Byproduct Formation During the Reduction of TCE by Zero-Valence Iron and Palladized Iron   总被引：4，自引：0，他引：4  

Liyuan Liang  Nic Korte  J.D. Goodlaxson  Jay Clausen  Quintus Fernando  Rosy Muftikian 《Ground Water Monitoring & Remediation》1997,17(1):122-127

Trichloroethene (TCE) was reduced with zero-valence iron and palladized iron in zero-head-space extractors. Progress of the reaction in these batch studies was monitored with purge-and-trap gas chromatography and a flame ionization detector. When a 5 ppm initial concentration of TCF. reacts with zero-valence iron, approximately 140 ppb of vinyl chloride persists for as long as 73 days. The concentration of vinyl chloride (approximately If) ppb) remaining with palladized iron is approximately an order of magnitude less than when zero-valence iron is the reductant. These data suggest that volatile byproducts may be under-represented in oilier published data regarding reduction with zero-valence metals. These results also demonstrate that the reduction of TCE with palladized iron (0.05 percent palladium) is more than an order of magnitude faster than with zero-valence iron. Wilh a 5:1 solution-to-solid ratio the TCE half-life with zero-valence iron is 7.41 hours. but is only 0.59 hours with the palladized iron.  相似文献   

An attenuation model for distant earthquakes     

Adrian Chandler  Nelson Lam 《地震工程与结构动力学》2004,33(2):183-210

Large magnitude earthquakes generated at source–site distances exceeding 100km are typified by low‐frequency (long‐period) seismic waves. Such induced ground shaking can be disproportionately destructive due to its high displacement, and possibly high velocity, shaking characteristics. Distant earthquakes represent a potentially significant safety hazard in certain low and moderate seismic regions where seismic activity is governed by major distant sources as opposed to nearby (regional) background sources. Examples are parts of the Indian sub‐continent, Eastern China and Indo‐China. The majority of ground motion attenuation relationships currently available for applications in active seismic regions may not be suitable for handling long‐distance attenuation, since the significance of distant earthquakes is mainly confined to certain low to moderate seismicity regions. Thus, the effects of distant earthquakes are often not accurately represented by conventional empirical models which were typically developed from curve‐fitting earthquake strong‐motion data from active seismic regions. Numerous well‐known existing attenuation relationships are evaluated in this paper, to highlight their limitations in long‐distance applications. In contrast, basic seismological parameters such as the Quality factor (Q‐factor) could provide a far more accurate representation for the distant attenuation behaviour of a region, but such information is seldom used by engineers in any direct manner. The aim of this paper is to develop a set of relationships that provide a convenient link between the seismological Q‐factor (amongst other factors) and response spectrum attenuation. The use of Q as an input parameter to the proposed model enables valuable local seismological information to be incorporated directly into response spectrum predictions. The application of this new modelling approach is demonstrated by examples based on the Chi‐Chi earthquake (Taiwan and South China), Gujarat earthquake (Northwest India), Nisqually earthquake (region surrounding Seattle) and Sumatran‐fault earthquake (recorded in Singapore). Field recordings have been obtained from these events for comparison with the proposed model. The accuracy of the stochastic simulations and the regression analysis have been confirmed by comparisons between the model calculations and the actual field observations. It is emphasized that obtaining representative estimates for Q for input into the model is equally important.Thus, this paper forms part of the long‐term objective of the authors to develop more effective communications across the engineering and seismological disciplines. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

The causes and environmental effects of land use conversion during agricultural restructuring in Northeast China     

