Glacial sediment causing regional-scale elevated arsenic in drinking water     

Erickson ML  Barnes RJ 《Ground water》2005,43(6):796-805

In the upper Midwest, USA, elevated arsenic concentrations in public drinking water systems are associated with the lateral extent of northwest provenance late Wisconsin-aged drift. Twelve percent of public water systems located within the footprint of this drift (212 of 1764) exceed 10 microg/L arsenic, which is the U.S. EPA's drinking water standard. Outside of the footprint, only 2.4% of public water systems (52 of 2182) exceed 10 microg/L arsenic. Both glacial drift aquifers and shallow bedrock aquifers overlain by northwest provenance late Wisconsin-aged sediment are affected by arsenic contamination. Evidence suggests that the distinct physical characteristics of northwest provenance late Wisconsin-aged drift--its fine-grained matrix and entrained organic carbon that fosters biological activity--cause the geochemical conditions necessary to mobilize arsenic via reductive mechanisms such as reductive desorption and reductive dissolution of metal oxides. This study highlights an important and often unrecognized phenomenon: high-arsenic sediment is not necessary to cause arsenic-impacted ground water--when "impacted" is now defined as >10 microg/L. This analysis also demonstrates the scientific and economic value of using existing large but imperfect statewide data sets to observe and characterize regional-scale environmental problems.  相似文献   

A New Late Middle Cambrian Paleomagnetic Pole for the Ellsworth Mountains, Antarctica     

Randall DE  Curtis ML  Millar IL 《The Journal of geology》2000,108(4):403-425

A paleomagnetic study of the late Middle to possibly early Late Cambrian Liberty Hills Formation in the Ellsworth Mountains, Antarctica, reveals a stable magnetization with positive fold and reversal tests. The paleopole is based on 16 sites from volcanic and sedimentary rocks and lies at lat 7.3 degrees N and long 326.3 degrees E (A95=6.0&j0;). The new paleomagnetic data support the view that the Ellsworth Mountains are part of a microplate-the Ellsworth-Whitmore Mountains crustal block-that rotated independently of the main Gondwana continental blocks during breakup. The Liberty Hills pole differs from both previous poles recovered from Cambrian rocks in the Ellsworth Mountains and from the available Gondwana reference pole data. Our pole indicates a more northerly prebreakup position for the Ellsworth Mountains than previously suggested, contradicting the overwhelming geologic evidence for a prebreakup position close to southern Africa. The reasons for this are uncertain, but we suggest that problems with the Gondwana apparent polar wander path may be important. More well constrained, early Paleozoic paleomagnetic data are required from the Ellsworth Mountains and the Gondwana continents if the data are to constrain further the Middle-Late Cambrian location of the Ellsworth-Whitmore Mountains block.  相似文献   

使用印度强震台阵数据估算峰值地面水平加速度的衰减关系     

Shar.  ML 于海英 《世界地震译丛》2000,(4):43-49

研究了印度境内的喜马拉雅山地区峰值地面水平加速度的一种衰减关系。资料源自印度强震台阵记录的５次地震中提取的６６个峰值地面水平加速度。目前使用的分析方法是两步成层的回归模型,其衰减关系假设为：ｌｏｇ（Ａ）＝－１．０７２＋０．３９０３Ｍ－１．２１ｌｏｇ（Ｘ＋ｅ＾０．５８７３Ｍ）式中,Ａ为峰值地面加速度（ｇ）,Ｍ为城级,Ｘ为震源距。残差平方和为０．１４。把这一衰减关系与其他的衰减关系进行了比较。与其它关  相似文献   

Remediation of NAPL source zones: lessons learned from field studies at Hill and Dover AFB     

McCray JE  Tick GR  Jawitz JW  Gierke JS  Brusseau ML  Falta RW  Knox RC  Sabatini DA  Annable MD  Harwell JH  Wood AL 《Ground water》2011,49(5):727-744

Innovative remediation studies were conducted between 1994 and 2004 at sites contaminated by nonaqueous phase liquids (NAPLs) at Hill and Dover AFB, and included technologies that mobilize, solubilize, and volatilize NAPL: air sparging (AS), surfactant flushing, cosolvent flooding, and flushing with a complexing-sugar solution. The experiments proved that aggressive remedial efforts tailored to the contaminant can remove more than 90% of the NAPL-phase contaminant mass. Site-characterization methods were tested as part of these field efforts, including partitioning tracer tests, biotracer tests, and mass-flux measurements. A significant reduction in the groundwater contaminant mass flux was achieved despite incomplete removal of the source. The effectiveness of soil, groundwater, and tracer based characterization methods may be site and technology specific. Employing multiple methods can improve characterization. The studies elucidated the importance of small-scale heterogeneities on remediation effectiveness, and fomented research on enhanced-delivery methods. Most contaminant removal occurs in hydraulically accessible zones, and complete removal is limited by contaminant mass stored in inaccessible zones. These studies illustrated the importance of understanding the fluid dynamics and interfacial behavior of injected fluids on remediation design and implementation. The importance of understanding the dynamics of NAPL-mixture dissolution and removal was highlighted. The results from these studies helped researchers better understand what processes and scales are most important to include in mathematical models used for design and data analysis. Finally, the work at these sites emphasized the importance and feasibility of recycling and reusing chemical agents, and enabled the implementation and success of follow-on full-scale efforts.  相似文献   

Assessment of sacrificial anode impact by aluminum accumulation in mussel Mytilus edulis: a large-scale laboratory test     

Mao A  Mahaut ML  Pineau S  Barillier D  Caplat C 《Marine pollution bulletin》2011,62(12):2707-2713

