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71.
Cavernous weathering (tafoni development) occurs on coastal slopes in greenschist bedrock at elevations up to 40 m above sea level. The freshly weathered surfaces of the cavern interiors are irregular in morphology, discordant to major rock structure, formed by substantially weakened rock and associated with granular weathering debris. The weathering debris contains soluble elements in proportions similar to those present in seawater, and the penetration of elements associated with sea salts into the weathering surface to estimated depths of at least 0·1–0·2 m is indicated by the presence of chlorine. Scanning electron microscopy and microprobe analyses suggest that rock breakdown occurs principally through limited chemical weathering at grain boundaries. The mechanism for the emplacement of marine salts within sheltered rock surfaces in the tafoni is postulated to be a combination of dry deposition under turbulent atmospheric conditions and wetting by coastal fog.  相似文献   
72.
The structure, crystal chemistry, and microstructure of disordered and ordered Mg-cordierites synthesized in a bismuth oxide flux system have been studied by a combination of x-ray and neutron powder diffraction and quantitative x-ray microanalysis using analytical electron microscopy. Microchemical data obtained on Bi-flux cordierites using energy-dispersive x-ray analysis is interpreted through comparison with data collected on stoichiometric Mg2Al4Si5O18 glass and α- and β-cordierite samples synthesized by subsolidus crystallization of the glass. Bi-flux cordierites crystallize in both the hexagonal and orthorhombic polymorphs and contain 5 to 10 at% occupancy of bismuth on the C1 and C2 channel sites. The microstructure of Bi-flux α-cordierite is characterized by the existence of local domains of disordered cordierite solid solutions with variable composition and significant vacancy concentrations on the octahedral site. The β-cordierites have a more homogeneous microstructure but are still Al-deficient, Si-rich solid solutions.  相似文献   
73.
The Oklahoma Geological Survey has developed several maps and reports for preliminary screening of the state of Oklahoma to identify areas that are generally acceptable or unacceptable for disposal of a wide variety of waste materials. These maps and reports focus on the geologic and hydrogeologic parameters that must be evaluated in the screening process. One map (and report) shows the outcrop distribution of 35 thick shale or clay units that are generally suitable for use as host rocks for surface disposal of wastes. A second map shows the distribution of unconsolidated alluvial and terrace-deposit aquifers, and a third map shows the distribution and hydrologic character of bedrock aquifers and their recharge areas. These latter two maps show the areas in the state where special attention must be exercised in permitting storage or disposal of waste materials that could degrade the quality of groundwater. State regulatory agencies and industry are using these maps and reports in preliminary screening of the state to identify potential disposal sites. These maps in no way replace the need for site-specific investigations to prove (or disprove) the adequacy of a site to safely contain waste materials.  相似文献   
74.
The Southern Oscillation is a major component in the interannual variations of global climate. The Oregon State University global climate model, with a dynamically interactive upper ocean, reproduces in qualitatively correct fashion some of the major characteristics of the Southern Oscillation. This model simulates the observed anti-correlation of annually averaged sea-level pressure (SLP) between the eastern Pacific and the Indonesian region, the primary atmospheric signal of the Southern Oscillation. In the composite of the simulated warm events positive sea-surface temperature (SST) anomalies expand eastward towards South America from the tropical western Pacific during the first half of the calendar year. The SST anomalies develop in conjunction with eastward mixed layer current anomalies in the tropical Pacific. In the late summer and early fall anomalously warm water near South America develops and moves westward to merge with the central Pacific anomalies. This lagged development in the eastern Pacific is analogous to the evolution of the 1982/83 and 1986/87 El Ninos. The temperature of the thermocline layer also increases, with the slope of the equatorial Pacific thermocline decreasing in response to the relaxation of the surface forcing. Enhanced precipitation occurs in the mid-Pacific while in the Indian and Australian monsoon regions a deficit occurs. The peak of the warm phase occurs in late northern fall/early winter, somewhat earlier than during observed El Ninos. The cold phase of the Southern Oscillation, enhancement of the zonal circulation, evolves in a fashion similar to the warm phase with the signs of the anomalies reversed, similar to observations. Occurrence of Southern Oscillation in this coarse resolution GCM indicates that high resolution ocean waves do not play a crucial role in the generation of this phenomenon as suggested by Pacific basin models. These results also show that ocean-atmosphere global climate models are useful tools for investigation of time dependent changes on the interannual timescale in addition to their hitherto accepted use for studying equilibrium properties of climate.  相似文献   
75.
