Geochronology in migmatites a SmNd, UPb and RbSr study from the Proterozoic Damara belt (Namibia): implications for polyphase development of migmatites in high-grade terranes     

S. Jung  K. Mezger 《Journal of Metamorphic Geology》2001,19(1):77-97

Sm–Nd (garnet), U–Pb (monazite) and Rb–Sr (biotite) ages from a composite migmatite sample (Damara orogen, Namibia) constrain the time of high‐grade regional metamorphism and the duration of regional metamorphic events. Sm–Nd garnet whole‐rock ages for a strongly restitic melanosome and an adjacent intrusive leucosome yield ages of 534±5, 528±11 and 539±8 Ma. These results provide substantial evidence for pre‐500 Ma Pan‐African regional metamorphism and melting for this segment of the orogen. Other parts of the migmatite yield younger Sm–Nd ages of 488±9 Ma for melanosome and 496±10, 492±5 and 511±16 Ma for the corresponding leucosomes. Garnet from one xenolith from the leucosomes yields an age of 497±2 Ma. Major element compostions of garnet are different in terms of absolute abundances of pyrope and spessartine components, but the flat shape of the elemental patterns suggests late‐stage retrograde equilibration. Rare earth element compositions of the garnet from the different layers are similar except for garnet from the intrusive leucosome suggesting that they grew in different environments. Monazite from the leucosomes is reversely discordant and records ²⁰⁷Pb/²³⁵U ages between 536 and 529 Ma, indicating that this monazite represents incorporated residual material from the first melting event. Monazite from the mesosome MES 2 and the melanosome MEL 3 gives ²⁰⁷Pb/²³⁵U ages of 523 and 526 Ma, and 529 and 531 Ma, respectively, which probably indicates another thermal event. Previously published ²⁰⁷Pb/²³⁵U monazite data give ages between 525 and 521 Ma for composite migmatites, and 521 and 518 Ma for monazite from neosomes. Monazite from granitic to granodioritic veins indicates another thermal event at 507–505 Ma. These ages are also recorded in ²⁰⁷Pb/²³⁵U monazite data of 508 Ma from the metasediment MET 1 from the migmatite and also in the Sm–Nd garnet ages obtained in this study. Taken together, these ages indicate that high‐grade metamorphism started at c. 535 Ma (or earlier) and was followed by thermal events at c. 520 Ma and c. 505 Ma. The latter event is probably connected with the intrusion of a large igneous body (Donkerhoek granite) for which so far only imprecise Rb–Sr whole‐rock data of 520±15 Ma are available. Rb–Sr biotite ages from the different layers of the migmatite are 488, 469 and 473 Ma. These different ages indicate late‐stage disturbance of the Rb–Sr isotopic system on the sub‐sample scale. Nevertheless, these ages are close to the youngest Sm–Nd garnet ages, indicating rapid cooling rates between 13 and 20°C Ma^?1 and fast uplift of this segment of the crust. Similar Sm–Nd garnet and U–Pb monazite ages suggest that the closure temperatures for both isotopic systems are not very different in this case and are probably similar or higher than the previously estimated peak metamorphic temperatures of 730±30°C. The preservation of restitic monazite in leucosomes indicates that dissolution of monazite in felsic water‐undersaturated peraluminous melts can be sluggish. This study shows that geochronological data from migmatites can record polymetamorphic episodes in high‐grade terranes that often contain cryptic evidence for the nature and timing of early metamorphic events.  相似文献   

Processes controlling metal ion attenuation in acid mine drainage streams   总被引：1，自引：0，他引：1  

B.M Chapman  D.R Jones  R.F Jung 《Geochimica et cosmochimica acta》1983,47(11):1957-1973

Two acid mine drainage streams have been investigated by detailed analysis of their sediments and waters, to obtain an understanding of the dominant processes which control the transport and attenuation of heavy metals under conditions of chronic high-level pollutant input. One of the water-courses has a thick hydrous iron oxide crust on its bed, where biotically mediated oxidation of ferrous iron resulted in precipitation of amorphous ferric hydroxide, along with substantial quantities of adsorbed silica, sulphate and Al and lesser quantities of As. Small amounts of K and Pb (and possibly hydronium) jarosites were also present in the sediments. Changes in pH and in the concentrations of Cu, Zn, and Cd appear to be mainly the result of dilution by seeps and tributaries.Although no sediment was recovered during collection of water samples from the second stream, saturation index calculations imply that precipitation should have been occurring. The observed down-stream loss of a number of elements supported this conclusion. The solids predicted to be precipitating were A1(OH)₃, Cu₂(OH)₂CO₃, and Fe(OH)₃. Observed decreases in the concentrations of Cd, Zn and Mn can be accounted for on the basis of dilution alone. However, the additional mechanism of neutralization by higher pH inflows is required to account for the decrease in hydrogen ion concentration downstream.The basis for a potentially useful new technique (congruent element analysis) which enables the identification of conservative components in streams is presented. Comparison of logarithmic concentration versus distance plots delineates the point where chemical removal mechanisms become important for each element.  相似文献   

