Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method     

LI Jin  TANG Suohan  ZHU Xiangkun  MA Jianxiong  ZHAO Xinmiao 《《地质学报》英文版》2022,96(2):517-524

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.  相似文献   

The improvement of the one-dimensional Mellor-Yamada and K-profile parameterization turbulence schemes with the non-breaking surface wave-induced verticalmixing     

LI Yan  QIAO Fangli  YIN Xunqiang  SHU Qi  MA Hongyu 《海洋学报(英文版)》2013,32(9):62-73

Both the level 2.5 Mellor-Yamada turbulence closure scheme(MY) and K-profile parameterization(KPP) are popularly used by the ocean modeling community.The MY and the KPP are improved through including the non-breaking surface wave-induced vertical mixing(Bv),and the improved schemes were tested by using continuous data at the Papa ocean weather station(OWS) during 1961–1965.The numerical results showed that the Bv can make the temperature simulations fit much better with the continuous data from Papa Station.The two improved schemes overcame the shortcomings of predicting too shallow upper mixed layer depth and consequently overheated sea surface temperature during summertime,which are in fact common problems for all turbulence closure models.Statistical analysis showed that the Bv effectively reduced the mean absolute error and root mean square error of the upper layer temperature and increased the correlation coefficient between simulation and the observation.Furthermore,the performance of vertical mixing induced by shear instability and the Bv is also compared.Both the temperature structure and its seasonal cycle significantly improved by including the Bv,regardless of whether shear instability was included or not,especially for the KPP mixing scheme,which suggested that Bv played a dominant role in the upper ocean where the mean current was relatively weak,such as at Papa Station.These results may provide a clue to improve ocean circulation models.  相似文献   

Rainfall effect on wind waves and the turbulence beneath air-sea interface   总被引：1，自引：0，他引：1  

ZHAO Dongliang  MA Xin  LIU Bin  XIE Lian 《海洋学报(英文版)》2013,32(11):10-20

Rainfall effects on wind waves and turbulence are investigated through the laboratory experiments in a large wind-wave tank. It is found that the wind waves are damped as a whole at low wind speeds, but are enhanced at high wind speeds. This dual effect of rain on the wind waves increases with the increase of rain rate, while the influence of rainfall-area length is not observable. At the low wind speed, the corresponding turbulence in terms of the turbulent kinetic energy （TKE） dissipation rate is significantly enhanced by rain- fall as the waves are damped severely. At the high wind speed, the augment of the TKE dissipation rate is suppressed while the wind waves are enhanced simultaneously. In the field, however, rainfall usually hin- ders the development of waves. In order to explain this contradiction of rainfall effect on waves, a possibility about energy transfer from turbulence to waves in case of the spectral peak of waves overlapping the inertial subrange of turbulence is assumed. It can be applied to interpret the damping phenomenon of gas trans- fer velocity in the laboratory experiments, and the variation of the TKE dissipation rates near sea surface compared with the law of wall.  相似文献   

The vertical structure of the atmospheric boundary layer over the central Arctic Ocean   总被引：2，自引：1，他引：1  

BIAN Lingen  MA Yongfeng  LU Changgui  LIN Xiang 《海洋学报(英文版)》2013,32(10):34-40

The tropopause height and the atmospheric boundarylayer （PBL） height as well as the variation of inversion layer above the floating ice surface are presented using GPS （global position system ） radiosonde sounding data and relevant data obtained by Chinas fourth arctic scientific expedition team over the central Arctic Ocean （86°-88°N, 144°-170°W） during the summer of 2010. The tropopause height is from 9.8 to 10.5 km, with a temperature range between -52.2 and -54.10C in the central Arctic Ocean. Two zones of maximum wind （over 12 m/s） are found in the wind profile, namely, low- and upper-level jets, located in the middle troposphere and the tropopause, respectively. The wind direction has a marked variation point in the two jets from the southeast to the southwest. The average PBL height determined by two methods is 341 and 453 m respectively. These two methods can both be used when the inversion layer is very low, but the results vary significantly when the inversion layer is very high. A significant logarithmic relationship exists between the PBL height and the inversion intensity, with a correlation coefficient of 0.66, indicating that the more intense the temperature inversion is, the lower the boundary layer will be. The observation results obviously differ from those of the third arctic expedition zone （800-85° N）. The PBL height and the inversion layer thickness are much lower than those at 870-88° N, but the inversion temperature is more intense, meaning a strong ice- atmosphere interaction in the sea near the North Pole. The PBL structure is related to the weather system and the sea ice concentration, which affects the observation station.  相似文献   

