Syngenetic inclusions of yimengite in diamond from Sese kimberlite (Zimbabwe) — evidence for metasomatic conditions of growth     

G.P. Bulanova  E. Muchemwa  D.G. Pearson  B.J. Griffin  S.P. Kelley  S. Klemme  C.B. Smith 《Lithos》2004,77(1-4):181-192

Syngenetic inclusions of yimengite K (Cr, Ti, Mg, Fe, Al)₁₂O₁₉, a potassium member of the magnetoplumbite mineral group, have been recorded in an octahedral macrodiamond from the Sese kimberlite (50 km south of Masvingo, Zimbabwe). One yimengite inclusion carries lamellae of chromite suggesting peridotitic diamond paragenesis. The diamond and inclusions were studied in situ in a plate polished parallel to (011). Cathodoluminescence (CL) imaging has shown blue colour and octahedral zonation of the diamond, lack of cracks and the location of five yimengites in different growth zones. Nitrogen (N) contents (at. ppm) in the diamond determined by Fourier transform infrared spectroscopy (FTIR) steadily decrease from 576 (core) to 146 (rim). N aggregation (%1aB) is correspondingly 40% in the core and 30% in the rim. Hydrogen (H) content is high in the core, moderate in the intermediate and very high in the rim zones. Four yimengites were dated using the laser ⁴⁰Ar/³⁹Ar method. Three inclusions yielded total gas ages that agree with, or are younger than, or within error of, the Sese kimberlite eruption age (538±11 Ma) but may be compromised by gas loss. One inclusion, with the highest tapped interface gas yield, gave a total gas age of 892±21 Ma that is a likely minimum yimengite age. Time–T °C constraints from N aggregation systematics give a range of possible ages from kimberlite eruption date back to Archean and do not resolve the variable results of the ⁴⁰Ar/³⁹Ar dating. Compared with the published chemistry of yimengite from kimberlites, inclusions from the Sese diamond contain higher Al, Mg, and Sr and have lower concentration of Fe³⁺. The chondrite-normalised REE pattern of the yimengite shows enrichment in LREE and depletion in HREE, but LREE/HREE fractionations are lower than for lindsleyite–mathiasite series mantle titanates and rather similar to the REE concentrations in kimberlite and lamproite rocks. It is suggested that Sese yimengite formed in the lithospheric mantle from metasomatism of chrome spinel by a fluid rich in Ti, K, Ba and LREE.  相似文献   

植被和气候对阿拉斯加和加拿大北部北极苔原地区多年冻土活动层厚度的影响   总被引：2，自引：4，他引：2  

Alexia M. Kelley  Howard E. Epstein  Donald A. Walker 《冰川冻土》2004,26(Z1):269-274

The active layer is the top layer of permafrost soils that thaws during the summer season due to increased ambient temperatures and solar radiation inputs. This layer is important because almost all biological activity takes place there luring the summer. The depth of active layer thaw is influenced by climatic conditions. Vegetation has also been found to have a strong impact on active layer thaw, because it can intercept incoming radiation, thereby insulating the soil from ambient conditions. In order to look at the role of vegetation and climate on active layer thaw, we measured thaw depth and the Normalized Difference Vegetation Index (NDVI; a proxy for aboveground plant biomass) along a latitudinal temperature gradient in arctic Alaska and Canada. At each site several measurements of thaw and NDVI were taken in areas with high amounts of vegetation and areas with little to no vegetation. Results show that the warmest regions, which had the greatest levels of NDVI, had relatively shallow thaw depths, and the coldest regions, which had the lowest levels of NDVI, also had relatively shallow thaw depths. The intermediate regions, which had moderate levels of NDVI and air temperature, had the greatest depth of thaw. These results indicate that temperature and vegetation interact to control the depth of the active layer across a range of arctic ecosystems. By developing a relationship to explain thaw depth through NDVI and temperature or latitude, the possibility exists to extrapolate thaw depth over large scales via remote sensing applications.  相似文献   

Ar and K partitioning between clinopyroxene and silicate melt to 8 GPa     

E.M. Chamorro  R.A. Brooker  J.-A. Wartho  B.J. WoodS.P. Kelley  J.D. Blundy 《Geochimica et cosmochimica acta》2002,66(3):507-519

