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Abstract— The composition of surface deposits on vesicle walls in irghizites (i.e., impact glasses at site) from the Zhamanshin meteorite crater were studied using time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS). The cavity walls are unique interfaces for condensation of gases from the superheated, high‐silica melt during the impact. Initially, signals from the cavity wall are dominated by hydrocarbon fragments whereas the glass fracture face surrounding the cavity gave only signals corresponding to glass components. After 12 h in ultra high vacuum (UHV), signals from the cavity wall are dominated by peaks corresponding to fragments normally measured from organosilanes and organosiloxanes with the majority of the hydrocarbon signals markedly reduced. Characteristic hydrocarbon fragments are now observed on the glass fracture surface next to the cavity in an annulus around the cavity perimeter. There are also minor signals in this region from organosilanes and organosiloxanes. In contrast, four tektites (Australites) (i.e., glassy distal ejecta) gave no organosilane or organosiloxane signals after the same preparation and vacuum evaporation procedure. These species appear to be formed only at the impact site where higher levels of organic material are likely to be present in soil and are trapped before evaporation. This appears to be the first report of naturally occurring silicon‐organic compounds.  相似文献   
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In probabilistic seismic demand analysis, evaluation of the sufficiency of an intensity measure (IM) is an important criterion to avoid biased assessment of the demand hazard. However, there exists no metric to quantify the degree of sufficiency as per the criterion of Luco and Cornell (2007). This paper proposes a site‐specific unified measure for degree of sufficiency from all seismological parameters under consideration using a total information gain metric. This unified metric for sufficiency supports not only comparison of the performance of different IMs given a response quantity but also assessment of the performance of a particular IM across different response quantities. The proposed sufficiency metric was evaluated for a 4‐story steel moment frame building, and the influence of ground motion selection on the degree of sufficiency was investigated. It was observed that ground motion selection can have a significant impact on IM sufficiency. Because computing the total information gain requires continuous deaggregation across the IM space, an approximate deaggregation technique that allows for a more practical estimation of marginal deaggregation probabilities is proposed. It is expected that the total information gain metric proposed in this paper will aid in understanding the efficiency‐sufficiency relation, thus enabling the selection of a proper scalar IM for a given site and application in probabilistic seismic demand analysis.  相似文献   
235.
Mössbauer spectra of equilibrated ordinary chondrites consist of two doublets due to paramagnetic iron present in olivines and pyroxenes and two sextets due to magnetically ordered iron present in metallic phases and troilite. The spectral areas of the different mineralogical phases found by Mössbauer spectroscopy in meteorites are proportional to the number of iron atoms in this mineralogical phase. This property of Mössbauer spectra can be the basis for constructing a method for the classification of ordinary chondrites. This idea was first explored at the Mössbauer Laboratory in Kanpur. This group suggested a qualitative method based on 2‐dimensional plots of Mössbauer spectral areas and thus classified properly some meteorites. We constructed a quantitative method using Mössbauer spectral areas, multidimensional discriminant analysis, and Mahalanobis distance (4M method) to determine the probability of a meteorite to be of type H, L, or LL. Based on 59 Mössbauer spectra, we calculated by the 4M method, S cluster , the level of similarity of the Goronyo meteorite to the clusters. On the plot of ferrosilite versus fayalite, the point representing Goronyo is located on the border between H and L areas. Calculated by the 4M method, the meteorite Goronyo is 32% similar to type H, 75% to type L, and 11% to type LL. Additional mineralogical analyses suggested that the Goronyo meteorite would be classified as type L, although it was originally reported as type H in the Meteoritical Bulletin Database.  相似文献   
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Groundwater-dependent ecosystems represent globally rare edaphic islands of scattered distribution, often forming areas of regionally unique environmental conditions. A stable groundwater supply is a key parameter defining their ecological specificity, promoting also soil thermal buffering. Still, a limited number of studies dealt with the importance of water temperature in mire ecosystems and virtually no data exist on within-site variation in the temperature buffer effect. Three temperature dataloggers, placed in patches potentially differing in groundwater supply, were installed in each of 19 Western Carpathian spring mire sites from May 2019 to July 2020. Spring source plots statistically differed in water temperature parameters from the plots located towards the spring mire margin, which did not significantly differ from one another. At the majority of sites, the temperature values changed gradually from spring source to mire margins, fitting the pattern expected in the groundwater temperature buffering scenario. Dataloggers placed in the spring sources were the most distinctive from the others in thermal buffering parameters in conditional principal component analysis. The difference between the spring source and its margin was on average 3.25 °C for 95th percentile of the recorded water temperature data points (i.e. warm extremes) and 1.91 °C for 5th percentile (i.e. cold extremes). This suggests that if the temperature at spring source area is considered, thermal buffering within a site may mitigate mainly warm extremes. Thus, our data may provide an important baseline for predictions of possibly upcoming changes in spring mire hydrology caused by climate change. Both warming and precipitation decrease can give rise to the loss or substantial reduction of buffering effect if the contrasting parameters now recorded at the central part shift to those found towards the margins of groundwater-fed areas.  相似文献   
237.
