Processes governing the carbon chemistry during the SAGE experiment     

K.I. Currie  B. MacaskillM.R. Reid  C.S. Law 《Deep Sea Research Part II: Topical Studies in Oceanography》2011,58(6):851-860

Measurements of pCO₂, pH and alkalinity in the surface waters of an iron fertilised patch of sub-Antarctic water were made during SAGE (SOLAS SAGE: Surface-Ocean Lower Atmosphere Studies Air-Sea Gas Experiment). The iron addition induced a minor phytoplankton bloom, however the patch dynamics were dominated by physical processes which suppressed and masked the biological effects. The Lagrangian nature of the experiment allowed the carbonate chemistry in the patch to be followed for 15.5 days, and the relative importance of the biological and physical factors influencing the surface water pCO₂ was estimated. The pCO₂ of the surface waters of the patch increased from 327 ??atm prior to iron addition to 338 ??atm on Day 14, effects of vertical and horizontal mixing offset the 15 ??atm drawdown that would have occurred had the induced biological uptake been the sole factor to influence the pCO₂. The air-sea carbon flux calculated using the measured skin temperature and a piston velocity parameterisation determined during SAGE (Ho et al., 2006) was 98.5% of the flux determined using conventional bulk temperature measurement and the Wanninkhof (1992) piston velocity parameterisation. The skin temperature alone contributed to an 8% increase in the flux compared with that determined using bulk temperature.  相似文献   

Impacts of maintenance dredged material disposal on macrobenthic structure and secondary productivity     

Bolam SG  Barry J  Bolam T  Mason C  Rumney HS  Thain JE  Law RJ 《Marine pollution bulletin》2011,62(10):2230-2245

The results of a monitoring programme to assess the spatial impacts associated with ongoing dredged material disposal activity at a dispersive, coastal disposal site (southwest UK) are described. Benthic impacts were assessed using benthic community structure and secondary productivity estimates.Analyses of univariate indices (including secondary production) and multivariate community structure revealed differences between stations inside and those outside the disposal site were minimal. Generally, stations within and outside the disposal site were characterised by the same species. Regression models indicated that the variability in biological structure and secondary production was predominantly accounted for by natural variables (e.g., depth, sediment granulometry) with only a small amount of residual variability being due to contaminant variables. Thus, the elevated levels of certain contaminants in the vicinity of the disposal area were not sufficient to result in significant ecological or ecotoxicological changes. We ascribe such findings partly to the dispersive nature of the disposal site.  相似文献   

Chlorobiphenyls in the blubber of harbour porpoises (Phocoena phocoena) from the UK: Levels and trends 1991-2005     

Robin J. Law  Philippe Bersuder  Rob Deaville  Paul D. Jepson 《Marine pollution bulletin》2010,60(3):470-145

Harbour porpoises sampled within the UK Cetacean Strandings Investigation Programme have been analysed for 25 chlorobiphenyl congeners. In all, 440 porpoises stranded or bycaught during the period 1991-2005 were studied. There are regional differences in the trend in summed congener concentrations over time but, despite controls on PCBs having been in place for decades, they are declining only slowly. Their toxic impacts in UK porpoises - increased susceptibility to infectious disease mortality in the most contaminated individuals - looks likely to continue for some time yet. Further efforts to limit or eliminate PCB discharges to the marine environment are still needed.  相似文献   

Contaminants in cetaceans from UK waters: status as assessed within the Cetacean Strandings Investigation Programme from 1990 to 2008     

Law RJ  Barry J  Barber JL  Bersuder P  Deaville R  Reid RJ  Brownlow A  Penrose R  Barnett J  Loveridge J  Smith B  Jepson PD 《Marine pollution bulletin》2012,64(7):1485-1494

Since 1990, tissue samples from UK-stranded and -bycaught cetaceans have been available for study of contaminant burdens. These have been used to study spatial and temporal trends in concentrations in UK waters, and to investigate potential associations between contaminants and health status. We describe the current status of cetaceans (primarily harbour porpoises, Phocoena phocoena) in UK waters in relation to pollution. Concentrations of BDEs, HBCD, and the organochlorine pesticides are declining. In contrast, concentrations of CBs have plateaued following earlier reductions due to regulation of use, and further reductions are likely to take decades. Blubber PCB concentrations are still at toxicologically significant levels in many harbour porpoises and regularly occur at even higher levels in bottlenose dolphins and killer whales due to their higher trophic level in marine food chains. Further reductions in PCB inputs into the marine environment are needed to mitigate risk from PCB exposure in these species.  相似文献   

Experimental study of human-induced effects on floor slab of an ancient Tibetan structure     

