A study of lignin degradation in leaf and needle litter using C-labelled tetramethylammonium hydroxide (TMAH) thermochemolysis: Comparison with CuO oxidation and van Soest methods     

Thimo Klotzbücher  Timothy R. FilleyKlaus Kaiser  Karsten Kalbitz 《Organic Geochemistry》2011,42(10):1271-1278

We studied the degradation of lignin in leaf and needle litter of ash, beech, maple, pine and spruce using ¹³C-labelled tetramethylammonium hydroxide (¹³C TMAH) thermochemolysis. Samples were allowed to decompose for 27 months in litter bags at a German spruce forest site, resulting in a range of mass loss from 26% (beech) to 58% (ash). In contrast to conventional unlabelled TMAH thermochemolysis, ¹³C-labelling allows thermochemolysis products from lignin, demethylated lignin and other polyphenolic litter compounds (e.g. tannins) to be distinguished. Proxies for lignin degradation (phenol yield; acid/aldehyde ratio of products) changed considerably upon correction for the contribution of non-lignin sources to the thermochemolysis products. Using the corrected values, we found increasing acid/aldehyde values as well as decreasing or constant yield of lignin derived phenols normalised to litter carbon, suggesting pronounced lignin degradation by wood-rotting fungi. No indication for build up of demethylated lignin through the action of brown rot fungi on ring methoxyls was found. The results were compared with those of other analytical techniques applied in previous studies. Like ¹³C-TMAH thermochemolysis, CuO oxidation showed increasing lignin oxidation (acid/aldehyde ratio) and no/little enrichment of lignin derived phenols in the litter. Molecular lignin degradation patterns did not match those from analysis of total acid unhydrolysable residues (AURs). In particular, the long assumed selective preservation of lignin during the first months of litter decomposition, based on AUR analysis, was not supported by results from the CuO and ¹³C TMAH methods.  相似文献   

Eocene to Miocene geometry of the West Antarctic Rift System     

R. D. Müller  K. Gohl  S. C. Cande  A. Goncharov  A. V. Golynsky 《Australian Journal of Earth Sciences》2013,60(8):1033-1045

Tectonic models for the Late Cretaceous/Tertiary evolution of the West Antarctic Rift System range from hundreds of kilometres of extension to negligible strike-slip displacement and are based on a variety of observations, as well as kinematic and geodynamic models. Most data constraining these models originate from the Ross Sea/Adare Trough area and the Transantarctic Mountains. We use a new Antarctic continental crustal-thinning grid, combined with a revised plate-kinematic model based on East Antarctic – Australia – Pacific – West Antarctic plate circuit closure, to trace the geometry and extensional style of the Eocene – Oligocene West Antarctic Rift from the Ross Sea to the South Shetland Trench. The combined data suggest that from chron 21 (48 Ma) to chron 8 (26 Ma), the West Antarctic Rift System was characterised by extension in the west to dextral strike-slip in the east, where it was connected to the Pacific – Phoenix – East Antarctic triple junction via the Byrd Subglacial Basin and the Bentley Subglacial Trench, interpreted as pullapart basins. Seismic-reflection profiles crossing the De Gerlache Gravity Anomaly, a tectonic scar from a former spreading ridge jump in the Bellingshausen Sea, suggest Late Tertiary reactivation in a dextral strike-slip mode. This is supported by seismic-reflection profiles crossing the De Gerlache Gravity Anomaly in the Bellingshausen Sea, which show incised narrow sediment troughs and vertical faults indicating strike-slip movement along a north – south direction. Using pre-48 Ma plate circuit closure, we test the hypothesis that the Lord Howe Rise was attached to the Pacific Plate during the opening of the Tasman Sea. We show that this plate geometry may be plausible at least between 74 and 48 Ma, but further work especially on Australian – Antarctic relative plate motions is required to test this hypothesis.  相似文献   

On-line fluorometry of multiple reactive and conservative tracers in streams   总被引：1，自引：0，他引：1  

Dennis Lemke  Pierre-André Schnegg  Marc Schwientek  Karsten Osenbrück  Olaf A. Cirpka 《Environmental Earth Sciences》2013,69(2):349-358

Performing tracer tests using artificial tracer compounds is a common practice to characterize natural streams regarding their (reactive) transport properties. Recently, the fluorescent compound resazurin was introduced as a reactive stream tracer to quantify hyporheic exchange and metabolic activity of streams. This tracer, together with its reaction product resorufin and a conservative tracer (in our case fluorescein), provides additional information about transport properties of the stream and its hyporheic zone and can therefore overcome restrictions that are commonly affiliated with the use of conservative tracers alone. However, all previously published studies using this tracer system were based on manual sampling of the water. This usually limits the number of measurements and thus the achievable temporal resolution, and potentially endangers data quality due to inadequate handling of samples. In this paper, a modified version of the GGUN-FL30 on-line fluorometer is presented in which the optics have been modified to allow measuring the concentrations of all three tracers simultaneously at intervals of 10 s. Experiments under controlled and natural conditions showed that the performance of the on-line fluorometer regarding tracer separation efficiency and practical detection limits is comparable to a high-performance laboratory spectrofluorometer. Furthermore, suggestions are given on how to correct tracer signal fluctuations caused by temporal changes in temperature and pH that might occur during a field tracer test.  相似文献   

