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141.
Roger L. Nielsen 《Geochimica et cosmochimica acta》1985,49(8):1775-1779
In an investigation of Sm, Sc, Sr, and Ti partitioning between diopside and silicate melt, Rayet al. (1983) showed that the compositional dependence of multicomponent exchange equilibria can not be eliminated by the application of the melt model of Bottinga and Weill (1972), and that the propagation of analytical error is an important contributor in the observed internal error in the calculated equilibria for those exchange reactions. We can demonstrate that the compositional dependence of single component distribution coefficients can be reduced below analytical error by the application of the two-lattice melt model first reported by Nielsenand Drake (1979) in a study of major element partitioning between pyroxene and melt. This model was later used for the calculation of major, minor and trace element partitioning by Nielsen and Dungan (1983). The two-lattice model is a modified version of the Bottinga-Weill model used by Drake (1976) for plagioclase-melt equilibria, and differs from that model in the assumed role of Al. The Nielsen and Dungan (1983) model has been modified here to assume Ti to mix in silicate melts as a network former. Single component distribution coefficients were used in place of multicomponent reactions in order to reduce the propagated analytical and experimental error. 相似文献
142.
The equation of heat conduction is solved for a horizontally stratified medium initially at constant temperature and subject to a step-function surface temperature change. The problem is solved by Laplace transformation and by applying a concept of further stratifications of the medium into unitary layers of constant ratio of thickness to the square root of thermal diffusivity. The solution takes the form of an infinite sum of complementary error functions, with coefficients given by recursion relations, is suitable for numerical applications and offers an attractive alternative to harmonic and quasi transient approaches in calculating the penetration of transient surface temperature variations into a layered medium. Use of the theorem of superposition yields a general expression for an arbitrary surface temperature function. The utility of the theory is illustrated by modelling examples of palaeoclimatically induced subsurface temperature and heat flow perturbations. 相似文献
143.
Natrocarbonatite flows in the crater of the volcano Oldoinyo Lengai (Tanzania) are the only carbonatite magmas observed to erupt and have provided strong arguments in favor of a magmatic origin for carbonatite. The currently favored explanation for the genesis of these carbonatites by liquid immiscibility between a silicate and a carbonatite melt is questioned based on the extremely low eruption temperatures of 544-593 °C and compositional and mineralogical characteristics not in agreement with experimental constraints. Experimental investigations of the relationship between Oldoinyo Lengai natrocarbonatite and related silicate rock compositions do indicate that alkali-bearing peralkaline carbonatite with liquidus calcite can form by liquid immiscibility. At the same time, these experiments result in evidence which speaks against a liquid immiscibility origin for the highly alkaline and peralkaline Oldoinyo Lengai natrocarbonatite. On the carbonatite side of the miscibility gap, fractional crystallization cannot account for a liquid evolution from alkali-bearing peralkaline carbonatite to highly alkaline natrocarbonatite. Such an evolution does not seem to be compatible with the liquidus mineral assemblages and the chemistry of Oldoinyo Lengai natrocarbonatite. No natural silicate magma is known to produce natrocarbonatite compositions by liquid immiscibility. The best interpretation of the Oldoinyo Lengai natrocarbonatite flows involves expulsion of a cognate, mobile, alkaline, and CO2-rich fluid condensate. This conclusion is supported by recent studies of silicate and carbonatite melt inclusions in minerals of ultramafic alkaline complexes, trace element partitioning, isotopic constraints, and by experimental data on major element partitioning between coexisting H2O-CO2-rich fluid and carbonatitic melt. In contrast to all other suggested modes of formation, an origin of Oldoinyo Lengai natrocarbonatite from cognate fluid appears best to be in agreement with the field observations, the petrography, mineralogy, and geochemistry of Oldoinyo Lengai natrocarbonatite and the dynamics of the Oldoinyo Lengai natrocarbonatite extrusion. 相似文献
144.
145.
Torben Mikkelsen Hans E. Jørgensen Morten Nielsen Søren Ott 《Boundary-Layer Meteorology》2002,105(3):483-505
Concentration fluctuation data from surface-layer released smokeplumes have been investigated with the purpose of finding suitable scaling parametersfor the corresponding two-particle, relative diffusion process.Dispersion properties have been measured at downwind ranges between 0.1 and 1 km from a continuous, neutrally buoyant ground level source. A combinationof SF6 and chemical smoke (aerosols) was used as tracer. Instantaneous crosswind concentration profiles of high temporal (up to 55 Hz) and spatialresolution (down to 0.375 m) were obtained from aerosol-backscatter Lidar detectionin combination with simultaneous gas chromatograph (SF6) reference measurements. The database includes detailed crosswind concentration fluctuation measurements. Each experiment, typically of 1/2-hour duration, containsplume mean and variance concentration profiles, intermittency profiles andexceedence and duration statistics. The diffusion experiments were accompanied by detailed in-situ micrometeorological mean and turbulence measurements. In this paper, a new distance-neighbour function for surface-released smoke plumes is proposed, accompanied by experimental evidence in its support. The new distance-neighbour function is found to scale with the surface-layer friction velocity,and not with the inertial subrange dissipation rate, over the range of distance-neighbour separations considered. 相似文献
146.