The relative incompatibility of Ar and K are fundamental parameters in understanding the degassing history of the mantle. Clinopyroxene is the main host for K in most of the upper mantle, playing an important role in controlling the K/Ar ratio of residual mantle and the subsequent time-integrated evolution of ⁴⁰Ar/³⁶Ar ratios. Clinopyroxene also contributes to the bulk Ar partition coefficient that controls the Ar degassing rate during mantle melting. The partitioning of Ar and K between clinopyroxene and quenched silicate melt has been experimentally determined from 1 to 8 GPa for the bulk compositions Ab₈₀Di₂₀ (80 mol% albite-20 mol% diopside) and Ab₂₀Di₈₀ with an ultraviolet laser ablation microprobe (UVLAMP) technique for Ar analysis and the ion microprobe for K. Data for Kr (UVLAMP) and Rb (ion probe) have also been determined to evaluate the role of crystal lattice sites in controlling partitioning. By excluding crystal analyses that show evidence of glass contamination, we find relatively constant Ar partition coefficients (D_Ar) of 2.6 × 10⁻⁴ to 3.9 × 10⁻⁴ for the Ab₈₀Di₂₀ system at pressures from 2 to 8 GPa. In the Ab₂₀Di₈₀ system, D_Ar shows similar low values of 7.0 × 10⁻⁵ and 3.0 × 10⁻⁴ at 1 to 3 GPa. All these values are several orders of magnitude lower than previous measurements on separated crystal-glass pairs.D_K is 10 to 50 times greater than D_Rb for all experiments, and both elements follow parallel trends with increasing pressure, although these trends are significantly different in each system studied. The D_K values for clinopyroxene are at least an order of magnitude greater than D_Ar under all conditions investigated here, but D_Ar appears to show more consistent behavior between the two systems than K or Rb. The partitioning behavior of K and Rb can be explained in terms of combined pressure, temperature, and crystal chemistry effects that result in changes for the size of the clinopyroxene M2 site. In the Ab₂₀Di₈₀ system, where clinopyroxene is diopside rich at all pressures, D_K and D_Rb increase with pressure (and temperature) in an analogous fashion to the well-documented behavior of Na. For the Ab₈₀Di₂₀ system, the jadeite content of the clinopyroxene increases from 22 to 75 mol% with pressure resulting in a contraction of the M2 site. This has the effect of discriminating against the large K⁺ and Rb⁺ ions, thereby countering the effect of increasing pressure. As a consequence D_K and D_Rb do not increase with pressure in this system.In contrast to the alkalis (Na, K, and Rb), D_Kr values are similar to D_Ar despite a large difference in atomic radius. This lack of discrimination (and the constant D_Ar over a range of crystal compositions) is also consistent with incorporation of these heavier noble gases at crystal lattice sites and a predicted consequence of their neutrality or “zero charge.” Combined with published D_Ar values for olivine, our results confirm that magma generation is an efficient mechanism for the removal of Ar from the uppermost 200 km of the mantle, and that K/Ar ratios in the residuum are controlled by the amount of clinopyroxene. Generally, Ar is more compatible than K during mantle melting because D_Ar for olivine is similar to D_K for clinopyroxene. As a result, residual mantle that has experienced variable amounts of melt extraction may show considerable variability in time-integrated ³⁶Ar/⁴⁰Ar.  相似文献   

ESC and KAIT observations of the transitional Type Ia SN 2004eo     

A. Pastorello  P. A. Mazzali  G. Pignata  S. Benetti  E. Cappellaro  A. V. Filippenko  W. Li  W. P. S. Meikle  A. A. Arkharov  G. Blanc  F. Bufano  A. Derekas  M. Dolci  N. Elias-Rosa  R. J. Foley  M. Ganeshalingam  A. Harutyunyan  L. L. Kiss  R. Kotak  V. M. Larionov  J. R. Lucey  N. Napoleone  H. Navasardyan  F. Patat  J. Rich  S. D. Ryder  M. Salvo  B. P. Schmidt  V. Stanishev  P. Székely  S. Taubenberger  S. Temporin  M. Turatto  W. Hillebrandt 《Monthly notices of the Royal Astronomical Society》2007,377(4):1531-1552

  相似文献   

Theory and operation of the split langmuir probe     

E.A. Bering  M.C. Kelley  F.S. Mozer  U.V. Fahleson 《Planetary and Space Science》1973,21(11):1983-2001

An instrument, the split Langmuir probe, has been developed to make in situ measurements of current density and plasma bulk flow. The split Langmuir probe consists of two conducting elements that are separated by a thin insulator that shield each other over a 2π solid angle, and that are simultaneously swept from negative to positive potentials with respect to the plasma. By measuring the current to each plate and the difference current between plates, information can be obtained on the plasma's current density, bulk flow, electron temperature, and density. The instrument was successfully test flown from Fort Churchill on 2 August 1968, with results in reasonable agreement with those from another experiment on the same rocket. Sources of error indicated by these results include plate area differences, plate work function differences, input resistor differences, and probe wake effects. The error signal in the difference current data due to plate work function differences rose to a sharp maximum at plasma potential, which served the useful purpose of precisely marking plasma potential. Possible changes in probe geometry, sweep rate, and telemetry designed to reduce these errors are discussed.  相似文献   

Identification of an E3 ubiquitin-protein ligase in the softshell clam (Mya arenaria).     

