Controls of 234Th removal from the oligotrophic ocean by polyuronic acids and modification by microbial activity     

Chen Xu  Peter H. Santschi  Chin-Chang Hung  Saijin Zhang  Kathleen A. Schwehr  Kimberly A. Roberts  Laodong Guo  Gwo-Ching Gong  Antonietta Quigg  Richard A. Long  James L. Pinckney  Shuiwang Duan  Rainer Amon  Ching-Ling Wei 《Marine Chemistry》2011,123(1-4):111-126

To gain new insights into the variability of particulate organic carbon (POC) fluxes and to better understand the factors controlling the POC/²³⁴Th ratios in suspended and sinking particulate matter, we investigated the relationships between POC/²³⁴Th ratios and biochemical composition (uronic acids, URA; total carbohydrates, TCHO; acid polysaccharides, APS; and POC) of suspended and sinking matter from the Gulf of Mexico in 2005 and 2006. Our data show that URA/POC in sediment traps (STs), APS/POC in the suspended particles, and turnover times of particulate ²³⁴Th in the water column and those of bacteria in STs inside eddies usually increased with depth, whereas particulate POC/²³⁴Th (10–50 μm) and the sediment-trap parameters (POC flux, POC/²³⁴Th ratio, bacterial biomass, and bacterial production) decreased with depth. However, this trend was not the case for most biological parameters (e.g., phytoplankton and bacterial biomass) or for the other parameters at the edges of eddies or at coastal-upwelling sites.In general, the following relationships were observed: 1) ²³⁴Th/POC ratios in STs were correlated with APS flux, and these ratios in the 10–50 μm suspended particles also correlated with URA/POC ratios; 2) neither URA fluxes nor URA/POC ratios were significantly related to bacterial biomass; 3) the sum of two uronic acids (G2, glucuronic, and galacturonic acid, which composed most of the URA pool) was positively related to bacterial biomass; and 4) the POC/²³⁴Th ratios in intermediate-sized particles (10–50 μm) were close to those in sinking particles but much lower than those in > 50 μm particles. The results indicate that acid polysaccharides, though a minor fraction (~ 1%) of the organic carbon, act more likely as proxy compound classes that might contain the more refractory ²³⁴Th-binding biopolymer, rather than acting as the original ²³⁴Th “scavenger” compound. Moreover, these acid polysaccharides, which might first be produced by phytoplankton and then modified by bacteria, also influence the on-and-off “piggy-back” processes of organic matter and ²³⁴Th, thus causing additional variability of the POC/²³⁴Th in particles of different sizes.  相似文献   

Effects of sediment burial on tropical ruderal seagrasses are moderated by clonal integration     

Jillian Lean Sim Ooi  Gary A. Kendrick  Kimberly P. Van Niel 《Continental Shelf Research》2011,31(19-20):1945-1954

Seagrasses are clonal plants that grow submerged in dynamic sedimentary environments where burial is a common occurrence. Clonal organisms may respond to burial in very different ways depending on how strongly integrated they are through horizontal rhizomes, but the effect of clonal integration under conditions of stress such as burial is poorly studied for seagrasses. We test the effect of burial on tropical seagrasses that occur in multispecific meadows by subjecting plants in mixed stands to burial of 0, 2, 4, 8 and 16 cm for 27 days. Treatments were divided into those where rhizomes were severed and those where rhizomes were left intact. We hypothesize that species withstand burial better if clonal integration is maintained (intact rhizomes). Results showed that all species tolerated burial of up to 4 cm without adverse effects but significant reductions in shoot density and biomass become evident at 8 cm of burial. Furthermore, Cymodocea serrulata and Syringodium isoetifolium were strong integrators, i.e. they provide support for buried shoots, whereas Halophila ovalis and Halodule uninervis were weak integrators that did not show evidence of subsidizing buried shoots. Vertical elongation was observed for C. serrulata and H. uninervis as a response to burial only when rhizomes were severed, leading us to speculate on whether species rely on vertical elongation as an escape strategy only in the absence of resource translocation. Our distinction between the responses of treatments with intact rhizomes from those with severed rhizomes may be extended to an interpretation of burial scale (intact rhizomes=broad spatial?scale burial; severed rhizomes=fine spatial?scale burial). We concluded that broad spatial?scale burial exceeding 4 cm leads to rapid loss or reduction of all species. However, fine spatial–scale burial exceeding 4 cm, such as those caused by shrimp mounds (bioturbation), is expected to favor C. serrulata and S. isoetifolium, while H. ovalis and H. uninervis are disadvantaged. Clonal integration is an important trait in moderating the response of seagrasses to sediment burial and in this way, helps them to cope in high-stress habitats.  相似文献   

