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991.
H. Rönkkömäki Ph.D. R. Pöykiö Ph.D. H. Nurmesniemi Ph.D. K. Popov D.Sc. E. Merisalu Dr. T. Tuomi PhD I. Välimäki M.Sc. 《International Journal of Environmental Science and Technology》2008,5(4):485-494
The particles in the examined cyclone fly ash were all smaller than 0.25 mm. in diameter, and particles smaller than 0.075 mm. in diameter accounted for 88.4 % of the ash weight. This result indicates that cyclone fly ash consists of particles with a small diameter. The metals in the cyclone fly ash were enriched in small particles. The highest concentrations for zinc, copper, lead, cadmium and molybdenum in the cyclone fly ash were found in the smallest particle size fraction (< 0.075 mm.) and for Barium, chromium, nickel, Vanadium and Cobalt in the second to smallest particle size fraction (0.075-0.125 mm.). From an environmental and toxicological standpoint, the smallest particles are of the greatest concern when ash is handed at landfill disposal sites (transport and disposal especially in stormy weather conditions), and some studies have reported risks to workers from prolonged exposure to ash. The results of the comparison of various dissolution methods for metals showed that the digestion procedures with nitric acid alone (USEPA 3051) or with a mixture of nitric acid + hydrogen peroxide (USEPA 3050B) slightly underestimated the metal concentrations in the cyclone fly ash. Although the use of hydrofluoric acid is often necessary for the determination of a number of elements associated with siliceous minerals, its use can result in loss of trace elements during dissolution. 相似文献
992.
R. A. Oktyabrsky A. A. Vrzhosek A. M. Lennikov T. A. Yasnygina S. V. Rasskazov E. Yu. Moskalenko T. A. Velivetskaya 《Russian Journal of Pacific Geology》2008,2(4):325-335
New geochemical data are presented on the magmatic rocks of the Late Jurassic Koksharovka alkaline-ultrabasic massif, which is associated with deposits of vermiculite, apatite, V-bearing titanomagnetite, and placer isoferroplatinum. The REE geochemistry and strontium, oxygen, and carbon isotopic composition of carbonatites and related ijolites and pyroxenites, together with geological observations, point to the magmatic origin of the Koksharovka carbonatites. The origin of associated magmatic rocks is discussed. Trace element modeling of partial melting of mantle sources was conducted to decipher the genesis of the melts of the Koksharovka carbonatites and host titanite-kaersutite pyroxenites. 相似文献
993.
The advent of the Virtual Observatory has begun an evolution in the space physics data environment. A number of nascent and
discipline specific Virtual Observatories have started to emerge with an emphasis on data search and retrieval. As this new
data environment takes shape an emphasis will be placed on interdisciplinary communication in attempts to address large scale
and global problems. To this end we formulate the development of a query language to facilitate Virtual Observatory to Virtual
Observatory communication. Furthermore, we outline the goals of such a language, how it would work and how existing community
efforts can be leveraged to speed the development of this query language.
相似文献
T.W. NarockEmail: |
994.
Summary The efficacy of ion exchange in petrological systems, for example the Fe-Mg exchange between garnet and biotite, is a function of grainsize, temperature, rates of temperature change and diffusion parameters. The combination of these variables determines the final zoning profile of minerals. Therefore, zoning profiles may be used to derive one of these variables if the others are known. For example, a mineral grain that experienced a short thermal event may still preserve a zoning profile characteristic of the heating path. In contrast, if that grain experienced a long thermal event it may develop a zoning profile typical of the cooling path. Conversely, for the same temperature-time cycle, large grains may not completely equilibrate at the metamorphic peak, and in smaller grains any previous record may have been erased. This is commonly observed in natural rocks where different grains within one thin section preserve often qualitatively different zoning profiles. Thus, a critical grainsize,l
crit, may exist that separates grains with qualitatively different zoning profiles so that grains of sizel >
l
crit still retain zoning information about the heating path and grains of sizel <l
crit contain only information about the cooling path. If the critical grainsize can be measured and an independent estimate for the peak metamorphic temperature exists, the duration of the thermal event may, in principle, be estimated.The applicability of this method to natural garnets is hampered by a range of uncertainties. However, a parameterisation of the critical grain size may be used to illustrate the relative importance of grain size, temperature and event duration to the equilibration of minerals. In this paper, the critical grainsize is parameterized for various temperature-time cycles and its dependence on diffusion parameters is discussed. It is shown that, for Barrovian conditions,l
crit between 0.1 and 1 mm separates garnets retaining prograde information from garnets retaining cooling path information. For illustration, we compare the results with the critical grainsize of garnets from two metamorphic terranes, the Prydz Bay region (Antarctica) and the Koralm complex (Eastern Alps). Despite the large range of uncertainties attached to the method, it is shown that the critical grainsize of garnets in both terranes is consistent with a very short duration of the last thermal event that affected the two regions.
