Bioaccumulation of heavy metals in organs of fresh water fish Cyprinus carpio (Common carp)   总被引：3，自引：2，他引：1  

R. Vinodhini M.Sc.  M.Phil.  M. Narayanan M.Sc.  Ph.D. 《International Journal of Environmental Science and Technology》2008,5(2):179-182

The objective of the present study is to determine the bioaccumulation of heavy metals in various organs of the fresh water fish exposed to heavy metal contaminated water system. The experimental fish was exposed to Cr, Ni, Cd and Pb at sublethal concentrations for periods of 32 days. The elements Cd, Pb, Ni and Cr were assayed using Shimadzu AA 6200 atomic absorption spectrophotometery and the results were given as μ/g dry wt. The accumulation of heavy metal gradually increases in liver during the heavy metal exposure period. All the results were statistically significant at p < 0.001. The order of heavy metal accumulation in the gills and liver was Cd > Pb > Ni > Cr and Pb > Cd > Ni > Cr. Similarly, in case of kidney and flesh tissues, the order was Pb > Cd > Cr > Ni and Pb > Cr > Cd > Ni. In all heavy metals, the bioaccumulation of lead and cadmium proportion was significantly increased in the tissues of Cyprinus carpio (Common carp).  相似文献   

Influence of biotic-abiotic factors on the degradation of novaluron in tropical soil   总被引：2，自引：2，他引：0  

P. Das Ph.D.  R. Pal Ph.D.  A. Chowdhury 《International Journal of Environmental Science and Technology》2008,5(3):425-429

In this study, the degradation of novaluron (benzoylphenyl urea insect growth regulator) was investigated under controlled laboratory conditions in clay loam alluvial and coastal saline soils of West Bengal, India. The application rates were field rate (FR); 2FR and 10FR. The incubation study was carried out at 30 °C and 60% of maximum water holding capacity of both the soils. Degradation of novaluron in both the soils followed first order reaction kinetics at all application rates under non-sterile and sterile conditions. The half-lives of novaluron in non-sterilized soils ranged from 17.0–17.8 days (alluvial soil) and 11.4–12.7 days (coastal saline soil), while the values in case of the sterilized soils were 53.7–59.0 days (alluvial soil) and 28.9–29.8 days (coastal saline soil) respectively. The novaluron degradation patterns were found to be highly influenced by soil types, application rates, and biotic abiotic factors. Abiotic factors strongly influenced novaluron degradation in both the soils. Biotic degradation was higher in alluvial soil compared to the coastal saline soil.  相似文献   

Particle size distribution and dissolution properties of metals in cyclone fly ash   总被引：1，自引：0，他引：1  

H. Rönkkömäki Ph.D.  R. Pöykiö Ph.D.  H. Nurmesniemi Ph.D.  K. Popov D.Sc.  E. Merisalu Dr.  T. Tuomi PhD  I. Välimäki M.Sc. 《International Journal of Environmental Science and Technology》2008,5(4):485-494

The particles in the examined cyclone fly ash were all smaller than 0.25 mm. in diameter, and particles smaller than 0.075 mm. in diameter accounted for 88.4 % of the ash weight. This result indicates that cyclone fly ash consists of particles with a small diameter. The metals in the cyclone fly ash were enriched in small particles. The highest concentrations for zinc, copper, lead, cadmium and molybdenum in the cyclone fly ash were found in the smallest particle size fraction (< 0.075 mm.) and for Barium, chromium, nickel, Vanadium and Cobalt in the second to smallest particle size fraction (0.075-0.125 mm.). From an environmental and toxicological standpoint, the smallest particles are of the greatest concern when ash is handed at landfill disposal sites (transport and disposal especially in stormy weather conditions), and some studies have reported risks to workers from prolonged exposure to ash. The results of the comparison of various dissolution methods for metals showed that the digestion procedures with nitric acid alone (USEPA 3051) or with a mixture of nitric acid + hydrogen peroxide (USEPA 3050B) slightly underestimated the metal concentrations in the cyclone fly ash. Although the use of hydrofluoric acid is often necessary for the determination of a number of elements associated with siliceous minerals, its use can result in loss of trace elements during dissolution.  相似文献   

