Native Sn-Pb droplets in a zeolitic amygdale (Isle of Mull, Inner Hebrides)     

Vesselin M. Dekov  Ulf Hålenius  George D. Kamenov  Lars Eriksson  Mark Schmidt 《Geochimica et cosmochimica acta》2009,73(10):2907-2919

Despite the particular scientific interest in the elements with high affinity to S and O₂, but found in zero-valence state in nature, the origin of these native minerals has been little explored and remains obscure. Here we describe unique Sn-Pb droplets found in a closed analcime-calcite amygdale collected from a basaltic unit cropping out at Carsaig Bay (Isle of Mull, Inner Hebrides). The droplets consist of intimate intergrowths of nearly pure Sn⁰ and Pb⁰ domains in proportion 88:12 and are enveloped in a thin, brownish film of organic composition. The occurrence of the Sn-Pb droplets in a closed amygdale, their relationship with the host analcime + calcite and their Pb isotope composition (which does not match any known anthropogenic Pb source) rule out the possibility of anthropogenic contamination and support the natural origin of the Sn-Pb alloy.The variable isotope (Pb, Sr, Nd) compositions in different members of the host basaltic sequence suggest that a parent basaltic magma was modified by crustal assimilation and post-emplacement alteration processes. Considering all possible explanations, it appears that the most likely source of Pb for the Sn-Pb alloy is a discrete basaltic unit with an isotopic composition comparable to the Antrim basalts (Northern Ireland). The amygdale phases, on the other hand, show isotopic evidence for incorporation of elements from both local basaltic and sedimentary units. The apparent isotopic disequilibrium between Sn-Pb droplets and amygdale phases indicates a complex, multi-stage fluid evolution. The occurrence of Sn-Pb droplets in organic capsules suggests that the droplets and the enveloping organic substances are co-precipitates. This implies that the transportation and deposition of Sn and Pb might have occurred through organometallic compounds. We assume interaction of seawater fluids carrying metals leached from basaltic rocks with hydrocarbons from sedimentary units as a prerequisite for the formation of the organometallic complexes. The zeolites lining the basaltic vesicles might have destabilized the migrating organo-Sn and Pb compounds causing their breakdown and precipitation of Sn-Pb alloy.  相似文献   

Depletion and recharge of soil water in two stands of norway spruce (picea abies (l.) karst)     

Lars G. Nordn 《水文研究》1990,4(3):197-213

Depletion and recharge dynamics of soil water were studied at two forest sites in Northern and Southern Sweden during three growing seasons. At each site, having a stand of Norway spruce (Picea abies (L.) Karst), soil water potential was measured with 90 gypsum blocks in 30 profiles at depths of 6, 20, and 50 cm from the soil surface. The size of the rectangular plots was 250 m². The large variation in soil water potential during desiccation periods extended throughout the measuring range of the gypsum blocks. The soil water potentials, at different times and depths, were log-normally distributed during only parts of the desiccation periods. Due to the large variation and skewed distribution of soil water potentials the nonparametric Spearman rank correlation statistics was used to analyse the pattern of desiccation and rewetting of the soil. In the beginning of a dry period the topsoil was more efficiently desiccated than the subsoil at both sites. This difference lasted throughout all droughts at the southern site and was explained by a higher root density in the topsoil. At the northern site, however, there was no difference in the degree of desiccation at different soil depths during an extended desiccation period. While certain microsites tended to be more depleted than others during desiccation periods, this did not prove to be significantly correlated to the rewetting of the soil after the different droughts. There was a vertical relationship in soil water desiccation in which an accentuated water depletion at the 6 cm soil depth was followed by a similar strong depletion 14 cm lower in the same observation profile. Strongly desiccated observation profiles were not necessarily situated close to each other but seemed randomly spread over the site. There was no relationship between extracted water at any of the three soil depths in the different observation profiles and proximity to trees or tree size.  相似文献   

Predicted wavelengths of coronal transitions in the configurations 3s 23p 2, 3s 23p 3 and 3s 23p 4     

Lars Åke Svensson 《Solar physics》1971,18(2):232-243

The level intervals in the ground configurations 3s ²3p ^k(k = 2, 3, 4) have been studied through the isoelectronic sequences up to Ni. Semiempirical expressions for the parameters F ₂(pp) and _p, are derived from observed data and the intervals are recalculated from interpolated or extrapolated values of the parameters. As a result, predicted wavelengths of magnetic-dipole transitions within the configurations are obtained with an estimated uncertainty of one or two Å.  相似文献   

Pitch angle and energy distributions of auroral electrons measured by the ESRO 4 satellite     

Lars Eliasson  Lars-Åke Holmgren  Kjell Rönnmark 《Planetary and Space Science》1979,27(1):87-97

Energy spectra and angular distributions of auroral electrons in the energy range 0.2–16 keV measured by the low-altitude polar orbiting satellite ESRO 4 are presented. The observations were made in the altitude range 800–1000 km near magnetic midnight. Energy-time spectrograms show inverted-V structures with peaked energy spectra. The inverted-V events are associated with anisotropic electron pitch angle distributions peaked at 0 deg. Frequently these distributions have a maximum also at 90 deg. Measurements of >43 keV electrons indicate that the acceleration probably occurs on closed field lines. It is found that many properties of the observed particle distributions can be explained by acceleration in an electric field parallel to the magnetic field lines, if trapping of particles under an increasing potential drop is included in the model.  相似文献   