Hybrid seismic protection of cable‐stayed bridges     

H.‐J. Jung  K.‐S. Park  B. F. Spencer  I.‐W. Lee 《地震工程与结构动力学》2004,33(7):795-820

This paper proposes a hybrid control strategy combining passive and semi‐active control systems for seismic protection of cable‐stayed bridges. The efficacy of this control strategy is verified by examining the ASCE first‐generation benchmark problem for a seismically excited cable‐stayed bridge, which employs a three‐dimensional linearized evaluation bridge model as a testbed structure. Herein, conventional lead–rubber bearings are introduced as base isolation devices, and semi‐active dampers (e.g., variable orifice damper, controllable fluid damper, etc.) are considered as supplemental damping devices. For the semi‐active dampers, a clipped‐optimal control algorithm, shown to perform well in previous studies involving controllable dampers, is considered. Because the semi‐active damper is a controllable energy‐dissipation device that cannot add mechanical energy to the structural system, the proposed hybrid control strategy is fail‐safe in that the bounded‐input, bounded‐output stability of the controlled structure is guaranteed. Numerical simulation results show that the performance of the proposed hybrid control strategy is quite effective in protecting seismically excited cable‐stayed bridges. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Trace element fractionation during high-grade metamorphism and crustal melting—constraints from ion microprobe data of metapelitic, migmatitic and igneous garnets and implications for Sm–Nd garnet chronology     

S. Jung  E. Hellebrand 《Lithos》2006,87(3-4):193-213

Rare earth element (REE) and other trace element (Y, Sr, Ti, Cr, V, Na) abundances in garnet from a garnet-bearing metapelite, a pelitic migmatite, a syn-tectonic granite and a post-tectonic leucogranite were measured by secondary ion mass spectrometry (SIMS) in order to identify the effective variables on the trace element distribution between garnet and the host rock. Garnet from the garnet-bearing metapelite, the pelitic migmatite and the syn-tectonic granite is zoned with respect to REE. The cores are enriched by a factor of 2–3 relative to the rims. For the garnets from the garnet-bearing metapelite equilibrium distribution following a simple Rayleigh fractionation is responsible for the decreasing concentrations in REE from core to rim. Garnet from the pelitic migmatite shows a more complex trace element pattern following distinct enrichment and depletion patterns for Ti, V, Cr and REE from core to rim. These features suggest disequilibrium between garnet and the associated melt in which the enrichment of trace elements probably correspond to a period of open-system behaviour in these rocks at a time when the garnet, originally nucleated in the metamorphic environment was incorporated into the melt. The garnet from the syn-tectonic granite shows stepwise decreasing concentrations in REE from core to rim: a REE-rich core can be distinguished from a broad REE-depleted rim. Notably, from core to rim an inflection of the Yb / Er and Yb / Dy ratios is visible. Whereas the decrease of HREE abundance in the core region of the garnet from the syn-tectonic granite may arise from equilibrium partitioning during garnet growth, the inflection can be interpreted as a result of partial melting. Garnet cores with high Yb / Er and Yb / Dy >  1 nucleated in the metamorphic environment without the presence of a melt whereas the rims with lower Yb / Er and Yb / Dy <  1 crystallized in the presence of a melt. Garnet from the leucogranite has lower REE abundances and is considered to be of igneous origin. In contrast to garnet from the other samples, its core has low trace element abundances, whereas its rim is significantly enriched in REE but depleted in Ti. These features suggest that only the outermost rim was in equilibrium with the melt. For this garnet, liquid diffusion controlled partitioning is more likely to explain the extreme trace element variation. An evaluation of Sm and Nd concentrations in garnet and a comparison of Sm–Nd and U–Pb garnet ages and U–Pb monazite ages form the terrane indicate that the observed LREE systematics in the different garnet species are a primary feature and are not homogenized by volume diffusion during high grade amphibolite facies conditions.  相似文献   

Microbial effects on geochemical behavior of arsenic in As-contaminated sediments   总被引：4，自引：0，他引：4  

J.M. Park  J.S. Lee  J.-U. Lee  H.T. Chon  M.C. Jung 《Journal of Geochemical Exploration》2006,88(1-3):134

