Aluminous goethite: A mössbauer study     

Stuart A. Fysh  Paul E. Clark 《Physics and Chemistry of Minerals》1982,8(4):180-187

Mössbauer measurements at 300 K, 77 K and 4.2 K and X-ray data are presented for synthetic aluminous goethites (α Fe_1?x Al _x OOH) in two series containing up to 15 mole percent aluminium (hydrothermal preparation) and 19 mole percent aluminium (low-temperature preparation). The Mössbauer spectra for specimens at 300 K and 77 K display broadened and relaxed line-shapes with the relaxation rate increasing with aluminium substitution, whereas all the 4.2 K spectra can be described by a single magnetically split spectrum. At 4.2 K the magnitude of this splitting is 505 kOe for pure goethite and it decreases by 0.52 kOe per mole percent aluminium substitution. The absolute value of the recoil-free fraction f at 4.2 K has been measured for pure goethite and for aluminous goethites containing 7, 15 and 19 mole percent aluminium; it increases from f=0.69±0.02 to f=0.89±0.02 in this range. The increase is attributed to a stiffening of the goethite lattice as it contracts to accommodate the smaller aluminium ion. At 300 K f is found to decrease from f=0.65±0.05 for pure goethite to f=0.50±0.03 for goethite with 19 mole percent aluminium.  相似文献   

Reviews     

Isobel Clark  C. J. Readings  Peter J. Smith  L. Thomas 《Surveys in Geophysics》1983,5(4):409-412

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Who makes the decisions,anyway?     

R.B. Clark 《Marine pollution bulletin》1983,14(10):365-366

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Optimal processing of satellite-derived magnetic anomaly data     

Malcolm G. McLeod 《Physics of the Earth and Planetary Interiors》1983,31(1):10-26

The statistical concept of the power spectrum has proven to be of great value in the analysis of time series and linear systems for which the inputs and outputs are functions of time. This paper shows how the concept can be extended to two-dimensional spatial power spectra and illustrates, by example, how the concept can be applied to the determination of optimal data processing methods for satellite-derived magnetic anomaly data and to the planning of missions to obtain such data.The analysis techniques indicated are applied to a data set and data processing procedure described by Mayhew et al. (1980). These authors describe magnetic anomaly data for Australia and surrounding ocean obtained by the polar orbit POGO series satellites. This paper shows that the data processing method used by these authors is approximately equivalent to an invariant two-dimensional linear filter and that it is reasonably close to optimal with respect to accuracy, though some possible improvements are suggested. Nevertheless, as is usual when filtering data, some real “signal” is unavoidably removed along with the “noise”, resulting in errors that can be quite large.A method for reducing these errors by using additional data from a medium inclination orbit satellite (for example, 60° inclination) is suggested.  相似文献   

Water movement within lac du bonnet batholith as revealed by detailed thermal studies of three closely-spaced boreholes     

Malcolm J. Drury  Trevor J. Lewis   《Tectonophysics》1983,95(3-4)

Successive temperature logs have been obtained over a period of two years in three closely-spaced boreholes in the Lac du Bonnet batholith of the Superior Province of the Canadian Shield. Two of the boreholes, of depth 450 m and 830 m, intersect a dipping fracture zone at 435–450 m. In both holes water is flowing from near the surface to the fracture zone at approximately 1.5–1.9·10⁻⁵ m³ s⁻¹, the flow being inferred from analysis of the temperature logs. Below 25 m, temperatures in these two holes are 0.22–0.28 K lower than those in the third, 145 m, hole.The temperature data have been combined with over 200 thermal conductivity measurements on core samples to produce heat flow values. In the deepest hole heat flow above the fracture zone is 16% higher than that below the zone. This indicates that water is flowing up the fracture zone. The flow rate is approximately 0.3 g s⁻¹ m⁻¹, and the flow has existed for thousands of years.Observation of thermal effects of water flow in massive, relatively unfractured plutons in a region having little topographic relief causes one to be concerned about the reliability of heat flow values measured in similar environments.The regional heat flow is taken to be 50 mW m⁻² after correction for glaciation effects. The average value of 24 determinations of radioactive heat generation in granitic core samples is 5.23 ± 1.11 μW m⁻³, which is more than three times higher than expected for such a heat flow in the Superior Province. This implies that the layer of high radioactive heat generation is thin, being not more than 4 km and probably about 1.3 km thick.  相似文献   

Hominid sites: Their geologic settings : Edited by George Rapp, Jr., and Carl F. Vondra. Westview Press, Boulder, Colo., 1981, 310 pp     

F. Clark Howell 《Quaternary Research》1983,19(3):408-409

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The contribution of humic substances to the acidity of colored natural waters   总被引：1，自引：0，他引：1  

Barry G. Oliver  Earl M. Thurman  Ronald L. Malcolm 《Geochimica et cosmochimica acta》1983,47(11):2031-2035

An operationally defined carboxyl content of humic substances extracted from rivers, streams, lakes, wetlands, and groundwaters throughout the United States and Canada is reported. Despite the diversity of the samples, only small variations were observed in this humic carboxyl content. The dissociation behavior of two combined fulvic/humic acid extracts was studied and it was found that the dissociation of the humics varied in a predictable manner with pH. Using a carboxyl content of 10 μeq/ mg humic organic carbon, and mass action quotient calculated from sample pH, the ionic balances of three highly colored Nova Scotia rivers were estimated.  相似文献   

