Interpreting CO2–SIc relationship to estimate CO2 baseline in limestone aquifers     

N. Peyraube  R. Lastennet  A. Denis  P. Malaurent  J. D. Villanueva 《Environmental Earth Sciences》2014,72(10):4207-4215

Saturation index with respect to calcite (SIc) and equilibrium CO₂ partial pressure are important parameters to study groundwater in limestone aquifers. Aside from their use in time series, CO₂ and SIc are used to estimate the baseline of CO₂ in the vadose zone. The objective of this paper is to present conceptual examples on the use of the CO₂–SIc relationship to have new information from usual parameters. Case study was considered as an example of use from Cussac site, a limestone aquifer in southwest of France. The result showed that CO₂ baseline in unsaturated zone is found close to 25,000 ± 1,000 ppm.  相似文献   

The lower limit of the Doppler factor for a Fermi blazar sample     

Jun-Hui Fan  Denis Bastieri  Jiang-He Yang  Yi Liu  Tong-Xu Hua  Yu-Hai Yuan  De-Xiang Wu 《中国天文和天体物理学报》2014,(9)

We selected 457 blazars(193 flat spectrum radio quasars, 61 lowsynchrotron peaked blazars, 69 intermediate-synchrotron peaked blazars and 134high-synchrotron peaked blazars) from the second Fermi-LAT catalog(2FGL) of γ-ray sources, which have X-ray observations. We calculated the lower limits for their Doppler factors, δγ, and compared the lower limits with the available Doppler factors and the apparent superluminal velocities in the literature.  相似文献   

The activity coefficients of Fe(III) hydroxide complexes in NaCl and NaClO₄ solutions     

Frank J. Millero  Denis Pierrot 《Geochimica et cosmochimica acta》2007,71(20):4825-4833

The osmotic coefficients of FeCl₃ at 25 °C from 0.15 to 1.7 m [Rumyantsev et al., Z. Phys. Chem., 218, 1089-1127, 2004] have been used to determine the Pitzer parameters (β⁽⁰⁾, β⁽¹⁾ and C^?) for FeCl₃. Since the differences in the Pitzer coefficients of rare earths in NaCl and NaClO₄ are small, the values of Fe(ClO₄)₃ have been estimated using the differences between La(ClO₄)₃ and LaCl₃. The Pitzer coefficients for FeCl₃ combined with enthalpy and heat capacity data for the rare earths can be used to estimate the activity coefficients of Fe³⁺ in NaCl over a wide range of temperatures (0 to 50 °C) and ionic strength (0 to 6 m).The activity coefficients of Fe³⁺ in NaCl and NaClO₄ solutions have been used to determine the activity coefficients of Fe(OH)²⁺ in these solutions from the measured first hydrolysis constants of Fe³⁺ [Byrne et al., Mar. Chem., 97, 34-48, 2005]. The activity coefficients of , Fe(OH)₃ and from 0 to 50 °C have also been determined from the solubility measurements of Fe(III) in NaCl solutions [Liu and Millero, Geochim. Cosmochim Acta, 63, 3487-3497, 1999]. These activity coefficients have been fitted to the Pitzer equations. These results can be used to estimate the speciation of Fe(III) with OH⁻ in natural waters with high concentrations of NaCl from 0 to 50 °C.  相似文献   

Towards a climate event stratigraphy for New Zealand over the past 30 000 years (NZ‐INTIMATE project)     

Brent V. Alloway  David J. Lowe  David J. A. Barrell  Rewi M. Newnham  Peter C. Almond  Paul C. Augustinus  Nancy A. N. Bertler  Lionel Carter  Nicola J. Litchfield  Matt S. McGlone  Jamie Shulmeister  Marcus J. Vandergoes  Paul W. Williams  NZ‐INTIMATE members 《第四纪科学杂志》2007,22(1):9-35

It is widely recognised that the acquisition of high‐resolution palaeoclimate records from southern mid‐latitude sites is essential for establishing a coherent picture of inter‐hemispheric climate change and for better understanding of the role of Antarctic climate dynamics in the global climate system. New Zealand is considered to be a sensitive monitor of climate change because it is one of a few sizeable landmasses in the Southern Hemisphere westerly circulation zone, a critical transition zone between subtropical and Antarctic influences. New Zealand has mountainous axial ranges that amplify the climate signals and, consequently, the environmental gradients are highly sensitive to subtle changes in atmospheric and oceanic conditions. Since 1995, INTIMATE has, through a series of international workshops, sought ways to improve procedures for establishing the precise ages of climate events, and to correlate them with high precision, for the last 30 000 calendar years. The NZ‐INTIMATE project commenced in late 2003, and has involved virtually the entire New Zealand palaeoclimate community. Its aim is to develop an event stratigraphy for the New Zealand region over the past 30 000 years, and to reconcile these events against the established climatostratigraphy of the last glacial cycle which has largely been developed from Northern Hemisphere records (e.g. Last Glacial Maximum (LGM), Termination I, Younger Dryas). An initial outcome of NZ‐INTIMATE has been the identification of a series of well‐dated, high‐resolution onshore and offshore proxy records from a variety of latitudes and elevations on a common calendar timescale from 30 000 cal. yr BP to the present day. High‐resolution records for the last glacial coldest period (LGCP) (including the LGM sensu stricto) and last glacial–interglacial transition (LGIT) from Auckland maars, Kaipo and Otamangakau wetlands on eastern and central North Island, marine core MD97‐2121 east of southern North Island, speleothems on northwest South Island, Okarito wetland on southwestern South Island, are presented. Discontinuous (fragmentary) records comprising compilations of glacial sequences, fluvial sequences, loess accumulation, and aeolian quartz accumulation in an andesitic terrain are described. Comparisons with ice‐core records from Antarctica (EPICA Dome C) and Greenland (GISP2) are discussed. A major advantage immediately evident from these records apart from the speleothem record, is that they are linked precisely by one or more tephra layers. Based on these New Zealand terrestrial and marine records, a reasonably coherent, regionally applicable, sequence of climatically linked stratigraphic events over the past 30 000 cal. yr is emerging. Three major climate events are recognised: (1) LGCP beginning at ca. 28 000 cal. yr BP, ending at Termination I, ca. 18 000 cal. yr BP, and including a warmer and more variable phase between ca. 27 000 and 21 000 cal. yr BP, (2) LGIT between ca. 18 000 and 11 600 cal. yr BP, including a Lateglacial warm period from ca. 14 800 to 13 500 cal. yr BP and a Lateglacial climate reversal between ca. 13 500 and 11 600 cal. yr BP, and (3) Holocene interglacial conditions, with two phases of greatest warmth between ca. 11 600 and 10 800 cal. yr BP and from ca. 6 800 to 6 500 cal. yr BP. Some key boundaries coincide with volcanic tephras. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Bias in hydraulic head measurements from multilevel vibrating-wire piezometers with excessively permeable backfill     

