds new light onto its potential with respect to epithermal gold mineralization, as well. The model also suggests that there are larger non-exposed bodies of Santonian–Campanian volcanics and near-surface hydrothermally altered rocks than it is inferred from geological maps. The results of our study suggest that further interdisciplinary investigations in the TMC, in particular those integrating geophysics and geology, may have potential of advancing the existing exploration models.  相似文献   

A critical evaluation of using bulk sediment instead of fine fraction in environmental marine studies, investigated on example of Rijeka harbor, Croatia     

Stanislav Frančišković-Bilinski  Neven Cukrov 《Environmental Earth Sciences》2014,71(1):341-356

This work tested the preferential use of fine (<63 μm) or bulk sediment (<2 mm) in environmental research of marine sediments in the Eastern Adriatic. Fine fraction sediment containing silt and clay (<63 μm), predominating in the studied area, was examined to evaluate past and present anthropogenic inputs and to test our hypothesis that investigation of bulk sediment should be preferred. Following aqua regia digestion, chemical analyses of 58 elements were performed by ICP/OES, ICP-MS and cold vapor AAS, and statistical analysis was performed. The concentrations of the majority of the analyzed elements increased with age of the sediment, except for Ag and Sn, which had higher concentrations in recent sediments. The previous main sources of metal contamination in Rijeka harbor were now abandoned municipal-sewage outflow and oil refinery, and continuing harbor activities and antifouling paint use. All activities except of antifouling paint use have been decreasing significantly. Anomalies of selected elements were determined by the box-plot method. More anomalies were found in the bulk sediment than in the fine fraction. Results of Q-modality clustering and factor analysis in the fine fraction almost correlate with that applied on bulk sediments. Thus, it can be said that the differences between the element distribution in the bulk and fine fraction are not statistically significant. Our conclusion is that analysis of bulk marine sediment gives a better insight into the state of pollution and supports previous recommendations to use bulk sediment as a chosen media for environmental studies.  相似文献   

3D modeling and monitoring of karst system as a base for its evaluation and utilization: a case study from eastern Serbia     

Saša Milanović  Zoran Stevanović  Ljiljana Vasić  Vesna Ristić-Vakanjac 《Environmental Earth Sciences》2014,71(2):525-532

Beljanica Mountain in eastern Serbia is a part of the Carpathian Balkan arch (northern Alpine branch). It covers an area of about 300 km² and consists mostly of Jurassic and Cretaceous limestones. Numerous surface karst features, long caves and several large karstic springs located in Beljanica’s piedmont along the contact of karstic and non-karstic rocks are all indicators of an intense karstification. Currently, the large karstic water reserves of Beljanica Mountain are not properly utilized because of their distance from main consumers, the objection by national water managers that the springs lack a stable and sufficient discharge particularly during recession periods. Due to its unpolluted and high quality water, the area is a great prospect for future water supply, and provides an opportunity for artificial regulation and for the design and implementation of specific tapping structures. This paper includes an analysis of the created 3D ArcGIS model of karst interior and its correlation with historical and newly collected data of spring discharges and groundwater physico-chemical characteristics. The results of karst aquifer monitoring (both quantitative and qualitative) are linked with the results of extensive field geological and speleological survey of the upper non-saturated part of the karst (such as sinkholes, pits and caves) and with the investigation of the permanently saturated deeper part of the aquifer (including the diving methods). The model of karst interior is based on the data from the 69 caves, 15 sinks and 1,682 dolines (sinkholes) surveyed. The total length of the karst channels network, calculated using the GIS model and presented in a 3D environment, is 647 km. The catchment areas of five major springs that drain the areas are estimated to range from only 7 km² (Malo Vrelo Spring) to 124 km² (Vrelo Mlave Spring). The groundwater exploitable reserves of Beljanica karst aquifer are estimated to be over 4 m³/s. The waters are low mineralized, unpolluted and have a great potential for water supply.  相似文献