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Andreas?LüttgeEmail author Edward?W.?Bolton Danny?M.?Rye 《Contributions to Mineralogy and Petrology》2004,146(5):546-565
We use a kinetic model of a metamorphic system to study the effect of competing rates of reaction, fluid injection, and heating on the evolution of the reaction pathway in temperature/composition space at constant pressure. We show that for rocks in contact with mixed volatile (e.g., CO2-H2O) fluids the reaction path may be quite different from what is expected from equilibrium-based petrologic models. Equilibrium-based models, used to understand the development of rock systems undergoing mineral reactions during a metamorphic event, rely on the Gibbs phase rule and only consider stable phases. For constant pressure, the temperature-composition paths follow univariant curves and significant reactions may occur at invariant points. By contrast, the more general kinetic treatment is not constrained by equilibrium, although with the proper competing rates equilibrium is a possible endmember of the kinetic approach. The deviation from equilibrium depends on the competing rates of reaction, heating, and fluid injection. A key element required by the kinetic approach is the inclusion of metastable reactions in the formulation, whereas such reactions are irrelevant for equilibrium-based models. Metastable reactions are often involved in a complex interplay with common prograde stable metamorphic reactions. We present model results for the well-studied CaO-MgO-SiO2-CO2-H2O (CMS) system to show how the system evolves under kinetic control. Our simulations and discussion focus on the behavior of the CMS system under a number of closed and open system conditions. Special attention is paid to closed system behavior in the vicinity of the (first) isobaric invariant point (with Dol, Qtz, Tlc, Cal, and Tr). Also, for open systems with massive fluid infiltration we consider heating rates varying from contact to regional metamorphic conditions. For some geologically reasonable rates of reactions, heating, and fluid injection, our results demonstrate that equilibrium conditions may be significantly overstepped in metamorphic systems. We used overall mineral reactions in this model with rates based on experimental results. Future models could rely on more fundamental dissolution and precipitation reactions. Such an extension would require additional kinetic rate data, as well as mineral solubilities in mixed volatile fluids.Editorial responsibility: J. Hoefs 相似文献
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Gabriel Grigorescu Paul Alexander Rosie C. Bolton Roshene McCool 《Experimental Astronomy》2009,27(1-2):95-107
The future Square Kilometre Array (SKA) radio telescope is an interferometer array that will use a variety of collector types, including approximately 2500 dishes distributed with separations up to a few thousand kilometres, and about 250 aperture array (AA) stations located within 200 km of the core. The data rates associated with each individual collector are vast: around 10 GBytes/s for each dish and 2 TBytes/s for an AA station. As each of these must be connected directly to a central correlator, designing a cost-effective cabling and trenching infrastructure presents a great engineering challenge. In this paper we discuss approaches to performing this optimisation. In graph theory, the concept of a minimum spanning tree (MST) is equivalent to finding the minimum total trench length joining a set of n arbitrary points in the plane. We have developed a set of algorithms which optimise the infrastructure of any given telescope layout iteratively, taking into consideration not only trenching but also cabling and jointing costs as well. Solutions for few example configurations of telescope layout are presented. We have found that these solutions depend significantly on the collectors’ output data rates. When compared to a “traditional” MST-based approach which minimises trenching costs only, our algorithms can further reduce total costs by up to 15–20%. This can influence greatly the SKA infrastructure related costs. 相似文献
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One of the important geotechnical considerations for many engineering installations, such as pipelines and anchors, in an oceanic environment involving sand deposits is that of potential ocean floor instability due to the development of high pore pressures caused by the direct action of waves. This article presents a procedure for evaluating the magnitude and distribution of wave‐induced pore pressures in ocean floor deposits. The method takes into account the distribution of wave‐induced pore pressures in ocean floor deposits. The method takes into account the distribution of cyclic shear stresses in the soil profile as well as the important factor of pore‐pressure dissipation. The variation of properties within the soil profile can also be easily incorporated into the analytical procedure. The analysis provides the complete time history of pore‐pressure response and shows clearly that failure to include the pore‐pressure dissipation effects would lead to radically conservative design. The results also provide a basis for designing remedial measures, if required, to avert the development of high pore pressures and their deleterious effects. 相似文献