Yang Na  Guo Ting  S.S. Law 《地震工程与工程振动(英文版)》2012,11(4):513-523

With the opening of ancient Tibetan structures to visitors worldwide, human load has become the principal live load on these structures. This project studies the properties of the floor structure of an ancient Tibetan building and its behavior under human-induced load effects. Tests were conducted with static and dynamic crowd load, including stepping and jogging by people at a fixed position. The tests show that the floor structure does not behave as a continuous slab. It takes the load from local areas with minimal load transference properties. The acceleration response shows significant peaks when the footstep frequency is close to the natural frequency of the structure, but the human jogging excitation frequency does not have any obvious effect on the structural response. The elastic modulus of the Agatu material is estimated to be close to zero from the measured natural frequency of the slab. The Agatu material is concluded to be a discrete compacted material with insignificant contribution to the structural rigidity of the floor slab.  相似文献   

The chaotic characteristics of landslide evolution: a case study of Xintan landslide     

Zhiquan Huang  K. Tim Law  Handong Liu  Tong Jiang 《Environmental Geology》2009,56(8):1585-1591

A new method based on the chaos theory is used to assess the evolution process of a slope system. The method is applied to the Xintan landslide and the results show: (1) the slope movement is a complex process of the slope going in and out of the stable and chaotic state; (2) the method reveals the evolution process of the slope pointing to the slope failure while the observed movement shows a simple monotonic increase with time; (3) the method is not sufficiently mature to precisely predict the time of failure but it has potential for improvement with further research and more field data for analysis.  相似文献   

Subsonic aircraft and ozone trends     

A. E. Jones  K. S. Law  J. A. Pyle 《Journal of Atmospheric Chemistry》1996,23(1):89-105

Growth in subsonic air traffic over the past 20 years has been dramatic, with an annual increase of }6.1% over the decade between 1978 and 1988. Furthermore, aircraft activities in the year 2000 are predicted to be double those of 1990, with a shift towards more high-flying, longhaul subsonics. Aircraft exhaust gases increase the amount of nitrogen oxides (NO _x ) in the upper troposphere/lower stratosphere through injection at cruise altitudes. Given that NO _x is instrumental in tropospheric ozone production and stratospheric ozone destruction, it is important to determine the influence of subsonic aircraft NO _x emissions on levels of atmospheric ozone. This paper describes calculations designed to investigate the impact that subsonic aircraft may already have had on the atmosphere during the 1980s, run in a 2-D chemical-radiative-transport model. The results indicate a significant increase in upper tropospheric ozone over the decade arising from aircraft emissions. However, when comparing model results with observational data, certain discrepancies appear. Lower stratospheric ozone loss over the 1980s does not appear to be greatly altered by the inclusion of aircraft emissions in the model. However, given the trend in greater numbers of long-haul subsonic aircraft, this factor must be considered in any further calculations.  相似文献   

Hydrocarbon concentrations in water and sediments from UK marine waters,determined by fluorescence spectroscopy     

R.J. Law 《Marine pollution bulletin》1981,12(5):153-157

Between January 1978 and September 1979 samples of subsurface (1 m) water and surface sediment were collected from sites in the North Sea, English Channel, Irish Sea and a number of estuarine areas. These have been analysed by fluorescence spectroscopy (UVF) in order to provide information on the levels of hydrocarbons generally present in UK marine waters.Total hydrocarbon concentrations (THCs) of water samples ranged from 1.1–74 μg l.^?1 Ekofisk crude oil equivalents, all values greater than 3.5 μg l.^?1 occurring inshore. In offshore areas the mean THCs were: 1.3 μg l.^?1 in the northern North Sea, 1.5 μg l.^?1 in the western Channel, 2.5 μg l.^?1 in the eastern Channel and southern North Sea, and 2.6 μg l.^?1 in the Irish Sea.THCs of sediment samples ranged from 0.27–340 μ g^?1 dry weight Ekofisk crude oil equivalents, the highest concentration being in the Queen's Channel, the main entrance to the River Mersey.  相似文献   

Uranium mineralisation near surda in the singhbhum copper belt of bihar (India)     

Y. D. Law 《Mineralium Deposita》1970,5(4):390-395

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The Eleni V oil spill: Fate and effects of the oil over the first twelve months: Part II. Biological effects     

R.A.A. Blackman  R.J. Law 《Marine pollution bulletin》1980,11(8):217-220

The general effects of the Eleni V oil spill on fisheries and intertidal organisms are described. There appears to have been little damage except by direct smothering. Oil hydrocarbon concentrations have been followed in a small intertidal population of mussels (Mytilus edulis) at Corton beach. Although the area became visually clean of oil, hydrocarbon concentrations in mussel flesh remained high 12 months after the spill and depuration rates in the laboratory were very slow. Shrimps (Crangon crangon) exposed to a water extract of beached Eleni V oil for 42 days showed no ill effects and little uptake of hydrocarbons. At the North Harbour site, where beached oil has not been disturbed, it appears that the fauna, used to oil contamination from other sources, has been little affected by the additional Eleni V oil.  相似文献