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991.
992.
We use cosmogenic 10Be and 26Al in both bedrock and fluvial sediments to investigate controls on erosion rates and sediment supply to river basins at the regional scale in the Kimberley, NW Australia. The area is characterised by lithologically controlled morphologies such as cuestas, isolated mesas and extensive plateaus made of slightly dipping, extensively jointed sandstones. All sampled bedrock surfaces at plateau tops, ridgelines, and in the broader floodplain of major rivers over the region show similar slow lowering rates between 0.17 and 4.88 m.Myr-1, with a mean value of 1.0 ± 0.6 m.Myr-1 (n=15), whilst two bedrock samples collected directly within river-beds record rates that are one to two orders of magnitude higher (14.4 ± 1.5 and 20.9 ± 2.5 m.Myr-1, respectively). Bedrock 26Al/10Be ratios are all compatible with simple, continuous sub-aerial exposure histories. Modern river sediment yield lower 10Be and 26Al concentrations, apparent 10Be basin-wide denudation rates ranging between 1.8 and 7.7 m.Myr-1, with a median value of 2.6 m.Myr-1, more than double the magnitude of bedrock erosion rates. 26Al/10Be ratios of the sediment samples are lower than those obtained for bedrock samples. We propose that these depleted 26Al/10Be ratios can largely be explained by the supply of sediment to river basins from the slab fragmentation and chemical weathering of channel gorge walls and plateau escarpments that result in diluting the cosmogenic nuclide concentration in river sediments measured at the basin outlets. The results of a mass-balance model suggest that ~60–90% of river sediment in the Kimberley results from the breakdown and chemical weathering of retreating vertical sandstone rock-walls in contrast to sediment generated by bedrock weathering and erosion on the plateau tops. This study emphasises the value of analysing two or more isotopes in basin-scale studies using cosmogenic nuclides, especially in slowly eroding post-orogenic settings. © 2019 John Wiley & Sons, Ltd.  相似文献   
993.
994.
The exceptionally large gold resource at Ladolam (>1,300 metric tons of gold), Lihir Island, resulted from the transition of an early-stage, low-grade porphyry gold system to a low-sulfidation epithermal gold event. This transition was probably triggered by rapid decompression during the partial slope failure of Luise stratovolcano and accompanied by the ingress of seawater. The original porphyry stage is indicated by remnant hydrothermal breccia clasts of strongly biotite-magnetite altered monzodiorite with disseminated pyrite - chalcopyrite and poorly developed pyrite - quartz stockwork veins. The breccias are overprinted by biotite-magnetite alteration and their matrix is strongly mineralized with disseminated auriferous pyrite. The breccias are cut by late-stage epithermal quartz-chalcedony-illite-adularia-pyrite veins and associated illite-adularia alteration that locally contain bonanza gold grades of up to 120 g/t. Isotope data suggest a magmatic source of sulfur in the gold-bearing fluids at Ladolam. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00126-001-0230-y  相似文献   
995.
Aromatic amines are important metabolites of nitroaromatic explosives, hence monitoring of aromatic amines’ content at former ammunition plants is necessary. Twenty years ago, a threshold limit value of 0.1 μg/L for the sum of diazotizable aromatic amines in water distributed from the waterworks at the former ammunition plant in Stadtallendorf/Hesse was established. This value is still measured with a spectrometric sum parameter, in which diazotization and a subsequent azo coupling of the analytes are utilized. The sum parameter is well suited for the long‐term monitoring of filter installations, and it allows very quick measurements and a non‐target screening of aniline contents, both of which are important in research. Nevertheless, as several problems are associated with this parameter, we developed analytical methods suitable for the determination of the most important single compounds contributing to the overall sum. Initial results of these methods show that amphoteric anilines are of considerable importance in ammunition waste but have been neglected up to now in official monitoring schemes. The summation of single compound contents in ammunition wastewater generally gives 3 to 6 times higher values than the spectrometrically determined sum, which is mainly due to the choice of the reference substance 4‐nitroaniline in the sum parameter.  相似文献   
996.
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