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61.
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Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl2 or CaCl2), with binary mixtures of MgCl2 and CaCl2, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl2, while it is increased by the other electrolytes used in this work.  相似文献   
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The transport pathways of fine sediments (fraction <2 μm) along the Brazilian continental shelf from Ceará to the Amazon River mouth were studied by means of clay mineral analyses. On the continental shelf southeast of the Amazon mouth, fluctuations in clay mineral compositions reflect simple mixing between the suspended load of the North Brazil Current and sediment from several smaller rivers. Previously, clay mineral variations west of the Amazon mouth have been explained by variable settling velocities of different grain-size classes within the <2 μm fraction or by selective coagulation of individual clay mineral groups. By contrast, our experiments with river bank samples show that selective coagulation does not occur in Amazon River sediments. A more appropriate explanation for observed variations in clay mineral composition off the Amazon mouth seems to be, similarly to that for the shelf between Ceará and the Amazon mouth, a mixing of Amazon sediments with suspended material of the North Brazil Current. This interpretation is supported by data on clay mineral composition east and south of the Amazon mouth, showing more affinity to sediments of the North Brazil Current than to the suspended load of the Amazon River. Additionally, relatively low sedimentation rates and low concentrations of fine-grained sediments on the shelf suggest that high riverine input by the Amazon River does not overprint the sediments of the North Brazil Current in this region. The strong North Brazil Current shunts the Amazon suspended load in a north-westerly direction along the north-eastern coast of South America. Hence, stronger sedimentation of Amazon sediments would occur only west of the river mouth.  相似文献   
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Lagoa de Araruama in the state of Rio de Janeiro, Brazil, is a hypersaline lagoon with salinity varying spatially from 45 to 56. We collected water samples during monthly cruises throughout the lagoon, and along the streams feeding the system, from April 1991 to March 1992. Nutrients and other water quality parameters exhibited great spatial and temporal variations. Mass balance calculations indicate large amounts of anthropogenic nutrient inputs. The data indicate that the lagoon currently is oligotrophic but is in a state of transition to become a mesotrophic system. Molar dissolved inorganic nitrogen:dissolved inorganic phosphorus (DIN/DIP) varied between 2.2:1 and 659:1 with a volume-weighted average of 22:1. The high DIN/DIP ratio contrasts with that found in nearby lagoons, suggesting that phytoplankton primary production is limited by phosphorus in Lagoa de Araruama. The major loss of DIP is apparently driven by biological assimilation and diagenic reactions in the sediments. Calculations indicate that the lagoon is slightly net autotrophic at +0.9 mol C m−2 yr−1. This suggests that the biomass of the primary producers is restricted by phosphorus availability. Phosphorus retention in the sediment and the hypersaline state of the lagoon prevent changes in autotrophic communities and the formation of eutrophic conditions.  相似文献   
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Measurements of surface partial pressure of CO2 and water column alkalinity, pHT, nutrients, oxygen, fluorescence and hydrography were carried out, south of the Canary Islands during September 1998. Cyclonic and anticyclonic eddies were alternatively observed from the northwestern area to the central area of the Canary Islands. Nutrient pumping and vertical uplifting of the deep chlorophyll maximum by cyclonic eddies were also ascertained by upward displacement of dissolved inorganic carbon. A model was applied to determine the net inorganic carbon balance in the cyclonic eddy. The fluxes were determined considering both the diffusive and convective contributions from the upward pumping and the corresponding horizontal transport of water outside the area. An increase in the total inorganic carbon concentration in the upper layers inside the eddy field of 133 mmol C m− 2 d− 1 was determined. The upward flux of inorganic carbon decreased the effect of the increased primary production on the carbon dioxide chemistry. The reduced fCO2 inside the cyclonic eddy, 15 μatm lower than that observed in non-affected surface water, was explained by thermodynamic aspects, biological activity, eddy upward pumping and diffusion and air–sea water exchange effects.  相似文献   
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We analyze the hypothesis of quantization in bands for the angular momenta of binary systems and for the maount of actionA c in stable and pulsating stars. This parameter isA c=Mv eff R eff, where the effective velocity corresponds to the kinetic energy in the stellar interior and the effective radius corresponds to the potential energyGM 2/R eff. Analogous parameters can be defined for a pulsating star withm=M where is the rate of the massm participating in the oscillation to the total massM andv osc,R osc the effective velocity and oscillation radius.From an elementary dimensional analysis one has thetA c (energy x time) (period)1/3 independently ifA c corresponds to the angular momentum in a binary system, or to the oscillation in a pulsating star or the inner energy and its time-scaleP eff in a stable star.From evolving stellar models one has that P effP eff(solar)1.22 hr a near-invariant for the Main Sequence and for the range of masses 0.6M <M<1.6M .With this one can give scalesn k=kn 1 withk integers andn 1=(P/P 1)1/3 withP 1=P eff1.22 hr. In these scales proportional toA c, one sees that the periods in binary and pulsating stars are clustered in discrete unitsn 1,n 2,n 3, etc.This can be seen in pulsating Scuti, Cephei, RR Lyrae, W Virginis, Cephei, semi-regular variables, and Miras and in binary stars as cataclysmic binaries, W Ursa Majoris, Algols, and Lyrae with the corresponding subgroups in all these materials. Phase functions (n k) in RR Lyrae and Cephei are also associated with discrete levelsn k.the suggested scenario is that the potential energies and the amounts of actionE p(t), Ac(t) are indeed time-dependent, but the stars remain more time in determinated most proble states. The Main Sequence itself is an example of this. These most probable states in binary systems, or pulsating or stable stars, must be associated with velocities sub-multiplesc/ F , given by the velocity of light and the fine structure constant.Additional tests for such a hypothesis are suggested when the sufficient amount of observational data are available. They can made with oscillation velocities in pulsating stars and velocity differences of pairs of galaxies.  相似文献   
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