With 5 Figures 相似文献
Die qualitative Form von Zonierungsprofilen in Mineralen. Information über die Dauer metamorpher Ereignisse?
Zusammenfassung Zonierungsprofile von Paragenesen im Ionenaustausch, zum Beispiel das Fe-Mg Austauschsgleichgewicht zwischen Granat und Biotit, sind eine Funktion von (i) Korngröße, (ii) Temperatur, (iii) Kühl- und Heizgeschwindigkeit sowie (iv) den Diffusionskonstanen. Es sollte daher möglich sein, Zonierungsprofile dazu zu verwenden, einen dieser Parameter zu bestimmen, wenn die anderen bekannt sind. Zonierungsprofile von Kristallen die ein kurzes thermisches Ereignis erfahren haben, mögen daher prograde Information beinhalten, wogegen derselbe Kristall ein retrogrades Profil aufweisen mag, wenn er einem langlebigen thermischen Ereignis unterlag (prograd und retrograd ist hier als: bei ansteigender Temperatur und bei abfallender Temperatur definiert). In Kristallen die dem gleichen Temperatur-Zeitpfad unterworfen waren, könnten kleine Körner nur die Kühlgeschichte dokumentieren, wogegen große noch Zonierungsinformation vom Heizpfad aufweisen. In natürlichen Gesteinen wird das oft dadurch beobachtet, daß verschiedene Körner auseinem Dünnschliff qualitativ verschiedene Zonierungsprofile aufweisen. Es ist daher möglich eine kritische Korngöße,l crit, zu definieren, die Korngrößen mit qualitativ verschiedenen Zonierungsprofilen voneinander trennt. Körner mit einem Durchmesserl > l crit haben, zumindest teilweise, noch prograde Profile, wogegen Körner mitl <l crit nur retrograde Information dokumentieren. Wenn man diese kritische Korngröße messen kann, sollte sie dazu benutzt werden können, etwas über die Dauer des thermischen Ereignisses auszusagen.Die Anwendbarkeit dieser Methode ist durch eine Reihe von Fehlern limitiert. Nichtsdestotrotz, ist eine Parameterisierung der kritischen Korngröße nützlich um die relative Wichtigkeit von Korngröße, Temperatur und Zeit, für die Entwicklung von Zonierungsprofilen, zu illustrieren. Unser Modell kann dazu benutzt werden, um die Größenordnung von Granaten abzuschätzen, die noch prograde Information dokumentieren können. Die Abhängigkeit der kritischen Korngröße von Diffusionsparametern und der Form des Temperatur-Zeit Pfades wird ebenfalls diskutiert. Es wird gezeigt, daß für Metamorphose in der mittleren Grünschiefer und Amphibolit fazies,l crit zwischen 0.1 and 1 mm prograd zonierte von retrograd zonierten Granaten trennt. Um das Modell zu illustrieren, werden die Ergebnisse auf die Prydz Bay Region (Antarktis) und den Koralm Komplex (Ostalpen) angewendet. Trotz der großen Fehlergrenzen der Methode glauben wir zeigen zu können, daß die kritische Korngröße beider Terrains andeutet, daß das letzte thermische Ereignis in beiden Gebieten kurzlebig war.