A climate model intercomparison at the dynamics level     

Karsten Steinhaeuser  Anastasios A. Tsonis 《Climate Dynamics》2014,42(5-6):1665-1670

Until now, climate model intercomparison has focused primarily on annual and global averages of various quantities or on specific components, not on how well the general dynamics in the models compare to each other. In order to address how well models agree when it comes to the dynamics they generate, we have adopted a new approach based on climate networks. We have considered 28 pre-industrial control runs as well as 70 20th-century forced runs from 23 climate models and have constructed networks for the 500 hPa, surface air temperature (SAT), sea level pressure (SLP), and precipitation fields for each run. We then employed a widely used algorithm to derive the community structure in these networks. Communities separate “nodes” in the network sharing similar dynamics. It has been shown that these communities, or sub-systems, in the climate system are associated with major climate modes and physics of the atmosphere (Tsonis AA, Swanson KL, Wang G, J Clim 21: 2990–3001 in 2008; Tsonis AA, Wang G, Swanson KL, Rodrigues F, da Fontura Costa L, Clim Dyn, 37: 933–940 in 2011; Steinhaeuser K, Ganguly AR, Chawla NV, Clim Dyn 39: 889–895 in 2012). Once the community structure for all runs is derived, we use a pattern matching statistic to obtain a measure of how well any two models agree with each other. We find that, with the possible exception of the 500 hPa field, consistency for the SAT, SLP, and precipitation fields is questionable. More importantly, none of the models comes close to the community structure of the actual observations (reality). This is a significant finding especially for the temperature and precipitation fields, as these are the fields widely used to produce future projections in time and in space.  相似文献   

Numerical study on wave dynamics and wave-induced bed erosion characteristics in Potter Cove, Antarctica   总被引：1，自引：0，他引：1  

Chai Heng Lim  Karsten Lettmann  Jörg-Olaf Wolff 《Ocean Dynamics》2013,63(11-12):1151-1174

Wave generation, propagation, and transformation from deep ocean over complex bathymetric terrains to coastal waters around Potter Cove (King George Island, South Shetland Islands, Antarctica) have been simulated for an austral summer month using the Simulating Waves Nearshore (SWAN) wave model. This study aims to examine and understand the wave patterns, energy fluxes, and dissipations in Potter Cove. Bed shear stress due to waves is also calculated to provide a general insight on the bed sediment erosion characteristics in Potter Cove.A nesting approach has been implemented from an oceanic scale to a high-resolution coastal scale around Potter Cove. The results of the simulations were compared with buoy observations obtained from the National Data Buoy Center, the WAVEWATCH III model results, and GlobWave altimeter data. The quality of the modelling results has been assessed using two statistical parameters, namely the Willmott’s index of agreement D and the bias index. Under various wave conditions, the significant wave heights at the inner cove were found to be about 40–50 % smaller than the ones near the mouth of Potter Cove. The wave power in Potter Cove is generally low. The spatial distributions of the wave-induced bed shear stress and active energy dissipation were found to be following the pattern of the bathymetry, and waves were identified as a potential major driving force for bed sediment erosion in Potter Cove, especially in shallow water regions. This study also gives some results on global ocean applications of SWAN.  相似文献   

Numerical study on wave dynamics and wave-induced bed erosion characteristics in Potter Cove,Antarctica     

Lim  Chai Heng  Lettmann  Karsten  Wolff  J&#;rg-Olaf 《Ocean Dynamics》2013,63(11):1151-1174

Wave generation, propagation, and transformation from deep ocean over complex bathymetric terrains to coastal waters around Potter Cove (King George Island, South Shetland Islands, Antarctica) have been simulated for an austral summer month using the Simulating Waves Nearshore (SWAN) wave model. This study aims to examine and understand the wave patterns, energy fluxes, and dissipations in Potter Cove. Bed shear stress due to waves is also calculated to provide a general insight on the bed sediment erosion characteristics in Potter Cove.A nesting approach has been implemented from an oceanic scale to a high-resolution coastal scale around Potter Cove. The results of the simulations were compared with buoy observations obtained from the National Data Buoy Center, the WAVEWATCH III model results, and GlobWave altimeter data. The quality of the modelling results has been assessed using two statistical parameters, namely the Willmott’s index of agreement D and the bias index. Under various wave conditions, the significant wave heights at the inner cove were found to be about 40–50 % smaller than the ones near the mouth of Potter Cove. The wave power in Potter Cove is generally low. The spatial distributions of the wave-induced bed shear stress and active energy dissipation were found to be following the pattern of the bathymetry, and waves were identified as a potential major driving force for bed sediment erosion in Potter Cove, especially in shallow water regions. This study also gives some results on global ocean applications of SWAN.

