Assessment of groundwater chemistry in a coastal region (Kunsan, Korea) having complex contaminant sources: a stoichiometric approach   总被引：1，自引：0，他引：1  

Kangjoo Kim  Natarajan Rajmohan  Hyun Jung Kim  Gab-Soo Hwang  Min Joe Cho 《Environmental Geology》2004,46(6-7):763-774

Groundwater chemistry in a coastal region (Kunsan, Korea) having complex contaminant sources was investigated. Water analysis data for 197 groundwater samples collected from the uniformly distributed sixty-six wells were used. Chemical analysis results indicate that groundwaters show wide concentration ranges in major inorganic ions, reflecting complex hydrochemical processes. Due to the complexity of groundwater chemistry, the samples were classified into four groups based on Cl and NO₃ concentrations and the processes controlling water chemistry were evaluated based on the reaction stoichiometry. The results explained the importance of mineral weathering, anthropogenic activities (nitrification and oxidation of organic matters), and Cl-salt inputs (seawater, deicer, NaCl, etc.) on groundwater chemistry. It was revealed that mineral dissolution is the major process controlling the water chemistry of the low Cl and NO₃ group (Group 1). Groundwaters high in NO₃ (Groups 2 and 4) are acidic in nature, and their chemistry is largely influenced by nitrification, oxidation of organic matters and mineral dissolution. In the case of chloride rich waters (Group 3), groundwater chemistry is highly influenced by mineral weathering and seawater intrusion associated with cation-exchange reactions.  相似文献   

Constructed wetland technology and mosquito populations in Arizona     

Martin M. Karpiscak  Kenneth J. Kingsley  Roland D. Wass  Frederick A. Amalfi  John Friel  Aaron M. Stewart  Joe Tabor  Jeffrey Zauderer 《Journal of Arid Environments》2004,56(4):681

Constructed wetlands and other aquatic habitat creation or restoration efforts offer both potential benefits and problems for arid areas. An unintentional consequence of these efforts has been the potential for an increase in local adult mosquito populations. Shallow water-emergent plant zones may provide ideal conditions for mosquito larval growth, and areas of high humidity, dense vegetation, and abundant birds and other wildlife may provide ideal conditions for adult mosquitoes. Three constructed wetlands in southern Arizona were studied over a period of years before and after they were constructed and operational. Mosquito populations were sampled using a variety of methods, primarily trapping of adults with CO₂-baited traps. Populations apparently increased, sometimes by several orders of magnitude, after wetlands became operational. Several methods of mosquito abatement were initiated and their results are discussed. However, no definitive conclusions can be drawn because no untreated areas were available for comparison and many factors that may have affected mosquito populations also changed. Based on the experience gained at these three sites, mosquito control is an especially important design and management component for constructed wetlands in arid environments with low background populations of mosquitoes.  相似文献   

Multiple detachment levels and their control on fold styles in the compressional domain of the deepwater west Niger Delta   总被引：2，自引：0，他引：2  

Sepribo E. Briggs  Richard J. Davies†  Joe A. Cartwright  Richard Morgan‡ 《Basin Research》2006,18(4):435-450

We interpret recently acquired two‐dimensional (2D) and 3D seismic data from the contractional domain of the Tertiary deepwater west Niger Delta, which is an area of current hydrocarbon exploration and development to show that during its gravitational collapse, multiple detachments were active. Detachments are located within (1) what we herein refer to as the ‘Dahomey unit’, (2) the transition between the Agbada and Akata formations (Top Akata) and (3) the Akata formation. Seismic interpretation and quantitative measurements of fault displacements show that the utilisation of different detachments results in contrasting styles of thrust propagation and fold growth. Two geographical zones are defined. In zone A (NW sector of the study area), the stratigraphically shallowest Dahomey detachment is dominant and is associated with thrust truncated folds. In zone B (SE sector of the study area), a stratigraphically lower detachment approximately at the Agbada–Akata formation boundary is associated with thrust propagation folds. A third detachment, within the Akata formation, is locally developed and is also associated with thrust propagation folds. The different deformational histories are probably related to the mechanical stratigraphy and the pore‐pressure characteristics of the succession.  相似文献   

Origin and variability of a terminal Proterozoic primary silica precipitate,Athel Silicilyte,South Oman Salt Basin,Sultanate of Oman          下载免费PDF全文

Ibrahim M. Al Rajaibi  Cathy Hollis  Joe H. Macquaker 《Sedimentology》2015,62(3):793-825