LIU Yansui  GAN Hong  Jay GAO  DENG Xusheng 《地理学报》2004,14(4):488-494

During the last decade of the 20th century, extensive conversion in agricultural land use took place in Northeast China. The goal of this study is to ascertain its spatial distribution and regional differentiation, determine its causes, and analyze its environmental impact. Especially we attempt to elucidate how institutional constraints have facilitated the change at a time of agrarian restructuring when newly emerging free market was hybridized with the former planned economy. Information on six categories of land use was mapped from interpretation of Landsat TM images recorded in 1990, 1995 and 2000. Most of land use changes took place during the first half of the decade, coinciding with abrupt and chaotic changes in government directives. Farmland was changed mainly to woodland, water body and built-up areas while woodland and grassland were converted chiefly to farmland. Spatially, the change from farmland to woodland was restricted to the west of the study area. The change from grassland to farmland took place in the grazing and farming interlocked west. These chaotic and occasionally conflicting changes were largely caused by lack of stability and consistency in agricultural land use policies promulgated. They have exerted adverse impacts on the local environment, including land degradation, increased flooding, and modified climate regime.  相似文献   

Grassland productivity in an alpine environment in response to climate change   总被引：1，自引：0，他引：1  

Yong Zha  Jay Gao  Ying Zhang 《Area》2005,37(3):332-340

Situated in a climatically stressful environment, alpine grassland is sensitive to subtle climate changes in its productivity. We remedy the current deficiency in studying grassland productivity by taking the integrated effect of all relevant factors into consideration. The relative importance of temperature, rainfall and evaporation to the alpine grassland productivity in western China was determined through analysis of their relationship with the normalized difference vegetation index (NDVI) between 1981 and 2000. Climate warming stimulated grassland productivity in the 1980s, but hampered it in the 1990s. Temperature is more important than rainfall to grassland productivity early in the growing season. However, their relative importance is reversed late in the growing season. Monthly summer month rainfall modified by maximum monthly temperature is a good predictor of alpine grassland productivity at 62.0 per cent. However, the best predictor is water deficiency, which is able to improve the estimation accuracy to 78.3 per cent. Hence, the impact of temperature on grassland productivity is better studied indirectly through evaporation.  相似文献   

Isotopic variability in the aragonite shells of freshwater gastropods living in springs with nearly constant temperature and isotopic composition     

Timothy M. Shanahan  Jeffrey S. Pigati  David L. Dettman  Jay Quade 《Geochimica et cosmochimica acta》2005,69(16):3949-3966

We conducted a year-long, intensive monitoring program of live aquatic gastropods (Helisoma duryi, Melanoides tuberculata, Physa virgata, Pyrgulopsis sp., and Tyronia sp.) and their host springs in the Ash Meadows National Wildlife Refuge of southern Nevada. Our purpose was to constrain the degree of natural variation in the isotopic values of shell aragonite for gastropods living in near-constant conditions. Inter- and intraspecies variations, as well as within-shell variations, of δ¹⁸O and δ¹³C values for all taxa were larger than predicted based on variations in environmental conditions alone. This result suggests that different organisms growing in identical or nearly identical environmental conditions may not produce shells with equilibrium isotopic compositions and that these offsets from equilibrium may differ by small, but statistically significant amounts. For the gill-breathing, fully aquatic gastropods M. tuberculata, Pyrgulopsis sp., and Tyronia sp., the deviation of measured isotopic values compared to predicted values based on average environmental conditions were consistent with differences between taxa in the seasonal timing of shell growth. Measured values for the lung-breathing gastropods H. duryi and P. virgata were higher for δ¹⁸O and lower for δ¹³C than predicted at isotopic equilibrium, even when accounting for seasonality effects. We suggest that explaining the differences between the shell isotopic composition of lung- and gill-breathing snails requires a combination of both behavioral and physiologic factors. Our results illustrate the potential complexities of interpreting stable isotopic data from fossil gastropod shells even when environmental conditions are nearly constant, and place limitations on the paleoenvironmental deductions that can be made from the isotopic measurements on fossil gastropods.  相似文献   

Importance of mixotrophic nanoplankton in Aysén Fjord (Southern Chile) during austral winter     

Till Czypionka  Cristian A. Vargas  Nelson Silva  Giovanni Daneri  Humberto E. González  José Luis Iriarte 《Continental Shelf Research》2011,31(3-4):216-224

