A composite Fe,Ni‐FeS and enstatite‐forsterite‐diopside‐glass vitrophyre clast in the Larkman Nunatak 04316 aubrite: Origin by pyroclastic volcanism     

Klaus KEIL  Timothy J. McCOY  Lionel WILSON  Jean‐Alix BARRAT  Doug RUMBLE  Matthias M. M. MEIER  Rainer WIELER  Gary R. HUSS 《Meteoritics & planetary science》2011,46(11):1719-1741

Abstract– We studied the mineralogy, petrology, and bulk, trace element, oxygen, and noble gas isotopic compositions of a composite clast approximately 20 mm in diameter discovered in the Larkman Nunatak (LAR) 04316 aubrite regolith breccia. The clast consists of two lithologies: One is a quench‐textured intergrowth of troilite with spottily zoned metallic Fe,Ni which forms a dendritic or cellular structure. The approximately 30 μm spacings between the Fe,Ni arms yield an estimated cooling rate of this lithology of approximately 25–30 °C s^?1. The other is a quench‐textured enstatite‐forsterite‐diopside‐glass vitrophyre lithology. The composition of the clast suggests that it formed at an exceptionally high degree of partial melting, perhaps approaching complete melting, and that the melts from which the composite clast crystallized were quenched from a temperature of approximately 1380–1400 °C at a rate of approximately 25–30 °C s^?1. The association of the two lithologies in a composite clast allows, for the first time, an estimation of the cooling rate of a silicate vitrophyre in an aubrite of approximately 25–30 °C s^?1. While we cannot completely rule out an impact origin of the clast, we present what we consider is very strong evidence that this composite clast is one of the elusive pyroclasts produced during pyroclastic volcanism on the aubrite parent body ( Wilson and Keil 1991 ). We further suggest that this clast was not ejected into space but retained on the aubrite parent body by virtue of the relatively large size of the clast of approximately 20 mm. Our modeling, taking into account the size of the clast, suggests that the aubrite parent body must have been between approximately 40 and 100 km in diameter, and that the melt from which the clast crystallized must have contained an estimated maximum range of allowed volatile mass fractions between approximately 500 and approximately 4500 ppm.  相似文献   

A chemostratigraphic method to determine the end of impact‐related sedimentation at marine‐target impact craters (Chesapeake Bay,Lockne, Tvären)     

Jens ORMÖ  Andrew C. HILL  Jean M. SELF‐TRAIL 《Meteoritics & planetary science》2010,45(7):1206-1224

Abstract– To better understand the impact cratering process and its environmental consequences at the local to global scale, it is important to know when in the geological record of an impact crater the impact‐related processes cease. In many instances, this occurs with the end of early crater modification, leaving an obvious sedimentological boundary between impactites and secular sediments. However, in marine‐target craters the transition from early crater collapse (i.e., water resurge) to postimpact sedimentation can appear gradual. With the a priori assumption that the reworked target materials of the resurge deposits have a different chemical composition to the secular sediments we use chemostratigraphy (δ¹³C_carb, %C_org, major elements) of sediments from the Chesapeake Bay, Lockne, and Tvären craters, to define this boundary. We show that the end of impact‐related sedimentation in these cases is fairly rapid, and does not necessarily coincide with a visual boundary (e.g., grain size shift). Therefore, in some cases, the boundary is more precisely determined by chemostratigraphy, especially carbonate carbon isotope variations, rather than by visual inspection. It is also shown how chemostratigraphy can confirm the age of marine‐target craters that were previously determined by biostratigraphy; by comparing postimpact carbon isotope trends with established regional trends.  相似文献   

Oxygen and carbon isotope ratios in the martian atmosphere     

Vladimir A. Krasnopolsky  Jean Pierre Maillard  Tobias C. Owen  Robert A. Toth  Michael D. Smith 《Icarus》2007,192(2):396-403