The purpose of this study is to investigate the contamination level and chemical speciation of As in sediments from the Hwachon Au mine area, and to study the effects of indigenous bacteria on geochemical behavior of As in As-contaminated sediments from the mine. Concentrations of heavy metal and metalloids in one composite sample of 9 Hwachon sediments were 24.9 As mg/kg, 16.6 Cd mg/kg, 230 Pb mg/kg and 1080 Zn mg/kg. This indicates that this area was seriously contaminated with As, Cd and Zn. From the result of sequential extraction analysis, most of As (87.9%) existed as a phase of As which coprecipitated with Fe oxyhydroxides. Under aerobic condition, As concentration leached from sediments were 4 times higher in non-sterile than in sterile condition. This enrichment of As leaching could be caused by increase of pH and exudation secreted during microbial metabolism. On the other hand, under anaerobic condition, As concentration has dramatically increased in non-sterile solution with time. This As leaching has begun on 4–5th days of incubation and the highest concentration of 511 As μg/l was recorded on about 11th day. Arsenic leaching under anaerobic condition was caused by microbial enhancement of Fe leaching. Total Fe concentration increased from the 4th day, and this Fe leaching might cause lixiviation of As which had been coprecipitated with Fe oxyhydroxide.  相似文献   

Petrology and geochemistry of syn- to post-collisional metaluminous A-type granites—a major and trace element and Nd–Sr–Pb–O-isotope study from the Proterozoic Damara Belt, Namibia     

S. Jung  K. Mezger  S. Hoernes 《Lithos》1998,45(1-4):147-175

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Bimodal wave spectra in lower Chesapeake Bay, sea bed energetics and sediment transport during winter storms     

John D. Boon  Malcolm O. Green  Kyung Duck Suh 《Continental Shelf Research》1996,16(15):1965-1988

The transition zone separating estuarine environments from the coastal ocean is characterized not only by distinctive morphological and sedimentary trends but by unique hydrodynamic forces as well. Lower Chesapeake Bay, a large coastal estuary within the Mid-Atlantic Bight of the U.S. East Coast, experiences complex wave and current-induced forces produced during winter storms. Wave and current measurements made near Thimble Shoal Light over five winter seasons show that most storms simultaneously produce both ocean and bay-generated wave trains that appear as distinct bimodal peaks in directional spectra. Analysis of selected storm wave records reveal that lower-frequency ocean waves, although nominally lower in amplitude than higher-frequency bay waves, are roughly equivalent to bay waves in terms of energy expended on beds of fine- to medium-grained sand at either end of the Thimble Shoal Channel. Grain-friction energy dissipation estimates calculated for waves and currents suggest that waves provide more net energy capable of transporting bottom sediment than currents, although strong barotropic flows briefly encountered during a major storm on 13–14 March 1993, exceeded wave energy expended at the bed by almost an order of magnitude. From analyses of wave orbital velocity spectra, it is shown that dual wave trains characterized by differences in peak frequency and direction may assist each other through interactions that increase their combined contribution to frictional energy dissipation and inferred sediment transport at the bed.  相似文献   

Occurrence,chemistry, and origin of immiscible silicate glasses in a tholeiitic basalt: A TEM/AEM study     

Lung -Chuan Kuo  Jung H. Lee  Eric J. Essene  Donald R. Peacor 《Contributions to Mineralogy and Petrology》1986,94(1):90-98

The occurrence and chemistry of immiscible silicate glasses in a tholeiite mesostasis from the Umtanum formation, Washington, were investigated with transmission electron microscopy and analytical electron microscopy (TEM/AEM). TEM observation reveals isolated, dark globules (2.1 micron or less in diameter) randomly distributed in a transparent matrix glass interstitial to plagioclase laths. The globules less than 0.3 micron and larger than 0.8 micron fall beyond the linear relationship defined by the 0.3–0.8 micron globules in a plot of the logarithm of number versus size. Large globules (0.7 micron or larger in diameter) range from homogeneous to heterogeneous in optical properties and chemistry. Homogeneous globules are completely glassy, whereas heterogeneous globules contain crystalline domains. AEM analyses show that the globules have high Si, Fe, Ca, and Ti with subordinate Mg, Al, P, S, Cl, K, and Mn, which gives high normative fa, px, il, and ap. The matrix glass consists dominantly of Si with low Al and minor Na and K, yielding a high normative qz, or, ab, and an.It is proposed that the silicate liquid immiscibility occurs by reaction of network-modifying cations (NMCs) with dominantly chain-like anionic units in the parental melt to form less polymerized, NMC-bearing units and highly polymerized, Si-rich units. The globules nucleated metastably under supercooled conditions, and medium-size globules become either larger or smaller at lower temperatures. Internal nucleation of NMC-rich phases occurred in some larger globules upon cooling.  相似文献   

Synthesis, properties and stability of end member boromuscovite, KAl2[BSi3O10](OH)2     

