Morphology, origin and infrared microthermometry of fluid inclusions in pyrite from the Radka epithermal copper deposit, Srednogorie zone, Bulgaria   总被引：3，自引：0，他引：3  

Kalin Kouzmanov  Laurent Bailly  Claire Ramboz  Olivier Rouer  Jean-Michel Bény 《Mineralium Deposita》2002,37(6-7):599-613

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Characterization and migration of atmospheric REE in soils and surface waters     

Dominique AubertPeter Stille  Anne ProbstFrançois Gauthier-lafaye  Laurent PourcelotMireille Del nero 《Geochimica et cosmochimica acta》2002,66(19):3339-3350

Rainwater and snow collected from three different sites in France (Vosges Mountains, French Alps and Strasbourg) show more or less similar shapes of their REE distribution patterns. Rainwater from Strasbourg is the most REE enriched sample, whereas precipitations from the two mountainous, less polluted catchments are less REE enriched and have concentrations close to seawater. They are all strongly LREE depleted.Different water samples from an Alpine watershed comprising snow, interstitial, puddle and streamwater show similar REE distributions with LREE enrichment (rainwater normalized) but MREE and HREE depletion. In this environment, where water transfer from the soil to the river is very quick due to the low thickness of the soils, it appears that REE in streamwater mainly originate from atmospheric inputs. Different is the behaviour of the REE in the spring- and streamwaters from the Vosges Mountains. These waters of long residence time in the deep soil horizons react with soil and bedrock REE carrying minerals and show especially significant negative Eu anomalies compared to atmospheric inputs. Their Sr and Nd isotopic data suggest that most of the Sr and Nd originate from apatite leaching or dissolution. Soil solutions and soil leachates from the upper soil horizons due to alteration processes strongly depleted in REE carrying minerals, have REE distribution patterns close to those of lichens and throughfall. Throughfall is slightly more enriched especially in light REE than filtered rainwater probably due to leaching of atmospheric particles deposited on the foliage and also to leaf excretion.Data suggest that Sr and Nd isotopes of the soil solutions in the upper soil horizons originate from two different sources: 1) An atmospheric source with fertilizer, dust and seawater components and 2) A source mainly determined by mineral dissolution in the soil. These two different sources are also recognizable in the Sr and Nd isotopic composition of the tree’s throughfall solution. The atmospheric contributions of Sr and Nd to throughfall and soil solution are of 20 to 70 and 20%, respectively. In springwater, however, the atmospheric Sr and REE contribution is not detectable.  相似文献   

Enrichissement en uranium authigène dans les sédiments glaciaires de l'océan AustralEnrichments in authigenic uranium in glacial sediments of the Southern Ocean     

Laurent Dezileau  Gilles Bareille  Jean-Louis Reyss 《Comptes Rendus Geoscience》2002,334(14):1039-1046

Four sediment cores from the Polar frontal zone and the Antarctic zone in the Indian sector of the Southern Ocean present an increase of authigenic uranium during glacial periods. We show that this increase in uranium is due to a combination of (i) an increase in the lateral transport of organic matter, (ii) a decrease in the oxygen in deep waters, and (iii) a process of diagenesis. It appears that uranium concentration cannot be used as a proxy of palaeoproductivity in the Southern Ocean, as previously suggested by Kumar et al. in 1995. To cite this article: L. Dezileau et al., C. R. Geoscience 334 (2002) 1039–1046.  相似文献   

Reconstruction of atmospheric CO2 from ice-core data and the deep-sea record of ontong Java plateau: the Milankovitch chron     

Wolfgang H. Berger  Memorie K. Yasuda  Torsten Bickert  Gerold Wefer 《International Journal of Earth Sciences》1996,85(3):466-495

