Structure of Cu-bearing orthopyroxene, Mg(Cu.56,Mg.44)Si2O6, and behavior of Cu2+ in the orthopyroxene structure     

T. Tachi  H. Horiuchi  H. Nagasawa 《Physics and Chemistry of Minerals》1997,24(7):463-476

Cu-bearing pyroxene, Mg(Cu.₅₆,Mg.₄₄)Si₂O₆, has been synthesized by a flux method and crystal structure refinement has been performed by single crystal X-ray diffraction. It is found that the crystal structure is orthorhombic (space group Pbca) with unit cell dimensions of a=18.221(4), b=8.890(1), c=5.2260(7)Å and the cell volume of 846.5( )3ų. In the M2-site one of the M-O bonds(M-O3B) is extremely expanded from 2.444(2) in enstatite to 2.732(2), thus the coordination polyhedron around M2-site is regarded as square pyramidal rather than square planar or octahedral. It is also found that the M1-site in the pyroxene structure is occupied almost exclusively by Mg, while the M2-site is almost evenly occupied by Mg and Cu. The observed extreme site preference shown by Cu²⁺ is unusual among the divalent cations with similar ionic sizes.  相似文献   

ELNES spectroscopy of mixed Si coordination minerals     

B. Poe  F. Seifert  T. Sharp  Z. Wu 《Physics and Chemistry of Minerals》1997,24(7):477-487

 Si K- and L-edge ELNES spectroscopy and multiple-scattering (MS) calculations are used to examine mixed Si coordination compounds varying in Si^VI:Si^IV ratio. As in previous studies, the edges are influenced mainly by silicon coordination (tetrahedral vs. octahedral), as supported by the MS calculations. We demonstrate two methods semi-quantitatively to extract the value of Si^VI/(Si^VI+Si^IV): (1) A linear relationship between the L_2,3-L₁ splitting and Si^VI/(Si^VI+Si^IV) is observed, (2) a fitting method based on the coaddition of reference tetrahedral and octahedral Si spectra is applied to both Si K- and L-edge ELNES spectra. Received: February 10, 1997 / Revised, accepted: May 23, 1997  相似文献   

Defect distribution and the diffuse X-ray diffraction pattern of wüstite, Fe1−xO     

T. R. Welberry  A. G. Christy 《Physics and Chemistry of Minerals》1997,24(1):24-38

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Diatoms in sediments of perennially ice-covered Lake Hoare, and implications for interpreting lake history in the McMurdo Dry Valleys of Antarctica     

S. A. Spaulding  D. M. McKnight  E. F. Stoermer  P. T. Doran 《Journal of Paleolimnology》1997,17(4):403-420

Diatom assemblages in surficial sediments, sediment cores, sediment traps, and inflowing streams of perennially ice-covered Lake Hoare, South Victorialand, Antarctica were examined to determine the distribution of diatom taxa, and to ascertain if diatom species composition has changed over time. Lake Hoare is a closed-basin lake with an area of 1.8 km², maximum depth of 34 m, and mean depth of 14 m, although lake level has been rising at a rate of 0.09 m yr^-1 in recent decades. The lake has an unusual regime of sediment deposition: coarse grained sediments accumulate on the ice surface and are deposited episodically on the lake bottom. Benthic microbial mats are covered in situ by the coarse episodic deposits, and the new surfaces are recolonized. Ice cover prevents wind-induced mixing, creating the unique depositional environment in which sediment cores record the history of a particular site, rather than a lake-wide integration. Shallow-water (<1 m) diatom assemblages (Stauroneis anceps, Navicula molesta, Diadesmis contenta var. parallela, Navicula peraustralis) were distinct from mid-depth (4–16 m) assemblages (Diadesmis contenta, Luticola muticopsis fo. reducta, Stauroneis anceps, Diadesmis contenta var. parallela, Luticola murrayi) and deep-water (26–31 m) assemblages (Luticola murrayi, Luticola muticopsis fo. reducta, Navicula molesta). Analysis of a sediment core (30 cm long, from 11 m water depth) from Lake Hoare revealed two abrupt changes in diatom assemblages. The upper section of the sediment core contained the greatest biomass of benthic microbial mat, as well as the greatest total abundance and diversity of diatoms. Relative abundances of diatoms in this section are similar to the surficial samples from mid-depths. An intermediate zone contained less organic material and lower densities of diatoms. The bottom section of core contained the least amount of microbial mat and organic material, and the lowest density of diatoms. The dominant process influencing species composition and abundance of diatom assemblages in the benthic microbial mats is episodic deposition of coarse sediment from the ice surface.  相似文献   