Oxygen and carbon isotope ratios in the martian CO₂ are key values to study evolution of volatiles on Mars. The major problems in spectroscopic determinations of these ratios on Mars are uncertainties associated with: (1) equivalent widths of the observed absorption lines, (2) line strengths in spectroscopic databases, and (3) thermal structure of the martian atmosphere during the observation. We have made special efforts to reduce all these uncertainties. We observed Mars using the Fourier Transform Spectrometer at the Canada–France–Hawaii Telescope. While the oxygen and carbon isotope ratios on Mars were byproducts in the previous observations, our observation was specifically aimed at these isotope ratios. We covered a range of 6022 to 6308 cm⁻¹ with the highest resolving power of ν/δν=3.5×10⁵ and a signal-to-noise ratio of 180 in the middle of the spectrum. The chosen spectral range involves 475 lines of the main isotope, 184 lines of ¹³CO₂, 181 lines of CO¹⁸O, and 119 lines of CO¹⁷O. (Lines with strengths exceeding 10⁻²⁷ cm at 218 K are considered here.) Due to the high spectral resolution, most of the lines are not blended. Uncertainties of retrieved isotope abundances are in inverse proportion to resolving power, signal-to-noise ratio, and square root of the number of lines. Laboratory studies of the CO₂ isotope spectra in the range of our observation achieved an accuracy of 1% in the line strengths. Detailed observations of temperature profiles using MGS/TES and data on temperature variations with local time from two GCMs are used to simulate each absorption line at various heights in each part of the instrument field of view and then sum up the results. Thermal radiation of Mars' surface and atmosphere is negligible in the chosen spectral range, and this reduces errors associated with uncertainties in the thermal structure on Mars. Using a combination of all these factors, the highest accuracy has been achieved in measuring the CO₂ isotope ratios: ¹³C/¹²C = 0.978 ± 0.020 and ¹⁸O/¹⁶O = 1.018 ± 0.018 times the terrestrial standards. Heavy isotopes in the atmosphere are enriched by nonthermal escape and sputtering, and depleted by fractionation with solid-phase reservoirs. The retrieved ratios show that isotope fractionation between CO₂ and oxygen and carbon reservoirs in the solid phase is almost balanced by nonthermal escape and sputtering of O and C from Mars.  相似文献   

Melt extraction and melt refertilization in mantle peridotite of the Coast Range ophiolite: an LA–ICP–MS study     

Marlon M. Jean  John W. Shervais  Sung-Hi Choi  Samuel B. Mukasa 《Contributions to Mineralogy and Petrology》2010,159(1):113-136

The middle Jurassic Coast Range Ophiolite (CRO) is one of the most important tectonic elements in western California, cropping out as tectonically dismembered elements that extend 700 km from south to north. The volcanic and plutonic sections are commonly interpreted to represent a supra-subduction zone (SSZ) ophiolite, but models specifying a mid-ocean ridge origin have also been proposed. These contrasting interpretations have distinctly different implications for the tectonic evolution of the western Cordillera in the Jurassic. If an SSZ origin is confirmed, we can use the underlying mantle peridotites to elucidate melt processes in the mantle wedge above the subduction zone. This study uses laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) to study pyroxenes in peridotites from four mantle sections in the CRO. Trace element signatures of these pyroxenes record magmatic processes characteristic of both mid-ocean ridge and supra-subduction zone settings. Group A clinopyroxene display enriched REE concentrations [e.g., Gd (0.938–1.663 ppm), Dy (1.79–3.24 ppm), Yb (1.216–2.047 ppm), and Lu (0.168–0.290 ppm)], compared to Group B and C clinopyroxenes [e.g., Gd (0.048–0.055 ppm), Dy (0.114–0.225 ppm), Yb (0.128–0.340 ppm), and Lu (0.022–0.05 ppm)]. These patterns are also evident in orthopyroxene. The differences between these geochemical signatures could be a result of a heterogeneous upper mantle or different degrees of partial melting of the upper mantle. It will be shown that CRO peridotites were generated through fractional melting. The shapes of REE patterns are consistent with variable degrees of melting initiated within the garnet stability field. Models call for 3% dry partial melting of MORB-source asthenosphere in the garnet lherzolite field for abyssal peridotites and 15–20% further partial melting in the spinel lherzolite field, possibly by hydrous melting for SSZ peridotites. These geochemical variations and occurrence of both styles of melting regimes within close spatial and temporal association suggest that certain segments of the CRO may represent oceanic lithosphere, attached to a large-offset transform fault and that east-dipping, proto-Franciscan subduction may have been initiated along this transform.  相似文献   