Petrogenesis of municipal solid waste combustion bottom ash     

J. Dykstra Eusden  T. Taylor Eighmy  Kenneth Hockert  Elizabeth Holland  Kimberly Marsella 《Applied Geochemistry》1999,14(8):133

A petrographic study was conducted on a suite of bottom ash particles from 3 different modern municipal solid waste combustors. The object of the study was to evaluate the mineralogical characteristics and formation process of the bottom ash by using standard geological techniques of light microscopy, electron microscopy, and X-ray microanalysis. This information was subsequently used to model the bottom ash petrogenesis based upon an examination of the mineralogy, melt structure, and composition of the ash.Bottom ash can be divided into two major groups: 1) refractory waste products and 2) melt products. The refractory waste products consist largely of rock and mineral fragments, various waste metals, and unmelted glass shards. The melt products consist of two distinct glasses: 1) isotropic glass, and 2) opaque glass. Complex silicate minerals are precipitated from and are abundant in the isotropic glass whereas both metal oxide and silicate minerals are precipitated from the opaque glass.The isotropic and opaque glasses formed simultaneously in different locations on the combustor grate. The contrast in melting (liquidus) temperatures shown by these glasses suggests that the isotropic melts were produced at localized hot spots (1500°C to 1650°C) and the opaque melts formed at cold spots (1150°C to 1400°C) on the grate. This could be the result of heterogeneous distribution of combustible municipal solid waste on the grate or from localized hot spots where air is introduced through the grates. In some instances the two glasses then had the opportunity to variably mix with each other. Fe-oxides represent waste metal fragments that were assimilated by melting and later recrystallized.Bottom ash is produced via a co-mingled two melt system that forms melilite-bearing, alkaline, volcanic-like rocks. The great similarity of the bottom ash residues between these 3 different MSW combustors suggests that, despite variable combustor designs and heterogeneous waste feed, high temperature combustion of MSW produces bottom ash of fairly uniform composition and structure that formed via the petrogenetic process described above. Alterations to the combustion process or implementations of secondary treatment technologies may render the bottom ash residue into a more environmentally stable material better suited for aggregate or long term secure disposal in landfills.  相似文献   

Ten guiding principles for the delineation of priority habitat for endangered small cetaceans     

Peter S. Ross  Jay Barlow  Thomas A. Jefferson  Brendan E. Hickie  Tatiana Lee  Christina MacFarquhar  E. Christien Parsons  Kimberly N. Riehl  Naomi A. Rose  Elisabeth Slooten  Chia-Yang Tsai  John Y. Wang  Andrew J. Wright  Shih Chu Yang 《Marine Policy》2011

The adoption of endangered species laws in various nations has intensified efforts to better understand, and protect, at-risk species or populations, and their habitats. In many countries, delineating a portion of a species' habitat as particularly worthy of protection has become a mantra of these laws. Unfortunately, the laws themselves often provide scientists and managers with few, if any, guidelines for how to define such habitat. Conservationists and scientists may view protecting part of the habitat of an endangered species as an ineffectual compromise, while managers may be under pressure to allow a range of human activities within the species' habitat. In the case of small cetaceans, establishing boundaries for such areas can also be complicated by their mobility, the fluid nature of their environment, and the often ephemeral nature of their habitat features. The convergence of multiple human impacts in coastal waters around the world is impacting many small cetaceans (and other species) that rely on these areas for feeding, reproducing, and resting. The ten guiding principles presented here provide a means to characterize the habitat needs of small, at-risk cetaceans, and serve as a basis for the delineation of ‘priority habitat’ boundaries. This conceptual approach should facilitate a constructive discourse between scientists and managers engaged in efforts to recover endangered species. The degree to which the recovery of an at-risk species can be reconciled with sustainable economic activity will depend in part on how well these principles are incorporated into the delineation of priority habitat.  相似文献   

An AzTEC 1.1 mm survey of the GOODS-N field – II. Multiwavelength identifications and redshift distribution     

Edward L. Chapin  Alexandra Pope †  Douglas Scott  Itziar Aretxaga  Jason E. Austermann  Ranga-Ram Chary  Kristen Coppin  Mark Halpern  David H. Hughes  James D. Lowenthal  Glenn E. Morrison  Thushara A. Perera  Kimberly S. Scott  Grant W. Wilson  Min S. Yun 《Monthly notices of the Royal Astronomical Society》2009,398(4):1793-1808