The (re)making of the western 'geographical tradition': some missing links   总被引：1，自引：0，他引：1  

James Derrick Sidaway 《Area》1997,29(1):72-80

Summary A brief investigation of certain missing links in the narration of the history of geography focuses on the need to consider the contribution of non-western geographical and scientific knowledges to the making of 'European discovery' and therefore to the development of a putatively western geographical tradition.  相似文献   

Racialised representations in British and American advertising     

James Taylor 《Area》1997,29(2):160-171

Summary This paper discusses the relationship between advertising and 'race', using as its foundation the replication of a study conducted in the US which used content analysis to examine the representation of Black characters in television advertisements. The replication facilitates a comparison of the British and American cases, revealing significant differences in the frequency and perceived importance of such representations. It can also help draw out the specificities of the UK situation. The paper attempts to convey the complexity of the interplay between advertising and racialisation, and emphasises that while such quantitative, textual studies offer a useful basis for further research, they are limited by their failure to address the motivations of producers and how advertisements are read by different groups in different places.  相似文献   

The diets of common and Brünnich's guillemots Uria aalge and U. lomvia in the Barents Sea region     

ROBERT T. BARRETT  VIDAR BAKKEN  JURI V. KRASNOV 《Polar research》1997,16(2):73-84

Guillemots Uria spp. account for ca. 70% of the total harvest of prey taken by seabirds breeding in the Barents Sea region. This paper presents guillemot chick diet data collected recently at four localities (Finnmark, Murman, Bjørnøya and Spitsbergen) and collates all the data found by the authors in the literature and in the archives of Tromsø Museum, the Norwegian Polar Institute and Kandalaksha State Nature Reserve. Guillemots consume a wide variety of prey and, in comparison to the harvest by predatory fish and marine mammals, their impact on the Barents Sea ecosystem is considered to be minimal. We point out the need for more systematic collection of data from different regions and at different times of the year before a final impact assessment can be made.  相似文献   

Numerical models of mantle convection with secular cooling     

Wanda DeLandro-Clarke  Gary T. Jarvis 《Geophysical Journal International》1997,129(1):183-193

A 2-D time-dependent finite-difference numerical model is used to investigate the thermal character and evolution of a convecting layer which is cooling as it convects. Two basic cooling modes are considered: in the first, both upper and lower boundaries are cooled at the same rate, while maintaining the same temperature difference across the layer; in the second, the lower boundary temperature decreases with time while the upper boundary temperature is fixed at 0°C. The first cooling mode simulates the effects of internal heating while the second simulates planetary cooling as mantle convection extracts heat from, and thereby cools, the Earth's core. The mathematical analogue between the effects of cooling and internal heating is verified for finite-amplitude convection. It is found that after an initial transient period the central core of a steady but vigorous convection cell cools at a constant rate which is governed by the rate of cooling of the boundaries and the viscosity structure of the layer. For upper-mantle models the transient stage lasts for about 30 per cent of the age of the Earth, while for the whole mantle it lasts for longer than the age of the Earth. Consequently, in our models the bulk cooling of the mantle lags behind the cooling of the core-mantle boundary. Models with temperature-dependent viscosity are found to cool in the same manner as models with depth-dependent viscosity; the rate of cooling is controlled primarily by the horizontally averaged variation of viscosity with depth. If the Earth's mantle cools in a similar fashion, secular cooling of the planet may be insensitive to lateral variations of viscosity.  相似文献   

Comment on: 'Can horizontal P waves be trapped and resonate in a shallow sedimentary basin?' by F. J. Sácnhez-Sesma and F. LuzÓ     

J. L. Mateos  O. Novaro  T. H. Seligman  J. Flores 《Geophysical Journal International》1997,129(1):212-214

We show that most of the arguments in the above paper are either incorrect or irrelevant to the point the authors are trying to make. We show that their results have no bearing on the model proposed by our group, as they claim. They discuss the seismic response of a valley with a 2-D trapezoidal cross-section in a vertical plane, whereas we dealt with a closed basin with a 2-D cross-section but of arbitrary geometry and in the horizontal plane. Even more significantly, the width of the valley they use is much smaller than the wavelength of the horizontal P waves that can resonate, thereby precluding any possibility of them being trapped. Therefore, their arguments do not clarify the issue posed in the title of their article.  相似文献   

Geomorphology in the tropics: A study of weathering and denudation in the low latitudes : M.F. Thomas. Wiley, New York, 1994. 460 pp. ISBN 0-471-93035-0     

T. Beach 《Geomorphology》1997,18(3-4)

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