Some remarks on making remote sensing-based mapping of elements at risk usable in international development cooperation     

Post  Joachim  Villagr&#;n  Juan Carlos de L&#;on  St-Pierre  Luc 《Natural Hazards》2016,81(1):189-201

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Assessing the susceptibility of gap-graded soils to internal erosion: proposition of a new experimental methodology     

Didier Marot  Abdul Rochim  Hong-Hai Nguyen  Fateh Bendahmane  Luc Sibille 《Natural Hazards》2016,81(1):365-385

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δ³⁰Si and δ²⁹Si Determinations on USGS BHVO-1 and BHVO-2 Reference Materials with a New Configuration on a Nu Plasma Multi-Collector ICP-MS     

Kathrin Abraham  Sophie Opfergelt  François Fripiat  Anne-Julie Cavagna  Jeroen T.M. de Jong  Stephen F. Foley  Luc André  Damien Cardinal 《Geostandards and Geoanalytical Research》2008,32(2):193-202

We report silicon isotopic determinations for USGS rock reference materials BHVO-1 and BHVO-2 using a Nu Plasma multi-collector (MC)-ICP-MS, upgraded with a new adjustable entrance slit, to obtain medium resolution, as well as a stronger primary pump and newly designed sampler and skimmer cones ("B" cones). These settings, combined with the use of collector slits, allowed a resolution to be reached that was sufficient to overcome the ¹⁴N¹⁶O and ¹⁴N₂ interferences overlying the ³⁰Si and the ²⁸Si peaks, respectively, in an earlier set-up. This enabled accurate measurement of both δ³⁰Si and δ²⁹Si. The δ value is expressed in per mil variation relative to the NBS 28 quartz reference material. Based on data acquired from numerous sessions spread over a period of six months, we propose a recommended average δ³⁰Si of −0.33 ± 0.05‰ and −0.29 ± 0.11‰ (2se) for BHVO-1 and BHVO-2, respectively. Our BHVO grand mean silicon isotope composition (δ³⁰Si =−0.31 ± 0.06‰) is significantly more negative than the only published value for BHVO-2, but is in very good agreement with the recently established average value of ocean island basalts (OIB), confirming the conclusion that the OIB reservoir has a distinct isotopic composition from the solar reservoir as sampled by chondrites.  相似文献   

Groundwater flow in the vicinity of two artificial recharge ponds in the Belgian coastal dunes     

A. Vandenbohede  Emmanuel Van Houtte  Luc Lebbe 《Hydrogeology Journal》2008,16(8):1669-1681

Since July 2002, tertiary treated wastewater has been artificially recharged through two infiltration ponds in the dunes of the Belgian western coastal plain. This has formed a lens of artificially recharged water in the dunes’ fresh water lens. Recharged water is recovered by extraction wells located around the ponds. Hydraulic aspects of the artificial recharge and extraction are described using field observations such as geophysical borehole loggings and a tracer test. Borehole logs indicate recharged water up to 20 m below surface, whereas the tracer test gives field data about the residence times of the recharged water. Furthermore, a detailed solute transport model was made of the area surrounding the ponds. Groundwater flow, capture zone, residence times and volume of recharged water in the aquifer are calculated. This shows that the residence time varies between 30 days and 5 years due to the complex flow pattern. The extracted water is a mix of waters with different residence times and natural groundwater, assuring a relatively stable water quality of the extracted water.  相似文献   

The Effect of Breaking Waves on $$\hbox {CO}_2$$ Air–Sea Fluxes in the Coastal Zone     

Lucía Gutiérrez-Loza  Francisco J. Ocampo-Torres  Héctor García-Nava 《Boundary-Layer Meteorology》2018,168(2):343-360

The influence of wave-associated parameters controlling turbulent \(\hbox {CO}_2\) fluxes through the air–sea interface is investigated in a coastal region. A full year of high-quality data of direct estimates of air–sea \(\hbox {CO}_2\) fluxes based on eddy-covariance measurements is presented. The study area located in Todos Santos Bay, Baja California, Mexico, is a net sink of \(\hbox {CO}_2\) with a mean flux of \(-1.3\, \upmu \hbox {mol m}^{-2}\hbox {s}^{-1}\) (\(-41.6\hbox { mol m}^{-2}\hbox {yr}^{-1}\)). The results of a quantile-regression analysis computed between the \(\hbox {CO}_2\) flux and, (1) wind speed, (2) significant wave height, (3) wave steepness, and (4) water temperature, suggest that the significant wave height is the most correlated parameter with the magnitude of the flux but the behaviour of the relation varies along the probability distribution function, with the slopes of the regression lines presenting both positive and negative values. These results imply that the presence of surface waves in coastal areas is the key factor that promotes the increase of the flux from and into the ocean. Further analysis suggests that the local characteristics of the aqueous and atmospheric layers might determine the direction of the flux.  相似文献   

