Surface phase transformations,surface complexation and solubilities of hydroxyapatite in the absence/presence of Cd(II) and EDTA     

Karin Viipsi  Staffan Sjöberg  Andrey Shchukarev  Kaia Tõnsuaadu 《Applied Geochemistry》2012

The removal of Cd from aqueous solutions by hydroxyapatite (HAP) was investigated with and without EDTA being present. Batch experiments were carried out using synthetic hydroxyapatite with Ca/P 1.57 and a specific surface area of 37.5 m²/g in the pH range 4–9 (25 °C; 0.1 M KNO₃). The surface composition of the solid phases were analysed by X-ray Photoelectron Spectroscopy (XPS). The surface layer of HAP was found to undergo a phase transformation with a (Ca + Cd)/P atomic ratio of 1.4 and the involvement of an ion exchange process (Ca²⁺ ↔ Cd²⁺). The amount of Cd removed from the solution increased with increasing pH, reaching ≈100% at pH 9. In the presence of EDTA Cd removal was reduced due to the formation of [CdEDTA]²⁻ in solution. The solubility of HAP increases in the presence of EDTA at pH values above 5, mainly due to the formation of [CaEDTA]²⁻. In contrast to this, the solubility was found to decrease in the presence of Cd²⁺ and CdEDTA²⁻. Using XPS the formation of a Cd-enriched HAP surface was found, which was interpreted as the formation of a solid solution of the general composition: Ca_8.4-xCd_x(HPO_4)1.6(PO_4)4.4(OH_)0.4${\text{Ca}}_{8.4-x}{\text{Cd}}_x({\text{HPO}}_4{)}_{1.6}({\text{PO}}_4{)}_{4.4}(\text{OH}{)}_{0.4}$.  相似文献   

Temporal trends in dioxins (polychlorinated dibenzo-p-dioxin and dibenzofurans) and dioxin-like polychlorinated biphenyls in Baltic herring (Clupea harengus)     

Aroha Miller  Jenny E. Hedman  Elisabeth Nyberg  Peter Haglund  Ian T. Cousins  Karin Wiberg  Anders Bignert 《Marine pollution bulletin》2013

Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and dioxin-like polychlorinated biphenyl (dl-PCBs) concentrations in Baltic herring (Clupea harengus) have been relatively stable since the mid to late 1990s. It is unclear why concentrations in Baltic herring are not following the observed decreases in other environmental matrices. Here, changes in long-term temporal trends in Baltic herring were examined. A number of biological variables were examined alongside the temporal trends to investigate whether fish biology e.g., growth (length, weight, age), lipid content, reproductive phase or fishing date may provide an explanation for the temporal trends observed.  相似文献   

Modeling the morphodynamic response of tidal embayments to sea-level rise   总被引：1，自引：1，他引：0  

Barend van Maanen  Giovanni Coco  Karin R. Bryan  Carl T. Friedrichs 《Ocean Dynamics》2013,63(11-12):1249-1262

Sea-level rise has a strong influence on tidal systems, and a major focus of climate change effect studies is to predict the future state of these environmental systems. Here, we used a model to simulate the morphological evolution of tidal embayments and to explore their response to a rising sea level. The model was first used to reproduce the formation of channels and intertidal flats under a stable mean water level in an idealised and initially unchannelled tidal basin. A gradual rise in sea level was imposed once a well-developed channel network had formed. Simulations were conducted with different sea-level rise rates and tidal ranges. Sea-level rise forced headward erosion of the tidal channels, driving a landward expansion of the channel network and channel development in the previously non-inundated part of the basin. Simultaneously, an increase in channel drainage width in the lower part of the basin occurred and a decrease in the overall fraction of the basin occupied by channels could be observed. Sea-level rise thus altered important characteristics of the tidal channel network. Some intertidal areas were maintained despite a rising sea level. However, the size, shape, and location of the intertidal areas changed. In addition, sea-level rise affected the exchange of sediment between the different morphological elements. A shift from exporting to importing sediment as well as a reinforcement of the existing sediment export was observed for the simulations performed here. Sediment erosion in the inlet and the offshore transport of sediment was enhanced, resulting in the expansion of the ebb-tidal delta. Our model results further emphasise that tidal embayments can exhibit contrasting responses to sea-level rise.  相似文献   

Quantitative palaeotemperature records inferred from fossil pollen and chironomid assemblages from Lake Gilltjärnen,northern central Sweden     