With 5 Figures 相似文献
995.
Summary In-situ microprobe LREE analyses of perovskite and titanite (La, Ce, Nd), and apatite (La, Ce), from SW Ugandan clinopyroxenite xenoliths and kamafugite lavas indicate that LREE distribution in these minerals is determined by a number of factors related to their different parageneses: In particular LREE content is affected by whether the LREE-bearing minerals have crystallised from metasomatic carbonate or from silicate (i.e. metasomatic or magmatic) melts in the mantle. In this situation LREE partition favours carbonate over silicate melts. Distribution of LREE in perovskite and apatite crystallised from magmatic mantle melts or mantle-derived lavas is chiefly determined by preference of LREE for perovskite > apatite > titanite. LREE zoning in perovskite is influenced by changes in melt structure: increasing melt polymerisation enhancing mineralLREE/meltLREE partition into perovskite rims in magmatic xenoliths; decreasing melt polymerisation depleting LREE in lava perovskite rims. This zoning is reinforced by perovskite competition with apatite for LREE: perovskite (cores/rims) co-crystallising with apatite is reduced in LREE. There are 37 instances of perovskitewith Ce below detection while La and Nd levels are normal. These occur in both xenoliths and lavas; in grain zones or whole grains. Likewise Ce alone of the LREE is below detection in six out of ten titanite analyses. These observations are interpreted as evidence for increased fO
2, Ce4 + being excluded from these mineral structures. Recognition of these various processes can elucidate the interpretation of bulk rock and bulk mineral LREE signatures in kamafugite volcanism.
With 3 Figures 相似文献
LREE Verteilung in Perovskit, Apatit und Titanit aus Xenolithen und kamafugitischen Laven Südwest-Ugandas
Zusammenfassung In-situ LREE Analysen von Perovskit und Titanit (La, Ce, Nd) und Apatit (La, Ce) aus Klinopyroxenit-Xenolithen und kamafugitischen Laven Südwest-Ugandas zeigen, daß die LREE Verteilung in diesen Mineralen durch eine Vielzahl von Faktoren, die mit Unterschieden in den Paragenesen zusammenhängen, bestimmt wird: Der LREE-Gehalt wird im besonderen davon bestimmt, ob die LREE-führenden Minerale aus metasomatischen Karbonat- oder aus (metasomatischen oder magmatischen) Silikatschmelzen im Mantel auskristallisierten. Dabei erfolgt die LREE Fraktionierung zu Gunsten der Karbonatschmelzen. Die LREE-Verteilung von Perovskit und Apatit, die aus magmatischen Mantelschmelzen oder -laven kristallisierten, wird vorrangig durch den bevorzugten Einbau der LREE in Perovskit > Apatit > Titanit kontrolliert. Der LREE Zonarbau von Perovskit wird durch die Änderungen der Schmelzstruktur beinflußt: Verstärkte Schmelzpolymerisation führt zu verstärkter MineralLFEE/SchmelzeLREE Fraktionierung in den Perovskiträndern magmatischer Xenolithe, eine Abnahme der Schmelzpolymerisation hingegen resultiert in einer Abreicherung der LREE in den Perovskiträndern. Diese Art der Zonierung wird durch den Wettbewerb von Perovskit mit Apatit um die LREE verstärkt. Perovskit (Kerne/Ränder), der mit Apatit gemeinsam auskristallisierte, ist ärmer an LREE. 37 Fälle, in denenCe nicht nachweisbar war, La und Nd aber in normaler Konzentration auftreten, wurden sowohl in den Xenolithen als auch in den Laven gefunden; und zwar entweder in Kornbereichen oder in ganzen Körnern. Vergleichsweise liegt Ce nur in sechs von zehn Titanitproben unterhalb der Nachweisgrenze. Diese Beobachtungen werden als Hinweise auf erhöhte SauerstoffFugazitäten, bei denen Ce4– aus der Mineralstruktur ausgeschlossen wird, angesehen.Ein Verständnis dieser verschiedenen Prozesse kann zur besseren Interpretation von LREE Gesamtgesteins- und Gesamtmineral-Signaturen in Kamafugiten beitragen.