76.
A new form of equation of state is described with application to carbon dioxide from 215 K to T>2000 K and from zero pressure to more than 105 bar (10 GPa). The equation was calibrated using properties predicted by existing formulations at low to moderate PT conditions, original experimental PVT data at higher pressures, corresponding states comparisons at higher temperatures and using shock compression data at still higher PTs. Extensive comparisons illustrating the correlation of our new EOS with available phase equilibria and volumetric data are provided. Fugacities of carbon dioxide at high pressures and temperatures predicted using our EOS are in agreement with mineral equilibria calculated from internally consistent thermodynamic data for minerals.  相似文献   
77.
Dacitic lavas and ignimbrites were examined from seven localities that span the entire 700 km width of the mid- to late Cenozoic magmatic arc of northwestern Mexico and adjacent west Texas. These rocks have remarkably similar REE patterns that are parallel in the heavy REE and have modest negative Eu anomalies. Samples from three localities including Baja California, the Sierra Madre Occidental, and the Chihuahuan Basin and Range have initial 87Sr/86Sr between 0.7044 and 0.7050 and Nd near 0.0±1.0. These dacites are isotopically similar to associated basalts, and they show no systematic isotopic variation that is correlated with age or composition of the basement. There is no evidence that magmas parental to these dacites interacted significantly with continental crust. Samples form three other localites in the Basin and Range vary in initial 87Sr/86Sr from 0.7051 to 0.7070 and Nd from about -1 to –2. The composition of these rocks reflects contamination of the parental magmas by relatively small amounts of Precambrian crust. Collectively, the dacites of this study show much less isotopic variation than do Mesozoic granitoids (Farmer and DePaolo 1983) and late Cenozoic olivine tholeiites (Hart 1985) from similar transects of the western United States. The distinctive source region for the magmas parental to the Mexican dacites was relatively uniform isotopically, but it was enriched in LIL and HFS elements beneath the eastern Basin and Range.  相似文献   
78.
79.
Three areas located in northern Arkansas, U.S.A., representing differing host rock and mineralization, were selected to investigate the usefulness of hydrogeochemical exploration for Mississippi Valley-type Pb-Zn mineralization. Despite the geologic differences among the areas, there were no great differences in groundwater chemistry and threshold values. Anomalous Pb concentrations, and also anomalous Zn concentrations to a lesser extent, are useful in detecting the Pb-Zn mineralized areas; however, specific deposits could not be located. Because of the low threshold values (about 20 μg/1) for Pb and Zn, spring water must be utilized in order to avoid plumbing contamination.  相似文献   
80.
A two-year trawling and gill-netting study of vegetated and unvegetated bottoms near Parson’s Island, Maryland and near the mouth of the York River, Virginia was carried out to assess the nursery function of submerged vegetation for populations of fishes and decapod crustaceans in the Chesapeake Bay. Results revealed that vegetated bottoms supported substantially larger numbers of decapods, but not fishes, than unvegetated substrates. The lower Bay grassbed was an important nursery area for juvenile blue crabs, although neither of the grassbeds functioned as a nursery for commercially or recreationally valuable fishes. Our results suggest that: (1) further decreases in lower Bay Seagrass biomass would result in reduced numbers of adult blue crabs, but should not substantially affect populations of valuable fish species; (2) additional decreases in Upper Bay submerged vegetation should not produce dramatic change in the population sizes of either adult blue crabs or fishes.  相似文献   
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