Investigating the response of biotite to impact metamorphism: Examples from the Steen River impact structure,Canada          下载免费PDF全文

E. L. Walton  T. G. Sharp  J. Hu  O. Tschauner 《Meteoritics & planetary science》2018,53(1):75-92

Impact metamorphic effects from quartz and feldspar and to a lesser extent olivine and pyroxene have been studied in detail. Comparatively, studies documenting shock effects in other minerals, such as double chain inosilicates, phyllosilicates, carbonates, and sulfates, are lacking. In this study, we investigate impact metamorphism recorded in crystalline basement rocks from the Steen River impact structure (SRIS), a 25 km diameter complex crater in NW Alberta, Canada. An array of advanced analytical techniques was used to characterize the breakdown of biotite in two distinct settings: along the margins of localized regions of shock melting and within granitic target rocks entrained as clasts in a breccia. In response to elevated temperature gradients along shock vein margins, biotite transformed at high pressure to an almandine-Ca/Fe majorite-rich garnet with a density of 4.2 g cm⁻³. The shock-produced garnets are poikilitic, with oxide and silicate glass inclusions. Areas interstitial to garnets are vesiculated, in support of models for the formation of shock veins via oscillatory slip, with deformation continuing during pressure release. Biotite within granitic clasts entrained within the hot breccia matrix thermally decomposed at ambient pressure to produce a fine-grained mineral assemblage of orthopyroxene + sanidine + titanomagnetite. These minerals are aligned to the (001) cleavage plane of the original crystal. In this and previous work, the transformation of an inosilicate (pargasite) and a phyllosilicate (biotite) to form garnet, an easily identifiable, robust mineral, has been documented. We contend that in deeply eroded astroblemes, high-pressure minerals that form within or in the environs of shock veins may serve as one of the possibly few surviving indicators of impact metamorphism.  相似文献   

A Laboratory-Testing-Based Study on the Strength,Deformability, and Dilatancy of Carbonate Rocks at Low Confinement     

G. Walton  J. Arzúa  L. R. Alejano  M. S. Diederichs 《Rock Mechanics and Rock Engineering》2015,48(3):941-958

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Impact of cold air surges on rainfall variability in the Sahel and wet African tropics: a multi-scale analysis     

Edward K. Vizy  Kerry H. Cook 《Climate Dynamics》2014,43(3-4):1057-1081

Satellite-derived rainfall estimates and the ERA-Interim reanalysis are used to better understand cold air surge/precipitation interactions and to identify the implications for rainfall variability in the Sahel and tropical Africa on synoptic to seasonal timescales. At the synoptic timescale, cold air surges are associated with cold conditions over the eastern Sahara throughout the year due to the eastward passage of surface low pressure systems over the Mediterranean and the subsequent ridging over northern Africa. Rainfall decreases over central and eastern Africa approximately 4–5 days after the cold air first arrives in northeastern Africa. These precipitation anomalies persist for 4 or more days. At the seasonal timescale, a significant relationship between eastern Saharan low-level temperatures and rainfall in the Sahel and tropical Africa is identified, with colder conditions associated with reduced convection on the northern flank of the primary convergence zone, and vice versa. During boreal winter, the anomalous rainfall occurs over tropical Africa (0°N–8°N). During the summer, rainfall anomalies associated with cold air surges occur over the Sahel (10°N–16°N). These relationships are mediated by anomalous anticyclonic flow over northwestern Africa and western Europe. The analysis shows that cold air surges are significantly associated with summertime cooling over the Sahara, but less so during the winter.  相似文献   

How well are daily intense rainfall events captured by current climate models over Africa?     

