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81.
Paul H. Whitfield Donald H. Burn Jamie Hannaford Hélène Higgins Glenn A. Hodgkins Terry Marsh 《水文科学杂志》2013,58(8):1562-1579
Abstract Identifying climate-driven trends in river flows on a global basis is hampered by a lack of long, quality time series data for rivers with relatively undisturbed regimes. This is a global problem compounded by the lack of support for essential long-term monitoring. Experience demonstrates that, with clear strategic objectives, and the support of sponsoring organizations, reference hydrologic networks can constitute an exceptionally valuable data source to effectively identify, quantify and interpret hydrological change—the speed and magnitude of which is expected to a be a primary driver of water management and flood alleviation strategies through the future—and for additional applications. Reference hydrologic networks have been developed in many countries in the past few decades. These collections of streamflow gauging stations, that are maintained and operated with the intention of observing how the hydrology of watersheds responds to variations in climate, are described. The status of networks under development is summarized. We suggest a plan of actions to make more effective use of this collection of networks. Editor Z.W. Kundzewicz; Associate editor K. Hamed Citation Whitfield, P.H., et al., 2012. Reference hydrologic networks I. The status and potential future directions of national reference hydrologic networks for detecting trends. Hydrological Sciences Journal, 57 (8), 1562–1579. 相似文献
82.
Natasha M. JOHNSON Jamie E. ELSILA Mickey KOPSTEIN Joseph A. NUTH III 《Meteoritics & planetary science》2012,47(6):1029-1034
Abstract— Fischer‐Tropsch‐type (FTT) reactions have been hypothesized to contribute to the formation of organic compounds in the early solar system, but it has been difficult to identify a signature of such reactions in meteoritic organics. The work reported here examined whether temperature‐dependent carbon isotopic fractionation of FTT reactions might provide such a signature. Analyses of bulk organic deposits resulting from FTT experiments show a slight trend toward lighter carbon isotopic ratios with increasing temperature. It is unlikely, however, that these carbon isotopic signatures could provide definitive provenance for organic compounds in solar system materials produced through FTT reactions, because of the small scale of the observed fractionations and the possibility that signatures from many different temperatures may be present in any specific grain. 相似文献
83.
In arid environments, thermal oscillations are an important source of rock weathering. Measurements of temperature have been made on the surface of rocks in a desert environment at a sampling interval of 0·375 s, with simultaneous measurements of wind speed, air temperature, and incoming shortwave radiation. Over timescales of hours, the temperature of the rock surface was determined primarily by shortwave radiation and air temperature, while rapid temperature variations, high dT/dt, at intervals of seconds or less, were determined by wind speed. The maximum values of temperature change and time spent above 2°C min?1 increased at high measurement rates and were much higher than previously reported. The maximum recorded value of dT/dt was 137°C min?1 and the average percentage time spent above 2°C min?1 was ~70 ± 13%. Maximum values of dT/dt did not correlate with the maximum values of time spent above 2°C min?1. Simultaneous measurements of two thermocouples 5·5 cm apart on a single rock surface had similar temperature and dT/dt values, but were not correlated at sampling intervals of less than 10 s. It is suggested that this is resulting from rapid fluctuations due to small spatial and timescale wind effects that are averaged out when data is taken at longer sampling intervals, ~10 s or greater. Published in 2010 by John Wiley & Sons, Ltd. 相似文献
84.
85.
Jamie E. Elsila Daniel P. Glavin Jason P. Dworkin 《Meteoritics & planetary science》2009,44(9):1323-1330
Abstract— Our previous analysis of cometary samples returned to Earth by NASA's Stardust spacecraft showed several amines and amino acids, but the origin of these compounds could not be firmly established. Here, we present the stable carbon isotopic ratios of glycine and ε‐amino‐n‐caproic acid (EACA), the two most abundant amino acids identified in Stardust‐returned foil samples measured by gas chromatography‐mass spectrometry coupled with isotope ratio mass spectrometry. The δ13C value for glycine of +29 ± 6‰ strongly suggests an extraterrestrial origin for glycine, while the δ13C value for EACA of ?25 ± 2‰ indicates terrestrial contamination by Nylon‐6 during curation. This represents the first detection of a cometary amino acid. 相似文献
86.
Janet Frame is a New Zealand writer who was institutionalized for nearly nine years in mental illness hospitals. Her experiences have been fictionalized in her novel, Faces in the Water, and it is these novelistic representations of the asylum that we explore in this paper. As Frame has suggested in her second volume of autobiography, An Angel at My Table, there is a personal, geographic and linguistic exclusiveness to the asylum in that the patients are stripped of their identity and forced to conform. How these themes are developed in Faces in the Water will be the focus of this paper. 相似文献
87.