The Hercynian mountain ranges were islands of mountain glaciation and alpine tundra in a Central European ice‐free corridor during the Late Pleistocene. Today they are notable areas of glacial landforms, alpine‐forest free areas, peatlands and woodlands. However, our knowledge of the Lateglacial and early Holocene environmental changes in this region is limited. We present a new multi‐proxy reconstruction of a mid‐altitude environment in the Bohemian Forest spanning this period. A core (5.2 m length) in the ?erné Lake cirque (1028 m a.s.l.) was subjected to lithological, geochemical, pollen and macrofossil analysis supplemented by two optically stimulated luminescence (OSL) and 10 AMS radiocarbon dates. We determined the impact of regional and supraregional climate changes on the environment. The two most significant changes in sedimentation during the Lateglacial (17.6 and 15.8–15.5 cal. ka BP) were synchronous with regional glacial chronostratigraphy. Unlike Central European mountain ranges, in the Bohemian Forest the Younger Dryas was not coincident with glacier re‐advance, but was a dry, cold episode with low lake levels, which prevailed until the early Preboreal. Plant macrofossils indicate local establishment of Betula nana and Betula pendula/pubescens at 15.4–13.4 cal. ka BP. Comparison with Holocene records from Central Europe shows a similar immigration history of vegetation at mid and higher altitudes. The tree line exceeded an altitude of ~1000 m a.s.l. around 10.5 cal. ka BP and coincided with rapid geochemical changes in the sediment. The 8.2 ka BP event did not have any response in the sedimentary record, but corresponded to stabilization of the Picea abies population and expansion of Fagus. Fagus colonized the Bohemian Forest earlier than other Hercynian mid‐mountains, but never predominated in the composition of the forest at higher elevations. Abies alba was the last tree species that immigrated to the study area.  相似文献   
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We provide the circumstances and details of the fireball observation, search expeditions, recovery, strewn field, and physical characteristics of the Ko?ice meteorite that fell in Slovakia on February 28, 2010. The meteorite was only the 15th case of an observed bolide with a recovered mass and subsequent orbit determination. Despite multiple eyewitness reports of the bolide, only three videos from security cameras in Hungary were used for the strewn field determination and orbit computation. Multiple expeditions of professionals and individual searchers found 218 fragments with total weight of 11.3 kg. The strewn field with the size of 5 × 3 km is characterized with respect to the space distribution of the fragments, their mass and size‐frequency distribution. This work describes a catalog of 78 fragments, mass, size, volume, fusion crust, names of discoverers, geographic location, and time of discovery, which represents the most complex study of a fresh meteorite fall. From the analytical results, we classified the Ko?ice meteorite as an ordinary H5 chondrite.  相似文献   
240.
We show that both the mass and composition of dark matter (DM) particles strongly influence the formation of low mass DM halos. Comparison of theoretical predictions with observations allows us to select the more promising DM models. More details can be found in our paper arXiv:1404.3362.  相似文献   
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