Uncertainties of geochemical modeling during CO<Subscript>2</Subscript> sequestration applying batch equilibrium calculations     

Frank?DethlefsenEmail author  Christoph?Haase  Markus?Ebert  Andreas?Dahmke 《Environmental Earth Sciences》2012,65(4):1105-1117

One of the uncertainties in the field of carbon dioxide capture and storage (CCS) is caused by the parameterization of geochemical models. The application of geochemical models contributes significantly to calculate the fate of the CO₂ after its injection. The choice of the thermodynamic database used, the selection of the secondary mineral assemblage as well as the option to calculate pressure dependent equilibrium constants influence the CO₂ trapping potential and trapping mechanism. Scenario analyses were conducted applying a geochemical batch equilibrium model for a virtual CO₂ injection into a saline Keuper aquifer. The amount of CO₂ which could be trapped in the formation water and in the form of carbonates was calculated using the model code PHREEQC. Thereby, four thermodynamic datasets were used to calculate the thermodynamic equilibria. Furthermore, the equilibrium constants were re-calculated with the code SUPCRT92, which also applied a pressure correction to the equilibrium constants. Varying the thermodynamic database caused a range of 61% in the amount of trapped CO₂ calculated. Simultaneously, the assemblage of secondary minerals was varied, and the potential secondary minerals dawsonite and K-mica were included in several scenarios. The selection of the secondary mineral assemblage caused a range of 74% in the calculated amount of trapped CO₂. Correcting the equilibrium constants with respect to a pressure of 125 bars had an influence of 11% on the amount of trapped CO₂. This illustrates the need for incorporating sensitivity analyses into reaction pathway modeling.  相似文献   

Modeling, parameterization and evaluation of monitoring methods for CO2 storage in deep saline formations: the CO2-MoPa project     

S. Bauer  H. Class  M. Ebert  V. Feeser  H. G?tze  A. Holzheid  O. Kolditz  Sabine Rosenbaum  W. Rabbel  D. Sch?fer  A. Dahmke 《Environmental Earth Sciences》2012,67(2):351-367

Capture and geological sequestration of CO₂ from large industrial sources is considered a measure for reducing anthropogenic emissions of CO₂ and thus mitigating climate change. One of the main storage options proposed are deep saline formations, as they provide the largest potential storage capacities among the geologic options. A thorough assessment of this type of storage site therefore is required. The CO₂-MoPa project aims at contributing to the dimensioning of CO₂ storage projects and to evaluating monitoring methods for CO₂ injection by an integrated approach. For this, virtual, but realistic test sites are designed geometrically and fully parameterized. Numerical process models are developed and then used to simulate the effects of a CO₂ injection into the virtual test sites. Because the parameterization of the virtual sites is known completely, investigation as well as monitoring methods can be closely examined and evaluated by comparing the virtual monitoring result with the simulation. To this end, the monitoring or investigation method is also simulated, and the (virtual) measurements are recorded and evaluated like real data. Application to a synthetic site typical for the north German basin showed that pressure response has to be evaluated taking into account the layered structure of the storage system. Microgravimetric measurements are found to be promising for detecting the CO₂ phase distribution. A combination of seismic and geoelectric measurements can be used to constrain the CO₂ phase distribution for the anticline system used in the synthetic site.  相似文献   

Degradation of TCE with Iron: The Role of Competing Chromate and Nitrate Reduction   总被引：11，自引：0，他引：11  

Oliver Schlicker  Markus Ebert  Margit Fruth  Markus Weidner  Wolfgang Wüst  reas Dahmke 《Ground water》2000,38(3):403-409

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Land Cover Change and its Environmental Significance in the Herbert River Catchment,North-east Queensland     

A.K.L. Johnson  S.P. Ebert  A.E. Murray 《The Australian geographer》2000,31(1):75-86

There has been considerable recent concern over the amount of vegetation clearance in the wet tropics of northern Australia. This paper reports on the results of a case study undertaken in the lower Herbert River catchment in north-east Queensland, which utilised remote sensing and Geographic Information Systems (GIS) to assess both spatial and temporal changes in land cover since European settlement in the mid-nineteenth century. We demonstrate that since European settlement there has been a substantial reduction in the area of Melaleuca, rainforest, and eucalyptus-dominated land-cover patterns. We also provide a range of quantitative measures to show that the landscape diversity, integrity and quality of these ecosystems have also declined between the 1860s and 1996. We conclude that reform is required at policy, planning and enterprise levels if the ecological, economic and social values of these systems are to be maintained in the future.  相似文献   

