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81.
The drying-induced deformation behaviour of Opalinus Clay and tuff, which are being investigated under international and local collaborative projects for nuclear waste disposal in Switzerland and Japan, was investigated under a no-stress condition in the laboratory to evaluate their generic susceptibility to the formation of excavation damaged zone. The cylindrical core samples of Opalinus Clay and tuff were prepared to a one-dimensional drying condition and submitted to an uncontrolled laboratory environment. The strain evolution, evaporative water loss and environmental entities, such as temperature and relative humidity, were recorded simultaneously and quasi-continuously. It was observed that the drying phase induced significant strain magnitude and damage in Opalinus Clay samples, which was evidenced by the formation of hairy cracks on the surface parallel to the bedding. On the contrary, the strain occurrences in tuff samples were relatively insignificant, and no tendency of cracking was observed. In addition, the quasi-continuous availability of volumetric strains was further used in poroelastic relation for the estimation of capillary suction evolution. The calculated results were validated with pore size distributions obtained from mercury intrusion porosimetry.  相似文献   
82.
We investigate the coherent structure of atmosphere turbulence over very large roughness within a fully rough, high Reynolds number turbulent flow. The horizontal distributions of coherent turbulence were determined by multipoint measurements of velocity fluctuations using sonic anemometers in a comprehensive outdoor scale model experiment for urban climate (COSMO). COSMO is made up of 512 cubical obstacles, each 1.5 m on a side, arranged in a rectangular pattern on a flat 50 m × 100 m concrete plate. A total of 15 sets of sonic anemometers were aligned horizontally within the logarithmic layer above this site. The velocity fluctuations observed in COSMO were decomposed into active and inactive contributions by applying a spatial-filtering method, and which used a simple moving average along the spanwise direction of the predominant flow as a filter function. The size of the filter should be between the sizes of the active and inactive fluctuations. This method potentially eliminates the considerable portion of low frequency modes included in the horizontal velocity fluctuation, while preserving well the Reynolds stress. The structural characteristics of the active turbulence were qualitatively similar to those measured over various surface configurations. Overall, the observed structures of the active turbulence are composed of very large streaks of low momentum fluid elongated in the streamwise direction with some sub-structures included in the streaks. The sub-structures were the main cause of the ejections, which accompany horizontal vortices. The active motion, including the streaky structures, did not reproduce the lower frequency peak of the bi-modal distribution of the horizontal velocity spectra, but reproduced the higher frequency mode that robustly follows inner-layer similarity (i.e. Monin–Obukhov similarity).  相似文献   
83.
84.
A method for measuring the two-dimensional distribution of wind velocity vectors near a surface exposed to solar radiation, by tracking brightness temperature images instead of particle images, is proposed. It is based on time-sequential thermography with the algorithm used for particle image velocimetry. This thermal image velocimetry (TIV) was tested on a full-scale building wall covered by polystyrene boards attached side-by-side over a vertically elongated area measuring 22.2 m by 2.73 m. A thermal infrared camera was installed 8 m from the test wall to capture the wall-surface temperature at 30 Hz frequency. A sonic anemometer was also installed 35 mm from the surface used for validation of the TIV. The advection velocity estimated from thermal infrared imagery had a linear relationship with the wind velocity measured by the sonic anemometer, irrespective of the wind speed and direction. This linear slope was multiplied by the advection velocity of the thermal infrared image to rescale it to the wind velocity, and the term ‘TIV velocity’ was then used. A histogram and power spectra of the TIV velocity showed quantitatively good agreement with the velocity measured by the sonic anemometer, except for the high-frequency region of the spectra, where the TIV velocity was overestimated compared with that of the sonic anemometer. The method was also tested on ground covered by artificial turf to demonstrate its application to a horizontal plane with a wider area, extending for more than 80 m by 60 m.  相似文献   
85.
Fe(III) complexed by organic ligands (Fe(III)L) is the primary form of dissolved Fe in marine and coastal environments. Superoxide, typically produced in biological and photochemical processes, is one of the reducing agents that contributes to transformation of Fe(III)L to bioavailable, free dissolved Fe(II) (Fe(II)′). In this work, the kinetics of superoxide-mediated Fe(II)′ formation from Fe(III)L in a simulated coastal water system were investigated and a comprehensive kinetic model was developed using citrate and fulvic acid as exemplar Fe-binding ligands. To simulate a coastal environment in laboratory experiments, Fe(III)L samples with various ligand/Fe ratios were incubated for 5 min to 1 week in seawater medium. At each ratio and incubation time, the rate of superoxide-mediated Fe(II)′ formation was determined in the presence of the strong Fe(II) binding ligand ferrozine by spectrophotometrically measuring the ferrous-ferrozine complex generated at a constant concentration of superoxide. The Fe(II)′ formation rate generally decreased with incubation time, as Fe(III)L gradually dissociated to form less reactive Fe(III) oxyhydroxide. However, when the ligand/Fe ratio was sufficiently high, the dissociation of Fe(III)L (and subsequent Fe precipitation) was suppressed and Fe(II)′ was formed at a higher rate. The rate of Fe(II)′ produced during the experiment was explained by the kinetic model. The model confirmed that both the ligand/Fe ratio and incubation time have a significant effect on the pathway via which Fe(II)′ is formed from Fe(III)-fulvic acid complexes.  相似文献   
86.