Cretaceous research     

Malcolm B. Hart 《Cretaceous Research》1983,4(1):1

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Reconstructions of spring/summer precipitation for the Eastern Mediterranean from tree-ring widths and its connection to large-scale atmospheric circulation     

Ramzi Touchan  Elena Xoplaki  Gary Funkhouser  Jürg Luterbacher  Malcolm K. Hughes  Nesat Erkan  Ünal Akkemik  Jean Stephan 《Climate Dynamics》2005,25(1):75-98

This study represents the first large-scale systematic dendroclimatic sampling focused on developing chronologies from different species in the eastern Mediterranean region. Six reconstructions were developed from chronologies ranging in length from 115 years to 600 years. The first reconstruction (1885–2000) was derived from principal components (PCs) of 36 combined chronologies. The remaining five, 1800–2000, 1700–2000, 1600–2000, 1500–2000 and 1400–2000 were developed from PCs of 32, 18, 14, 9, and 7 chronologies, respectively. Calibration and verification statistics for the period 1931–2000 show good levels of skill for all reconstructions. The longest period of consecutive dry years, defined as those with less than 90% of the mean of the observed May–August precipitation, was 5 years (1591–1595) and occurred only once during the last 600 years. The longest reconstructed wet period was 5 years (1601–1605 and 1751–1755). No long term trends were found in May–August precipitation during the last few centuries. Regression maps are used to identify the influence of large-scale atmospheric circulation on regional precipitation. In general, tree-ring indices are influenced by May–August precipitation, which is driven by anomalous below (above) normal pressure at all atmospheric levels and by convection (subsidence) and small pressure gradients at sea level. These atmospheric conditions also control the anomaly surface air temperature distribution which indicates below (above) normal values in the southern regions and warmer (cooler) conditions north of around 40°N. A compositing technique is used to extract information on large-scale climate signals from extreme wet and dry summers for the second half of the twentieth century and an independent reconstruction over the last 237 years. Similar main modes of atmospheric patterns and surface air temperature distribution related to extreme dry and wet summers were identified both for the most recent 50 years and the last 237 years. Except for the last few decades, running correlation analyses between the major European-scale circulation patterns and eastern Mediteranean spring/summer precipitation over the last 237 years are non-stationary and insignificant, suggesting that local and/or sub-regional geographic factors and processes are important influences on tree-ring variability over the last few centuries.  相似文献   

Coupling of oceanic and continental crust during Eocene eclogite-facies metamorphism: evidence from the Monte Rosa nappe,western Alps   总被引：1，自引：0，他引：1  

Thomas J. Lapen  Clark M. Johnson  Lukas P. Baumgartner  Giorgio V. Dal Piaz  Susanne Skora  Brian L. Beard 《Contributions to Mineralogy and Petrology》2007,153(2):139-157

High precision U–Pb geochronology of rutile from quartz–carbonate–white mica–rutile veins that are hosted within eclogite and schist of the Monte Rosa nappe, western Alps, Italy, indicate that the Monte Rosa nappe was at eclogite-facies metamorphic conditions at 42.6 ± 0.6 Ma. The sample area [Indren glacier, Furgg zone; Dal Piaz (2001) Geology of the Monte Rosa massif: historical review and personal comments. SMPM] consists of eclogite boudins that are exposed inside a south-plunging overturned synform within micaceous schist. Associated with the eclogite and schist are quartz–carbonate–white mica–rutile veins that formed in tension cracks in the eclogite and along the contact between eclogite and surrounding schist. Intrusion of the veins at about 42.6 Ma occurred at eclogite-facies metamorphic conditions (480–570°C, >1.3–1.4 GPa) based on textural relations, oxygen isotope thermometry, and geothermobarometry. The timing of eclogite-facies metamorphism in the Monte Rosa nappe determined in this study is identical to that of the Gran Paradiso nappe [Meffan-Main et al. (2004) J Metamorphic Geol 22:261–281], confirming that these two units have shared the same Alpine metamorphic history. Furthermore, the Gran Paradiso and Monte Rosa nappes underwent eclogite-facies metamorphism within the same time interval as the structurally overlying Zermatt-Saas ophiolite [∼50–40 Ma; e.g., Amato et al. (1999) Earth Planet Sci Lett 171:425–438; Mayer et al. (1999) Eur Union Geosci 10:809 (abstract); Lapen et al. (2003) Earth Planet Sci Lett 215:57–72]. The nearly identical P–T–t histories of the Gran Paradiso, Monte Rosa, and Zermatt-Saas units suggest that these units shared a common Alpine tectonic and metamorphic history. The close spatial and temporal associations between high pressure (HP) ophiolite and continental crust during Alpine orogeny indicates that the HP internal basement nappes in the western Alps may have played a key role in exhumation and preservation of the ophiolitic rocks through buoyancy-driven uplift. Coupling of oceanic and continental crust may therefore be critical in preventing permanent loss of oceanic crust to the mantle.  相似文献