Flowpath controls on high-spatial-resolution water-chemistry profiles in headwater streams     

Rémi Dupas  Jean Causse  Anne Jaffrezic  Luc Aquilina  Patrick Durand 《水文研究》2021,35(6):e14247

Stream water chemistry is routinely measured over time at fixed and sparse sites, which provides a coarse image of spatial variability. Here, we measured nitrate, dissolved organic carbon (DOC) and several chemical proxies for water flowpaths, catchment residence time and biogeochemical transformations, every 50–100 m along 13 km of streams in six agricultural headwater catchments (1.1–3.5km²). The objective was to examine controls on longitudinal nitrate profiles at a high spatial resolution during four seasons: rewetting of the catchments in autumn, winter high-flow, spring recession and summer low-flow. Our results showed monotonic trends in longitudinal profiles for nitrate and DOC, which were opposite for the two solutes. Spatial trends in water-chemistry profiles persisted across seasons, which suggests time-invariant controls on the spatial variations in concentrations. Four catchments exhibited decreasing nitrate and increasing DOC from upstream to downstream, while two catchments exhibited increasing nitrate and decreasing DOC. These smooth gradients did not reflect a longitudinal land-use gradient, but rather an increase in the proportion of groundwater inflows when moving downstream, as suggested by the chemical proxies and punctual discharge measurements. Water chemistry also changed abruptly at confluences, at a farm point source and at a localized groundwater inflow zone.  相似文献   

A Comparative Study of the Use of Organoclay‐Based Formulations and Organic Amendment to Reduce the Leaching of the Herbicide MCPA in Soil     

Alegría Cabrera  Carmen Trigo  Lucía Cox  Rafael Celis  Juan Cornejo 《洁净——土壤、空气、水》2008,36(12):990-995

MCPA (4‐chloro‐2‐methylphenoxyacetic acid) is an acidic herbicide widely used on olive crops in Spain. Due to its anionic form at natural soil pH, there is high risk of leaching and groundwater contamination by the use of this herbicide. The aim of this work was to study the effects of organoclay‐based formulations of MCPA and olive oil waste amendment on MCPA leaching in a sandy loam soil. For this purpose, batch adsorption and column leaching studies were performed. The organoclays used to prepare the clay‐based formulations of MCPA were obtained by treating Wyoming montmorillonite (SWy‐2) and Arizona montmorillonite (SAz‐1) with an amount of hexadecyltrimethylammonium (HDTMA) cation equal to 100% of the CEC of the montmorillonites. The organic residue used in this study was a solid waste from olive oil production (olive oil waste, OOW). The soil was amended with the organic residue at the rate of 10% (w/w). Batch release and column leaching studies indicated that organoclay‐based formulations of MCPA reduced the release rate and the leaching of the herbicide as compared to the use of a conventional formulation containing the herbicide in an immediately available form. The increase in soil organic matter of the soil upon amendment with the organic residue also resulted in greater adsorption and reduced leaching of MCPA in the soil. Accordingly, both the use of organoclay‐based formulations and the amendment of soil with OOW are proposed as efficient strategies to reduce extensive leaching losses associated with the application of MCPA in high‐risk scenarios, such as Mediterranean olive groves.  相似文献   

MODFLOW procedure to simulate axisymmetric flow in radially heterogeneous and layered aquifer systems     

Andy Louwyck  Alexander Vandenbohede  Mark Bakker  Luc Lebbe 《Hydrogeology Journal》2014,22(5):1217-1226

A procedure is outlined to simulate axisymmetric groundwater flow in radially heterogeneous and layered aquifer systems using the unmodified version of MODFLOW. The procedure is straightforward, as it only requires correction of some of the input parameters. In contrast to other MODFLOW procedures to simulate axisymmetric flow, no restrictions are imposed on the type of flow, the discretization of radial distance, or the parameter values. Hence, the method can deal with both confined and unconfined flow, wellbore storage, and axisymmetric aquifer inhomogeneities including effects of finite-thickness skin and gravel pack. Several test cases are presented, which compare the calculated results with existing analytical solutions, the analytic element solver TTim, and the axisymmetric, finite-difference model MAxSym. It is concluded that the MODFLOW procedure is capable of simulating accurately axisymmetric flow in radially heterogeneous multi-aquifer systems.  相似文献   

