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101.
The purpose of this paper is to report on some intensity measurements of the Fe xiii lines at 10 747 Å and 10 798 Å made during the total eclipse of 12 November, 1966. Infrared spectra were taken of the solar corona at a dispersion of 90 Å per mm, using an RCA image converter and spectrograph aboard the NASA CV 990 aircraft off the coast of southern Brazil. The spectra have been reduced to equivalent width in terms of the coronal continuum and values derived for different points in the corona.The observed equivalent widths of the lines lie in the range 10 to 30 Å for the 10 747 line and 5 to 12 Å for the 10 798 line. The ratio of these equivalent widths is found to vary from 2.3 in the inner corona to 6 at a point 1.36 solar radii from the center of the Sun.The above results are discussed in terms of the excitation mechanisms involved in producing the lines. In particular, the results are compared with the recent theoretical calculations of Chevalier and Lambert, who are the first to include the effects of proton collisions in the excitation of the 3p 2 3 P levels of Fexiii. Our observations are consistent with an electron density of 4 × 108 in the inner corona; a value which compares favorably with those derived by other observers from the strength of the K continuum. These are, to our knowledge, the first eclipse observations of the infrared Fe xiii lines which indicate that proton collisions are important in the excitation of the coronal lines. The coronal abundance of iron is estimated from the equivalent width of the 10 747 line, and in common with other observers we find an overabundance as compared to the photospheric abundance by a factor of 10.  相似文献   
102.
The solution to the problem of the motion of the Moon relative to spatial irregularities in the interplanetary magnetic field is found. The lunar electrical conductivity is modeled by a two-layer conductivity profile. For the interaction of the Moon with the corotating sector structure of the interplanetary magnetic field it is found that the magnetic field in the lunar shell is the superposition of an oscillatory uniform field, an oscillatory dipole field and anoscillatory field that is toroidal about the axis of the motional electric field. With various lunar conductivity models and the theory of this paper, lunar surface magnetometer data can be quantitatively interpreted to yield information on the conductivity and consequently the temperature of the lunar core.Presently visiting the Max-Planck-Institut für Physik und Astrophysik, München, Germany.  相似文献   
103.
Monosaccharides were determined in waters and sediment pore waters from a wide variety of environments and locations. Desalting was performed by electrodialysis and concentrated extracts were analyzed by two forms of liquid chromatography. At least 12 sugars were identified. Glucose and fructose were the dominant monosaccharides in nearly all samples examined. Analyses of over 150 seawater and sediment pore water samples showed that fructose is highly significantly correlated (>0.99) with glucose concentrations. Laboratory kinetic experiments on the epimerization reaction, glucose ? fructose, in sterilized natural seawater in the dark, yielded a forward rate constant, k1, of 1.2 × 10?5 h?1 at 25°C and 1.6 × 10?7 h?1 at 2°C. The approximate time required to attain equilibrium at 25°C was 1.1 y and at 2°C, 15.4 y; the measured equilibrium constant was in the range 0.3–0.4. The actual ratio of fructose to glucose in natural water samples was usually in the range 1.0–1.4/l, independent of the total monosaccharide concentrations, which varied in the samples by a factor of ~100. Several possible explanations for the apparent discrepancy in the determined and found ratios are discussed: the presence of universal, as yet, undiscovered major biological sources for fructose in marine environments; preferential utilization of glucose; preferential incorporation of fructose into or onto inorganic colloids; and preferential formation of fructose-transition metal ion associations.  相似文献   
104.
We compared total mercury (THg) concentrations in the fur of northern fur seals (Callorhinus ursinus) from the depleted Pribilof Islands population with those of both declining and thriving populations of Steller sea lions (Eumetopias jubatus) from Prince William Sound (PWS) and Southeast Alaska (SEA), respectively. Relatively low wet weight concentrations (ranges) of THg were detected in the fur of Steller sea lion (SSL) pups (0.90-3.14 microg/g) and juveniles (0.56-6.75 microg/g) from both areas in 1998 and 2000 compared to northern fur seal (NFS) pups (3.15-8.14 microg/g) in 2000. The mean concentration +/- SD for SSLs sampled were 1.46 +/- 0.64 microg/g for pups (n = 22) and 2.74 +/- 2.89 microg/g for juveniles (n = 6). Analyses indicated higher THg concentrations from SSL pups from PWS compared to the SEA. Mean +/- SD. THg in the NFS pups was 4.90 +/- 1.42 microg/g (n = 34) and for post-partum dams was 7.84 +/- 1.78 microg/g (n = 12).  相似文献   
105.
The effect of No. 2 fuel oil on the biomass production of the salt marsh plant, Spartina alterniflora, was studied in a greenhouse dose-response experiment. S. alterniflora were transplanted into soil with 10 dosage levels of No. 2 fuel oil ranging from 0 to 456 mg g(-1) dry soil. Three months after transplantation, values for plant biomass, stem density, and shoot height decreased significantly with increasing fuel oil level in a dose-response fashion. Evapo-transpiration rates were correlated with the total biomass response. Relative to the control, a significant decrease in total (above- plus below-ground) plant biomass was observed at concentrations above 57 mg g(-1) dry soil. Within the 3-month experimental period, detrimental effects on below-ground biomass accumulation and bioluminescence of the marine bacterium Viberio fisheri in the Microtox Solid Phase Test were observed at oil concentrations >29 mg g(-1) dry soil, suggesting that biological effects of oil within the sediment matrix may be more pronounced than on above-ground biomass, requiring a dosage 228 mg g(-1) dry soil to elicit a significant detrimental effect. Hence, measurements of oil effects with biological end-points based solely on above-ground responses may underestimate the potential impacts of petroleum hydrocarbon spills, especially when the oil has penetrated the soil. While S. alterniflora was proved to be relatively tolerant to the No. 2 fuel oil spills, its effectiveness in phytoremediation operations may be limited at fuel oil levels 228 mg g(-1) dry soil, as both plant growth and microbial activity may be constrained.  相似文献   
106.