The Precambrian–Cambrian Athel Silicilyte is a 400 m thick, salt‐encased siliceous succession in the South Oman Salt Basin. It is a self‐sourcing hydrocarbon reservoir and comprises up to 95% microcrystalline quartz and exhibits wavy discontinuous lamination, comprising thin, alternating organic‐rich and silica‐rich layers. Textures and geochemical fingerprinting indicate that it is a primary precipitate formed by microbially mediated precipitation of silica from sea water, within the water column at the sulphidic/oxic interface. The unique occurrence of the Athel Silicilyte in the terminal Proterozoic implies that optimal conditions for this style of silica precipitation occurred only briefly. Basin anoxia, coupled with the growth of microbial mats, low pH and high silica pore water saturations, created optimal chemical conditions for silica precipitation. Volumes of microcrystalline quartz are highest within the transgressive and early highstand systems tract and towards the centre of the Athel Basin. At the basin margins, and within the late highstand systems tract, volumes of microcrystalline quartz decreased as the volume of detrital sediment increased. Mass‐balance calculations indicate that silica‐enriched sea water would have been supplied to the basin by infrequent marine incursions that replenished ambient sea water in the upper part of the water column. In conclusion, precipitation of the Athel Silicilyte was driven by the coincidence of basin restriction, limited clastic input, availability of organic matter and water column anoxia. The observation that there are few documented examples of chert deposits younger than ca 700 Ma, prior to the Cambrian explosion, suggests that although silica budgets within marine basins probably remained high prior to the evolution of silica‐secreting organisms, direct precipitation from sea water was restricted. This is tentatively related to the gradual increase in alkalinity of sea water through the Palaeo‐Proterozoic and Meso‐Proterozoic, such that silica precipitation could only occur through the coincidence of basin anoxia and low siliciclastic input.  相似文献   

Hydrochemical variations during flood pulses in the south‐west China peak cluster karst: impacts of CaCO3–H2O–CO2 interactions     

Zaihua Liu  Chris Groves  Daoxian Yuan  Joe Meiman  Guanghui Jiang  Shiyi He  Qiang Li 《水文研究》2004,18(13):2423-2437

High‐resolution measurements of rainfall, water level, pH, conductivity, temperature and carbonate chemistry parameters of groundwater at two adjacent locations within the peak cluster karst of the Guilin Karst Experimental Site in Guangxi Province, China, were made with different types of multiparameter sonde. The data were stored using data loggers recording with 2 min or 15 min resolution. Waters from a large, perennial spring represent the exit for the aquifer's conduit flow, and a nearby well measures water in the conduit‐adjacent, fractured media. During flood pulses, the pH of the conduit flow water rises as the conductivity falls. In contrast, and at the same time, the pH of groundwater in the fractures drops, as conductivity rises. As Ca²⁺ and HCO₃^? were the dominant (>90%) ions, we developed linear relationships (both r² > 0·91) between conductivity and those ions, respectively, and in turn calculated variations in the calcite saturation index (SI_C) and CO₂ partial pressure (P) of water during flood pulses. Results indicate that the P of fracture water during flood periods is higher than that at lower flows, and its SI_C is lower. Simultaneously, P of conduit water during the flood period is lower than that at lower flows, and its SI_C also is lower. From these results we conclude that at least two key processes are controlling hydrochemical variations during flood periods: (i) dilution by precipitation and (ii) water–rock–gas interactions. To explain hydrochemical variations in the fracture water, the water–rock–gas interactions may be more important. For example, during flood periods, soil gas with high CO₂ concentrations dissolves in water and enters the fracture system, the water, which in turn has become more highly undersaturated, dissolves more limestone, and the conductivity increases. Dilution of rainfall is more important in controlling hydrochemical variations of conduit water, because rainfall with higher pH (in this area apparently owing to interaction with limestone dust in the lower atmosphere) and low conductivity travels through the conduit system rapidly. These results illustrate that to understand the hydrochemical variations in karst systems, considering only water–rock interactions is not sufficient, and the variable effects of CO₂ on the system should be evaluated. Consideration of water–rock–gas interactions is thus a must in understanding variations in karst hydrochemistry. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Influence of the seasonal thermocline on the intrusion of Kuroshio across the continental shelf northeast of Taiwan     

