Radiometric evidence for an Acadian tectonometamorphic event in Western Massif Central Français     

Jean Bernard-Griffiths  Jean-Marie Cantagrel  Jean-Louis Duthou 《Contributions to Mineralogy and Petrology》1977,61(2):199-212

Systematic Rb-Sr determinations on granites and orthogneisses in the Western part of Massif Central Français (Limousin) permit us to say that metamorphism and associated folding occured in this area during the Devonian (between 400 and 350 m.y.) with anatexis stated at 360 m.y. Two premetamorphic magmatic episodes are located in the upper Cambrian-early Ordovician (520-490 m.y.) and in the Ordovician (460-450 m.y.). This should be compared with very similar radiometric results from Rouergue to South Brittany; thus a South Brittany-Limousin-Rouergue axis may be easily related to the acadian part from Appalachian belt.  相似文献   

Long-term thermal evolution and effect of low power heating in an underground quarry     

Catherine Crouzeix  Jean-Louis Le Mouël  Frédéric Perrier  Patrick Richon  Pierre Morat 《Comptes Rendus Geoscience》2003,335(4):345-354

Vertical profiles of temperature have been monitored in the atmosphere of an underground quarry since June 2001. A long-term temperature increase of the order of 0.1 °C per year is observed. Three heating experiments with 100-W sources, performed to study plume dynamics, can also be used to investigate the effect of visits on this increase. Ten days after the 24-h heatings, the initial state is not restored. Artificial contributions to the observed long-term temperature trend, triggered by internal heat release, thus cannot be ruled out. This experiment defines strict criteria for the underground monitoring of global warming or the preservation of painted caves. To cite this article: C. Crouzeix et al., C. R. Geoscience 335 (2003).  相似文献   

Quantitative Zn speciation in a contaminated dredged sediment by μ-PIXE, μ-SXRF, EXAFS spectroscopy and principal component analysis     

Marie-Pierre Isaure  Agnès LaboudigueAlain Manceau  Géraldine SarretChristophe Tiffreau  Patrick TrocellierGéraldine Lamble  Jean-Louis HazemannDaniel Chateigner 《Geochimica et cosmochimica acta》2002,66(9):1549-1567

Dredging and disposal of sediments onto agricultural soils is a common practice in industrial and urban areas that can be hazardous to the environment when the sediments contain heavy metals. This chemical hazard can be assessed by evaluating the mobility and speciation of metals after sediment deposition. In this study, the speciation of Zn in the coarse (500 to 2000 μm) and fine (<2 μm) fractions of a contaminated sediment dredged from a ship canal in northern France and deposited on an agricultural soil was determined by physical analytical techniques on raw and chemically treated samples. Zn partitioning between coexisting mineral phases and its chemical associations were first determined by micro-particle-induced X-ray emission and micro-synchrotron-based X-ray radiation fluorescence. Zn-containing mineral species were then identified by X-ray diffraction and powder and polarized extended X-ray absorption fine structure spectroscopy (EXAFS). The number, nature, and proportion of Zn species were obtained by a coupled principal component analysis (PCA) and least squares fitting (LSF) procedure, applied herein for the first time to qualitatively (number and nature of species) and quantitatively (relative proportion of species) speciate a metal in a natural system.The coarse fraction consists of slag grains originating from nearby Zn smelters. In this fraction, Zn is primarily present as sphalerite (ZnS) and to a lesser extent as willemite (Zn₂SiO₄), Zn-containing ferric (oxyhydr)oxides, and zincite (ZnO). In the fine fraction, ZnS and Zn-containing Fe (oxyhydr)oxides are the major forms, and Zn-containing phyllosilicate is the minor species. Weathering of ZnS, Zn₂SiO₄, and ZnO under oxidizing conditions after the sediment disposal accounts for the uptake of Zn by Fe (oxyhydr)oxides and phyllosilicates. Two geochemical processes can explain the retention of Zn by secondary minerals: uptake on preexisting minerals and precipitation with dissolved Fe and Si. The second process likely occurs because dissolved Zn and Si are supersaturated with respect to Zn phyllosilicate. EXAFS spectroscopy, in combination with PCA and LSF, is shown to be a meaningful approach to quantitatively determining the speciation of trace elements in sediments and soils.  相似文献   

Apport de la modélisation géophysique pour la compréhension de la structuration du pas de Calais     

Bruno Minguely  Jean-Louis Mansy  Michel Everaerts  Geoffrey M. Manby  Olivier Averbuch 《Comptes Rendus Geoscience》2005,337(3):305-313