  相似文献   

U‐Pb zircon dating of metaigneous rocks from the Nordbreen Nappe of Svalbard’s Ny‐Friesland suggests their affinity to Northeast Greenland     

Jakub Bazarnik  Jaros&#x;aw Majka  William C. McClelland  Justin V. Strauss  Karolina Komi&#x;ska  Karsten Piepjohn  Synnve Elvevold  Zbigniew Czupyt  Tom&#x; Miku&#x; 《地学学报》2019,31(6):518-526

SIMS U‐Pb zircon dating of metaigneous rocks of the Nordbreen Nappe from the West Ny‐Friesland terrane (Eastern Basement Province of Svalbard) yields crystallization ages of 1,761 ± 4 Ma for a felsic metatuff and 1,373 ± 4 Ma for a metagabbro dyke. The Palaeoproterozoic age of the metatuff is similar to previously obtained ages for various felsic rocks from the study area, whereas the Mesoproterozoic age of the metagabbro has not been thus far documented on Svalbard. However, a similar age pattern has been reported from Northeast Greenland. Therefore, we conclude that the West Ny‐Friesland terrane can be correlated with age equivalent units of Northeast Greenland. We also explore similarities and dissimilarities between the study area and other terranes of Svalbard and speculate on regional‐scale correlations. Together, the presented new ages provide critical piercing points in palaeogeographic reconstructions of the relatively poorly understood circum‐Arctic region.  相似文献   

Comment on “The Keisarhjelmen detachment records Silurian–Devonian extensional collapse in Northern Svalbard”          下载免费PDF全文

Winfried Dallmann  Karsten Piepjohn 《地学学报》2018,30(4):319-321

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The effects of the 2004 tsunami on a coastal aquifer in Sri Lanka   总被引：1，自引：0，他引：1  

Vithanage M  Engesgaard P  Villholth KG  Jensen KH 《Ground water》2012,50(5):704-714

On December 26, 2004, the earthquake off the southern coast of Sumatra in the Indian Ocean generated far-reaching tsunami waves, resulting in severe disruption of the coastal aquifers in many countries of the region. The objective of this study was to examine the impact of the tsunami on groundwater in coastal areas. Field investigations on the east coast of Sri Lanka were carried out along a transect located perpendicular to the coastline on a 2.4 km wide sand stretch bounded by the sea and a lagoon. Measurements of groundwater table elevation and electrical conductivity (EC) of the groundwater were carried out monthly from October 2005 to August 2007. The aquifer system and tsunami saltwater intrusion were modeled using the variable-density flow and solute transport code HST3D to understand the tsunami plume behavior and estimate the aquifer recovery time. EC values reduced as a result of the monsoonal rainfall following the tsunami with a decline in reduction rate during the dry season. The upper part of the saturated zone (down to 2.5 m) returned to freshwater conditions (EC < 1000 μS/cm) 1 to 1.5 years after the tsunami, according to field observations. On the basis of model simulations, it may take more than 15 years for the entire aquifer (down to 28 m) to recover completely, although the top 6 m of the aquifer may become fresh in about 5 years.  相似文献   

Simulating Martian regolith in the laboratory   总被引：1，自引：0，他引：1  

Karsten Seiferlin  Pascale Ehrenfreund  Kurt Gunderson  Günter Kargl  Jonathan Peter Merrison 《Planetary and Space Science》2008,56(15):2009-2025

Regolith and dust cover the surfaces of the Solar Systems solid bodies, and thus constitute the visible surface of these objects. The topmost layers also interact with space or the atmosphere in the case of Mars, Venus and Titan. Surface probes have been proposed, studied and flown to some of these worlds. Landers and some of the mechanisms they carry, e.g. sampling devices, drills and subsurface probes (“moles”) will interact with the porous surface layer. The absence of true extraterrestrial test materials in ample quantities restricts experiments to the use of soil or regolith analogue materials. Several standardized soil simulants have been developed and produced and are commonly used for a variety of laboratory experiments. In this paper we intend to give an overview of some of the most important soil simulants, and describe experiments (penetrometry, thermal conductivity, aeolian transport, goniometry, spectroscopy and exobiology) made in various European laboratory facilities.  相似文献