Young  Nathan L.  Lemieux  Jean-Michel  Locat  Pascal  Demers  Denis  Delottier  Hugo  Mony  Laura 《Hydrogeology Journal》2022,30(4):1337-1344

Hydrogeology Journal - An extensive network of multilevel vibrating-wire piezometers (VWP) was recently created to monitor the spatial and temporal variation of pore pressure (and hydraulic head)...  相似文献   

Characterization of karst systems using SIc-Pco2 method coupled with PCA and frequency distribution analysis. Application to karst systems in the Vaucluse county (Southeastern France)     

S. Minvielle  R. Lastennet  A. Denis  N. Peyraube 《Environmental Earth Sciences》2015,74(12):7593-7604

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Quantified,multi-scale X-ray fluorescence element mapping using the Maia detector array: application to mineral deposit studies     

Louise A. Fisher  Denis Fougerouse  James S. Cleverley  Christopher G. Ryan  Steven Micklethwaite  Angela Halfpenny  Robert M. Hough  Mary Gee  David Paterson  Daryl L. Howard  Kathryn Spiers 《Mineralium Deposita》2015,50(6):665-674

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Influence d'un changement climatique dû à une hausse de gaz à effet de serre sur l'agriculture au quebec     

Bhawan Singh  Mustapha El Maayar  Pierre André  Jean‐Pierre Thouez  Christopher Bryant  Denis Provençal 《大气与海洋》2013,51(2):379-399

Abstract

This study, using a climate change scenario generated by the Canadian Climate Centre (CCC) general circulation model (GCM) examines the impacts of such a climate change on agriculture in southern Quebec. Using a crop model from the Food and Agriculture Organization (FAO), yield responses of a variety of cereals, legumes, oleaginous and special crops to climate change are analysed and discussed.

Results show that under the 2 × CO₂ climate scenario the growing season would be longer and accumulation of corn heat units and growing degree days would be more important than under actual climate (1961–1990). One of the more important results of this study is that, on the one hand yield of C₃ cereals would be lower and that of C₄ cereals higher in most agricultural regions. On the other hand, the direct fertilisation effect of increased CO₂ is not considered. It must be cautioned however that we can not generalise results obtained for one legume crop to all legumes.  相似文献   

A search for evidence of critical internal wave reflection on the continental rise and slope off Nova Scotia     

Denis Gilbert 《大气与海洋》2013,51(1):99-122

Abstract

According to linear inviscid theory, the reflection of internal waves off a uniformly sloping bottom should lead to greatly enhanced energy density, and a cross‐isobath alignment of motions, near the critical frequency ω_c for which the wave ray slope equals the bottom slope. Current‐meter data from the continental rise and slope off Nova Scotia are used to test this hypothesis. Near‐bottom energy enhancement at ω_c was found to be significant at the 95% level for 8 out of 30 tests performed, whereas cross‐isobath alignment of motions near ω_c was significant at the 95% level for 10 out of 15 tests performed. Some aspects of the observations that appear to be consistent with non‐linear reflection theory are briefly discussed.  相似文献   

Acidification of Lower St. Lawrence Estuary Bottom Waters     

Alfonso Mucci  Michel Starr  Denis Gilbert  Bjorn Sundby 《大气与海洋》2013,51(3):206-218

Accumulation of metabolic CO₂ can acidify marine waters above and beyond the ongoing acidification of the ocean by anthropogenic CO₂. The impact of respiration on carbonate chemistry and pH is most acute in hypoxic and anoxic basins, where metabolic CO₂ accumulates to high concentrations. The bottom waters of the Lower St. Lawrence Estuary (LSLE), where persistently severe hypoxia has developed over the last 80 years, is one such case. We have reconstructed the evolution of pH in the bottom waters from historical and recent data, and from first principles relating the stoichiometry of CO₂ produced to oxygen consumed during microbial degradation of organic matter. Based on the value of the atmospheric partial pressure of CO₂ that best reproduces the preformed dissolved inorganic carbon concentration in the bottom waters, we estimate the average ventilation age of the bottom waters to be 16?±?3 years. The pH of the bottom waters has decreased by 0.2 to 0.3 over the last 75 years, which is four to six times greater than can be attributed to the uptake of anthropogenic CO₂. The pH decrease is accompanied by a decline in the saturation state with respect to both calcite and aragonite. As of 2007, bottom waters in the LSLE are slightly supersaturated with respect to calcite (Ω_c?≈?1.06?±?0.04) but are strongly undersaturated with respect to aragonite (Ω_a?≈?0.67?±?0.03).

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