We present results from a multiwavelength study of 29 sources (false detection probabilities <5 per cent) from a survey of the Great Observatories Origins Deep Survey-North (GOODS-N) field at 1.1 mm using the Astronomical Thermal Emission Camera (AzTEC). Comparing with existing 850 μm Submillimetre Common-User Bolometer Array (SCUBA) studies in the field, we examine differences in the source populations selected at the two wavelengths. The AzTEC observations uniformly cover the entire survey field to a 1σ depth of ∼1 mJy. Searching deep 1.4 GHz Very Large Array (VLA) and Spitzer 3–24 μm catalogues, we identify robust counterparts for 21 1.1 mm sources, and tentative associations for the remaining objects. The redshift distribution of AzTEC sources is inferred from available spectroscopic and photometric redshifts. We find a median redshift of   z = 2.7  , somewhat higher than   z = 2.0  for  850 μm  selected sources in the same field, and our lowest redshift identification lies at a spectroscopic redshift   z = 1.1460  . We measure the 850 μm to 1.1 mm colour of our sources and do not find evidence for '850 μm dropouts', which can be explained by the low signal-to-noise ratio of the observations. We also combine these observed colours with spectroscopic redshifts to derive the range of dust temperatures T , and dust emissivity indices β for the sample, concluding that existing estimates   T ∼ 30 K  and  β∼ 1.75  are consistent with these new data.  相似文献   

Sedimentary architecture and genesis of Holocene shallow-water mud-mounds, northern Belize     

S. J. Mazzullo  Chellie S. Teal  William D. Bischoff  Kimberly Dimmick-Wells  Brian W. Wilhite 《Sedimentology》2003,50(4):743-770

Abstract Cangrejo and Bulkhead Shoals are areally extensive, Holocene biodetrital mud‐mounds in northern Belize. They encompass areas of 20 km² and 35 km² in distal and proximal positions, respectively, on a wide and shallow‐water, microtidal carbonate shelf where storms are the major process affecting sediment dynamics. Sediments at each mound are primarily biodetrital and comprise part of a eustatically forced, dominantly subtidal cycle with a recognizable deepening‐upward transgressive systems tract, condensed section and shallowing‐upward highstand systems tract. Antecedent topographic relief on Pleistocene limestone bedrock also provided marine accommodation space for deposition of sediments that are a maximum of 7·6 m thick at Cangrejo and 4·5 m thick at Bulkhead. Despite differences in energy levels and location, facies and internal sedimentological architectures of the mud‐mounds are similar. On top of Pleistocene limestone or buried soil developed on it are mangrove peat and overlying to laterally correlative shelly gravels. Deposition of these basal transgressive, premound facies tracked the rapid rate of sea‐level rise from about 6400–6500 years BP to 4500 years BP, and the thin basal sedimentation unit of the overlying mound‐core appears to be a condensed section. Following this, the thick and complex facies mosaic comprising mound‐cores represents highstand systems tract sediments deposited in the last ≈ 4500 years during slow and decelerating sea‐level rise. Within these sections, there is an early phase of progradationally offlapping catch‐up deposition and a later (and current) phase of aggradational keep‐up deposition. The mound‐cores comprise stacked storm‐deposited autogenic sedimentation units, the upper bounding surfaces of which are mostly eroded former sediment–water interfaces below which depositional textures have largely been overprinted by biogenic processes associated with Thalassia‐colonized surfaces. Vertical stacking of these units imparts a quasi‐cyclic architecture to the section that superficially mimics metre‐scale parasequences in ancient rocks. The locations of the mud‐mounds and the tidal channels transecting them have apparently been stable over the last 50 years. Characteristics that might distinguish these mud‐mounds and those mudbanks deposited in more restricted settings such as Florida Bay are their broad areal extent, high proportion of sand‐size sediment fractions and relatively abundant biotic particles derived from adjoining open shelf areas.  相似文献   

Production patterns in Massachusetts Bay with outfall relocation     

Candace A. Oviatt  Kimberly J. W. Hyde  Aimee A. Keller  Jefferson T. Turner 《Estuaries and Coasts》2007,30(1):35-46