Sedimentary Environments of Cambrian–Ordovician Source Rocks and Ultra-deep Petroleum Accumulation in the Tarim Basin     

ZHANG Shuichang  SU Jin  WANG Xiaomei  MA Sihong 《《地质学报》英文版》2022,96(4):1259-1276

The Tarim Basin is the only petroliferous basin enriched with marine oil and gas in China. It is presently also the deepest basin for petroleum exploration and development in the world. There are two main sets of marine Source Rocks (SRs) in the Tarim Basin, namely the high over-mature Cambrian–Lower Ordovician (∈–O1) and the moderately mature Middle–Upper Ordovician (O2–3). The characteristic biomarkers of SRs and oils indicate that the main origin of the marine petroleum is a mixed source of ∈–O1 and O2–3 SRs. With increasing burial, the hydrocarbon contribution of the ∈–O1 SRs gradually increases. Accompanied by the superposition of multi-stage hydrocarbon-generation of the SRs and various secondary alteration processes, the emergence and abnormal enrichment of terpenoids, thiophene and trimethylaryl isoprenoid in deep reservoirs indicate a complex genesis of various deep oils and gases. Through the analysis of the biofacies and sedimentary environments of the ∈–O1 and O2–3 SRs, it is shown that the lower Paleozoic high-quality SRs in the Tarim Basin were mainly deposited in a passive continental margin and the gentle slope of the platform, deep-water shelf and slope facies, which has exhibited a good response to the local tectonic-sedimentary environment. The slope of the paleo-uplift is the mutual area for the development of carbonate reservoirs and the deposition of marine SRs, which would be favorable for the accumulation of petroleum. Due to the characteristics of low ground temperature, the latest rapid and deep burial does not cause massive oil-cracking in the paleo-uplift and slope area. Therefore, it is speculated that the marine reservoirs in the slope of the Tabei Uplift are likely to be a favorable area for deep petroleum exploration, while the oil-cracking gas would be a potential reserve around the west margin of the Manjiaer Depression. Hydrocarbons were generated from various unit SRs, mainly migrating along the lateral unconformities or reservoirs and the vertical faults. They eventually brought up three major types of exploration fields: middle and lower Cambrian salt-related assemblages, dolomite inner reservoirs and Middle and Lower Ordovician oil-bearing karst, which would become the most favorable target of marine ultra-deep exploration in the Tarim Basin.  相似文献   

Stramonita haemastoma as a bioindicator for organotin contamination in coastal environments     

Limaverde AM  Wagener Ade L  Fernandez MA  Scofield Ade L  Coutinho R 《Marine environmental research》2007,64(3):384-398

Stramonita haemastoma was investigated as a suitable bioindicator of TBT and TPhT contamination in the tropical Atlantic Ocean by: 1. Imposex induction in healthy females after inoculation with TBT and TPhT in the laboratory; and 2. Determining incidence of imposex in S. haemastoma collected from areas with various levels of tributyltin (TBT) and triphenyltin (TPhT) and determining the concentrations of these chemical in its tissues and that of its prey, the mussell Perna pernas. Imposex intensities and organotin concentrations in tissues showed good correlation, indicating S. haemastoma as a reliable bioindicator of TBT and TPhT contamination in coastal waters. Body burden threshold of TBT and TPhT for imposex induction was estimated to be 10-20 ng g(-1).  相似文献   

Behavior of REE Fractionation during Weathering of Dolomite Regolith Profile in Southwest China   总被引：3，自引：0，他引：3  

GONG Qingjie  ZHANG Gaixi  ZHANG Jing  JIANG Biao  MA Nan 《《地质学报》英文版》2010,84(6):1439-1447