Boundary-Layer Meteorology - We investigate the characteristics of a dust-devil-like vortex (DDLV) observed using thermal image velocimetry (TIV) at a sports ground in Tokyo. Thermal image...  相似文献   
87.
We have investigated the chemical forms, reactivities and transformation kinetics of Fe(III) species present in coastal water with ion exchange and filtration methods. To simulate coastal water system, a mixture of ferric iron and fulvic acid was added to filtered seawater and incubated for a minute to a week. At each incubation time, the seawater sample was acidified with hydrochloric acid and then applied to anion exchange resin (AER) to separate negatively charged species (such as fulvic acid, its complexes with iron and iron oxyhydroxide coated with fulvic acid) from positively charged inorganic ferric iron (Fe(III)′). By monitoring the acid-induced Fe(III)′ over an hour, it was found that iron complexed by fulvic acid dissociated rapidly to a large extent (86–92% at pH 2), whereas amorphous ferric oxyhydroxide particles associated with fulvic acid (AFO-L) dissociated very slowly with the first-order dissociation rate constants ranging from 6.1 × 10− 5 for pH 3 to 2.7 × 10− 4 s− 1 for pH 2. Therefore, a brief acidification followed by the AER treatment (acidification/AER method) was likely to be able to determine fulvic acid complexes and thus differentiate the complexes from the AFO-L particles (the dissolution of AFO-L was insignificant during the brief acidification). The acidification/AER method coupled with a simple filtration technique suggested that the iron–fulvic acid complexes exist in both the < 0.02 μm and 0.02–0.45 μm size fractions in our coastal water system. The truly dissolved iron (< 0.02 μm) was relatively long-lived with a life-time of 14 days, probably due to the complexation by strong ligands. Such an acid-labile iron may be an important source of bioavailable iron in coastal environments, as a significant relationship between the chemical lability and bioavailability of iron has been well recognised.  相似文献   
88.
Preferred orientation of the dominant phyllosilicate phase (serpentine) in the matrix of the Murchison meteorite (C2) was determined by X-ray pole figure goniometry. The basal plane (001) of the phyllosilicate shows a clear preferred orientation of an axial concentration type. The preferred orientation is very weak in comparison with the orientations of known terrestrial tectonites, and it resembles the weakest case observed in the loosely consolidated clayey sediments from the deep ocean bottom. However, gentle sedimentation of platy phyllosilicate grains on a flat surface under a weak gravity field does not generate a sufficient preferred orientation. It is suggested that the preferred orientation in the matrix of Murchison was generated by uniaxial compaction, and the magnitude of strain to give rise to the observed degree of preferred orientation is evaluated as ?9%. There are two possible explanations of the deformation: dynamic compression caused by impact, and static compaction in a parent body. Though the latter case appears to be appropriate in the present case, it is not straightforward, however, to conclude that the suggested deformation is caused by burial compaction along gravity under lithostatic stress in a small primitive parent body.  相似文献   
89.
Physical and chemical properties of two 100 m sediment cores (BDP-93-1, 93-2) obtained from the Buguldeika saddle of Lake Baikal in the eastern Siberia and a 14C-based age scale for the core show that the core bottom is about 400000 years ago and that the changes in the sedimentological environment of the area during the interval were that comparatively coarse and high C/N ratio sediments accumulated in the lake during interglacial periods, and fine material and low C/N ratio during glacial periods. The tentative age scale suggests that the first excursion in the earth's magnetic field at about 26 m (BDP-93-1 and 93-2) from the sediment surface corresponds to the Blake event. Statistical analyses of the data-sets for the some properties show that the fluctuations have distinct periods; 20000 years, 40000 years and 100000 years, that are related to the Milankovitch parameters and support that the tentative age scale is approximately acceptable.  相似文献   
90.
The possible origin and cause of the less saline shelf water detected in the Kuroshio subsurface layer around the shelf edge of the East China Sea are investigated using observational results obtained in May 1998–2001 in conjunction with a dataset archived by Japan Oceanographic Data Center and a numerical model. The observations show that subsurface intrusions of less saline water are always detected in May in layers above 24.5σθ isopycnal surface, and that salinity inversions (i.e., areas in which the less saline water lies beneath the saline water) are detected around the trough of the Kuroshio frontal eddy (or wave). Analyses of the archived dataset reveal that the isopycnal surface of 24.5σθ is the deepest layer of the Kuroshio pycnocline outcropping to the sea surface on the shallow shelf in early spring. Outcropping isopycnals above 24.5σθ encounter a less saline water plume originating from the Changjiang, especially in the western East China Sea. Thereafter, the less saline water moves along isopycnal layers and reaches the Kuroshio front around the shelf edge. Numerical models demonstrate that, when the frontal wave captures the less saline water, the shelf water takes the form of a salinity inversion in the trough because isohalines in the frontal wave have a phase lag between the upper and lower layers in consequence of the baroclinic instability.  相似文献   
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