Ingo Jung  Werner Schreyer 《Contributions to Mineralogy and Petrology》2002,143(6):684-693

End member boromuscovite, with nearly the ideal composition, was synthesized as a single phase from mixtures of its own composition, or with excess boron and water, at high pressures of between 15 and 30 kbar at 700 °C. The mica synthesized consists of a mixture of 2M₁ and 1M polytypes with the cell dimensions of 2M₁: a=5.071(4), b=8.786(4), c=19.830(89) Å, #=95.84(12)°, V=878.5(1.4) ų; and 1M: a=5.059(5), b=8.819(6), c=10.025(17) Å, #=101.39(57)°, V=438.4(1.3) Å. The IR spectrum shows characteristic differences relative to that of muscovite. DTA registers an endothermic peak due to dehydration breakdown above 680 °C. Seeded experiments indicate that boromuscovite is a high-pressure phase requiring minimum pressures of 3 to 10 kbar at temperatures that concomitantly increase from 300 to 750 °C. At lower pressures, the anhydrous solid assemblage K-feldspar + Al-borate (probably Al₄B₂O₉) coexists with a vapor rich in boric acid. The conversion of this assemblage to boromuscovite is connected with increases in the coordination number of B from [3] to [4], and of Al from [4] to [6]. Above 10 kbar, the boromuscovite stability field is limited along its high-temperature side by congruent (or incongruent?) melting of the mica, starting near 750 °C and 10 kbar and increasing to about 900 °C at 50 kbar, although, at such very high pressures a supercritical fluid may be present. Because, even in the presence of excess-boron fluid, the synthetic mica shows invariable X-ray properties, it is concluded that one B atom per formula unit represents the maximum, and - contrary to olenitic tourmalines - no further substitution of Si by B linked with addition of hydrogen takes place. In contrast to muscovite, KAl₂[AlSi₃O₁₀](OH)₂, end member boromuscovite is not stable under normal P-T conditions of the Continental Crust along a 30 °C/km geotherm, and especially not during the intrusion of acidic igneous rocks including their pegmatites, which may explain its scarcity in nature. However, it may form in the waning hydrothermal stages of deep-seated (>10.5 km) pegmatites and - providing sufficient boron is available - in HP/LT subduction zone environments, where it may carry boron to considerable depths.  相似文献   

Synorogenic melting of mafic lower crust: constraints from geochronology, petrology and Sr, Nd, Pb and O isotope geochemistry of quartz diorites (Damara orogen, Namibia)   总被引：4，自引：0，他引：4  

S. Jung  S. Hoernes  K. Mezger 《Contributions to Mineralogy and Petrology》2002,143(5):551-566

Quartz diorites represent the earliest (ca. 540 Ma) and most primitive plutonic rocks in the Pan African Damara belt and they pre-date the main phase of high-T regional metamorphism. Two suites of synorogenic quartz diorites are unusual among Damaran intrusive rocks in their elemental and isotopic features. Comparison of the diorite compositions with melts from amphibolite-dehydration melting experiments points to a garnet-bearing meta-tholeiite, probably enriched in K₂O, as a likely source rock. Partial melting processes generated mafic (ca. 50 wt% SiO₂) quartz diorites in the deep crust at temperatures of between 1,000 and 1,100 °C, based on comparison with experimental results and similar temperature estimates based on P₂O₅ solubility in mafic rocks. Subsequently, the quartz diorites evolved by multistage, polybaric differentiation processes including fractional crystallization of mainly hornblende and plagioclase and assimilation of felsic basement gneisses. Although their chemical characteristics (high LILE, low HFSE) resemble those of other quartz diorites with calc-alkaline affinities, they differ in their enriched Sr (initial ⁸⁷Sr/⁸⁶Sr: 0.70943-0.71285), Nd (initial ) Nd: -9.1 to -15.2 ) and O ('¹⁸O: 6.8-8.1‰) isotope compositions. Neodymium model ages (T_DM) that range from 1.7 to 2.2 Ga and large variation in ²⁰⁷Pb/²⁰⁴Pb relative to ²⁰⁶Pb/²⁰⁴Pb indicates involvement of ancient crustal material. Lead (²⁰⁶Pb/²⁰⁴Pb: 17.08-17.23, ²⁰⁷Pb/²⁰⁴Pb: 15.53-15.62, ²⁰⁸Pb/²⁰⁴Pb: 37.71-38.16) isotope compositions are strongly retarded, indicating that the source underwent a pre-Pan-African U/Pb fractionation and U depletion. It is proposed that the quartz diorites originated by synorogenic high temperature melting of mafic lower crust. This contrasts with previous suggestions favouring an origin of these rocks by melting of an enriched mantle during Pan-African times with characteristics modified by subduction of oceanic crust and sedimentary rocks.  相似文献