<正>REE fractionation during the weathering of dolomite has been recognized for decades.A regolith profile on dolomite in southwest Yunnan of China was selected to investigate the behaviors of REE during weathering.The weathering of dolomite is divided into two stages:the pedogenesis stage and soil evolution stage,corresponding to the saprolites and soils respectively in the regolith profile. SiO_2,TiO_2,P_2O_5,Zr,Hf,Nb and Ta were immobile components during the weathering by and large, while Al_2O_3,K_2O and Fe_2O_3 were lost during the soil evolution stage in the physical form(clay minerals probably).REE were fractionated during the whole weathering of dolomite.The field weathering profile and the lab acid-leaching experiments on dolomite indicate that MREE were enriched clearly relative to other REE during the pedogenesis stage in a "capillary ascending-adsorption" mechanism, but they did not fractionate clearly in the soil evolution stage.REE were lost and accumulated in the weathering front of dolomite during the soil evolution stage in a "physical-chemical leaching" mechanism.  相似文献   

Rapid Identification and Emergency Investigation of Surface Ruptures and Geohazards Induced by the M_s 7.1 Yushu Earthquake   总被引：1，自引：0，他引：1  

ZHANG Yongshuang  YAO Xin  XIONG Tanyu  MA Yinsheng  HU Daogong  YANG Nong  GUO Changbao 《《地质学报》英文版》2010,84(6):1315-1327

<正>The rapid identification based on InSAR technology was proved to be effective in our emergency investigation of surface ruptures and geohazards induced by the Yushu earthquake.The earthquake-generating fault of the Yushu earthquake is the Yushu section of the Garze-Yushu faults zone.It strikes NWW-NW,23 km long near the Yushu County seat,dominated by left-lateral strike slip,and appearing as a surface rupture zone.The macroscopic epicenter is positioned at Guo-yang-yan -song-duo of Gyegu Town(33°03'11"N,96°51'26"E),where the co-seismic horizontal offset measured is 1.75 m.Geohazards induced by the Yushu earthquake are mainly rockfalls,landslides,debris flows, and unstable slopes.They are controlled by the earthquake-generating fault and are mostly distributed along it.There are several geohazard chains having been established,such as earthquake,canal damage,soil liquefying,landslide-debris flow,earthquake,soil liquefying,roadbed deformation,etc.In order to prevent seismic hazards,generally,where there is a visible surface rupture induced by the Yushu earthquake,reconstruction should be at least beyond 20 m,on each side,from it.Sufficient attention should also be given to potential geohazards or geohazard chains induced by the earthquake.  相似文献   

Petrogenesis and tectonic setting of granite porphyry in Keyouzhongqi area,Inner Mongolia     

WU Qing  YANG Weihong  HE Zhonghua  YANG Deming  MA Rui  WANG Jianguo 《世界地质(英文版)》2014,17(1):24-33

The authors studied the geochemistry,zircon U-Pb ages,Hf isotope of the granite porphyry and its petrogenesis and tectonic setting in the studied area． The zircon U-Pb dating indicates the formation of the gran- ite porphyry is in Early Cretaceous (125． 1 ±1． 5 Ma)． The granite porphyry has high-SiO2and alkali-rich fea- tures,which belongs to high-K calc-alkaline series rocks (A/CNK = 0． 95%--1． 25%)． The analyses of trace elements show the characteristics of a swallow-shaped ＲEE distribution pattern with enrichment in LＲEEs and most of LILEs and HFSEs,depletion in Ba,Sr,Nb,P and Ti,and especially strong depletion in Eu,which indicates the granite porphyry belongs to the aluminous A-type granite． Their εHf(t)range from 5． 94 to 8． 80 with Hf two-stage model ages (TDM2) of 620 Ma to 803 Ma． Combining with the regional tectonic background, we conclude that the source of the rocks is the new crust materials accreted from depleted mantle in Neoprotero- zoic and is the product of partial melting of middle and lower crustal rocks,which may be suffered from the dual impact of the subduction of the Palaeo-Pacific Ocean and the closure of the Mongol-Okhotsk Ocean．  相似文献   

Guojiadian Mantle Branch Structure and Its Ore-Controlling , Zhaoyuan,Shandong Province, China     

NIU Shuyin  ZHANG Jianzhen  SUN Aiqun  CHENG Guangsuo  ZHANG Fuxiang  CHEN Chao  MA Baojun  XU Meng 《地质学报》2014,88(Z2):1656-1658

Please refer to the attachment(s) for more details.  相似文献