Analyses of precipitation,temperature and evapotranspiration in a French Mediterranean region in the context of climate change     

Keltoum Chaouche  Luc Neppel  Claudine Dieulin  Nicolas Pujol  Bernard Ladouche  Eric Martin  Dallas Salas  Yvan Caballero 《Comptes Rendus Geoscience》2010,342(3):234-243

This study is focused on the western part of the French Mediterranean area, namely the Pyrénées-Orientales and Aude administrative departments. The water resources (surface and groundwater) in the region are sensitive to climate change. The study addresses the question of whether any trend in the annual and monthly series of temperature, rainfall and potential evapotranspiration (PET) already appears at the scale of this region. Two data sources have been used: (a) direct local measurements using the meteorological network; and (b) spatially interpolated data from the French weather service model SAFRAN for the period 1970–2006. The non-parametric Mann–Kendall test was applied to identify significant trends at the local scale and, because of the natural spatial variability of the Mediterranean climate, regional interpretation was also performed. The trends observed in the 13 catchments of interest are consistent with those observed at a larger scale. An increase in annual mean temperature and annual PET was observed throughout the study area, whereas annual precipitation has not exhibited any trend. The monthly scale has revealed strong seasonal variability in trend. The trend for an increase in monthly PET has been observed mainly in the spring, and has not been seen in the coastal areas. A trend for an increase in monthly temperature has been observed in June and in the spring throughout the entire area. Monthly rainfall has been found to decrease in June and increase in November throughout the area. The significant trends observed in rainfall and temperature seem to be consistent between the different data sources.  相似文献   

Isotopic constraints on the Si-biogeochemical cycle of the Antarctic Zone in the Kerguelen area (KEOPS)     

François Fripiat  Anne-Julie Cavagna  Nicolas Savoye  Frank Dehairs  Luc André  Damien Cardinal 《Marine Chemistry》2011,123(1-4):11-22

Estimation of the silicon (Si) mass balance in the ocean from direct measurements (Si uptake-dissolution rates …) is plagued by the strong temporal and spatial variability of the surface ocean as well as methodological artifacts. Tracers with different sensitivities toward physical and biological processes would be of great complementary use. Silicon isotopic composition is a promising proxy to improve constraints on the Si-biogeochemical cycle, since it integrates over longer timescales in comparison with direct measurements and since the isotopic balance allows to resolve the processes involved, i.e. uptake, dissolution, mixing. Si-isotopic signatures of seawater Si(OH)₄ and biogenic silica (bSiO₂) were investigated in late summer 2005 during the KEOPS experiment, focusing on two contrasting biogeochemical areas in the Antarctic Zone: a natural iron-fertilized area above the Kerguelen Plateau (< 500 m water depth) and the High Nutrient Low Chlorophyll area (HNLC) east of the plateau (> 1000 m water depth). For the HNLC area the Si-isotopic constraint identified Upper Circumpolar Deep Water as being the ultimate Si-source. The latter supplies summer mixed layer with 4.0 ± 0.7 mol Si m^? 2 yr^? 1. This supply must be equivalent to the net annual bSiO₂ production and exceeds the seasonal depletion as estimated from a simple mixed layer mass balance (2.5 ± 0.2 mol Si m^? 2 yr^? 1). This discrepancy reveals that some 1.5 ± 0.7 mol Si m^? 2 yr^? 1 must be supplied to the mixed layer during the stratification period. For the fertilized plateau bloom area, a low apparent mixed layer isotopic fractionation value (?³⁰Si) probably reflects (1) a significant impact of bSiO₂ dissolution, enriching the bSiO₂ pool in heavy isotope; and/or (2) a high Si uptake over supply ratio in mixed layer at the beginning of the bloom, following an initial closed system operating mode, which, however, becomes supplied toward the end of the bloom (low Si uptake over supply ratio) with isotopically light Si(OH)₄ from below when the surface Si(OH)₄ pool is significantly depleted. We estimated a net integrated bSiO₂ production of 10.5 ± 1.4 mol Si m^? 2 yr^? 1 in the AASW above the plateau, which includes a significant contribution of bSiO₂ production below the euphotic layer. However, advection which could be significant for this area has not been taken into account in the latter estimation based on a 1D approach of the plateau system. Finally, combining the KEOPS Si-isotopic data with those from previous studies, we refined the average Si-isotopic fractionation factor to ? 1.2 ± 0.2‰ for the Antarctic Circumpolar Current.  相似文献