Selected ore deposits of Brazil     

Steffen Hagemann  Jose Carlos Frantz  Hardy Jost 《Mineralium Deposita》2008,43(2):127-128

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Changes of cloud microphysical properties during the transition from supercooled to mixed-phase conditions during CIME     

Stephan Mertes  Alfons Schwarzenbck  Paolo Laj  Wolfram Wobrock  Jean-Marc Pichon  Giordano Orsi  Jost Heintzenberg 《Atmospheric Research》2001,58(4)

A ground-based seeding experiment using carbon dioxide and propane sprayed from pressurized bottles was carried out under supercooled cloud conditions on a small spatial and short time scale. Water vapor deposition on the artificially generated dry ice and propane ice germs as the main ice formation process (nucleation and growth) is consistent with the experimental results. After nucleation, diffusional growth of the ice particles, partly at the expense of evaporating small droplets, was identified during the mixing of the seeding line with the ambient supercooled cloud. Within the seeding plume, ice water contents up to 80% of the total condensed water are observed, although the size of the formed ice particles did not exceed 25 μm. From the changes of the ice and supercooled liquid phase with time under mixed-phase conditions, liquid water content (LWC) evaporation, ice water content (IWC) formation, and ice crystal growth rates are estimated, which are not affected by the artificial nucleation process. Thus, these rates are assessed to be applicable for a growing ice phase of small ice particles in a young mixed-phase cloud, where other growth mechanisms, like riming or aggregation, are negligible.  相似文献   

On the distribution of physical and chemical particle properties in the atmospheric aerosol     

Jost Heintzenberg  David S. Covert 《Journal of Atmospheric Chemistry》1990,10(4):383-397

Consideration of sources and growth dynamics of aerosols has led to the conclusion that there may be a distribution or variation of chemical composition and physical structure among atmospheric aerosol particles as a function of size, and within a narrow size range as well. A mathematical representation of these particle properties in terms of an additional dimension to the number size distribution is described. Examples of the relevance of this aspect of aerosol characterization for physical and chemical processes in the atmosphere are discussed. A review of the available techniques shows that several methods are available which can and have provided quantitative results on the distribution of particle properties. Examples of data from the literature have been selected and are presented as three-dimensional distributions illustrating the wide range of particle properties which may exist in narrow size intervals. An evaluation of these results reiterates the value of taking the distribution of particle properties in the atmosphere into account for sampling and modeling purposes.  相似文献   

Stratigraphy and palaeoecology of the Upper Marine Molasse (OMM) of the central Swiss Plateau     

Jürg Jost  Oliver Kempf  Daniel Kälin 《Swiss Journal of Geoscience》2016,109(2):149-169

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Complex mathematical model of the WIG motion including the take-off mode     

Knud Benedict  Nikolai Kornev  Michael Meyer  Jost Ebert 《Ocean Engineering》2002,29(3):1-357

This paper describes an effort to develop a predictive tool for the design of a new promising marine transport — the WIG craft. The presented mathematical model of the WIG craft is capable of modeling the aerodynamics of a WIG system including the ground effect, the hydrodynamics of a stepped planing hull with a hydrofoil and also the simulation of motion for the craft. Based on extensive experience using the model, it is shown that the most important and necessary features of WIG aero- and hydrodynamics are taken into account. The results of simulations have been validated through comparison with other theoretical approaches and also with model experiments. The mathematical model is applied to investigate the dynamics of the small manually piloted WIG craft: “Hydrowing VT01”. The numerical study resulted in recommendations allowing the pilot to overcome the pitch-up tendency and also to perform the take-off manoeuvre smoothly. The stability of the WIG with a hydrofoil and also the dynamic properties of anti-collision manoeuvres have been studied and are presented.  相似文献   

Assessment of population size and migration routes of silver eel in the River Rhine based on a 2-year combined mark-recapture and telemetry study     

Breteler  Jan Klein; Vriese  Tim; Borcherding  Jost; Breukelaar  Andre; Jorgensen  Lothar; Staas  Stefan; de Laak  Gerard; Ingendahl  Detlev 《ICES Journal of Marine Science》2007,64(7):1450-1456

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