Mixotrophy, the combination of autotrophic and heterotrophic nutrition in the same organism, is widespread in planktonic algae. Several reports from temperate and high-latitude fjords in Scandinavia suggest the occurrence of a niche in late summer and autumn during post-bloom conditions in which mixotrophic algae can become important grazers in pelagic ecosystems, accessing the nutrients bound in their prey to overcome nutrient limitation. Here, we experimentally determined the trophic modes and bacterivory rates for the nanoplankton community (2–20 μm) in Aysén Fjord located in the Chilean Northern Patagonia during two contrasting seasons: winter and spring. While mixotrophic nanoplankton was virtually absent from the system in spring, in winter at occasions it even constituted the dominant trophic group of the nanoplankton with abundances of >900 cells mL^?1. This indicates a second niche for mixotrophs in winter, when mixotrophy allows overcoming light limitation.  相似文献   

Population structure of two deep sea tubeworms,Lamellibrachia luymesi and Seepiophila jonesi,from the hydrocarbon seeps of the Gulf of Mexico     

Erin R. McMullin  Kimberlyn Nelson  Charles R. Fisher  Stephen W. Schaeffer 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(11):1499-1509

Vestimentiferan tubeworms are a group of large sessile marine polychaete annelids (family Siboglinidae) found in the regions of hydrothermal venting or seepage of the reduced chemical hydrogen sulfide. Hydrocarbon seeps on the Louisiana Slope of the Gulf of Mexico support large communities of the co-occurring vestimentiferan species Lamellibrachia luymesi and Seepiophila jonesi. These sessile species have the opportunity to disperse between the patchy sites of active seepage on the seafloor during a planktonic larval stage. However, it is unclear whether dispersal occurs at a local or global scale. Four (L. luymesi) and seven (S. jonesi) microsatellite loci were used to test for population substructure among ten hydrocarbon seep sites on the Louisiana Slope. Both species showed high levels of allelic diversity, averaging 18.5 (L. luymesi) and 22 (S. jonesi) alleles/locus, respectively, and high observed heterozygosity at all microsatellite loci (0.71–0.9 in L. luymesi, 0.27–0.84 in S. jonesi). The two species showed a significant deficiency in heterozygotes compared to that predicted under the Hardy–Weinberg equilibrium. L. luymesi showed a small but significant amount of population structure, with a positive correlation between genetic and geographic distance among the sample sites spanning 540 km. S. jonesi, in contrast, showed no evidence for isolation by distance, but did show a significant genetic difference between aggregations of different ages. These results suggest that these two species differ in how larvae are able to colonize new seep sites through space (L. luymesi) and though time (S. jonesi).  相似文献   

Estimating Pile Set-up Using 24-h Restrike Resistance and Computed Static Capacity for PPC Piles Driven in Soft Lousiana Coastal Deposits   总被引：1，自引：0，他引：1  

Jay X. Wang  Neha Verma  Eric J. Steward 《Geotechnical and Geological Engineering》2016,34(1):267-283

In this paper, the CPT-based predicted ultimate pile resistances (R_p) were compared with the measured pile resistances (R_m) at different elapsed time for the piles driven into saturated soft clays where piles displayed significant set-up effect. The measured pile resistances were based on 115 restrike records collected from 95 production piles, and 74 records of 9 tested piles. The predicted ultimate pile resistances were calculated from the LCPC, the Schmertmann, and the de Ruiter–Beringen methods, respectively. With the significant pile set-up effect taken into account, the relationship between measured resistances and predicted capacities at different times after pile installation were investigated. The ratios of the measured pile resistances to the predicted capacities scattered in a large spectrum. The ratios fluctuated and stayed within a range of 0.6–1.6 for different CPT methods since end of initial driving until more than 2 months after pile installation. Plots of the ratios versus the predicted pile capacities using different CPT methods have revealed that the ratio (R_m/R_p) presented a strong dependence on the predicted capacities. Great research efforts have been devoted to the analyses of the ratios of the 24-h measured resistance to the predicted capacity based on different CPT methods, in an attempt to find a feasible empirical correlation. It is found that a simple linear relationship exists between the quad root of the ratio and the predicted capacity. The developed empirical equations will give pile foundation engineers an insight into the ultimate resistances of driven piles demonstrating significant pile set-up effects. Pile set-up makes pile resistances grow with time, and it might be one of the reasons that cause the frequently reported large discrepancy between calculated static capacity and measured resistance at a certain time after pile installation.  相似文献   