We provide a reconstruction of atmospheric CO₂ from deep-sea sediments, for the past 625000 years (Milankovitch chron). Our database consists of a Milankovitch template of sea-level variation in combination with a unique data set for the deep-sea record for Ontong Java plateau in the western equatorial Pacific. We redate the Vostok ice-core data of Barnola et al. (1987). To make the reconstructions we employ multiple regression between deep-sea data, on one hand, and ice-core CO₂ data in Antarctica, on the other. The patterns of correlation suggest that the main factors controlling atmospheric CO₂ can be described as a combination of sea-level state and sea-level change. For best results squared values of state and change are used. The square-of-sea-level rule agrees with the concept that shelf processes are important modulators of atmospheric CO₂ (e.g., budgets of shelf organic carbon and shelf carbonate, nitrate reduction). The square-of-change rule implies that, on short timescales, any major disturbance of the system results in a temporary rise in atmospheric CO₂.  相似文献   

Foliation fields and 3D cartography in geology: Principles of a method based on potential interpolation   总被引：4，自引：0，他引：4  

Christian Lajaunie  Gabriel Courrioux  Laurent Manuel 《Mathematical Geology》1997,29(4):571-584

A modeling method that takes into account known points on a geological interface and plane orientation data such as stratification or foliation planes is described and tested. The orientations data do not necessarily belong to one of the interfaces but are assumed to sample the main anisotropy of a geological formation as in current geological situations. The problem is to determine the surfaces which pass through the known points on interfaces and which are compatible with the orientation data. The method is based on the interpolation of a scalar field defined in the space the gradient in which is orthogonal to the orientations, given that some points have the same but unknown scalar value (points of the same interface), and that scalar gradient is known on the other points (foliations). The modeled interfaces are represented as isovalues of the interpolated field. Preliminary two-dimensional tests carried-out with different covariance models demonstrate the validity of the method, which is easily transposable in three dimensions.  相似文献   

Assessing rapid environmental change using geoindicators   总被引：1，自引：1，他引：1  

A. R. Berger 《Environmental Geology》1997,32(1):36-44

 Geoindicators are high-resolution measures of short-term (<100 years) surface or near-surface changes in earth processes, and phenomena that are significant for environmental monitoring and assessment. They are based on standard concepts and procedures and can be used to track changes in fluvial, coastal, desert, mountain, permafrost and other terrestrial areas. Geoindicators assess both catastrophic events and those that are more gradual, but evident within a human lifespan. Most deal with changes on the landscape (0.1–10 km) and meso-scales (10–100 km), but some, such as relative sea level and volcanic unrest, have regional and global dimensions. Some are complex and costly to measure, others are relatively simple and easy to apply. Geoindicators can also be used to unravel trends over the past few centuries and longer through paleoenvironmental research, thus providing the important baselines against which human-induced and natural stresses can be better understood. Geoindicators have been designed by the International Union of Geological Sciences as an aid to state-of-the-environment reporting and long-term ecological monitoring. Received: 26 July 1996 / Accepted: 1 November 1996  相似文献   

Remote sensing detection of atmospheric pollutants by differential absorption LIDAR 510M/SODAR PA2 mobile system     

J. Keder  M. Střižík  P. Berger  A. Černý  P. Engst  I. Němcová 《Meteorology and Atmospheric Physics》2004,85(1-3):155-164

Summary Air pollution problem in the Czech Republic is very complex due to large number of factors as turbulent dispersion and chemical reactions concurring in the status of the PBL. For this 3D distribution of pollutants is a key information that cannot be given by conventional monitoring stations. Combined use of DIAL lidar and sodar can give access to such information. Case studies of air pollutants transport are presented using 3D concentration fields of NO₂ and ozone measured by lidar and meteorological conditions monitored by Doppler Sodar.  相似文献   

Mountain Protection Forests against Natural Hazards and Risks: New French Developments by Integrating Forests in Risk Zoning   总被引：4，自引：0，他引：4  