With 3 Figures 相似文献
996.
Based on four UK Schmidt Telescope (UKST) IIIa-j direct plates which had been digitized by the Automated Plate Measuring System (APM), a detailed identification of the disk galaxies in the Virgo cluster has been carried out. The certain and possible member galaxies are mainly selected from the updated Catalogue of 2096 Galaxies in the Virgo Cluster Area (VCC). The area of this identification covers a 85 square degree region centered on this cluster. As a result, we compiled a new catalogue of 340 certain and possible member disk galaxies, including 85 lenticulars (SO), 136 spirals (S) and 119 irregulars (Irr), where the APM-measured values of the position angle (P.A.) and diameters of 299 disk galaxies are provided. For at least 149 galaxies, the values of the P.A. and diameters are published for the first time.Comparison between the APM-measured P.A. and diameters of galaxies and those given by the Uppsala General Catalog of Galaxies (UGC) demonstrates the reliability of our data. The statistical properties and completeness of this database are also discussed. Compared with the UGC-given P.A. and diameters which were determined by eyes, our data has no selection effect owing to the instrument measurements. Within our searching region, this might be the largest and relatively complete photometric database published so far for investigating the spatial orientation of the spin vectors of galaxies in the Virgo cluster. 相似文献
997.
L1498 is a classic example of a dense cold pre-protostellar core. To study the evolutionary status, the structure, dynamics, and chemical properties of this core we have obtained high spatial and high spectral resolution observations of molecules tracing densities of 10(3)-10(5) cm-3. We observed CCS, NH3, C3H2, and HC7N with NASA's DSN 70 m antennas. We also present large-scale maps of C18O and 13CO observed with the AT&T 7 m antenna. For the high spatial resolution maps of selected regions within the core we used the VLA for CCS at 22 GHz, and the Owens Valley Radio Observatory (OVRO) MMA for CCS at 94 GHz and CS (2-1). The 22 GHz CCS emission marks a high-density [n(H2) > 10(4) cm -3] core, which is elongated with a major axis along the SE-NW direction. NH3 and C3H2 emissions are located inside the boundary of the CCS emission. C18O emission traces a lower density gas extending beyond the CCS boundary. Along the major axis of the dense core, CCS, NH3 and C3H2 emission show evidence of limb brightening. The observations are consistent with a chemically differentiated onion-shell structure for the L1498 core, with NH3 in the inner and CCS in the outer parts of the core. The high angular resolution (9"-12") spectral line maps obtained by combining NASA Goldstone 70 m and VLA data resolve the CCS 22 GHz emission in the southeast and northwest boundaries into arclike enhancements, supporting the picture that CCS emission originates in a shell outside the NH3 emitting region. Interferometric maps of CCS at 94 GHz and CS at 98 GHz show that their emitting regions contain several small-scale dense condensations. We suggest that the differences between the CCS, CS, C3H2, and NH3 emission are caused by a time-dependent effect as the core evolves slowly. We interpret the chemical and physical properties of L1498 in terms of a quasi-static (or slowly contracting) dense core in which the outer envelope is still growing. The growth rate of the core is determined by the density increase in the CCS shell resulting from the accretion of the outer low-density gas traced by C18O. We conclude that L1498 could become unstable to rapid collapse to form a protostar in less than 5 x 10(6) yr. 相似文献
998.
