Governance,enabling frameworks and policies for the transfer and diffusion of low carbon and climate adaptation technologies in developing countries     

James Haselip  Ulrich Elmer Hansen  Daniel Puig  Sara Trærup  Subash Dhar 《Climatic change》2015,131(3):363-370

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Erratum to: Quantifying and monetizing potential climate change policy impacts on terrestrial ecosystem carbon storage and wildfires in the United States     

David Mills  Russell Jones  Karen Carney  Alexis St. Juliana  Richard Ready  Allison Crimmins  Jeremy Martinich  Kate Shouse  Benjamin DeAngelo  Erwan Monier 《Climatic change》2015,131(1):179-181

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The importance of defining chemical potentials,substitution mechanisms and solubility in trace element diffusion studies: the case of Zr and Hf in olivine     

Michael?C.?JollandsEmail author  Hugh?St.?C.?O’Neill  J?rg?Hermann 《Contributions to Mineralogy and Petrology》2014,168(3):1055

The diffusion, substitution mechanism and solubility limits of Zr and Hf in synthetic forsterite (Mg₂SiO₄) and San Carlos olivine (Mg_0.9Fe_0.1)₂SiO₄ have been investigated between 1,200 and 1,500 °C as a function of the chemical potentials of the components in the system MgO(FeO)–SiO₂–ZrO₂(HfO₂). The effect of oxygen fugacity and crystallographic orientation were also investigated. The solubilities of Zr in forsterite are highest and diffusion fastest when the coexisting three-phase source assemblage includes ZrSiO₄ (zircon) or HfSiO₄ (hafnon), and lower and slower, respectively, when the source assemblage includes MgO (periclase). This indicates that Zr and Hf substitute on the octahedral sites in olivine, charge balanced by magnesium vacancies. Diffusion is anisotropic, with rates along the crystal axes increasing in the order a < b < c. The generalized diffusion relationship as a function of chemical activity (as \(a_{{{\text{SiO}}_{2} }}\)), orientation and temperature is: \(logD_{\text{Zr}} = \frac{1}{4}loga_{{{\text{SiO}}_{2} }} + logD_{0} - \left( {\frac{{368 \pm 17\;{\text{kJ}}\;{\text{mol}}^{ - 1} }}{{2.303\;{\text{RT}}}}} \right)\) where the values of log D ₀ are ?3.8(±0.5), ?3.4(±0.5) and ?3.1(±0.5) along the a, b and c axes, respectively. Most experiments were conducted in air (fO₂ = 10^?0.68 bars), but one at fO₂ = 10^?11.2 bars at 1,400 °C shows no resolvable effect of oxygen fugacity on Zr diffusion. Hf is slightly more soluble in olivine than Zr, but diffuses slightly slower. Diffusivities of Zr in experiments in San Carlos olivine at 1,400 °C, fO₂ = 10^?6.6 bars are similar to those in forsterite at the same conditions, showing that the controls on diffusivities are adequately captured by the simple system (nominally iron-free) experiments. Diffusivities are in good agreement with those measured by Spandler and O’Neill (Contrib Miner Petrol 159:791–818, 2010) in San Carlos olivine using silicate melt as the source at 1,300 °C, and fall within the range of most measurements of Fe–Mg inter-diffusion in olivine at this temperature. Forsterite–melt partitioning experiments in the CaO–MgO–Al₂O₃–SiO₂–ZrO₂/HfO₂ show that the interface concentrations from the diffusion experiments represent true equilibrium solubilities. Another test of internal consistency is that the ratios of the interface concentrations between experiments buffered by Mg₂SiO₄ + Mg₂Si₂O₆ + ZrSiO₄ or Mg₂SiO₄ + ZrSiO₄ + ZrO₂ (high silica activity) to those buffered by Mg₂SiO₄ + MgO + ZrO₂ (low silica activity) agree well with the ratios calculated from thermodynamic data. This study highlights the importance of buffering chemical potentials in diffusion experiments to provide constraints on the interface diffusant concentrations and hence validate the assumption of interface equilibrium.  相似文献   

Thermodynamic properties of chlorite and berthierine derived from calorimetric measurements     

Philippe Blanc  Hélène Gailhanou  Jacques Rogez  Georges Mikaelian  Hitoshi Kawaji  Fabienne Warmont  Stéphane Gaboreau  Sylvain Grangeon  Jean-Marc Grenèche  Philippe Vieillard  Claire I. Fialips  Eric Giffaut  Eric C. Gaucher  F. Claret 《Physics and Chemistry of Minerals》2014,41(8):603-615

In the context of the deep waste disposal, we have investigated the respective stabilities of two iron-bearing clay minerals: berthierine ISGS from Illinois [USA; (Al_0.975FeIII_0.182FeII_1.422Mg_0.157Li_0.035Mn_0.002)(Si_1.332Al_0.668)O₅(OH)₄] and chlorite CCa-2 from Flagstaff Hill, California [USA; (Si_2.633Al_1.367)(Al_1.116FeIII_0.215Mg_2.952FeII_1.712Mn_0.012Ca_0.011)O₁₀(OH)₈]. For berthierine, the complete thermodynamic dataset was determined at 1 bar and from 2 to 310 K, using calorimetric methods. The standard enthalpies of formation were obtained by solution-reaction calorimetry at 298.15 K, and the heat capacities were measured by heat-pulse calorimetry. For chlorite, the standard enthalpy of formation is measured by solution-reaction calorimetry at 298.15 K. This is completing the entropy and heat capacity obtained previously by Gailhanou et al. (Geochim Cosmochim Acta 73:4738–4749, 2009) between 2 and 520 K, by using low-temperature adiabatic calorimetry and differential scanning calorimetry. For both minerals, the standard entropies and the Gibbs free energies of formation at 298.15 K were then calculated. An assessment of the measured properties could be carried out with respect to literature data. Eventually, the thermodynamic dataset allowed realizing theoretical calculations concerning the berthierine to chlorite transition. The latter showed that, from a thermodynamic viewpoint, the main factor controlling this transition is probably the composition of the berthierine and chlorite minerals and the nature of the secondary minerals rather than temperature.  相似文献   