Julien Crétat  Edward K. Vizy  Kerry H. Cook 《Climate Dynamics》2014,42(9-10):2691-2711

The ability of state-of-the-art climate models to capture the mean spatial and temporal characteristics of daily intense rainfall events over Africa is evaluated by analyzing regional climate model (RCM) simulations at 90- and 30-km along with output from four atmospheric general circulation models (AGCMs) and coupled atmosphere–ocean general circulation models (AOGCMs) of the Climate Model Intercomparison Project 5. Daily intense rainfall events are extracted at grid point scale using a 95th percentile threshold approach applied to all rainy days (i.e., daily rainfall ≥1 mm day^?1) over the 1998–2008 period for which two satellite-derived precipitation products are available. Both RCM simulations provide similar results. They accurately capture the spatial and temporal characteristics of intense events, while they tend to overestimate their number and underestimate their intensity. The skill of AGCMs and AOGCMs is generally similar over the African continent and similar to previous global climate model generations. The majority of the AGCMs and AOGCMs greatly overestimate the frequency of intense events, particularly in the tropics, generally fail at simulating the observed intensity, and systematically overestimate their spatial coverage. The RCM performs at least as well as the most accurate global climate model, demonstrating a clear added value to general circulation model simulations and the usefulness of regional modeling for investigating the physics leading to intense events and their change under global warming.  相似文献   

Equilibrium modeling of U(VI) speciation in high carbonate groundwaters: Model error and propagation of uncertainty     

Janet J. Leavitt  Kerry J. Howe  Stephen E. Cabaniss 《Applied Geochemistry》2011,26(12):2019-2026

Remediation of U-contaminated sites relies upon thermodynamic speciation calculations to predict U(VI) movement in the subsurface. However, reliability and applicability of geochemical speciation and reactive transport models may be limited by determinate (model) errors and random (uncertainty) errors in the equilibrium speciation calculations. This study examines propagated uncertainty in two types of subsurface calculations: I. Dissolved U(VI) speciation based on measured analytical constraints and solution phase equilibria and II. Overall U(VI) speciation which combined the dissolved phase equilibria with previously published adsorption reactions. Three levels of uncertainty, instrumental uncertainty, temporal variation and spatial variation across a site, were investigated using first-derivative sensitivity calculations and Monte Carlo simulations. Dissolved speciation calculations were robust, with minimal amplification of uncertainty and normal output distributions. The most critical analytical constraints in the dissolved system are pH, DIC, total U and total Ca, with some effect from dissolved . When considering adsorption equilibria, calculations were robust with respect to adsorbed U(VI) concentration prediction, but bimodal distributions of dissolved U(VI) concentrations were observed in simulations with background levels of total U(VI) and higher (spatial and temporal variability) estimates of input uncertainty. Consequently, sorption model predictions of dissolved U(VI) may not be robust with respect these higher levels of uncertainty.  相似文献   

Identification of probable groundwater paths in the Amargosa Desert vicinity     

Omar Al-Qudah  Arturo Woocay  John Walton 《Applied Geochemistry》2011,26(4):565-574

In this study, the hydrogeochemical program PHREEQC was used to determine the chemical speciation and mineral saturation indices (SIs) of groundwater in the vicinity of the proposed high-level nuclear waste repository at Yucca Mountain, Nevada (USA). In turn, these data were used to interpret the origin and recharge mode of groundwater, to elucidate the mechanisms of flow and transport, and to determine potential sources of groundwater contamination. PHREEQC was run to determine aqueous dissolved species and minerals that would be in equilibrium with the study area’s groundwater. Selected major ions, associated SI, F⁻ and Ca/Na ion exchange were then examined using the multivariate statistical methods of principal component factor analysis and k-means cluster analysis. Analysis of dissolved ion concentrations, SIs, and Ca/Na ion exchange allows simultaneous consideration of arithmetic (raw concentrations) and logarithmic (SI, ion exchange) variables that describe the hydrochemical system and, therefore, can provide further insight into the system’s behavior. The analysis indicates that the dominant processes and reactions responsible for the hydrochemical evolution in the system are (1) evaporative concentration prior to infiltration, (2) carbonate equilibrium, (3) silicate weathering reactions, (4) limited mixing with saline water, (5) dissolution/precipitation of calcite, dolomite and fluorite, and (6) ion exchange. Principal component factor analysis and k-means cluster analysis of factor scores allow the reduction of dimensions describing the system and the identification of hydrogeochemical facies and the processes that defined and govern their evolution.Statistical analysis results indicate that the northern, west face and southern Yucca Mountain groundwater is fresh water with low concentrations of Ca²⁺, Mg²⁺, Cl⁻, Ca²⁺/(Na⁺)², and CaF₂. The Fortymile Wash groundwater is dilute. The carbonate signature is shown in the Ash Meadows and Death Valley waters with high fluorite SI. Finally, the Crater Flat, Stripped Hills, and Skeleton Hills are dominated by Ca/Na ion exchange, Mg and Ca. The hydrochemical and statistical analyses showed three main groundwater signatures or hydrochemical processes indicating groundwater evolution, potential flowpaths, and recharge areas. The flowpaths are the trace of the Amargosa River, the trace of Fortymile Wash, and its convergence with the Amargosa River. This appears to represent not just a groundwater flow path, but traces of surface runoff infiltration as well.  相似文献   