Energy properties and shoaling of higher-order stokes waves on a current   总被引：1，自引：0，他引：1  

Ivar G. Jonsson  Lars Arneborg 《Ocean Engineering》1995,22(8)

The energy density, the energy flux, the set-down, the radiation stress, and some wave energy velocities have been derived correct to fourth order in wave steepness for waves on a vorticity-free current. The energy flux and the set-down have been used for shoaling predictions for finite amplitude waves with and without a net volume flux. The results with a zero volume flux are compared with more accurate shoaling predictions showing rather good accordance, except for large steepnesses. This also applies to the deep water wave energy transport velocity. The results with a net volume flux show that the steepness of the waves reduces the influence of this flux on the wave evolution. Some problems in connection with the orders in Stokes waves are discussed, among others concerning the dispersion relation and the orders of integral properties. Bed shear and accompanying dissipation is neglected.  相似文献   

Reproductive success in relation to salinity for three flatfish species, dab (Limanda limanda), plaice (Pleuronectes platessa), and flounder (Pleuronectes flesus), in the brackish water Baltic Sea     

Nissling  Anders; Westin  Lars; Hjerne  Olle 《ICES Journal of Marine Science》2002,59(1):93-108

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An ecosystem modeling approach to predicting cod recruitment     

Einar Svendsen  Morten Skogen  Paul Budgell  Geir Huse  Jan Erik Stiansen  Bjrn dlandsvik  Frode Vikeb  Lars Asplin  Svein Sundby 《Deep Sea Research Part II: Topical Studies in Oceanography》2007,54(23-26):2810

The Norwegian Ecological Model (NORWECOM) biophysical model system implemented with the ROMS ocean circulation model has been run to simulate conditions over the last 25 years for the North Atlantic. Modeled time series of water volume fluxes, primary production, and drift of cod larvae through their modeled ambient temperature fields have been analyzed in conjunction with VPA estimated time series of 3-year-old cod recruits in the Barents Sea. Individual time series account for less than 50% of the recruitment variability; however, a combination of simulated flow of Atlantic water into the Barents Sea and local primary production accounts for 70% of the variability with a 3-year lead. The associated regression predicts increased recruitment between 2007 and 2008 from about 450–700 million individuals with a standard error of nearly 150 million.  相似文献   

Bottom friction caused by boundary layer streaming beneath random waves for laminar and smooth turbulent flow     

Dag Myrhaug  Lars Erik Holmedal 《Ocean Engineering》2005,32(2):578-222

The effect of boundary layer streaming on the sea bed shear stresses, beneath random waves, is investigated for laminar flow as well as smooth turbulent flow. It is demonstrated how bottom friction formulas for regular waves can be used to obtain the bed shear stresses resulting from steady streaming under random waves. As a result, friction factors for steady streaming under random waves are provided, and the effect of streaming versus the effect of linear waves is discussed. For laminar flow the effect of second order Stokes waves is also included. Examples are included to illustrate the applicability of the present practical method, and results are obtained using data typical for field conditions.  相似文献   

Models to predict Secchi depth in small glacial lakes     

Lars Håkanson 《Aquatic Sciences - Research Across Boundaries》1995,57(1):31-53

This study quantifies and ranks variables of significance to predict mean values of Secchi depth in small glacial lakes. The work is based on a new, extensive set of data from 88 Swedish lakes and their catchments. Several empirical models based on catchment and lake morphometric parameters are presented. These empirical models can only be used to predict Secchi depth for lakes of the same type, and the models based on geological map parameters can evidently not be used for time-dependent and site typical predictions of Secchi depth. However, many of the principles behind the results ought to be valid for lakes in general. Various hypotheses concerning the factors regulating the variability in mean Secchi depth among lakes are formulated and tested. The most important variables are: Lake colour (expressing allogenic input of different types of humic materials), total-P and lake temperature (measures of production of autogenic materials). The most important map parameters are: The mean depth (linked to resuspension and lake morphometry) and the ratio between the drainage area and lake area (expressing the linkage between catchment and lake). The predictability of some of the models cannot be markedly improved by accounting for the distribution of the characteristics in the drainage area (using the drainage area zonation technique). The variability in mean Secchi depth from other factors, such as precipitation and anthropogenic load, may then be quantitatively differentiated from the impact of these geological factors, which can statistically explain 68% of the variability in Secchi depth among these lakes. The model based on map parameters can also be used to estimate natural, preindustrial reference values of Secchi depth.  相似文献   

Radiation pressure correction to meteor orbits     

Bo ». S. Gustafson  Lars G. Adolfsson 《Earth, Moon, and Planets》1995,71(3):327-332

We present a method to calculate the radiation pressure force to gravity ratio on meteoroids from their atmospheric flight. Radiation pressure corrections to meteor orbits are negligible for fireballs; of the order of or less than the measurement errors ( 1%) for photographic meteors; of the order of and in some cases substantially larger than the measurement errors ( 10%) for radar meteors.  相似文献