Since the early 1960s, the application of aluminum alloy sacrificial anodes to mitigate marine corrosion has been well known. The aim of this work was to study aluminum bioconcentration in Mytilus edulis by an in vitro test performed in two tanks: the first containing non-contaminated water (NCW) and the second containing aluminum-contaminated water (CW) (530 μg L⁻¹) released by sacrificial anode. The mussels were collected and examined over a period of 8 weeks. A comparison between the aluminum concentrations in the digestive glands of mussels from the CW and NCW tanks shows that the highest value (1700 mg/kg d.w.) was found in the CW mussels collected after 13 days. In NCW, the mean aluminum concentration in digestive glands during the test was 281 mg/kg d.w. The rapid concentration decrease in digestive glands is probably due to the inhibition of filtering activity due to valve closure at the high concentration as well as the induction of the detoxification response.  相似文献   

Validation of Arenicola marina in field toxicity bioassays using benthic cages: biomarkers as tools for assessing sediment quality     

Ramos-Gómez J  Martins M  Raimundo J  Vale C  Martín-Díaz ML  DelValls TA 《Marine pollution bulletin》2011,62(7):1538-1549

Sediment toxicity assessments using caged organisms present advantages over using laboratory and native community studies. The use of caged Arenicola marina in sediment toxicity assessments was evaluated. Lugworms were exposed in situ to sediments from coastal and port areas in Spain for seven days, and the activities of the biotransformation enzymes ethoxyresorufin O-deethylase, dibenzylfluorescein dealkylase and glutathione S-transferase, the activities of the antioxidant enzymes glutathione reductase and glutathione peroxidase and lipid peroxidation were then analyzed as biomarkers. Biomarker results and sediment physicochemical data were integrated. Cádiz Bay (SW Spain) sediments presented metal contamination that was not linked to a biochemical response. In LPGC Port (SW Spain), Pb contamination exhibited a moderate toxic potential, while PAHs, and presumably pharmaceuticals, provoked biochemical responses that efficiently prevented lipid peroxidation. In Santander Bay (N Spain), exposure to PAHs and, presumably, pharmaceuticals induced biomarker responses, but lipid peroxidation occurred nevertheless. These results indicated that caged A. marina were effective for the assessment of sediment quality and that the selected biomarkers were sufficiently sensitive to identify chemical exposure and toxicity.  相似文献   

Recovery of macrobenthos in defaunated tropical estuarine sediments     

Botter-Carvalho ML  Carvalho PV  Santos PJ 《Marine pollution bulletin》2011,62(8):1867-1876

In the estuarine environment, hypoxia and/or anoxia have become a major cause of benthic defaunation and are strongly associated with increased eutrophication. Mesoscale field experiments were carried out to examine the recolonization and recovery time of macrobenthos after defaunation. Azoic sediments were achieved by covering four areas with polyethylene sheeting. Temporal changes and depth distribution of macrobenthos within the defaunated sediments were compared with those in undisturbed natural sediments at the same site. Within 3 days, annelids appeared as the first immigrants. After 153 days, the process of recovery had not yet been completed in terms of species richness. Whereas diversity and evenness showed no significant differences between treatments during the entire experiment, multivariate analyses proved that differences between treatments were still significant 93 days after the start of the experiment.  相似文献   

Hypoxia in Manila Bay, Philippines during the northeast monsoon     

Jacinto GS  Sotto LP  Senal MI  San Diego-McGlone ML  Escobar MT  Amano A  Miller TW 《Marine pollution bulletin》2011,63(5-12):243-248

Herein we present results from one of the first extensive bay-wide oceanographic surveys of Manila Bay, wherein 31 stations were sampled during the northeast monsoon (cold and dry season). A band of hypoxic bottom water (dissolved oxygen<2.8 mg/L) spanned the midsection of the bay from east to west. Bottom nitrate concentrations (5.7-16.8 μM; avg. 11.1 μM) and total organic carbon values in sediments (1.7-3.1%; avg. 2.4%) were high in the midsection, which coincided with the band of hypoxic bottom water. Physical processes and site-specific accumulation of organic material likely lead to hypoxic conditions in Manila Bay, even during the northeast monsoon period when the water column is relatively well mixed. The results of this study complement the previously reported widespread hypoxia that occurs during the rainy season. Thus, hypoxia may be pervasive in the bay throughout the year, although it varies in intensity and spatial extent.  相似文献   

Nutrient inputs from submarine groundwater discharge on the Santiago reef flat, Bolinao, Northwestern Philippines     

Senal MI  Jacinto GS  San Diego-McGlone ML  Siringan F  Zamora P  Soria L  Cardenas MB  Villanoy C  Cabrera O 《Marine pollution bulletin》2011,63(5-12):195-200

Submarine groundwater discharge (SGD) on the reef flat of Bolinao, Pangasinan (Philippines) was mapped using electrical resistivity, 222Rn, and nutrient concentration measurements. Nitrate levels as high as 126 μM, or 1-2 orders of magnitude higher than ambient concentrations, were measured in some areas of the reef flat. Nutrient fluxes were higher during the wet season (May-October) than the dry season (November-April). Dissolved inorganic nitrogen (DIN=NO3+NO2+NH4) and soluble reactive phosphorus (SRP) fluxes during the wet season were 4.4 and 0.2 mmoles m(-2) d(-1), respectively. With the increase population size and anthropogenic activities in Bolinao, an enhancement of SGD-derived nitrogen levels is likely. This could lead to eutrophic conditions in the otherwise oligotrophic waters surrounding the Santiago reef flat.  相似文献   

矩张量的研究指南与回顾     

Jost  ML 于克涛 《地震地质译丛》1991,13(1):52-59

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