Berger  F.  Rey  F. 《Natural Hazards》2004,33(3):395-404

Forests can play a very significant role in protection against natural hazards and risks in mountain lands, especially against erosion and rockfalls. This paper first assesses knowledge concerning the capacity of forests to control natural hazards, with emphasis placed on forest location in catchments or slopes. Zoning aspects are then presented; based on the use of GIS, they allow determining priorities for forestry operations (cuts and biological engineering), in view to setting up an 'optimal management' of mountain forest ecosystems. Finally, an explanation is given of how the results of research are used for the management and planning of mountain ecosystems, illustrated by an example of researcher-practitioner transfer in France. Zoning, prevention, display and regular aspects are developed. On the basis of the experience and knowledge presented here, recommendations are proposed to better take into account the role of mountain forests in the control of natural hazards and risks. It is necessary to have an adapted legislative and economic framework, define priority forest intervention zones and determine an adapted sylviculture.  相似文献   

Grain coarsening in contact metamorphic carbonates: effects of second-phase particles, fluid flow and thermal perturbations   总被引：3，自引：0，他引：3  

A. Berger  M. Herwegh 《Journal of Metamorphic Geology》2004,22(5):459-474

Under contact metamorphic conditions, carbonate rocks in the direct vicinity of the Adamello pluton reflect a temperature‐induced grain coarsening. Despite this large‐scale trend, a considerable grain size scatter occurs on the outcrop‐scale indicating local influence of second‐order effects such as thermal perturbations, fluid flow and second‐phase particles. Second‐phase particles, whose sizes range from nano‐ to the micron‐scale, induce the most pronounced data scatter resulting in grain sizes too small by up to a factor of 10, compared with theoretical grain growth in a pure system. Such values are restricted to relatively impure samples consisting of up to 10 vol.% micron‐scale second‐phase particles, or to samples containing a large number of nano‐scale particles. The obtained data set suggests that the second phases induce a temperature‐controlled reduction on calcite grain growth. The mean calcite grain size can therefore be expressed in the form D = C₂ e^Q*/RT(d_p/f_p)^m*, where C₂ is a constant, Q* is an activation energy, T the temperature and m* the exponent of the ratio d_p/f_p, i.e. of the average size of the second phases divided by their volume fraction. However, more data are needed to obtain reliable values for C₂ and Q*. Besides variations in the average grain size, the presence of second‐phase particles generates crystal size distribution (CSD) shapes characterized by lognormal distributions, which differ from the Gaussian‐type distributions of the pure samples. In contrast, fluid‐enhanced grain growth does not change the shape of the CSDs, but due to enhanced transport properties, the average grain sizes increase by a factor of 2 and the variance of the distribution increases. Stable δ¹⁸O and δ¹³C isotope ratios in fluid‐affected zones only deviate slightly from the host rock values, suggesting low fluid/rock ratios. Grain growth modelling indicates that the fluid‐induced grain size variations can develop within several ka. As inferred from a combination of thermal and grain growth modelling, dykes with widths of up to 1 m have only a restricted influence on grain size deviations smaller than a factor of 1.1. To summarize, considerable grain size variations of up to one order of magnitude can locally result from second‐order effects. Such effects require special attention when comparing experimentally derived grain growth kinetics with field studies.  相似文献   

Occurence of abundant diradicaloid moieties in the insoluble organic matter from the Orgueil and Murchison meteorites: a fingerprint of its extraterrestrial origin?     

Laurent Binet  Didier Gourier  François Robert 《Geochimica et cosmochimica acta》2004,68(4):881-891

The highly aromatic structure of the macromolecular organic matter (OM) of the Murchison and Orgueil meteorites was recently shown to contain free organic radicals which are concentrated in micro-regions in contrast with terrestrial samples which always show an homogeneous distribution of radicals. An additional signature is revealed, in the present study, by the evolution of the radical concentration with temperature. Whereas in terrestrial samples, this concentration is independent of temperature (Curie magnetism), a significant increase is observed above 150 K in the two meteorites. Based on the electronic structure of organic radicals, calculated by Extended Hückel and Density Functional methods, this behavior was assigned to the occurrence of diradicaloid moieties hosted by aromatic structures of 10 to 15 rings and having a quinoidal structure. They represent 40 and 25% of the total radicals in Orgueil and Murchison, respectively. The search for the cosmochemical interpretation of this unique observation should open a new field of experimental investigations.  相似文献