Interannual variability of East African rainfall: role of seasonal transitions of the low-level cross-equatorial flow     

Vizy  Edward K.  Cook  Kerry H. 《Climate Dynamics》2020,54(11):4563-4587

Climate Dynamics - During boreal spring and fall, the low-level cross-equatorial flow along the East African coast weakens and reverses. These transition periods are embedded within the East...  相似文献   

Application of a water balance model to estimating hay growth in the peace river region     

C.H. Wallis  T.A. Black  O. Hertzman  V.J. Walton 《大气与海洋》2013,51(3):326-343

Abstract

A model that uses daily climate data for calculating hay crop growth in the Peace River region of British Columbia was developed and evaluated using data obtained over four growing seasons. The performances of the ratio of growth to transpiration and the ratio of growth to transpiration (J) divided by vapour pressure deficit (VPD) in estimating crop growth were compared. Transpiration was calculated by subtracting evaporation losses from the soil and foliage from the calculated evapotranspiration. Evapotranspiration was calculated using solar radiation and air temperature, and a one‐layer root zone water balance model, which accounted for soil water supply limitation. Soil water storage measurements showed that the water balance model worked well. The model provided satisfactory estimates of growing season yield of above‐ground dry matter. The use of the ratio of growth toT/ vpd showed no improvement in growth estimation over the ratio of growth to transpiration.  相似文献   

Development of a technique for modelling clay liner desiccation     

Y. Zhou  R. Kerry Rowe 《国际地质力学数值与分析法杂志》2003,27(6):473-493

This paper presents a model for the analysis of clay liner desiccation in a landfill barrier system due to temperature effects. The model incorporates consideration of fully coupled heat‐moisture‐air flow, a non‐linear constitutive relationship, the dependence of void ratio and volumetric water content on stress, capillary pressure and temperature, and the effect of mechanical deformation on all governing equations. Mass conservative numerical schemes are proposed to improve the accuracy of the finite element solution to the governing equations. The application of the model is then demonstrated by examining three test problems, including isothermal infiltration, heat conduction and non‐isothermal water and heat transport. Comparisons are made with results from literature, and good agreement is observed. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Modeling Solar Spectral Irradiance and Total Magnetic Flux Using Sunspot Areas     

Dora G. Preminger  Stephen R. Walton 《Solar physics》2006,235(1-2):387-405

We show that daily sunspot areas can be used in a simple, single parameter model to reconstruct daily variations in several other solar parameters, including solar spectral irradiance and total magnetic flux. The model assumes that changes in any given parameter can be treated mathematically as the response of the system to the emergence of a sunspot. Using cotemporal observational data, we compute the finite impulse response (FIR) function that describes that response in detail, and show that the response function has been approximately stationary over the time period for which data exist. For each parameter, the impulse response function describes the physical evolution of that part of a solar active region that is the source of the measured variability. We show that the impulse response functions are relatively narrow functions, no more than 3 years wide overall. Each exhibits a pre-active, active, and post-active region component; the active region component dominates the variability of most of the parameters studied.  相似文献