We report on observations of a large eruptive event associated with a flare that occurred on 27 September 1998 made with the Richard B. Dunn Solar Telescope at Sacramento Peak Observatory (several wave bands including off-line-center H), in soft and hard X-rays (GOES and BATSE), and in several TRACE wave bands (including Feix/x 171 Å, Fexii 195 Å, and Civ 1550 Å). The flare initiation is signaled by two H foot-point brightenings which are closely followed by a hard X-ray burst and a subsequent gradual increase in other wavelengths. The flare light curves show a complicated, three-component structure which includes two minor maxima before the main GOES class C5.2 peak after which there is a characteristic exponential decline. During the initial stages, a large spray event is observed within seconds of the hard X-ray burst which can be directly associated with a two-ribbon flare in H. The emission returns to pre-flare levels after about 35 min, by which time a set of bright post-flare loops have begun to form at temperatures of about 1.0–1.5 MK. Part of the flare plasma also intrudes into the penumbra of a large sunspot, generally a characteristic of very powerful flares, but the flare importance in GOES soft X-rays is in fact relatively modest. Much of the energy appears to be in the form of a second ejection which is observed in optical and ultraviolet bands, traveling out via several magnetic flux tubes from the main flare site (about 60° from Sun center) to beyond the limb.  相似文献   
107.
108.
Current research on bioremediation of uranium-contaminated groundwater focuses on supplying indigenous metal-reducing bacteria with the appropriate metabolic requirements to induce microbiological reduction of soluble uranium(VI) to poorly soluble uranium(IV). Recent studies of uranium(VI) bioreduction in the presence of environmentally relevant levels of calcium revealed limited and slowed uranium(VI) reduction and the formation of a Ca-UO2-CO3 complex. However, the stoichiometry of the complex is poorly defined and may be complicated by the presence of a Na-UO2-CO3 complex. Such a complex might exist even at high calcium concentrations, as some UO2-CO3 complexes will still be present. The number of calcium and/or sodium atoms coordinated to a uranyl carbonate complex will determine the net charge of the complex. Such a change in aqueous speciation of uranium(VI) in calcareous groundwater may affect the fate and transport properties of uranium. In this paper, we present the results from X-ray absorption fine structure (XAFS) measurements of a series of solutions containing 50 μM uranium(VI) and 30 mM sodium bicarbonate, with various calcium concentrations of 0-5 mM. Use of the data series reduces the uncertainty in the number of calcium atoms bound to the UO2-CO3 complex to approximately 0.6 and enables spectroscopic identification of the Na-UO2-CO3 complex. At nearly neutral pH values, the numbers of sodium and calcium atoms bound to the uranyl triscarbonate species are found to depend on the calcium concentration, as predicted by speciation calculations.  相似文献   
109.
Lavas from Klyuchevskoy and Bezymianny volcanoes, Kamchatka, appear to show a link between the extent of partial melting in their mantle source region and the subsequent degree of fractionation suffered by the magmas during passage through the crust. This fractionation may have occurred on timescales significantly less than 1000 years if observed 226Ra excesses largely reflect variable residual porosity in the source melting region. Unlike most arc lavas, those with the highest MgO contents and Ba/Th ratios have the lowest 226Ra excess. Forward models suggest that those portions of the source which had undergone the greatest addition of U by fluids from the subducting plate also underwent the greatest extents of partial melting at the highest residual porosity. At Kluchevskoy, a change from eruption of high-MgO to high-Al2O3 basaltic andesites around 1945 is reflected in an increase in size of 226Ra excess which seems to require a simultaneous decrease in residual porosity and suggests a rapid changes in the melting regime. The eruption of andesites at Bezyminanny, simultaneous with the eruption of basaltic andesites at Klyuchevskoy, further suggests that different degree melts produced at differing residual porosity can be formed and extracted from the melt region at the same time. Thus, the melting processes beneath Klyuchevskoy and Bezyminanny are demonstrably complex. They have clearly been influenced by both fluid addition from the subducting plate and extension and decompression beneath the Central Kamchatka Depression. Finally, the 210Pb data are, with one or two exceptions, in equilibrium with 226Ra, suggesting that there was restricted relative magma-gas movement in this highly productive magmatic system.  相似文献   
110.
Severe droughts in the middle-12th and late-13th centuries appear to have affected Anasazi (pre-Columbian Native American) populations. During the first drought most of the great houses in the central San Juan Basin were vacated; the second drought resulted in the abandonment of the Four Corners region. During the first drought, villages may not have been completely abandoned. The multi-year drought periods probably were characterized by reductions in both winter and summer precipitation. Maize is dependent on winter precipitation for its germination and initial growth and on summer (monsoonal) precipitation for its continued growth. Reductions in precipitation are hypothesized to have resulted in low yields of maize, the dietary staple of the Anasazi. A comparison of historic climate data and tree-ring-based reconstructions of precipitation in the Four Corners region with tree-ring-based reconstructions of the Pacific Decadal Oscillation (PDO) and the Atlantic Multidecadal Oscillation (AMO) indicate that severe and persistent drought in the Four Corners region occurs when the PDO is negative and the AMO is positive. Historic climate data from the greater San Juan Basin indicate that a negative PDO is characterized by reductions in both water-year and summer precipitation, reinforcing the concept that at least some multi-year droughts involved weakening of the summer monsoon with attendant decreases in the yields of maize.  相似文献   
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