Mid-infrared imaging of ultracompact H II regions     

T. L. Hayward  J. W. Miles  J. R. Houck  T. K. Timberlake 《Experimental Astronomy》1994,3(1-4):159-160

We discuss preliminary results of an 11.7 m imaging survey of ultracompact H II regions from the Wood and Churchwell radio survey. We find that that the morphologies of ionized gas and warm dust are often significantly different, indicating that an H II region classification scheme should be based on more than radio data.  相似文献   

Eta model forecasts of tropical cyclones from Australian Monsoon Experiment: Dynamical adjustment of initial conditions     

L. Lazić 《Meteorology and Atmospheric Physics》1993,52(3-4):101-111

Summary The University of Belgrade/National Meteorological Centre, Washington (UB/NMC) limited area Eta Model predicted the development, structure, associated precipitation and tracks of the Australian Monsoon Experiment (AMEX) (10 January through 15 February 1987) tropical cyclonesConnie, Irma, Damien andJason. The initial positions and intensities of the tropical cyclone vortices from the global European Centre for Medium-Range Weather Forecasts (ECMWF) analyses, which are used as initial data, do not quite agree with the observations. These disagreements produce additional erros in predicting the tropical cyclone tracks.To improve the initial position of the vortex, the flow is split into the small and the large scale motions, and during the first two hours of the integration, the small-scale part is forced in small steps towards its observed position. The adjustment is performaed with the reduced model dynamics (adjustment processes only) and no physics.With the adjustment during the first two hours of the integration, the model successfully adjusts to the new position of the initial vortex. After the completion of the adjustment stage, the model runs normally, i.e., without any modification. The tracks of the 48-h forecasts with the adjusted initial vortices are parallel to the tracks obtained in the control forecasts without the adjustment. However, e.g., the mean absolute error of the positions during 48-h forecast of the tropical cycloneConnie was reduced from 174 km in the control case to 129 km in the case with adjustment of the position.The latent heat, the thermal energy, the kinetic energy and the total energy of the extracted small scale vortices are calculated every three hours of the integration time. These small-scale energies obtained in the 48-h control forecast are compared to those of the rund with the initial vortex adjustment to monitor the spin up of the model.With 7 Figures  相似文献   

Correlation methods in fingerprint detection studies   总被引：2，自引：0，他引：2  

B D Santer  T M L Wigley  P D Jones 《Climate Dynamics》1993,8(6):265-276

This investigation addresses two general issues regarding the role of pattern similarity statistics in greenhouse warming detection studies: normalization, and the relative merits of centered versus uncentered statistics. A pattern correlation statistic is used to search for the greenhouse warming signals predicted by five different models in the observed records of land and ocean surface temperature changes. Two forms of this statistic were computed: R (t), which makes use of nonnormalized data, and (t), which employs point-wise normalized data in order to focus the search on regions where the signal-to-noise ratio is large. While there are no trends in the R (t) time series, the time series of (t) show large positive trends. However, it is not possible to infer from the (t) results that the observed pattern of temperature change is, in fact, becoming increasingly similar to the model-predicted signal. This is because point-wise normalization of the observed and simulated mean change fields by a single common field introduces a common factor effect, which means that the quantities being compared should show some similarity a priori. This does not necessarily make normalization inapplicable, because the detection test involves seeking a trend in the similarity statistic. We show, however, that trends in (t) must arise almost completely from the observed data, and cannot be an indicator of increasing observed data/signal similarity. We also compare the information provided by centered statistics such as R(t) and the uncentered C(t) statistic introduced by Barnett. We show that C(t) may be expressed as the weighted sum of two terms, one proportional to R(t) and the other proportional to the observed spatial mean. For near-surface temperatures, the spatial average term dominates over the R(t) term. In this case the use of C(t) is equivalent to the use of spatial-mean temperature. We conclude that at present, the most informative pattern correlation statistic for detection purposes is R(t), the standard product-moment correlation coefficient between the observed and model fields. Our failure to find meaningful trends in R(t) may be due to the fact that the signal is being obscured by the background noise of natural variability, and/or because of incorrect model signals or sensitivities.  相似文献   

Coupling an ocean wave model to an atmospheric general circulation model     

Susanne L Weber  Hans von Storch  Pedro Viterbo  Liana Zambresky 《Climate Dynamics》1993,9(2):63-69