M L Kelley  R J Van Beneden 《Marine environmental research》2000,50(1-5):289-293

Softshell clams (Mya arenaria) were exposed to dioxin in controlled laboratory experiments in order to study their molecular response to dioxin exposure. A complementary DNA (cDNA) fragment with sequence similarity to E3 ubiquitin-protein ligase appeared to be upregulated in dioxin-exposed clams compared to controls. E3 covalently ligates ubiquitin onto a protein, targeting it for degradation. Our findings suggest that the ubiquitin-mediated proteolytic pathway in the softshell clam may be activated by dioxin exposure. Because the clam E3-predicted amino acid sequence is most similar to a specific vertebrate E3 protein (E6-AP), we hypothesize that dioxin may stimulate ubiquitin-mediated degradation of cell-cycle regulatory proteins, such as the tumor suppressor p53, which promotes cell proliferation. This pathway has been observed in human cervical cancer. Partial cDNA sequence of the clam E3 has been identified using the differential display polymerase chain reaction (ddPCR) and RACE (Rapid Amplification of cDNA Ends) PCR; the full-length sequence is currently being determined. Discovering the molecular mechanism(s) stimulated by dioxin exposure in this invertebrate model may contribute to a better understanding of the effects of dioxin on marine organisms.  相似文献   

Overview of the Late Cretaceous Biota of the western São Paulo State,Brazil, Bauru Group     

Carlos Roberto A. Candeiro  Thomas Rich 《Journal of South American Earth Sciences》2010,29(2):346-353

The Turonian–Maastrichtian beds of the Bauru Group, western São Paulo State (Brazil), have yielded a diverse biota. The nine species of mesoecrocodilians are all mesosuchians. There is a single frog, a Neubatrachia. The vertebrates include, four types of fishes, a neobatrachian frog, an anilioid snake, two lizard, six species of podocnemid turtles, nine species of mesosuchian mesoecrocodilians three theropods, two birds, five titanosaurid sauropods, and one mammalian. The invertebrates include one cyclo, one cyclophoroid and eight pulmonates. Plants are represented by only two carophyte species. The biota from western São Paulo State is one the most diverse of the Late Cretaceous in Brazil. The biota from this area confirms that Bauru Group was connected to Patagonia and other Gondwanan areas during the Late Cretaceous.  相似文献   

More than a century of bathymetric observations and present-day shallow sediment characterization in Belfast Bay, Maine, USA: implications for pockmark field longevity   总被引：5，自引：4，他引：1  

Laura L. Brothers  Joseph T. Kelley  Daniel F. Belknap  Walter A. Barnhardt  Brian D. Andrews  Melissa Landon Maynard 《Geo-Marine Letters》2011,31(4):237-248

Mechanisms and timescales responsible for pockmark formation and maintenance remain uncertain, especially in areas lacking extensive thermogenic fluid deposits (e.g., previously glaciated estuaries). This study characterizes seafloor activity in the Belfast Bay, Maine nearshore pockmark field using (1) three swath bathymetry datasets collected between 1999 and 2008, complemented by analyses of shallow box-core samples for radionuclide activity and undrained shear strength, and (2) historical bathymetric data (report and smooth sheets from 1872, 1947, 1948). In addition, because repeat swath bathymetry surveys are an emerging data source, we present a selected literature review of recent studies using such datasets for seafloor change analysis. This study is the first to apply the method to a pockmark field, and characterizes macro-scale (>5 m) evolution of tens of square kilometers of highly irregular seafloor. Presence/absence analysis yielded no change in pockmark frequency or distribution over a 9-year period (1999–2008). In that time pockmarks did not detectably enlarge, truncate, elongate, or combine. Historical data indicate that pockmark chains already existed in the 19th century. Despite the lack of macroscopic changes in the field, near-bed undrained shear-strength values of less than 7 kPa and scattered downcore ¹³⁷Cs signatures indicate a highly disturbed setting. Integrating these findings with independent geophysical and geochemical observations made in the pockmark field, it can be concluded that (1) large-scale sediment resuspension and dispersion related to pockmark formation and failure do not occur frequently within this field, and (2) pockmarks can persevere in a dynamic estuarine setting that exhibits minimal modern fluid venting. Although pockmarks are conventionally thought to be long-lived features maintained by a combination of fluid venting and minimal sediment accumulation, this suggests that other mechanisms may be equally active in maintaining such irregular seafloor morphology. One such mechanism could be upwelling within pockmarks induced by near-bed currents.  相似文献   

On the diversity of diversity; is there still a poace for small area classification?     

Rich Harris 《Area》2001,33(3):329-336

  相似文献   

Baseline concentrations of total mercury and methylmercury in salmon returning via the Bering Sea (1999-2000).     

X Zhang  A S Naidu  J J Kelley  S C Jewett  D Dasher  L K Duffy 《Marine pollution bulletin》2001,42(10):993-997

  相似文献