Karin Antonsson  Stephen J. Brooks  Heikki Sepp  Richard J. Telford  H. John B. Birks 《第四纪科学杂志》2006,21(8):831-841

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Development of habitat models for Nephtys species (Polychaeta: Nephtyidae) in the German Bight (North Sea)     

Karin Meißner  Alexander Darr  Eike Rachor 《Journal of Sea Research》2008,60(4):276-291

The aim of the study was the development of habitat models for Nephtys species (Polychaeta: Nephtyidae). The investigation area was the German Bight, the southeastern part of the North Sea. Models were developed based on field data collected between 2000 and 2006. In addition, data on environmental variables were retrieved from long-term monitoring data sets and from the sediment map by Figge [Figge, K., 1981. Nordsee. Sedimentverteilung in der Deutschen Bucht. Map No. 2900. Publisher: Deutsches Hydrographisches Institut, Hamburg]. The statistical modelling technique used was multivariate adaptive regression splines (MARS). Models were fitted individually for each species. Evaluation of predictive discrimination and predictive accuracy of the developed models was by calculation of the area under the receiver operating curve (AUC) or sensitivity and specificity, respectively. Habitat models with best predictive fit were selected for the presentation of habitat suitability maps.Six Nepthys species were found: Nephtys assimilis, N. caeca, N. cirrosa, N. hombergii, N. incisa and N. longosetosa. N. hombergii was most common whereas N. incisa and N. longosetosa were rare. Habitat preferences varied considerably among the species. For all investigated Nephtys species except N. longosetosa a habitat model could be developed based on four predictor variables. The habitat models with best predictive fit were those for N. cirrosa and N. hombergii. The N. caeca habitat model was of limited predictive accuracy and only accept predictive discrimination. The number of predictors as well as the relative importance of the respective predictors in the model varied among the different species. Direct comparison of most suitable habitats for the different species based on modelling revealed that in the mostly sandy regions parallel to the German coast in water depths up to 20 m an overlap between N. caeca, N. hombergii and N. cirrosa exists. In the deeper central German Bight with mostly fine sands with increased mud contents N. hombergii, N. assimilis and, at least partially and rare in numbers, N. incisa co-occur. It can be concluded that important sediment characteristics like grain size median and mud content as well as water depth and mean salinity are useful parameters to describe the habitat requirements of most Nepthys species in the German Bight. However, additional variables need to be incorporated into such analyses.  相似文献   

Distribution of Bacteria Injected in Body of Giant Black Shrimp,Penaeus Monodon     

郭志勋  KarinvandeBraak  MagrietBotterbloom 《中国海洋湖沼学报》2004,22(2):186-191

Distribution of injected Vibrio anguillarum in body of P,,naeus monodon was studied with immunohistochemical method. Bacteria could be detected throughout the experiment in some individuals; however in lymphoid tissue, gill, heart and haemolymph of all vibrio injected shrimp, the bacteria could be observed only 5 min after injection. The bacteria density in haemolymph, haemolymph of the hepatopancreas and gills decreased with time. In the lymphoid organ and heart, the bacteria density was the highest 48 h after injection, then decreased. Nodules could be formed in the heart, lymphoid organ and injection site.  相似文献   

Compositional variations at ultra-structure length scales in coral skeleton   总被引：1，自引：0，他引：1  

Anders Meibom  Jean-Pierre Cuif  Smail Mostefaoui  Karin L. Meibom 《Geochimica et cosmochimica acta》2008,72(6):1555-1569

Distributions of Mg and Sr in the skeletons of a deep-sea coral (Caryophyllia ambrosia) and a shallow-water, reef-building coral (Pavona clavus) have been obtained with a spatial resolution of 150 nm, using the NanoSIMS ion microprobe at the Muséum National d’Histoire Naturelle in Paris. These trace element analyses focus on the two primary ultra-structural components in the skeleton: centers of calcification (COC) and fibrous aragonite. In fibrous aragonite, the trace element variations are typically on the order of 10% or more, on length scales on the order of 1-10 μm. Sr/Ca and Mg/Ca variations are not correlated. However, Mg/Ca variations in Pavona are strongly correlated with the layered organization of the skeleton.These data allow for a direct comparison of trace element variations in zooxanthellate and non-zooxanthellate corals. In both corals, all trace elements show variations far beyond what can be attributed to variations in the marine environment. Furthermore, the observed trace element variations in the fibrous (bulk) part of the skeletons are not related to the activity of zooxanthellae, but result from other biological activity in the coral organism. To a large degree, this biological forcing is independent of the ambient marine environment, which is essentially constant on the growth timescales considered here.Finally, we discuss the possible detection of a new high-Mg calcium carbonate phase, which appears to be present in both deep-sea and reef-building corals and is neither aragonite nor calcite.  相似文献   