A coupled model, consisting of an ocean wave model and an atmospheric general circulation model (AGCM), is integrated under permanent July conditions. The wave model is forced by the AGCM wind stress, whereas the wind waves modify the AGCM surface fluxes of momentum, sensible and latent heat. We investigate the following aspects of the coupled model: how realistic are the wave fields, how strong is the coupling, and how sensitive is the atmospheric circulation to the spatially and temporally varying wave field. The wave climatology of the coupled model compares favorably with observational data. The interaction between the two models is largest (although weak) in the storm track in the Southern Hemisphere. Young windsea, which is associated with enhanced surface fluxes is generated mostly in the equatorward frontal area of an individual cyclone. However, the enhancement of the surface fluxes is too small to significantly modify the climatological mean atmospheric circulation.This paper was presented at the Second International Conference on Modelling of Global Climate Variability, held in Hamburg 7–11 September 1992 under the auspices of the Max Planck Institute for Meteorology. Guest Editor for these papers is L. Dümenil  相似文献   

Experimental investigation and application of the equilibrium rutile + orthopyroxene = quartz + ilmenite     

Jodie L. Hayob  Steven R. Bohlen  Eric J. Essene 《Contributions to Mineralogy and Petrology》1993,115(1):18-35

Equilibria in the Sirf (Silica-Ilmenite-Rutile-Ferrosilite) system: $${\text{SiO}}_{\text{2}} + ({\text{Mg,Fe}}){\text{TiO}}_{\text{3}} {\text{ + (Mg,Fe)SiO}}_{\text{3}} $$ have been calibrated in the range 800–1100° C and 12–26 kbar using a piston-cylinder apparatus to assess the potential of the equilibria for geobarometry in granulite facies assemblages that lack garnet. Thermodynamic calculations indicate that the two end-member equilibria involving quartz + geikielite = rutile + enstatite, and quartz + ilmenite = rutile + ferrosilite, are metastable. We therefore reversed equilibria over the compositional range Fs_40–70, using Ag₈₀Pd₂₀ capsules with \(f_{{\text{O}}_{\text{2}} } \) buffered at or near iron-wüstite. Ilmenite compositions coexisting with orthopyroxene are \(X_{{\text{MgTiO}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.06 to 0.15 and \(X_{{\text{Fe}}_{\text{2}} {\text{O}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.00 to 0.01, corresponding toK _D values of 13.3, 10.2, 9.0 and 8.0 (±0.5) at 800, 900, 1000 and 1100° C, respectively, whereK _D =(XMg/XFe)^Opx/(XMg/XFe)^Ilm. Pressures have been calculated using equilibria in the Sirf system for granulites from the Grenville Province of Ontario and for granulite facies xenoliths from central Mexico. Pressures are consistent with other well-calibrated geobarometers for orthopyroxeneilmenite pairs from two Mexican samples in which oxide textures appear to represent equilibrium. Geologically unreasonable pressures are obtained, however, where oxide textures are complex. Application of data from this study on the equilibrium distribution of iron and magnesium between ilmenite and orthopyroxene suggests that some ilmenite in deep crustal xenoliths is not equilibrated with coexisting pyroxene, while assemblages from exposed granulite terranes have reequilibrated during retrogression. The Sirf equilibria are sensitive to small changes in composition and may be used for determination of activity/composition (a/X) relations of orthopyroxene if an ilmenite model is specified. A symmetric regular solution model has been used for orthopyroxene in conjunction with activity models for ilmenite available from the literature to calculatea/X relations in orthopyroxene of intermediate composition. Data from this study indicate that FeSiO₃?MgSiO₃ orthopyroxene exhibits small, positive deviations from ideality over the range 800–1100°C.  相似文献   

Thermodynamic data from redox reactions at high temperatures. II. The MnO-0Mn3O4 oxygen buffer,and implications for the thermodynamic properties of MnO and Mn3O4     

Hugh St. C. O'Neill  Mark I. Pownceby 《Contributions to Mineralogy and Petrology》1993,114(3):315-320

