Anisotropy of magnetic susceptibility studies in Tertiary ridge-parallel dykes (Iceland), Tertiary margin-normal Aishihik dykes (Yukon), and Proterozoic Kenora–Kabetogama composite dykes (Minnesota and Ontario)     

John P. Craddock  Bryan C. Kennedy  Avery L. Cook  Melissa S. Pawlisch  Stephen T. Johnston  Mike Jackson 《Tectonophysics》2008,448(1-4):115-124

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Identification and quantification of carbonyl-containing α-pinene ozonolysis products using <Emphasis Type="Italic">O</Emphasis>-<Emphasis Type="Italic">tert</Emphasis>-butylhydroxylamine hydrochloride     

Stephen R. Jackson  Jason E. Ham  Joel C. Harrison  J. R. Wells 《Journal of Atmospheric Chemistry》2017,74(3):325-338

The yields of carbonyl-containing reaction products from the ozonolysis of α-pinene have been investigated using concentrations of ozone found in the indoor environment ([O₃] ≤ 100 ppb). An impinger was used to collect gas-phase oxidation products in water, where the derivatization agent O-tert-butylhydroxylamine hydrochloride (TBOX) and gas chromatography-mass spectrometry were used to identify carbonyl-containing species. Seven carbonyl-containing products were observed. The yield of the primary product, pinonaldehyde was measured to be 76 %. Using cyclohexane as a hydroxyl radical (?OH) scavenger, the yield of pinonaldehyde decreased to 46 %, indicating the influence secondary OH radicals have on α-pinene ozonolysis products. Furthermore, the use of TBOX, a small molecular weight derivatization agent, allowed for the acquisition of the first mass spectral data of oxopinonaldehyde, a tricarbonyl reaction product of α-pinene ozonolysis. The techniques described herein allow for an effective method for the collection and identification of terpene oxidation products in the indoor environment.  相似文献   

Regional magma plumbing and emplacement mechanisms of the Faroe‐Shetland Sill Complex: implications for magma transport and petroleum systems within sedimentary basins          下载免费PDF全文

Nick Schofield  Simon Holford  John Millett  David Brown  David Jolley  Simon R. Passey  Dave Muirhead  Clayton Grove  Craig Magee  Joanne Murray  Malcolm Hole  Christopher A.‐L. Jackson  Carl Stevenson 《Basin Research》2017,29(1):41-63

The movement of magma through the shallow crust and the impact of subsurface sill complexes on the hydrocarbon systems of prospective sedimentary basins has long been an area of interest and debate. Based on 3D seismic reflection and well data, we present a regional analysis of the emplacement and magmatic plumbing system of the Palaeogene Faroe‐Shetland Sill Complex (FSSC), which is intruded into the Mesozoic and Cenozoic sequences of the Faroe‐Shetland Basin (FSB). Identification of magma flow directions through detailed seismic interpretation of approximately 100 sills indicates that the main magma input zones into the FSB were controlled primarily by the NE–SW basin structure that compartmentalise the FSB into its constituent sub‐basins. An analysis of well data shows that potentially up to 88% of sills in the FSSC are <40 m in thickness, and thus below the vertical resolution limit of seismic data at depths at which most sills occur. This resolution limitation suggests that caution needs to be exercised when interpreting magmatic systems from seismic data alone, as a large amount of intrusive material could potentially be missed. The interaction of the FSSC with the petroleum systems of the FSB is not well understood. Given the close association between the FSSC and potential petroleum migration routes into some of the oil/gas fields (e.g. Tormore), the role the intrusions may have played in compartmentalisation of basin fill needs to be taken fully into account to further unlock the future petroleum potential of the FSB.  相似文献   

Below-Ground Processes in Gap Models for Simulating Forest Response to Global Change   总被引：4，自引：0，他引：4  

Stan D. Wullschleger  Robert B. Jackson  William S. Currie  Andrew D. Friend  Yiqi Luo  Florent Mouillot  Yude Pan  Guofan Shao 《Climatic change》2001,51(3-4):449-473

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Distortion of tidal currents and the lateral transfer of salt in a shallow coastal plain estuary (O estuário do Mira, Portugal)     

Jackson O. Blanton  Francisco A. Andrade 《Estuaries and Coasts》2001,24(3):467-480

We describe the tidal circulation of a coastal plain estuary across a flood tide delta located at its entrance. The area connects the downstream portion of the main estuary extending 30–40 km inland to the more complex delta reach that consists of a shallow main channel and a series of smaller side channels. The delta acts as a frictionally dominated zone that modifies the tidal wave from a simple sinusoid to one with ebb currents that accelerate to maximum early in the tidal cycle and last more than one-half of the tidal cycle. Along smaller side channels, the tidal currents favor stronger flood or ebb currents, depending upon the local surrounding morphology. The phase difference between ebb currents in the small channels relative to those in the main channel cause some of the salt to be retained thus reducing the tendency of freshwater discharge to flush salt out of the system. This mechanism of retention differs from the selective withdrawal mechanism described for this estuary in Blanton et al. (2000).  相似文献   

Currents in the high drag environment of a coastal kelp stand off California     

George A. Jackson 《Continental Shelf Research》1997,17(15):1913-1928

The physical environment within a California kelp bed is modified from that of the region by the large drag of the massed plants. The change is greatest for longshore motions, where velocities diminish with distance upcoast of the leading edge of the bed in a manner consistent with the damping expected for coastally-trapped waves. Cross-shore velocity fluctuations are more important for the movement of material between offshore waters and the kelp bed interior. Results suggest that penetration of water for distances of 400 m into the kelp is common. The importance of water motions for ecological processes ranging from enhancing boundary layer transport to kelp blades to moving planktonic larvae implies that size of a kelp bed and position within it are important for the kelp ecosystem.  相似文献   