Intertidal animals and sediment from Kachemak Bay, Alaska were analysed to determine the concentrations of hydrocarbons. At Coal Point the herbivorous limpet Collisella pelta contained petroleum within its tissues while intertidal algae of the area have previously been shown to accumulate petroleum as a surface coating. At Coal Bay, a locality where both petroleum and coal are present, the filter feeding mussel Mytilus edulis contained petroleum hydrocarbons whereas the deposit feeding clam Macoma balthica contained an array of hydrocarbons suggesting detrital coal as the source. Animals higher in the food web including the gastropod Nucella lima and the urchin Strongylocentrotus droebachiensis showed no evidence of petroleum. All samples contained biogenic hydrocarbons of algal and planktonic origin. 相似文献
88.
Charles A. Brock Lawrence F. Radke Jamie H. Lyons Peter V. Hobbs 《Journal of Atmospheric Chemistry》1989,9(1-3):129-148
Airborne observations during August 1985 over Greenland and the North American Arctic revealed that dense, discrete haze layers were common above 850 mb. No such hazes were found near the surface in areas remote from local sources of particles. The haze layers aloft were characterized by large light-scattering coefficients due to dry particles (maximum value 1.24 × 10–4m–1) and relatively high total particle concentrations (maximum value 3100 cm–3). Sulfate was the dominant ionic component of the aerosol (0.06 – 1.9 g m–3); carbon soot was also present. Evidence for relatively fresh aerosols, accompanied by NO2 and O3 depletion, was found near, but not within, the haze layers. The hazes probably derived from anthropogenic sources and/or biomass burning at midlatitudes.It is hypothesized that the scavenging of particles by stratus clouds plays an important role in reducing the frequency and intensity of hazes at the surface in the Arctic in summer. Since the detection of haze layers aloft through measurements of column-integrated parameters from the surface (e.g., by lidar) cannot be carried out reliably when clouds are present, such measurements have likely underestimated the occurrence of haze layers in the Arctic, particularly in summer. 相似文献
89.
Heping Liu James T. Randerson Jamie Lindfors William J. Massman Thomas Foken 《Boundary-Layer Meteorology》2006,120(1):65-85
We present an approach for assessing the impact of systematic biases in measured energy fluxes on CO2 flux estimates obtained from open-path eddy-covariance systems. In our analysis, we present equations to analyse the propagation of errors through the Webb, Pearman, and Leuning (WPL) algorithm [Quart. J. Roy. Meteorol. Soc. 106, 85–100, 1980] that is widely used to account for density fluctuations on CO2 flux measurements. Our results suggest that incomplete energy balance closure does not necessarily lead to an underestimation of CO2 fluxes despite the existence of surface energy imbalance; either an overestimation or underestimation of CO2 fluxes is possible depending on local atmospheric conditions and measurement errors in the sensible heat, latent heat, and CO2 fluxes. We use open-path eddy-covariance fluxes measured over a black spruce forest in interior Alaska to explore several energy imbalance scenarios and their consequences for CO2 fluxes. 相似文献
90.
Chemical Separation and Isotopic Variations of Cu and Zn From Five Geological Reference Materials 总被引:6,自引:0,他引:6
John B. Chapman Thomas F.D. Mason Dominik J. Weiss Barry J. Coles Jamie J. Wilkinson 《Geostandards and Geoanalytical Research》2006,30(1):5-16
This paper presents an adapted anion exchange column chemistry protocol which allowed separation of high-purity fractions of Cu and Zn from geological materials. Isobaric and non-spectral interferences were virtually eliminated for consequent multiple-collector ICP-MS analysis of the isotopic composition of these metals. The procedure achieved ∼ 100% recoveries, thus ensuring the absence of column-induced isotopic fractionation. By employing these techniques, we report isotopic analyses for Cu and Zn from five geological reference materials: BCR-027 blende ore (BCR), δ65 Cu = 0.52 ± 0.15‰ (n = 10) and δ66 Zn = 0.33 ± 0.07‰ (n = 8); BCR-030 calcined calamine ore (BCR), δ66 Zn = -0.06 ± 0.09‰ (n = 8); BCR-1 basalt (USGS), δ66 Zn = 0.29 ± 0.12‰ (n = 8); NOD-P-1 manganese nodule (USGS), δ65 Cu = 0.46 ± 0.08‰ (n = 10) and δ66 Zn = 0.78 ± 0.09‰ (n = 9); SU-1 Cu-Co ore (CCRMP), δ65 Cu = -0.018 ± 0.08‰ (n = 10) and δ66 Zn = 0.13 ± 0.17‰ (n = 6). All uncertainties are ± 2s; copper isotope ratios are reported relative to NIST SRM-976, and zinc isotope ratios relative to the Lyon-group Johnson Matthey metal (batch 3-0749 L) solution, JMC Zn. These values agree well with the limited data previously published, and with results reported for similar natural sample types. Samples were measured using a GVi IsoProbe MC-ICP-MS, based at the Natural History Museum, London. Long-term measurement reproducibility has been assessed by repeat analyses of both single element and complex matrix samples, and was commonly better than ± 0.07‰ for both δ66 Zn and δ65 Cu. 相似文献