Geochemistry of magmatic rocks of the Koksharovka alkaline-ultrabasic massif,primorye, and results of trace-element modeling     

R. A. Oktyabrsky  A. A. Vrzhosek  A. M. Lennikov  T. A. Yasnygina  S. V. Rasskazov  E. Yu. Moskalenko  T. A. Velivetskaya 《Russian Journal of Pacific Geology》2008,2(4):325-335

New geochemical data are presented on the magmatic rocks of the Late Jurassic Koksharovka alkaline-ultrabasic massif, which is associated with deposits of vermiculite, apatite, V-bearing titanomagnetite, and placer isoferroplatinum. The REE geochemistry and strontium, oxygen, and carbon isotopic composition of carbonatites and related ijolites and pyroxenites, together with geological observations, point to the magmatic origin of the Koksharovka carbonatites. The origin of associated magmatic rocks is discussed. Trace element modeling of partial melting of mantle sources was conducted to decipher the genesis of the melts of the Koksharovka carbonatites and host titanite-kaersutite pyroxenites.  相似文献   

Some Results on the Spatial Breakdown Point of Robust Point Estimates of the Variogram     

R. M. Lark 《Mathematical Geosciences》2008,40(7):729-751

The effect of outliers on estimates of the variogram depends on how they are distributed in space. The ‘spatial breakdown point’ is the largest proportion of observations which can be drawn from some arbitrary contaminating process without destroying a robust variogram estimator, when they are arranged in the most damaging spatial pattern. A numerical method is presented to find the spatial breakdown point for any sample array in two dimensions or more. It is shown by means of some examples that such a numerical approach is needed to determine the spatial breakdown point for two or more dimensions, even on a regular square sample grid, since previous conjectures about the spatial breakdown point in two dimensions do not hold. The ‘average spatial breakdown point’ has been used as a basis for practical guidelines on the intensity of contaminating processes that can be tolerated by robust variogram estimators. It is the largest proportion of contaminating observations in a data set such that the breakdown point of the variance estimator used to obtain point estimates of the variogram is not exceeded by the expected proportion of contaminated pairs of observations over any lag. In this paper the behaviour of the average spatial breakdown point is investigated for cases where the contaminating process is spatially dependent. It is shown that in two dimensions the average spatial breakdown point is 0.25. Finally, the ‘empirical spatial breakdown point’, a tool for the exploratory analysis of spatial data thought to contain outliers, is introduced and demonstrated using data on metal content in the soils of Sheffield, England. The empirical spatial breakdown point of a particular data set can be used to indicate whether the distribution of possible contaminants is likely to undermine a robust variogram estimator.  相似文献   

Influence of initial plastic anisotropy of overconsolidated clays on ground behaviour during tunneling     

J. R. Maranha  A. Vieira 《Acta Geotechnica》2008,3(4):259-271

In order to evaluate the influence of the initial plastic anisotropy in the excavation of a tunnel, a “bubble” bounding surface model for structured soils, formulated by Kavvadas and Belokas (Proc. 10th IACMAG Conf., 2001), was implemented in the explicit finite difference code FLAC. Two different initial stress (K ₀) conditions were considered. The size and shape of the initial bounding surfaces were specified to be consistent with the initial stress field. The distorted and rotated shape of the bounding surface, supported by experimental results, defines the anisotropy of shear strength, which is shown to have a significant influence on the displacements. There is also considerable sensitivity of the soil model to the initial stress field.  相似文献   

Oxygen isotopes in the Cretaceous-Paleogene granites of Primorye and some problems of their genesis     

