The thermal evolution of Mars as constrained by paleo-heat flows     

Javier Ruiz  Patrick J. McGovern  Valle López  Jean-Pierre Williams  Rosa Tejero 《Icarus》2011,215(2):508-517

Lithospheric strength can be used to estimate the heat flow at the time when a given region was deformed, allowing us to constrain the thermal evolution of a planetary body. In this sense, the high (>300 km) effective elastic thickness of the lithosphere deduced from the very limited deflection caused by the north polar cap of Mars indicates a low surface heat flow for this region at the present time, a finding difficult to reconcile with thermal history models. This has started a debate on the current heat flow of Mars and the implications for the thermal evolution of the planet. Here we perform refined estimates of paleo-heat flow for 22 martian regions of different periods and geological context, derived from the effective elastic thickness of the lithosphere or from faulting depth beneath large thrust faults, by considering regional radioactive element abundances and realistic thermal conductivities for the crust and mantle lithosphere. For the calculations based on the effective elastic thickness of the lithosphere we also consider the respective contributions of crust and mantle lithosphere to the total lithospheric strength. The obtained surface heat flows are in general lower than the equivalent radioactive heat production of Mars at the corresponding times, suggesting a limited contribution from secular cooling to the heat flow during the majority of the history of Mars. This is contrary to the predictions from the majority of thermal history models, but is consistent with evidence suggesting a currently fluid core, limited secular contraction for Mars, and recent extensive volcanism. Moreover, the interior of Mars could even have been heating up during part of the thermal history of the planet.  相似文献   

The combined inelastic neutron scattering and solid state DFT study of hydrogen atoms dynamics in a highly ordered kaolinite     

Ľubomír Smrčok  Daniel Tunega  Anibal Javier Ramirez-Cuesta  Eva Scholtzová 《Physics and Chemistry of Minerals》2010,37(8):571-579

The dynamics of the hydrogen atoms in the highly ordered kaolinite was studied by vibrational spectroscopy based on inelastic neutron scattering method with the focus on the spectral region of 100–1,250 cm⁻¹. The experimental spectrum was interpreted by means of the solid state density functional theory calculations covering both normal mode analysis and molecular dynamics going beyond the harmonic approximation. The Al–O–H bending modes were found to be spread over the large interval of 100–1,100 cm⁻¹, with the dominant contributions located between 800 and 1,100 cm^-1. The shapes of the individual hydrogen spectra depend on the strengths of the individual interlayer O–H···O hydrogen bonds involving the inner surface hydroxyl groups. The modes assigned to the in-plane movements of the respective hydrogen atoms are well-defined and always appear on the top of the intervals of energy transfer. In contrast, the modes generated by the out-of-plane movements are spread over large intervals of energies spanning down to the region of external (lattice) modes.  相似文献   

Metalliferous sediments from the H.M.S. Challenger voyage (1872-1876)     

Vesselin M. Dekov  Javier Cuadros  Dominik Weiss  Chandranath Basak 《Geochimica et cosmochimica acta》2010,74(17):5019-102

The legendary cruise of H.M.S. Challenger (1872-1876) around the globe must always occupy an eminent place in the annals of oceanography, as being the first systematic attempt made on a global scale to explore the ocean. This expedition made fundamental discoveries in biology and geology which have not been surpassed by any later scientific cruise. Sediment with high content of metals (later called “metalliferous”) was among the enigmatic findings taken onboard. Although the nature of metalliferous sediments is well known today, the very first sampled sediments of this type have not been studied to date. Motivated by the historical value of Challenger’s metalliferous sediment collection we undertook an investigation addressing two questions: (1) the composition of sediments from seafloor for which we have very limited data; (2) Sr-Nd-Pb-Fe-Zn-isotope signature of these sediments collected before the substantial human impact on the ocean during the 20th century.The SE Pacific metalliferous sediments sampled by the Challenger’s explorers are of 2 types: (1) metalliferous oozes blanketing ridge crests and flanks down to the calcite compensation depth (CCD); and (2) stripped of CaCO₃ metalliferous sediments located beneath the CCD in the deeps near the mid-ocean ridges. The abiogenic part of these sediments is composed mainly of poorly-crystalline to X-ray amorphous Fe-Mn-oxyhydroxides, and an amorphous silicate phase. These sediments have geochemical features similar to those of all the other metalliferous sediments: very high Fe and Mn content (on abiogenic basis), very low Al/(Al + Fe + Mn), and high content (on abiogenic basis) of As, Ba, Be, Bi, Cd, Co, Cu, Mo, Ni, Pb, Sb, Th, Tl, U, V, W, Y, Zn and Zr. Their REE distribution patterns are similar to that of deep seawater and show weak signs of hydrothermal imprint (weak positive or no Eu anomaly).Seawater and/or terrigenous input from South America control the Sr-Nd-Pb-isotope signature of the Challenger metalliferous sediments and have almost completely obliterated any original MORB-derived hydrothermal signal. Zn isotopes are mainly contributed from seawater although other Zn sources (hydrothermal fluid and detrital aluminosilicates, barite and volcanic glass) are necessary to fully explain Zn-isotope ratios. Fe isotopes indicate relatively slow Fe²⁺ to Fe³⁺ oxidation in the non-buoyant plume, thus producing relatively lighter Fe-isotope signature of the FeOOH particles that formed the studied metalliferous sediments.  相似文献   

Hydrogeochemistry of abandoned Pb sulphide mines: the mining district of La Carolina (southern Spain)   总被引：1，自引：0，他引：1  

M. Carmen Hidalgo  Javier Rey  José Benavente  Julián Martínez 《Environmental Earth Sciences》2010,61(1):37-46

The impact of past mining activities on the quality of groundwater and surface water has been investigated in the mining district of La Carolina (southern Spain, province of Jaén), a region characterised by the presence of mineralisations of Pb–Ag, Cu and Fe sulphides and Ba sulphates. The chemistry of waters from flooded galleries, shafts and drainage adits has been compared with that of surface waters in the same area. Generally, waters present neutral pH, since carbonates neutralise the acidity produced by the oxidation of Fe-bearing sulphide minerals in the mine impacted water. Despite of this natural attenuation process, in most of the cases, the mine groundwater is of low quality and shows high dissolved SO₄ (up to 3.7 g/l), Fe and Mn contents (tens to hundreds mg/l), exceeding the limit established by the guidelines of the World Health Organization for drinking water. Generally, the surface waters are of the sulphate calcium–magnesium to magnesium types, with moderate mineralisation. Post-rebound mine waters caused degradation of receiving watercourses in which the Fe contents are usually high, with values close to 3 g/l, and the mineralisation is greater as the channels run down in the mining zone. During dry seasons a considerable increase of salts and metals dissolved in stream waters was found, due to the decreasing contributions by run-off in this semiarid region, whereas the abandoned mine discharges remained practically constant.  相似文献