Ohishi M Ishikawa SI Amano T Oka H Irvine WM Dickens JE Ziurys LM Apponi AJ 《The Astrophysical journal》1996,471(1):L61-L64
A new interstellar molecular ion, H2COH+ (protonated formaldehyde), has been detected toward Sgr B2, Orion KL, W51, and possibly in NGC 7538 and DR21(OH). Six transitions were detected in Sgr B2(M). The 1(1,0)-1(0,1) transition was detected in all sources listed above. Searches were also made toward the cold, dark clouds TMC-1 and L134N, Orion (3N, 1E), and a red giant, IRC + 10216, without success. The excitation temperatures of H2COH+ are calculated to be 60-110 K, and the column densities are on the order of 10(12)-10(14) cm-2 in Sgr B2, Orion KL, and W51. The fractional abundance of H2COH+ is on the order of 10(-11) to 10-(9), and the ratio of H2COH+ to H2CO is in the range 0.001-0.5 in these objects. The values in Orion KL seem to be consistent with the "early time" values of recent model calculations by Lee, Bettens, & Herbst, but they appear to be higher than the model values in Sgr B2 and W51 even if we take the large uncertainties of column densities of H2CO into account. We suggest production routes starting from CH3OH may play an important role in the formation of H2COH+. 相似文献
999.
Models of continental crustal magmagenesis commonly invoke theinteraction of mafic mantle-derived magma and continental crustto explain geochemical and petrologic characteristics of crustalvolcanic and plutonic rocks. This interaction and the specificmechanisms of crustal contamination associated with it are poorlyunderstood. An excellent opportunity to study the progressiveeffects of crustal contamination is offered by the compositeplutons of the Alaska Range, a series of nine early Tertiary,multiply intruded, compositionally zoned (Peridotite to granite)plutons. Large initial Sr and Nd isotopic contrasts betweenthe crustal country rock and likely parental magmas allow evaluationof the mechanisms and extents of crustal contamination thataccompanied the crystallization of these ultra-mafic throughgranitic rocks. Three contamination processes are distinguishedin these plutons. The most obvious of these is assimilationof crustal country rock concurrent with magmatic fractionalcrystallization (AFC), as indicated by a general trend towardcrustal-like isotopic signatures with increasing differentiation.Second, many ultramafic and mafic rocks have late-stage phenocrystreaction and orthocumulate textures that suggest interactionwith felsic melt. These rocks also have variable and enrichedisotopic compositions that suggest that this felsic melt wasisotopically enriched and probably derived from crustal countryrock. Partial melt from the flysch country rock may have reactedwith and contaminated these partly crystalline magmas followingthe precipitation and accumulation of the cumulus phenocrystsbut before complete solidification of the magma. This suggeststhat in magmatic mush (especially of ultramafic composition)crystallizing in continental crust, a second distinct processof crustal contamination may be super imposed on AFC or magmamixing involving the main magma body. Finally, nearly all rocks,including mafic and ultramafic rocks, have (87Sr/86Sr)i thatare too high, and (T) Nd that are too low, to represent theexpected isotopic composition of typical depleted mantle. However,gabbro xenoliths with typical depicted-mantle isotopic compositionsare found in the plutons. This situation requires either anadditional enriched mantle component to provide the parentalmagma for these plutons, or some mechanism of crustal contaminationof the parent magma that did not cause significant crystallizationand differentiation of the magma to more felsic compositions.Thermodynamic modeling indicates that assimilation of alkali-andwater-rich partial melt of the metapelite country rock by fractionating,near-liquidus basaltic magma could cause significant contaminationwhile suppressing significant crystallization and differentiation. KEY WORDS: crustal contamination; Alaska Range; isotope geochemistry; zoned plutons; assimilation
*Corresponding author. e-mail: preiners{at}u.washington.edu; fax: (206) 543-3836. 相似文献
1000.