Assessing shallow landslide hazards using the TRIGRS and SHALSTAB models,Serra do Mar,Brazil     

Bianca Carvalho Vieira  Nelson Ferreira Fernandes  Oswaldo Augusto Filho  Tiago Damas Martins  David R. Montgomery 《Environmental Earth Sciences》2018,77(6):260

The hillslopes of the Serra do Mar, a system of escarpments and mountains that extend more than 1500 km along the southern and southeastern Brazilian coast, are regularly affected by heavy rainfall that generates widespread mass movements, causing large numbers of casualties and economic losses. This paper evaluates the efficiency of susceptibility mapping for shallow translational landslides in one basin in the Serra do Mar, using the physically based landslide susceptibility models SHALSTAB and TRIGRS. Two groups of scenarios were simulated using different geotechnical and hydrological soil parameters, and for each group of scenarios (A and B), three subgroups were created using soil thickness values of 1, 2, and 3 m. Simulation results were compared to the locations of 356 landslide scars from the 1985 event. The susceptibility maps for scenarios A1, A2, and A3 were similar between the models regarding the spatial distribution of susceptibility classes. Changes in soil cohesion and specific weight parameters caused changes in the area of predicted instability in the B scenarios. Both models were effective in predicting areas susceptible to shallow landslides through comparison of areas predicted to be unstable and locations of mapped landslides. Such models can be used to reduce costs or to define potentially unstable areas in regions like the Serra do Mar where field data are costly and difficult to obtain.  相似文献   

Experimental study of quartz inclusions in garnet at pressures up to 3.0 GPa: evaluating validity of the quartz-in-garnet inclusion elastic thermobarometer     

Jay?B.?ThomasEmail authorView author&#;s OrcID profile  Frank?S.?Spear 《Contributions to Mineralogy and Petrology》2018,173(5):42

Garnet crystals with quartz inclusions were hydrothermally crystallized from oxide starting materials in piston–cylinder apparatuses at pressures from 0.5 to 3 GPa and temperatures ranging from 700 to 800 °C to study how entrapment conditions affect remnant pressures of quartz inclusions used for quartz-in-garnet (QuiG) elastic thermobarometry. Systematic changes of the 128, 206 and 464 cm^?1 Raman band frequencies of quartz were used to determine pressures of quartz inclusions in garnet using Raman spectroscopy calibrations that describe the P–T dependencies of Raman band shifts for quartz under hydrostatic pressure. Within analytical uncertainties, inclusion pressures calculated for each of the three Raman band frequencies are equivalent, which suggests that non-hydrostatic stress effects caused by elastic anisotropy in quartz are smaller than measurement errors. The experimental quartz inclusions have pressures ranging from ??0.351 to 1.247 GPa that span the range of values observed for quartz inclusions in garnets from natural rocks. Quartz inclusion pressures were used to model P–T conditions at which the inclusions could have been trapped. The accuracy of QuiG thermobarometry was evaluated by considering the differences between pressures measured during experiments and pressures calculated using published equation of state parameters for quartz and garnet. Our experimental results demonstrate that Raman measurements performed at room temperature can be used without corrections to estimate garnet crystallization pressures. Calculated entrapment pressures for quartz inclusions in garnet are less than ~?10% different from pressures measured during the experiments. Because the method is simple to apply with reasonable accuracy, we expect widespread usage of QuiG thermobarometry to estimate crystallization conditions for garnet-bearing silicic rocks.  相似文献