G. A. Valui  E. Yu. Moskalenko  A. A. Strizhkova  G. R. Sayadyan 《Russian Journal of Pacific Geology》2008,2(2):150-157

The Cretaceous-Paleogene granites of the Eastern Sikhote Alin volcanic belt (ESAVB) and Late Cretaceous granitoids of the Tatibin Series (Central Sikhote Alin) are subdivided into three groups according to their oxygen isotope composition: group I with δ¹⁸O from +5.5 to +6.5‰, group II with δ¹⁸O from +7.6 to +10.2‰, and group III with less than +4.5‰. Group I rocks are similar in oxygen isotope composition to that of oceanic basalts and can be derived by melting of basaltic crust. Group II (rocks of the Tatibin Series) have higher δ¹⁸O, which suggests that their parental melts were contaminated by sedimentary material. The low ¹⁸O composition of group III rocks can be explained by their derivation from ¹⁸O-depleted rocks or by subsolidus isotopic exchange with low-¹⁸O fluid or meteoric waters. The relatively low δ¹⁸O and ⁸⁷Sr/⁸⁶Sr in the granitoids of Primorye suggest their derivation from rocks with a short-lived crustal history and can result from the following: (1) melting of sedimentary rocks enriched in young volcanic material that was accumulated in the trench along the transform continental margin (granites of the Tatibin Series) and (2) melting of a mixture of abyssal sediments, ocean floor basalts, and upper mantle in the lithospheric plate that subsided beneath the continent in the subduction zone (granites of the ESAVB).  相似文献   

Upper Cretaceous carbonate hosted zinc–lead–barite deposits in Northern Thrust Zone, northern Iraq: petrography and geochemistry     

Salih M. Awadh  Habib R. Habib  Khaldoon S. Al-Bassam 《Arabian Journal of Geosciences》2008,1(1):75-85

Zinc–lead–barite deposits located in Lefan and Lower Banik localities of about 25 km northeast of Zakho City, Northern Iraq consist of a group of strata-bound sulfides hosted in Upper Cretaceous (Upper Campanian–Maastrichtian) dolomitic limestone. Carbonate-hosted ores contain 3.77% Zn, 2% Pb, and 5% Fe, while in lower Banik, they contain 1.5% Zn, 0.37% Pb, and 1.4% Fe. Diagenetic processes, such as dolomitization and recrystalization in addition to the type of microfacies, provided appropriate physical and chemical conditions that permitted the passage of ore-bearing fluids and participated in precipitation and ore localization. These deposits are precipitated in a platform and developed within the Foreland Thrust Belt. Ore precipitated as infill of intergranular dolomite porosity with replaced dolomite and rudist shells forming disseminated crystals that occupy intergranular pore spaces around dolomite and calcite and as infill of dissolution spaces and fractures.  相似文献   

Strain-softening behaviour of sand in strain path testing under plane-strain conditions     

D. Wanatowski  J. Chu  R. S.-C. Lo 《Acta Geotechnica》2008,3(2):99-114

Experimental data are presented in this paper to study the strain-softening behaviour of sand under plane-strain conditions. K ₀ consolidated strain path tests were conducted using a new plane-strain apparatus. The stress–strain behaviour of medium dense sand under plane-strain conditions was characterized. The test results show that the occurrence of pre-failure strain softening under plane-strain conditions is affected by the void ratio, the strain increment ratio and the initial effective confining stress. This is consistent with previous findings established under axisymmetric conditions. However, a pre-failure strain-softening behaviour in plane-strain tests conducted under high-confining stresses may consist of three stages, namely, material softening, banding softening, and ultimate state. This observation is different from that in triaxial tests where banding softening does not normally occur.  相似文献   

Attenuation relations for strong seismic ground motion in the Himalayan region   总被引：2，自引：0，他引：2  

R. P. Singh  Ashutosh Aman  Y. J. J. Prasad 《Pure and Applied Geophysics》1996,147(1):161-180

Strong motion data from various regions of India have been used to study attenuation characteristics of horizontal peak acceleration and velocity. The strong ground motion data base considered in the present work consists of various earthquakes recorded in the northern part of India since 1986 with magnitudes 5.7 to 7.2. Using these data, relations for horizontal peak acceleration and velocity, which are $$\begin{gathered} log_{10} a = 1.14 + 0.31M + 0.65log_{10} R \hfill \\ log_{10} v = 0.571 + 0.41M + 0.768log_{10} R \hfill \\ \end{gathered} $$ have been proposed wherea is the peak horizontal acceleration in cm/sec²,v is the peak horizontal velocity in mm/sec,M is body wave magnitude, andR is the hypocentral distance in km. The proposed relations are in reasonable agreement with the small amount of strong ground motion data available for the northern part of India. The present results will be useful in estimating strong ground motion parameters and in the earthquake resistant design in the Himalayan region.  相似文献