147.
The Vakkejokk Breccia: An Early Cambrian proximal impact ejecta layer in the North‐Swedish Caledonides
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The ≤27 m thick Vakkejokk Breccia is intercalated in autochthon Lower Cambrian along the Caledonian front north of Lake Torneträsk, Lapland, Sweden. The spectacular breccia is here interpreted as a proximal ejecta layer associated with an impact crater, probably ~2–3 km in size, located below Caledonian overthrusts immediately north of the main breccia section. The impact would have taken place in a shallow‐marine environment ~520 Ma ago. The breccia comprises i) a strongly disturbed lower polymict subunit with occasional, in themselves brecciated, crystalline mega‐clasts locally exceeding 50 m surrounded by contorted sediments; ii) a middle, commonly normally graded, crystalline‐rich, polymict subunit, in turn locally overlain by iii) a thin fine‐grained quartz sandstone, <30 cm thick. The upper sandstone is sporadically either overlain, or replaced, by a conglomerate. In progressively more distal parts of the ejecta layer, the lower subunit is better described as only slightly disturbed strata. The lower subunit is suggested to have formed by ejecta bombardment of the strata surrounding the impact crater, even causing some net outwards mobilization of the sediments. The middle subunit and the uppermost quartz sandstone are considered resurge deposits. The top conglomerate may be caused by subsequent wave reworking and slumping of material from the elevated rim. Quartz grains showing planar deformation features are present in the graded polymict subunit and the upper sandstone, that is, the inferred resurge deposits. 相似文献
148.
Peter Rasmussen George Pantopoulos Jørn B. Jensen Jesper Olsen Hans Røy Ole Bennike 《Boreas: An International Journal of Quaternary Research》2020,49(1):108-128
Holocene sedimentation patterns and environmental development in Aarhus Bay, Denmark, were reconstructed based on proxy analyses of two sediment cores (M1 and M5). Together, the two cores offer an opportunity to examine the history of the area during the past c. 10 000 years. The investigation consisted of acoustic mapping and multi-proxy analyses of the sediment cores including macrofossils, sediment physical properties, sediment accumulation rates, grain size, and X-ray fluorescence elemental counts. Radiocarbon dating of the two sediment successions revealed that they cover the periods c. 10 000–3700 cal. a BP (M1) and c. 4400 cal. a BP to the present (M5). The data from the M1 site indicate the presence of a near-shore lake environment between c. 10 000 and 9000 cal. a BP. The first intrusion of marine water into the area is dated to c. 9000 cal. a BP. In the following c. 1300 years, brackish-water conditions prevailed in the area characterized by a mixture of taxa from marine, limnic and terrestrial habitats, reflecting a shallow estuarine environment. Around 7700 cal. a BP full marine conditions were established, accompanied by a marked increase in sedimentation rates. The changes to full marine conditions and higher sedimentation rates are probably due to a significant sea-level rise leading to flooding of former land areas and intensified erosion. A subsequent distinct decrease in sedimentation rates around 6350 cal. a BP is presumably linked to a previously documented sea-level drop about this time. Continuous sedimentation ceased around 3700 cal. a BP in the central part of the bay, most probably due to a major sea-level lowering involving widespread erosion. In the eastern and deeper part of the bay, sedimentation continued until today. Fully marine conditions prevailed there for at least the last 4400 years. 相似文献
149.
The observed trend of peak storm surge ηmax increasing with storm size Rmax, roughly as ηmax ∞ Rmax0.22, particularly on gently sloping coasts, is discussed in relation to the simple 1D analytical solutions for forced long waves due to respectively surface pressure ps and wind stress τw. At constant depth h, the τw-driven surge is proportional to storm size while the ps-driven part is not. This could perhaps be seen to explain why the size-dependence is stronger on flatter slopes where the τw-driven surge dominates. However, this direct size dependence disappears in the sloping beach scenario if the typical depth is assumed proportional to storm size. The observed size dependence is then more likely due to a combination of two 2D effects: Firstly, the sideways radiation from a travelling surge which exceeds the “stationary height” Δp/ρg is relatively weaker for a wider system. Secondly, the wind stress field is a dipole, and the mutual cancellation of the two poles is weaker for larger systems. 相似文献
150.
Recent developments in extreme values modelling have been used to develop a framework for determining the coastal erosion hazard on sandy coastlines. This framework quantitatively reproduced the extreme beach erosion volumes obtained from field measurements at Narrabeen Beach, Australia. This encouraging finding was achieved using Kriebel and Dean's [Kriebel, D.L. and Dean, R.G., 1993. Convolution method for time-dependent beach profile response. Journal of Waterway, Port, Coastal and Ocean Engineering, 119(2): 204–226.] simple beach erosion and accretion model. The method includes allowances for joint probability between all basic erosion variates including; wave height, period and direction, event duration, tidal anomalies and event spacing. A new formulation for the dependency between wave height and period has been developed. It includes the physical wave steepness limitation. Event grouping, where significantly more erosion can occur from two closely spaced storms is handled by temporally simulating the synthetic wave climate and the resulting beach erosion and accretion. 相似文献