K. St. Seymour V. Tsikouras K. Kotopouli K. Hatzipanayiotou G. Pe-Piper 《Mineralogy and Petrology》1996,56(3-4):251-272
Summary The island of Samothrace, northeastern Aegean Sea, consists of five main geological units: (i) A basement unit consisting of low grade metamorphic rocks (metapelites, marbles, metavolcanic rocks, and a metaconglomerate); (ii) an ophiolitic complex with K-Ar hornblende date of 154 ± 7 and 155 ± 7 Ma; (iii) A granite intrusion with biotite K-Ar dates of 14.5 ± 0.3 and 14.5 ± 0.5 Ma, and a contact metamorphic event dated at 40.9 + 2.2 Ma; (iv) a unit of Cenozoic volcanic rocks: orogenic volcanism apparently occurred in two cycles with Upper Eocene tholeiitic to calc-alkaline volcanic rocks and post-Eocene high-K andesites to trachytes. (v) Quaternary clastic sedimentary rocks which occur around the peripheral parts of the island. The granitic intrusion is predominantly a hornblende-biotite granite, granodiorite or quartz monzonite, with porphyritic variants and mafic enclaves. The pluton is cut by granophyre, aplite and rare granodioritic veins. All lithological units of the Samothrace intrusion show smooth and continuous major element trends and similar chondrite- and Ocean Ridge Granite-normalized incompatible element profiles. ORG-normalized incompatible element contents of Hf, Zr, Sm are explained with fractionation close to the normalizing values Y and Yb contents combined with high K/Yb ratios; Rb and Th are significantly enriched relative to Nb and Ta. In Y-Nb and Rb-SiO2 space most samples of the Samothrace granite, plot in the volcanic arc and the syn-collisional granite fields. In Y + Nb-Rb space they are equally distributed within and transgress these two domains. The geochemical and regional data suggest a subduction or collision environment but biotite mineral data do not support a collisional setting for magma genesis. The Samothrace granite was probaby associated with a post-collisional domain after the closure of the Axios section of the Tethys Ocean.
With 7 Figures 相似文献
Ein Einblick in das Wirken von Mikroplattentektonik in der Tethys—Die Geochemie des Samothrake Granites, Agäisches Meer
Zusammenfassung Die Insel Samothrake in der nordöstlichen Ägäis besteht aus fünf geologischen Haupteinheiten: (i) einem schwach metamorphen Basement (Metapelite, Marmore, Metavulkanite und Metakonglomerate); (ii) einem ophiolithischem Komplex, der mit K-Ar Datierungen an Hornblende ein Alter von 154 ± 7 und 155 ± 7 Ma ergab; (iii) ein granitischer Intrusionskörper mit K-Ar Altern an Biotit von 14.0 ± 0.3 und 14.5 ± 0.5 Ma und einem kontaktmetamorphen Ereignis, das mit 40.9 ± 2.2 Ma datiert ist; (iv) eine Abfolge känozoischer Vulkanite, wobei der orogene Vulkanismus offensichtlich in zwei Zyklen ablief mit tholeiitischen bis kalkalkalischen Vulkaniten im oberen Eozän und high-K Andesiten bis Trachyten im post-Eozän; (v) quartären klastischen Sedimentgesteinen, die im Randbereich der Insel auftreten. Die Granitintrusion setzt sich hauptsächlich aus Hornblende-Biotitgraniten, Granodioriten oder Quarzmonzoniten mit teilweise porphyrischen und mafischen Enklaven enthaltenden Varietäten zusammen. Der Pluton wird von Granophyren, Apliten und seltener von granodioritischen Gängen durchschlagen. Alle lithologischen Einheiten der Samothrake Intrusion zeigen kontinuierliche Hauptelementtrends und ähnliche Chondrit und ORG-normalisierte inkompatible Elementprofile. Die Gehalte an den inkompatiblen Elementen Hf, Zr, Sm sind sehr ähnlich denen von ozeanischen Graniten (ORG). Die niedrigen Y und Yb-Gehalte und die hohen K/Yb Verhältnisse werden durch Fraktionierung erklärt. Rb und Th sind signifikant angereichert im Vergleich zu Nb und Ta. In Y-Nb und Rb-SiO2 Diagrammen plotten die meisten Proben des Samothrake Granites im Feld der vulkanischen Inselbogen- und Synkollisionsgranite. Im Y + Nb-Rb Diagramm zeigt sich eine gleichmäßige und überlappende Verteilung. Die geochemischen und regionalen Daten weisen auf einen Subduktions- oder Kollisionsbereich hin, obwohl die Biotitzusammensetzungen nicht für eine Bildung der Magmen in einem Kollisionsbereich sprechen. Die Bildung des Samothrake Granites steht möglicherweise mit post-Kollisionstektonik nach dem Schließen der Axioszone in der Tethys in Zusammenhang.
With 7 Figures 相似文献