The \(\mu _{O_2 } \) defined by the reaction 6 MnO+O₂ =2 Mn₃O₄ has been determined from 917 to 1,433 K using electrochemical cells (with calcia-stabilized zirconta, CSZ) of the type: Steady emfs were achieved rapidly at all temperatures on both increasing and decreasing temperature, indicating that the MnO-Mn₃O₄ oxygen buffer equilibrates relatively easily. It therefore makes a useful alternative choice in experimental petrology to Fe₂O₃-Fe₃O₄ for buffering oxygen potentials at oxidized values. The results are (in J/mol, temperature in K, reference pressure 1 bar); \(\mu _{O_2 } \) (±200)=-563,241+1,761.758T-220.490T inT+0.101819T ² with an uncertainty of ±200 J/mol. Third law analysis of these data, including a correction for the deviations in stoichiometry of MnO, impliesS _298.15 for Mn₃O₄ of 166.6 J/K · mol, which is 2.5 J/K · mol higher than the calorimetric determination of Robie and Hemingway (1985). The low value of the calorimetric entropy may be due to incomplete ordering of the magnetic spins. The third law value of Δ _r H _298.15 ⁰ is-450.09 kJ/mol, which is significantly different from the calorimetric value of-457.5±3.4 kJ/mol, calculated from Δ _f H _298.15 ⁰ of MnO and Mn₃O₄, implying a small error in one or both of these latter.  相似文献   

Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks     

HILL  R. J.; TSAMBOURAKIS  G.; MADSEN  I. C. 《Journal of Petrology》1993,34(5):867-900

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.  相似文献   

Stratiform and vein U,Mo and Cu mineralization in the Novoveská Huta area,CSFR     

I. Rojkovič  L. Novotny  M. Háber 《Mineralium Deposita》1993,28(1):58-65

U-Mo and Cu mineralization occurs in horizons as well as in veins in the Permian formations near Novoveská Huta. Ore mineralization is represented by uraninite, U-Ti oxides, coffinite, molybdenite, chalcopyrite, tennantite and pyrite. The isotopic composition of S and C displays a larger variability in the stratiform ores (³⁴S from –32.7 to +2.7 and ¹³C from –27.1 to — 0.5) These data suggest mixing of meteoric solutions with fluids of volcanic origin and a complex history. There is a narrower range of ³⁴S from –18.8 to –4.6 and ¹³C from –6.3 to –2.5% in quartz-carbonate veins with Cu mineralization suggesting a deep source of ore-bearing solutions. The Permian volcanics were a significant source of ore elements.Their contents of U, Mo, Cu and Y are from two to eight times higher than in sedimentary rocks. Accumulations of ore elements in the horizons were formed by the reduction and adsorption processes 240 ± 30 Ma ago according to U-Pb isotopic dating. Due to Alpine tectonism, these low-grade ores (U<0.1 wt%) were remobilized and higher-grade U-Mo ores (U>0.1 wt%) were formed 130 ± 20 Ma ago at temperatures ranging from 110 to 120° C, according to fluid inclusions. Younger veins with Cu mineralization were formed 115 ± 10 Ma according to the model age of Pb at temperatures ranging from 95 to 190°C.  相似文献   

Recreation on public lands in New Zealand — past,present and future     

Kay L. Booth 《GeoJournal》1993,29(3):299-305

Since the turn of the century, recreation has grown as a motivating force in public land administration. Today, the Department of Conservation manages approximately one third of New Zealand's outdoor recreation resources and has the mandate to foster the use of natural and historic resources for recreation, and to allow their use for tourism (Conservation Act 1987:8). This paper traces the emergence of a recreation perspective within public land administration and examines the development of a recreation philosophy and policy within the Department of Conservation. It suggests future directions for outdoor recreation management in New Zealand.  相似文献   

Electron paramagnetic resonance of Sc3+-stabilized CO 3 3− molecule-ion in natural calcite     

R. M. Mineyeva  L. V. Bershov  A. V. Speranskiy 《Physics and Chemistry of Minerals》1993,20(2):136-140

Electron paramagnetic resonance (EPR) spectra of CO ₃ ^3– molecule-ions stabilized by Sc³⁺ in natural calcite were identified and studied at X-band frequencies and room temperature. The principal values of the g-tensor (g _xx= 1.9997, g _yy = 2.0030, g _zz = 1.9972) and the direction cosines of the g and A tensors for CO ₃ ^3– -Sc³⁺ center were found to be close to that for the well-known CO ₃ ^3– -Y³⁺ center. A quantitative comparison of different impurity contents in calcite samples and analysis of the intensities of forbidden transitions were used to identify Sc³⁺. An estimation of the unpaired electron spin density on the nuclei of paramagnetic centers confirms that both centers, CO ₃ ^3– -Sc³⁺ and CO ₃ ^3– -Y³⁺, have the same nature.  相似文献