On September 6, 2000, the sewage outfall at the mouth of Boston Harbor was relocated 15 km offshore to alleviate pollution in Boston Harbor. The expected responses for nutrients and water column productivity parameters were for values to decrease at Boston Harbor, to increase at the outfall location, and to remain unchanged at the boundary of the near field region within 5 km of the outfall. Average values ofr water column measurements from 1992 to 2004 indicated these general responses with some exceptions. At the Harbor, nutrients decreased and chlorophyll increased but¹⁴C primary productivity remained statistically unchanged. At the new outfall location and at the boundary of the near field, nutrients increased and chlorophyll increased but primary productivity remained unchanged. Physical factors affecting primary production, such as pring water temperature, stratification, and wind, had more affects on productivity patters than nutrients from outfall relocation in the near field. A decrease in summer zooplankton after outfall relocation appeared to be due to a region-wide rather than outfall effluents.  相似文献   

Lacustrine evidence for moisture changes in the Nebraska Sand Hills during Marine Isotope Stage 3     

Kimberly C. Jacobs  James B. Swinehart 《Quaternary Research》2007,67(2):246-254

In the central Great Plains of North America, loess stratigraphy suggests that climate during the late Pleistocene was cold and dry. However, this record is discontinuous, and there are few other records of late-Pleistocene conditions. Cobb Basin, located on the northern edge of the Nebraska Sand Hills, contains lacustrine sediments deposited during Marine Isotope Stage 3, beginning approximately 45,000 cal yr BP and continuing for at least 10,000 yr. The lake was formed by a dune dam blockage on the ancient Niobrara River, and its deposits contain a diatom record that indicates changes through time in lake depth driven by changes in effective moisture. During the earliest stages of lake formation, the climate was arid enough to mobilize dunes and emplace dune sand into a blocking position within the Niobrara streambed. Diatom assemblages suggest that lake-level was shallow at formation, increased substantially during a wet interval, and then became shallow again, as arid conditions resumed. By about 27,000 cal yr BP the lake was filled, and a shallow ephemeral river occupied the basin.  相似文献   

Gendered access to customary land in East Timor     

Pyone Myat Thu  Steffanie Scott  Kimberly P. Van Niel 《GeoJournal》2007,69(4):239-255

Land tenure rights reflect the deeper structures of society, particularly gender distinctions in relation to land. Considering the structural differences between patrilineal and matrilineal customary tenure systems in East Timor are understudied, this paper explores men and women’s experiences in accessing land under such arrangements. The comparative analysis of two patrilineal with one matrilineal land tenure systems in Ainaro and Manufahi districts suggests a significant degree of flexibility within both systems with respect to the norms of gendered inheritance. Therefore, the binary constructs of ‘patrilineal’ and ‘matrilineal’ societies are limiting. Both men and women in these communities may acquire land rights under different circumstances, mainly through negotiations with their parents or hamlet chief. Daughters in the patrilineal communities could inherit family land upon their parents’ death and sons in the matrilineal community could gain land by cultivating and maintaining unclaimed customary land. Empirical evidence show that inheritance principally determines usufruct rights to land, but marriage exchange practices complicates a deeper understanding of traditional East Timorese land rights.

Pyone Myat ThuEmail:

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Global land mapping of satellite-observed CO2 total columns using spatio-temporal geostatistics     

Zhao-Cheng Zeng  Liping Lei  Kimberly Strong  Dylan B. A. Jones  Lijie Guo  Min Liu 《International Journal of Digital Earth》2017,10(4):426-456

ABSTRACT

This study presents an approach for generating a global land mapping dataset of the satellite measurements of CO₂ total column (XCO₂) using spatio-temporal geostatistics, which makes full use of the joint spatial and temporal dependencies between observations. The mapping approach considers the latitude-zonal seasonal cycles and spatio-temporal correlation structure of XCO₂, and obtains global land maps of XCO₂, with a spatial grid resolution of 1° latitude by 1° longitude and temporal resolution of 3 days. We evaluate the accuracy and uncertainty of the mapping dataset in the following three ways: (1) in cross-validation, the mapping approach results in a high correlation coefficient of 0.94 between the predictions and observations, (2) in comparison with ground truth provided by the Total Carbon Column Observing Network (TCCON), the predicted XCO₂ time series and those from TCCON sites are in good agreement, with an overall bias of 0.01?ppm and a standard deviation of the difference of 1.22?ppm and (3) in comparison with model simulations, the spatio-temporal variability of XCO₂ between the mapping dataset and simulations from the CT2013 and GEOS-Chem are generally consistent. The generated mapping XCO₂ data in this study provides a new global geospatial dataset in global understanding of greenhouse gases dynamics and global warming.  相似文献