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N Loiseau JJ Kiszka T Bouveroux MR Heithaus M Soria P Chabanet 《African Journal of Marine Science》2016,38(1):73-79
Bull sharks Carcharhinus leucas are common along the coast of Reunion Island (South-West Indian Ocean) and were suspected to aggregate in the vicinity of an aquaculture farm in Saint-Paul Bay on the west coast. In order to understand the behaviour and interaction of bull sharks near aquaculture cages at Saint-Paul Bay, we deployed an experimental unbaited stationary video camera. From 175 hours of recording during daylight hours from March to April 2012, eight individual female bull sharks (seven adults and one immature) were identified based on their natural markings. These sharks were resighted between 3 and 45 times. Residency analysis revealed site attachment under the aquaculture cages for at least three individuals over the course of the study. Recorded behaviours included intraspecific social interactions such as synchronised swimming. Social interactions and relatively strong paired associations for two pairs of females suggest some level of sociality among bull sharks around Reunion Island. Overall, our results demonstrate the utility of unbaited video systems to monitor the behaviour of adult coastal sharks. 相似文献
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James S. Bolton S. Peng Oh Steven R. Furlanetto 《Monthly notices of the Royal Astronomical Society》2009,396(4):2405-2418
Three independent observational studies have now detected a narrow (Δ z ≃ 0.5) dip centred at z = 3.2 in the otherwise smooth redshift evolution of the Lyα forest effective optical depth. This feature has previously been interpreted as an indirect signature of rapid photoheating in the intergalactic medium (IGM) during the epoch of He ii reionization. We examine this interpretation using a semi-analytic model of inhomogeneous He ii reionization and high-resolution hydrodynamical simulations of the Lyα forest. We instead find that a rapid (Δ z ≃ 0.2) boost to the IGM temperature (Δ T ≃ 104 K) beginning at z = 3.4 produces a well understood and generic evolution in the Lyα effective optical depth, where a sudden reduction in the opacity is followed by a gradual, monotonic recovery driven largely by adiabatic cooling in the low-density IGM. This behaviour is inconsistent with the narrow feature in the observational data. If photoheating during He ii reionization is instead extended over several redshift units, as recent theoretical studies suggest, then the Lyα opacity will evolve smoothly with redshift. We conclude that the sharp dip observed in the Lyα forest effective optical depth is instead most likely due to a narrow peak in the hydrogen photoionization rate around z = 3.2 , and suggest that it may arise from the modulation of either reprocessed radiation during He ii reionization, or the opacity of Lyman limit systems. 相似文献
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豫西沙沟脉状Ag-Pb-Zn矿床地质特征和成矿流体研究 总被引：6，自引：1，他引：5
豫西沙沟薄脉状Ag-Pb-Zn硫化物矿床位于华北陆块南缘熊耳山地区,主要由多金属硫化物-石英-碳酸盐脉型和石英-碳酸盐-绢云母-多金属硫化物蚀变岩型两种矿化类型组成。主要矿脉的矿物共生序列可以分为成矿前的石英-黄铁矿阶段(Ⅰ)、闪锌矿-石英-方铅矿-少量银矿物阶段(Ⅱ1)、方铅矿-石英-闪锌矿-含铁白云石-银矿物阶段(Ⅱ2)和成矿后的方解石-(石英)阶段(Ⅲ)。对不同阶段的成矿流体研究表明,石英-黄铁矿阶段(Ⅰ)中的含氯化钠子晶三相(LVH)包裹体(Ⅰ1)可能是直接从饱和水的结晶岩浆熔体中出溶形成或是由岩浆流体的减压沸腾形成,显示该区很可能存在岩浆流体端元。多金属硫化物阶段(Ⅱ1Ⅱ2)捕获富液相包裹体(LV型)和个别CO2包裹体(C型),这两个阶段流体包裹体反映了主成矿阶段流体的基本特征,结合包裹体气相和液相成分色谱分析以及包裹体初融温度,认为成矿流体应该为中-低温低盐度含CO2的H2O-NaCl体系。其中,阶段(Ⅱ2)的均一温度(145～288℃,平均为194℃)比阶段(Ⅱ1)的均一温度(185～357℃,平均240℃)低46℃;同时,阶段(Ⅱ2)的盐度(1.91%～10.86%,平均6.38%)较阶段(Ⅱ1)盐度(4.65%～10.11%,平均7.77%)略低。对这一温度和盐度的总体下降趋势的合理解释是大气水的逐渐混入。多金属硫化物阶段(Ⅱ1Ⅱ2)之后的方解石-(石英)阶段普遍为富液相包裹体(LV型),该阶段显著降低的温度(129～208℃,平均165℃)和盐度(1.40%～4.03%,平均2.50%),进一步佐证大气水的不断混入。而且,流体混合可能在引起矿石矿物从热液中沉淀方面起到重要作用。 相似文献
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E. M. Waldram R. C. Bolton G. G. Pooley J. M. Riley 《Monthly notices of the Royal Astronomical Society》2007,379(4):1442-1452
We have used multifrequency follow-up observations of a sample of extragalactic sources from the 9C survey at 15 GHz to make deductions about the expected source population at higher radio frequencies, such as those in the lower frequency bands of the Planck Surveyor satellite. In particular, we have made empirical estimates of the source counts at 22, 30, 43 and 70 GHz and compared these with both known data and current theoretical predictions. We have also made an estimate of the count at the Atacama Large Millimeter Array (ALMA) frequency of 90 GHz, with a view to assessing the possible population of point sources available for the phase calibration of that instrument. 相似文献