Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

Symplectic Mappings of Co-orbital Motion in the Restricted Problem of Three Bodies     

Zsolt Sándor  Bálint Érdi  Carl D. Murray 《Celestial Mechanics and Dynamical Astronomy》2002,84(4):355-368

The dynamics of co-orbital motion in the restricted three-body problem are investigated by symplectic mappings. Analytical and semi-numerical mappings have been developed and studied in detail. The mappings have been tested by numerical integration of the equations of motion. These mappings have been proved to be useful for a quick determination of the phase space structure reflecting the main characteristics of the dynamics of the co-orbital problem.  相似文献   

Book review     

D. W. Connell  Thomas M. Baugh 《Estuaries and Coasts》1992,15(2):255-255

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Radial velocity searches for other planetary systems:Current status and future prospects     

W. D. Cochran  A. P. Hatzes 《Astrophysics and Space Science》1996,241(1):43-60

Measurement of variations in the radial velocities of stars due to the reflex orbital motion of the star around the planetary-system barycenter constitutes a powerful method of searching for substellar or planetary mass companions. After several years of patient data acquisition, radial-velocity searches for planetary systems around other stars are now beginning to bear fruit. In late 1995 and early 1996, three candidate systems were announced with Jovian-mass planets around solar-type stars. The current paradigm for low-mass star formation suggests that planetary systems should be able to form in the circumstellar disks surrounding young stellar objects. These newly discovered systems, and other discoveries which will soon follow them, will test critically our understanding of the processes of star- and planet-formation. We review the techniques used in these radial-velocity searches and their results to date. We then discuss planned improvements in the surveys, and the prospects for the next 20 years.  相似文献   

The MPE X-ray test facility PANTER: Calibration of hard X-ray (15–50 kev) optics     

M. J. Freyberg  H. Bräuninger  W. Burkert  G. D. Hartner  O. Citterio  F. Mazzoleni  G. Pareschi  D. Spiga  S. Romaine  P. Gorenstein  B. D. Ramsey 《Experimental Astronomy》2005,20(1-3):405-412

The Max-Planck-Institut für extraterrestrische Physik (MPE) in Garching, Germany, uses its large X-ray beam line facility PANTER for testing X-ray astronomical instrumentation. A number of telescopes, gratings, filters, and detectors, e.g. for astronomical satellite missions like Exosat, ROSAT, Chandra (LETG), BeppoSAX, SOHO (CDS), XMM-Newton, ABRIXAS, Swift (XRT), have been successfully calibrated in the soft X-ray energy range (< 15keV). Moreover, measurements with mirror test samples for new missions like ROSITA and XEUS have been carried out at PANTER. Here we report on an extension of the energy range, enabling calibrations of hard X-ray optics over the energy range 15–50 keV. Several future X-ray astronomy missions (e.g., Simbol-X, Constellation-X, XEUS) have been proposed, which make use of hard X-ray optics based on multilayer coatings. Such optics are currently being developed by the Osservatorio Astronomico di Brera (OAB), Milano, Italy, and the Harvard-Smithsonian Center for Astrophysics (CfA), Cambridge, MA, USA. These optics have been tested at the PANTER facility with a broad energy band beam (up to 50 keV) using the XMM-Newton EPIC-pn flight spare CCD camera with its good intrinsic energy resolution, and also with monochromatic X-rays between C-K (0.277 keV) and Cu-Kα (8.04 keV). PACS: 95.55.Ka, 95.55.Aq, 41 50.+h, 07.85.Fv  相似文献   

Controlled Direction Reception Filtering of P- and S-Waves In τ-P Space     

S. A. Greenhalgh  I. M. Mason  E. Lucas  D. Pant  R. T. Eames 《Geophysical Journal International》1990,100(2):221-234

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Entry dynamics and acoustics/infrasonic/seismic analysis for the Neuschwanstein meteorite fall     

D. O. REVELLE  P. G. BROWN  P. SPURNÝ 《Meteoritics & planetary science》2004,39(10):1605-1626

Abstract— We have analyzed several types of data associated with the well‐documented fall of the Neuschwanstein meteorites on April 6, 2002 (a total of three meteorites have been recovered). This includes ground‐based photographic and radiometer data as well as infrasound and seismic data from this very significant bolide event (Spurný et al. 2002, 2003). We have also used these data to model the entry of Neuschwanstein, including the expected dynamics, energetics, panchromatic luminosity, and associated fragmentation effects. In addition, we have calculated the differential efficiency of acoustical waves for Neuschwanstein and used these values to compare against the efficiency calculated using available ground‐based infrasound data. This new numerical technique has allowed the source height to be determined independent of ray tracing solutions. We have also carried out theoretical ray tracing for a moving point source (not strictly a cylindrical line emission) and for an infinite speed line source. In addition, we have determined the ray turning heights as a function of the source height for both initially upward and downward propagating rays, independent of the explicit ray tracing (detailed propagation path) programs. These results all agree on the origins of the acoustic emission and explicit source heights for Neuschwanstein for the strongest infrasonic signals. Calculated source energies using more than four different independent approaches agree that Neuschwanstein was certainly <500 kg in initial mass, given the initial velocity of 20.95 km/s, resulting in an initial source energy ≤0.0157‐0.0276 kt TNT equivalent (4.185 times 10¹² J). Local source energies at the calculated infrasonic/seismic source altitudes are up to two orders of magnitude smaller than this initial source energy.  相似文献   

Spectroscopy of comet P/Schaumasse     

Neal James Joung Turner  Graeme H. Smith 《Earth, Moon, and Planets》1996,73(1):33-50

Column density profiles for CN, C₃, C₂ and NH have been determined from a long-slit CCD spectrum of periodic comet P/Schaumasse (1992x). Comparisons of these profiles with Haser models indicate that the ratios of the CN, C₃ and C₂ production rates are typical for a short-period comet. Although the scale lengths for NH and its parent species are uncertain, the results indicate that the production rate for NH is much greater than for either C₂ or CN.  相似文献   

Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites     

Milton BLANDER  Arthur D. PELTON  In‐Ho JUNG  Richard WEBER 《Meteoritics & planetary science》2004,39(12):1897-1910

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.  相似文献   

The discovery of new galaxy members in the NGC 5044 and 1052 groups     

N. P. F. MKay  C. G. Mundell †  S. Brough  Duncan A. Forbes  D. G. Barnes  P. A. James  P. Goudfrooij  V. Kozhurina-Platais  R. Whitaker 《Monthly notices of the Royal Astronomical Society》2004,352(4):1121-1134

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