The accumulation of Stone Age lithic artifacts in rock fragment mulches in northern Ethiopia     

Raf Aerts  Niall Finneran  Mitiku Haile  Jean Poesen 《Geoarchaeology》2010,25(1):137-148

Lithic artifacts buried in the soil profile may be transported to the surface during tillage‐induced kinetic sieving, differential erosion, or swell–shrink cycles of clays and become part of a rock fragment mulch. Archaeologically, these manifestations are recognized as surface scatters. Although artifacts at the soil surface are difficult to relate to the local stratigraphic context, surface assemblages may provide information on lithic industries and the archaeological significance of sparsely explored regions. Through in situ investigation of surface material in 60 1 × 1 m² plots in the Tembien district in the northern Ethiopian highlands, we show that rock fragment mulches can contain a significant number of lithic artifacts and we provide evidence for mid‐Pleistocene occupation of a site. Considering that severe rill and gully erosion may be a threat to the archaeological heritage and that well‐dated African Middle Stone Age sites are rare, we conclude that the region deserves more attention for archaeological research. © 2009 Wiley Periodicals, Inc.  相似文献   

Deep reflection seismic imaging of the internal zone of the South Armorican Hercynian belt (western France) (ARMOR 2/Géofrance 3D Program)     

Adnand Bitri  Jean-Pierre Brun  Denis Gapais  Florence Cagnard  Charles Gumiaux  Jean Chantraine  Guillaume Martelet  Catherine Truffert 《Comptes Rendus Geoscience》2010,342(6):448-452

We present results and interpretation of a 72 km long deep seismic reflection profile acquired across the internal zone of the Hercynian belt of South Brittany. The profile is of excellent quality, most of the crust being highly reflective. The “ARMOR 2 South” profile, is correlated with the “ARMOR 2 North” profile that was published in 2003. Correlation of the main subsurface reflections with surface geological and structural data provides important information about the crustal structure that resulted from thickening during Late Devonian and regional-scale extension during Late Carboniferous. In particular, seismics image shows a very high reflectivity zone, lying flat over more than 40 km at about 10–12 km depth. This zone is interpreted as a major zone of ductile crustal thinning.  相似文献   

Définition et datation de la Formation de Venaco (Corse) : dépôt d’origine gravitaire d’âge Priabonien     

Jean Ferrandini  Michelle Ferrandini  Philippe Rossi  Brengre Savary-Sismondini 《Comptes Rendus Geoscience》2010,342(12):921-929

Priabonian age is highlighted for the first time in Corsica in the Venaco Formation using the presence of specific microfauna (in particular some representatives of Turborotalia cerroazulensis lineage). This silicoclastic formation is mainly represented by coarse facies. It is composed of three members from south to north and from oldest towards youngest: member of Uboli, Cardo and Orsu. The sedimentologic analysis reveals a gravity depositional environment, involving different type of currents. Sedimentologic and chronologic characteristics make the Venaco Formation and the Annot Formation (p.p.) equivalent. Dating the Venaco Fm. brings confirmation that the green schist metamorphism of the Variscan batholith and the related deformation are from the pre-Priabonian period.  相似文献   

Fracture roughness and thermal exchange: A case study at Soultz-sous-Forêts     

Amélie Neuville  Renaud Toussaint  Jean Schmittbuhl 《Comptes Rendus Geoscience》2010,342(7-8):616-625

Heat exchange during laminar flow in an open fracture is studied numerically on the basis of the Stokes equation in the limit of hydrothermal lubrication. We examine the influence of fracture roughness on hydraulic permeability and heat flux through the fracture sides when a cold fluid is injected into a homogeneous hot host rock. Spatial temperature fluctuations inside the fluid are studied assuming the temperature of the rock to be constant and the fracture aperture to be self-affine. An application to the case study at the deep geothermal reservoir of Soultz-sous-Forêts, France, is presented. Finally, a thermal model based on sparse spatial information of the geometrical aperture is successfully proposed to reproduce the response of the fracture.  相似文献   