This study is based on an analysis of seismic, gravimetric and magnetic data to model the structure of the Dover Straits area. The Dover Straits are set in a transitional position within the Brabant para-autochthon, which lies between the Ardennes allochthon to the south and the Brabant Massif to the north. The seismic profiles show that this area is characterised by several superimposed Mesozoic basins, whose evolution has been controlled by the reactivation of Lower Palaeozoic faults. In common with the adjacent Weald–Wessex and southern North Sea basins, the Dover Straits area records a Jurassic extensional phase and a post-Cretaceous tectonic inversion. The geophysical modelling reveals the presence of a basement to these Mesozoic basins that exhibits Ordovician to Silurian structures, which cannot be detected on the seismic reflection profiles. In contrast to earlier interpretations, the modelling presented here suggests that the Brabant Massif continues southward beyond the Dover Straits and under the Brabant para-autochthon. Gravity data also provides evidence for the presence of granitic body at depth, in the vicinity of Km 27 on the seismic profile, which may have driven the uplift of the Silurian rocks in the area of the Straits. Similar granitic intrusions have been proposed to explain gravity anomalies along the Rhenohercynian Margin in Belgium, eastern and southern England. The geophysical modelling demonstrates the continuity of the basement and Mesozoic basin structures across the Dover Straits, suggesting a common geological evolution of the adjacent southern England–northern France regions. To cite this article: B. Minguely et al., C. R. Geoscience 337 (2005).  相似文献   

Premières datations de feux holocènes dans les Monts de Saint-Guilhem-le-Désert (Hérault,France), contribution à l'histoire de la forêt relique de Pinus nigra Arnold ssp Salzmanni (Dun.) Franco     

Jean-Louis Vernet  Anaïke Meter  Lamri Zéraïa 《Comptes Rendus Geoscience》2005,337(5):533-537

The charcoal discovery in the soils and sediments of the relic forest of Pinus nigra ssp Salzmanni near Saint-Guilhem-le-Désert allows us to establish a chronology of Holocene fires. Their origin dates from the Middle Holocene, but they are especially significant after the construction of the medieval abbey during the 9th century. The original pine plantation was heterogeneous, with another pine, Pinus sylvestris, which has now been eradicated. Changes in the fire modes have been observed, recent human fires being generalized, which resulted in a significant regression of the forest cover, which was replaced by box-tree formations. To cite this article: J.-L. Vernet et al., C. R. Geoscience 337 (2005).  相似文献   

Chemical weathering in the drainage basin of a tropical watershed (Nsimi-Zoetele site, Cameroon) : comparison between organic-poor and organic-rich waters   总被引：1，自引：0，他引：1  

Jer  me Viers  Bernard Dupr    Mireille Polv    Jacques Schott  Jean-Louis Dandurand  Jean-Jacques Braun 《Chemical Geology》1997,140(3-4):181-206

This study deals with the weathering processes operating at the scale of a small catchment (Nsimi-Zoetele, Cameroon) and is focused on the role of organic colloids on mineral weathering and transport of elements in natural waters. Samples of river, spring and groundwaters from Nsimi-Zoetele were filtered through membranes of decreasing pore size (0.22 μm, 0.025 μm, or: 300,000 Da, 5000 Da) to separate colloidal fractions from the truly dissolved one. Major and trace elements and dissolved organic carbon (DOC) were analysed in each fraction. Two kinds of waters can be distinguished in the catchment: clear and coloured waters. Clear waters exhibit low concentrations of major and trace elements and DOC. Elements are carried in these solutions in a true dissolved form except Al and rare earth elements (REEs). By contrast, the higher abundances of Al, Fe and trace elements in coloured waters are controlled by the colloidal fraction. Thermodynamic equilibrium calculations show that clear waters are in equilibrium with kaolinite and iron oxi-hydroxide which are major minerals in the weathered soil. For coloured waters, the aqueous speciation of Ca, Mg, Cu, Fe, Al, La and Th was calculated taking into account the complexes with humic acids. Speciation calculations for Cu, Fe, Al, La, Th show a strong complexation with humic acids, in good agreement with the results of the filtration experiments. By contrast, although filtration experiments show a strong control of major cations by organic matter (for example 75% for Ca), speciation calculations reveal that their complexes with humic ligands do not exceed a few percent of total dissolved elements. This discrepancy is explained as an artefact induced by the organic colloids and occurring during the filtration procedure. Finally, both filtration experiments and speciation calculations show that organic matter plays an important role in natural DOC-rich waters. Organic acids increase significantly the dissolution rates of silicates and oxi-hydroxides and thus the amounts of solutes and of complexed elements leaving the catchment.  相似文献   

Geochemical morphology of the North Mid-Atlantic Ridge, 10°–24°N: Trace element-isotope complementarity     

Laure Dosso  Henri Bougault  Jean-Louis Joron 《Earth and Planetary Science Letters》1993,120(3-4):443-462