Ching-Sheng Chern  Joe Wang 《Journal of Oceanography》1994,50(6):691-711

The hydrographic surveys in an area immediately northeast of Taiwan showed that the Kuroshio surface water intruded onto the shelf in the spring and there was a thick mixed layer and weak vertical stratification in the Kuroshio at the time. During the summer season, a strong thermocline was developed in the Kuroshio and the flow shifted offshore from Taiwan in front of the continental shelf break of the East China Sea. A numerical model is used to examine the effect of this seasonal thermocline on the flow pattern of the survey area. We find that the surface strength of the disturbance above the Su-Ao ridge is closely related to the occurrence of the on-shelf intrusion of Kuroshio. The presence of a seasonal thermocline in the Kuroshio can greatly diminish this disturbance in the surface level.  相似文献   

Yesterday's Freeway Network of Tomorrow          下载免费PDF全文

Joe Weber 《Geographical review》2016,106(1):54-71

In 1939, the Futurama exhibit at the New York World's Fair amazed visitors with its diorama showing futuristic freeways crossing the countryside and reshaping cities. After the fair, the exhibit's designer, Norman Bel Geddes, elaborated the model into a proposal for a national freeway network. This paper examines the network structure and geographic dimensions of Bel Geddes's vision and compares it to the Interstate Highway System, created several years later. Despite the futuristic trappings inherited from the Futurama model, the two networks are surprisingly similar except in their relation to cities, which Bel Geddes's network avoids. The majority of elements in Bel Geddes's system have been incorporated into actual routes and networks, and it can be expected that his system would have gone through many of the same adaptations to changing economic, environmental, and political circumstances as the Interstate Highway System.  相似文献   

Ti-in-zircon thermometry applied to contrasting Archean metamorphic and igneous systems     

Joe Hiess  Allen P. Nutman  Vickie C. Bennett  Peter Holden 《Chemical Geology》2008,247(3-4):323-338

Ti-in-zircon thermometry with SHRIMP II multi-collector has been applied to two well-documented Archean igneous and metamorphic samples from southern West Greenland. Zircons from 2.71 Ga partial melt segregation G03/38 formed in a small (< 1 m³), closed system within a mafic rock under high pressure granulite facies conditions. Results of 14 Ti analyses present a mean apparent zircon crystallization temperature of 679 ± 11 °C, underestimating independent garnet-clinopyroxene thermometry by 20–50 °C but consistent with reduced a_TiO2 in this system. 36 spot analysis on 15 zircons from 3.81 Ga meta-tonalite G97/18, with an estimated magmatic temperature > 1000 °C, yield a low-temperature focused normal distribution with a mean of 683 ± 32 °C, further demonstrated by high resolution Ti mapping of two individual grains. This distribution is interpreted to represent the temperature of the residual magma at zircon saturation, late in the crystallization history of the tonalite. Hypothetically, Ti-in-zircon thermometry on Eoarchaean detrital zircons sourced from such a high temperature tonalite would present a low-temperature biased image of the host magma, which could be misconstrued as being a minimum melt granite. Multiple analyses from individual zircons can yield complex Ti distributions and associated apparent temperature patterns, reflecting cooling history and local chemical environments in large magma chambers. In addition to inclusions and crystal imperfections, which can yield apparent high temperature anomalies, zircon surfaces can also record extreme (> 1000 °C) apparent Ti temperatures. In our studies these were traced to ⁴⁹Ti (or a molecular isobaric interference) contamination derived from the double sided adhesive tape used in sample preparation, and should not be assigned geological significance.  相似文献   

Analysis of Convective Heat Transfer in Deformed and Stratified Aquifers Associated with Frasch Thermal Mining     

Daphne D. Williams  Ming-Kuo Lee  Joe E. Crawford  Philip O. Tyree 《Ground water》1999,37(4):517-522

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辐射处理金刚石的谱学研究及其意义   总被引：2，自引：0，他引：2  

苑执中  彭明生  蒙宇飞 《矿物岩石》2005,25(3):47-51

利用傅立叶显微红外光谱、紫外-可见-近红外吸收光谱、低温光致发光谱、拉曼光谱等4种谱学方法,对10颗辐照改色（R1-R10）的彩色天然金刚石进行了研究。利用可见吸收光谱和低温光致发光谱研究了金刚石石中的点缺陷产生系列的色心峰,指出在可见吸收光谱中除了有N3心吸收峰外,还可见595和637色心峰;在低温光致发光谱中发现有色心组合峰575,595和637等的出现,此组合峰与近红外区4929cm^-1处的H1b和5156cm^-1处的H1C色心峰共同存时,不仅是辐照处理绿色金刚石的鉴定证据,也是辐照处理各种彩色金刚石的重要的标志之一。本研究为辐射处理金刚石的鉴别和工艺流程提供了新的谱学依据和思路。  相似文献