Trophic ecology of Pomatoschistus microps within an intertidal bay (Roscoff,France), investigated through gut content and stable isotope analyses     

Jean‐Charles Leclerc  Pascal Riera  Laure M.‐L. J. Noël  Cédric Leroux  Ann C. Andersen 《Marine Ecology》2014,35(2):261-270

The diet of Pomatoschistus microps has been studied using both gut content and stable isotope analyses. In the Roscoff Aber Bay (Brittany, France), this fish is commonly found on sandy muddy intertidal flats. Gut content analyses were also interpreted using trophic indices. Owing to the large diversity of prey consumed, these indices emphasised the opportunistic feeding behaviour of P. microps. Here, this species fed mainly on endofauna with meiofauna being of high relative importance. The main biotic components of its trophic habitat, characterized by δ¹³C and δ¹⁵N, provided evidence of a major trophic pathway based on drift Enteromorpha sp. Trophic positions estimated by both diet analyses and isotopic analyses led to similar results. In this bay, P. microps is a first‐order predator with a low degree of omnivory. Despite a preferential consumption of the amphipod Corophium arenarium, we assumed that this goby behaves as a generalist feeding on a uniform variety of endofauna taxa.  相似文献   

Authigenic carbonates related to active seepage of methane-rich hot brines at the Cheops mud volcano,Menes caldera (Nile deep-sea fan,eastern Mediterranean Sea)   总被引：1，自引：0，他引：1  

Catherine Pierre  Germain Bayon  Marie-Madeleine Blanc-Valleron  Jean Mascle  Stéphanie Dupré 《Geo-Marine Letters》2014,34(2-3):253-267

On the passive margin of the Nile deep-sea fan, the active Cheops mud volcano (MV; ca. 1,500 m diameter, ~20–30 m above seafloor, 3,010–3,020 m water depth) comprises a crater lake with hot (up to ca. 42 °C) methane-rich muddy brines in places overflowing down the MV flanks. During the Medeco2 cruise in fall 2007, ROV dives enabled detailed sampling of the brine fluid, bottom lake sediments at ca. 450 m lake depth, sub-surface sediments from the MV flanks, and carbonate crusts at the MV foot. Based on mineralogical, elemental and stable isotope analyses, this study aims at exploring the origin of the brine fluid and the key biogeochemical processes controlling the formation of these deep-sea authigenic carbonates. In addition to their patchy occurrence in crusts outcropping at the seafloor, authigenic carbonates occur as small concretions disseminated within sub-seafloor sediments, as well as in the bottom sediments and muddy brine of the crater lake. Aragonite and Mg-calcite dominate in the carbonate crusts and in sub-seafloor concretions at the MV foot, whereas Mg-calcite, dolomite and ankerite dominate in the muddy brine lake and in sub-seafloor concretions near the crater rim. The carbonate crusts and sub-seafloor concretions at the MV foot precipitated in isotopic equilibrium with bottom seawater temperature; their low δ¹³C values (–42.6 to –24.5‰) indicate that anaerobic oxidation of methane was the main driver of carbonate precipitation. By contrast, carbonates from the muddy lake brine, bottom lake concretions and crater rim concretions display much higher δ¹³C (up to –5.2‰) and low δ¹⁸O values (down to –2.8‰); this is consistent with their formation in warm fluids of deep origin characterized by ¹³C-rich CO₂ and, as confirmed by independent evidence, slightly higher heavy rare earth element signatures, the main driver of carbonate precipitation being methanogenesis. Moreover, the benthic activity within the seafloor sediment enhances aerobic oxidation of methane and of sulphide that promotes carbonate dissolution and gypsum precipitation. These findings imply that the coupling of carbon and sulphur microbial reactions represents the major link for the transfer of elements and for carbon isotope fractionation between fluids and authigenic minerals. A new challenge awaiting future studies in cold seep environments is to expand this work to oxidized and reduced sulphur authigenic minerals.  相似文献