The new data presented here from a 10–24°N segment of the North Mid-Atlantic Ridge show that this segment is the most depleted of the 10–70°N ridge section. They also show the existence of: (1) a geochemical gradient from the 14°N anomaly to 17°10′N; (2) a very depleted mantle source (the lowest Sr isotopic ratios found so far in the North Atlantic); and (3) a geochemical limit located at about 17°10′N without any obvious relation with any structural feature. The 15°20′N fracture zone does not show any relationship with respect to this gradient. The basalts located north of 17°10′N have very homogeneous features, which allow their characteristics to be averaged (i.e., ⁸⁷Sr/⁸⁶Sr= 0.70238 ± 0.00004, (Nb/Zr)_N = 0.28 ± 0.1) and they are defined as normal mid-ocean ridge basalts. The basaltic glasses located south of 17°10′N present a wide spectrum of isotopic compositions and extended rare earth element patterns (from depleted to enriched). Despite this, they have a constant K/Nb of 233 ± 9 (1s_M, n = 18) whereas this ratio is 344 ± 29 north of 17°10′N. These observations illustrate the strong coherence of behaviour between K and Nb (Ta) during the petrogenic processes involved in the generation of these mid-ocean ridge basalts and also their fractionation during previous mantle processes. Possible interpretations of mixing processes are discussed and sources at the ridge segment scale are favoured. However, when looking in detail, local heterogeneities are still common and can even be traced back off-axis to 115 my.

Placed in the context of the North Atlantic Ridge from 10° to 70°N, the Sr isotopic ratios reveal the Azores superstructure (23–50°N), whereas the trace element ratios (La/Sm-Nb/Zr) trace the second-order structures (33–40°N, 42–48°N) superimposed on the superstructure. This study illustrates the complementarity of information given by certain well chosen trace element ratios on the one hand and by isotopic ratios on the other. Since there is evidence of decoupling between isotopic ratios and/or trace element ratios, it introduces the notion of complementary “chemical memory” as recorded by a given type of trace element ratio or a given type of isotopic ratio  相似文献   

Diagenetic trends of a tertiary low-rank coal series     

Jean-Paul Boudou  Bernard Durand  Jean-Louis Oudin 《Geochimica et cosmochimica acta》1984,48(10):2005-2010

The Mahakam delta (Kalimantan, Indonesia) coals represent all the evolution stages between freshly-deposited plant/peat material, lignites and bituminous coals. The geochemical techniques used to study this coal series included elemental analysis, extraction of humic compounds, infrared spectroscopy and ¹³C nuclear magnetic resonance of the total coal.The main mechanisms of early maturation in this series are loss of oxygenated compounds, aromatisation and condensation of the organic matter. These changes, which have already been suggested for other coal series and partially reported for sedimentary organic matter, were confirmed and described in more detail for the Mahakam coal series.  相似文献   

Modelling the Mixing Function to Constrain Coseismic Hydrochemical Effects: An Example from the French Pyrénées     

Jean-Paul Toutain  Margot Munoz  Jean-Louis Pinaud  Stéphanie Levet  Matthieu Sylvander  Alexis Rigo  Jocelyne Escalier 《Pure and Applied Geophysics》2006,163(4):723-744

Groundwater coseismic transient anomalies are evidenced and characterized by modelling the mixing function F characteristic of the groundwater dynamics in the Ogeu (western French Pyrénées) seismic context. Investigations of water-rock interactions at Ogeu indicate that these mineral waters from sedimentary environments result from the mixing of deep waters with evaporitic signature with surficial karstic waters. A 3-year hydrochemical monitoring of Ogeu springwater evidences that using arbitrary thresholds constituted by the mean ± 1 or 2σ, as often performed in such studies, is not a suitable approach to characterize transient anomalies. Instead, we have used a mixing function F calculated with chemical elements, which display a conservative behavior not controlled by the precipitation of a mineral phase. F is processed with seismic energy release (E_s) and effective rainfalls (R). Linear impulse responses of F to E_s and R have been calculated. Rapid responses (10 days) to rainwater inputs are evidenced, consisting in the recharge of the shallow karstic reservoir by fresh water. Complex impulse response of F to microseismic activity is also evidenced. It consists in a 2-phase hydrologic signal, with an inflow of saline water in the shallow reservoir with a response delay of 10 days, followed by an inflow of karstic water with a response delay of 70 days, the amount being higher than the saline inflow. Such a process probably results from changes in volumetric strain with subsequent microfracturation transient episodes allowing short inflow of deep salted water in the aquifer. This study demonstrates that groundwater systems in such environments are unstable systems that are highly sensitive to both rainfall inputs and microseismic activity. Impulse responses calculation of F to E_s is shown to be a powerful tool to identify transient anomalies. Similar processing is suggested to be potentially efficient to detect precursors of earthquakes when long time-series (5 years at least) are available in areas with high seismicity.  相似文献   

Solute generation and transfer from a chemically reactive alpine glacial–proglacial system     

Ian J. Fairchild  Jacque A. Killawee  Martin J. Sharp  Baruch Spiro  Bryn Hubbard  Regi D. Lorrain  Jean-Louis Tison 《地球表面变化过程与地形》1999,24(13):1189-1211

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