Tsunami hazard assessment of Canada     

Lucinda J. Leonard  Garry C. Rogers  Stéphane Mazzotti 《Natural Hazards》2014,70(1):237-274

We present a preliminary probabilistic tsunami hazard assessment of Canadian coastlines from local and far-field, earthquake, and large submarine landslide sources. Analyses involve published historical, palaeotsunami and palaeoseismic data, modelling, and empirical relations between fault area, earthquake magnitude, and tsunami run-up. The cumulative estimated tsunami hazard for potentially damaging run-up (≥1.5 m) of the outer Pacific coastline is ~40–80 % in 50 years, respectively one and two orders of magnitude greater than the outer Atlantic (~1–15 %) and the Arctic (<1 %). For larger run-up with significant damage potential (≥3 m), Pacific hazard is ~10–30 % in 50 years, again much larger than both the Atlantic (~1–5 %) and Arctic (<1 %). For outer Pacific coastlines, the ≥1.5 m run-up hazard is dominated by far-field subduction zones, but the probability of run-up ≥3 m is highest for local megathrust sources, particularly the Cascadia subduction zone; thrust sources further north are also significant, as illustrated by the 2012 Haida Gwaii event. For Juan de Fuca and Georgia Straits, the Cascadia megathrust dominates the hazard at both levels. Tsunami hazard on the Atlantic coastline is dominated by poorly constrained far-field subduction sources; a lesser hazard is posed by near-field continental slope failures similar to the 1929 Grand Banks event. Tsunami hazard on the Arctic coastline is poorly constrained, but is likely dominated by continental slope failures; a hypothetical earthquake source beneath the Mackenzie delta requires further study. We highlight areas susceptible to locally damaging landslide-generated tsunamis, but do not quantify the hazard.  相似文献   

Web information monitoring and crowdsourcing for promoting and enhancing the Algerian geoheritage     

Oussama Annad  Abderrahmane Bendaoud  Stéphane Goria 《Arabian Journal of Geosciences》2017,10(13):276

The documentation and management of information concerning geological sites are important activities in all the steps of the geoheritage conservation and its day-to-day management. This documentation is mostly available on the web; it includes varied types of data such as pictures, scientific publications, news, and blog articles. In order to ensure the efficient management of the geoheritage resources, scientists and people involved in the promotion of the geoheritage and geotourism should have access to this documentation and kept updated of the most recent and relevant information. In this study, we propose the development of a web information monitoring system that automates the search and the collection of different types of documents related to the Algerian geosites available on the web. It is designed as a tool that continuously browses the web using the most popular search engines and then disseminates the results to the users through periodic newsletters. This proposed system will also serve to chronologically organize all the pictures of geosites gathered from the web and thus in order to study the evolution of Algerian geosites over time. For this purpose, we use one of the crowdsourcing methods in the field of knowledge management that is games with a purpose (GWAP). The idea here is to involve people in sorting pictures of geosites through a playful interface. The results obtained show that this system is a valuable tool that can assist geoscientists and decision makers in enhancing the geoheritage.  相似文献   

When plenty is not enough: an assessment of the white stumpnose (Rhabdosargus globiceps) fishery of Saldanha Bay,South Africa     

D Parker  SE Kerwath  TF Næsje  CJ Arendse  FJ Keulder-Stenevik  K Hutchings 《African Journal of Marine Science》2017,39(2):153-166

White stumpnose Rhabdosargus globiceps is the main target of the linefishery in Saldanha Bay. Increased fishing pressure over the last three decades, particularly by the recreational sector, has led to concerns regarding sustainability of the local white stumpnose stock. The fishery was exceptionally productive between 2006 and 2008, with an estimated annual catch of 141.2 tonnes (t). Only 3% of boat outings surveyed were commercial boats targeting white stumpnose, yet this sector accounted for 39.3 t (31%) of the average annual catch. The recreational boat sector accounted for most of the catch (70.0 t), and the recreational shore sector the least (31.9 t). Commercial boat catch per unit effort (CPUE; 3.7 fish angler^–1 h^–1) was more than 10 times that of recreational boats (0.3 fish angler^–1 h^–1). White stumpnose catch length-frequency differed significantly (p < 0.01) between the fishing sectors, with the commercial sector retaining larger fish (34.7 cm [SD 5.9]) than the recreational boat (33.9 cm [SD 5.9]) and shore (30.4 cm [SD 5.8]) sectors. A decline in commercial CPUE (2000–2015) of approximately 40% and a concomitant severe decline (>95%) in survey data for juvenile white stumpnose CPUE (2007–2016) indicate that the current rate of exploitation is not sustainable. Recovery of the white stumpnose stock will require a decrease in fishing mortality. Possible management regulations include sector-specific effort limitations, extending the ‘no take’ marine protected area, reducing the recreational-sector bag limit to 5 fish person^–1 day^–1, implementing a commercial-sector bag limit, and increasing the minimum size limit to 30 cm TL.  相似文献   

DIVA - An interferometric minisatellite for astrometry and photometry     

U. Bastian  S. Rserg  E. H  H. Mandel  W. Seifert  St. Wagner  A. Quirrenbach  C. Schalinski  E. Schilbach  A. Wicenec 《Astronomische Nachrichten》1996,317(4):281-288

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