A diatom record of recent environmental change in Lake Duluti, northern Tanzania     

Helena ?berg  Thorbj?rn J. Andersen  Lars-Ove Westerberg  Jan Risberg  Karin Holmgren 《Journal of Paleolimnology》2012,48(2):401-416

Lake Duluti is a small, topographically closed crater lake located on the flanks of Mt Meru, northern Tanzania. Analyses of diatoms in three short sediment cores and four modern samples from Lake Duluti were used to infer past environmental changes. ²¹⁰Pb and ¹³⁷Cs activity profiles combined with AMS ¹⁴C dates provide the chronological framework. Weak agreement between the ²¹⁰Pb and ¹⁴C records, together with dating uncertainty, precludes construction of precise age models. The modern diatom flora, from plankton and three periphytic habitats, is dominated by Aulacoseira ambigua (Grunow) Simonsen, Gomphonema parvulum (Kützing) Grunow and Nitzschia amphibia Grunow. All three cores display similar stratigraphic succession, but the relative ratio of habitats represented by the diatoms varies substantially between cores. Diatoms indicate that the oldest part of the record is characterized by relatively low lake level and swampy vegetation. In the late nineteenth or early twentieth century there was a rapid lake level rise and the swamp turned into an open-water lake. High lake levels have prevailed since that time.  相似文献   

Regional droughts in southern South America   总被引：1，自引：1，他引：0  

J. L. Minetti  W. M. Vargas  A. G. Poblete  L. R. de la Zerda  L. R. Acuña 《Theoretical and Applied Climatology》2010,102(3-4):403-415

From a regional inventory of monthly droughts, which was evaluated in six regions of southern South America, the seasonal occurrence of the phenomenon and its persistence together with the duration of monthly and annual sequences, extreme events, and other statistical estimates of the proposed index have been studied. In a primary analysis, it is possible to observe that regions present different behaviors regarding the duration of dry sequences, with more persistence in the Argentinean continental region. Temporal behaviors of the annual indexes have also been analyzed, in the attempt to determine any aspects of the impact of global warming. Through this analysis, the presence of long favorable tendencies regarding precipitations or the inverse of droughts occurrence are confirmed for the eastern Andes Mountains in Argentina (ARG) with its five sub-regions (Northwest Argentina-NWA, Northeast Argentina-NEA, Humid Pampa-HP, West-Centre Provinces-WC and Patagonia-PAT, and the inverse over the central region of Chile (CHI). Other climatic great-scale changes are interdecadales variations and variances explained according to ENSO.  相似文献   

The 11-year solar cycle, the Sun's rotation, and the middle stratosphere in winter. Part II: Response of planetary waves     

Boris Soukharev  Karin Labitzke   《Journal of Atmospheric and Solar》2001,63(18):344

The effect of the 11-year solar cycle on the response of planetary wavenumbers 1 and 2 at 10 and 30 hPa in winter to solar activity oscillations on the time scale of the Sun's rotation (27.2 day) is discussed in terms of statistical spectral analysis. The three oscillations studied are the 27.2 d (period of the Sun's rotation), 25.3 d (periodicity caused by modulation of the 27.2 d stratospheric response by annual atmospheric variation), and 54.4 d (doubled period of the solar rotation). A significant effect of the 11-year solar cycle is found for the 54.4 d periodicity in planetary wavenumber 1, and for the 27.2 and 25.3 d periodicities in planetary wavenumber 2. The effect of the 11-year solar cycle is expressed in the evident differences between the amplitudes of responses of planetary waves at maximum and minimum of the solar cycle: the amplitudes are much larger at high than at low solar activity. The 11-year modulation of planetary wave activity is most pronounced at mid-latitudes, mainly at 40–60°N, where the observed variability of planetary waves is large. The results obtained are in good agreement with results of the recent modeling study by Shindell et al. (Science 284 (1999) 305).  相似文献