A Compilation of New and Published Major and Trace Element Data for NIST SRM 610 and NIST SRM 612 Glass Reference Materials   总被引：37，自引：0，他引：37  

Nicholas J.G. Pearce  William T. Perkins  John A. Westgate  Michael P. Gorton  Simon E. Jackson  Clive R. Neal  Simon P. Chenery 《Geostandards and Geoanalytical Research》1997,21(1):115-144

Microanalytical trace element techniques (such as ion probe or laser ablation ICP-MS) are hampered by a lack of well characterized, homogeneous standards. Two silicate glass reference materials produced by National Institute of Standards and Technology (NIST), NIST SRM 610 and NIST SRM 612, have been shown to be homogeneous and are spiked with up to sixty one trace elements at nominal concentrations of 500 μg g-1 and 50 μg g-1 respectively. These samples (supplied as 3 mm wafers) are equivalent to NIST SRM 611 and NIST SRM 613 respectively (which are supplied as 1 mm wafers) and are becoming more widely used as potential microanalytical reference materials. NIST however, only certifies up to eight elements in these glasses. Here we have compiled concentration data from approximately sixty published works for both glasses, and have produced new analyses from our laboratories. Compilations are presented for the matrix composition of these glasses and for fifty eight trace elements. The trace element data includes all available new and published data, and summaries present the overall average and standard deviation, the range, median, geometric mean and a preferred average (which excludes all data outside ± one standard deviation of the overall average). For the elements which have been certified, there is a good agreement between the compiled averages and the NIST data. This compilation is designed to provide useful new working values for these reference materials.  相似文献   

Interatomic potentials for CaCO3 polymorphs (calcite and aragonite), fitted to elastic and vibrational data     

A. Pavese  M. Catti  G. D. Price  R. A. Jackson 《Physics and Chemistry of Minerals》1992,19(2):80-87

Calcite and aragonite have been modeled using rigid-ion, two-body Born-type potentials, supplemented by O-C-O angular terms inside the CO₃ groups. A shell model has also been developed for calcite. Atomic charges, repulsive parameters and force constants have been optimized to reproduce the equilibrium crystal structures, the elastic constants and the Raman and infrared vibrational frequencies. The rigid-ion potential RIM (atomic charges:z _O= -0.995e,z _C = 0.985e,z _Ca = 2.0e) fitted to calcite properties is able to account for those of aragonite as well. Experimental unit-cell edges, elastic constants, internal and lattice frequencies are reproduced with average relative errors of 2.1, 5.5, 2.4, 15.1% for calcite and of 0.2, 19.4, 2.5, 11.8% for aragonite, respectively. The RIM potential is suitable for thermodynamic and phase diagram simulations in the CaCO₃ system, and is discussed and compared to other potentials.  相似文献   

Investigation of Possible Contamination of Shallow Ground Water by Deeply Injected Liquid Industrial Wastes     

Suzanne Lesage  Richard E. Jackson  Mark Priddle  Paul Beck  Ken G. Raven 《Ground Water Monitoring & Remediation》1991,11(1):151-159

The objective of this study was to assess the possible impact of deep well disposal operations, conducted between 1958 and 1974, on the ground water quality in a shallow fresh water aquifer beneath Sarnia, Ontario, Canada. Because of the breakout of formation fluids in Sarnia and Port Huron, Michigan, in the early 1970s, it had been hypothesized that liquid waste from the disposal zone in bedrock had leaked through numerous abandoned oil, gas, and salt wells in the area up to the shallow fresh water aquifer and from there to the surface.
A monitoring well network of 29 5cm (2 inch) diameter piezometers was established in the thin sand and shale aquifer system, which exists between 30 and 70m (100 and 230 feet) below ground surface. In addition, a 300m (1000 foot) deep borehole was drilled and instrumented with a Westbay multilevel casing, which permitted sampling of the disposal zone.
Ground water samples from the shallow monitoring wells and the Westbay multilevel casing were analyzed for volatiles by GC/MS. Those volatile aromatics that were conspicuously present in the deep disposal zone, e.g., ethyl toluenes and trimethyl benzene, were not detected in the shallow monitoring wells. Thus, if contaminants from the disposal zone did indeed migrate to the shallow aquifer, contamination was not widespread and probably consisted mostly of displaced chloride-rich formation waters.  相似文献   

Carbonic fluid inclusions in South Indian granulites: evidence for entrapment during charnockite formation   总被引：1，自引：0，他引：1  

M. Santosh  D. H. Jackson  N. B. W. Harris  D. P. Mattey 《Contributions to Mineralogy and Petrology》1991,108(3):318-330

Field evidence and fluid inclusion studies on South Indian incipient charnockites suggest that charnockite formation occurred during a decompressional brittle regime following the ‘peak’ of metamorphism and regional deformation. The most abundant type of inclusions in quartz and garnet grains in these charnockites contain high-density carbonic fluids, although lower-density fluids occur in younger arrays of inclusions. Discrete fluid inclusion generations optically are observed to decrepitate over well-defined temperature intervals, and quantitative measurements of CO₂ abundance released from these inclusions by stepped thermal decrepitation show up to a four-fold increase (by volume) in the incipient charnockites relative to the adjacent gneisses from which they are derived. Studies based on optical thermometry, visual decrepitation and stepped-heating inclusion release together indicate that entrapment of carbonic fluids coincided with charnockite formation. We confirm that an influx of carbon dioxide-rich fluids is associated with the amphibolite-granulite transition, as recorded by the incipient charnockites, the remnants of which are commonly preserved as the earliest generation of high-density fluid inclusions.  相似文献