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81.
This study presents results of the first comprehensive research on ecotoxic trace metals (Cd, Pb, Cu and Zn) in aquatic anchialine ecosystems. Data show the influence of hydrological and geological characteristics on trace metals in highly stratified anchialine water columns.  相似文献   
82.
In this paper, I investigate a local effect of polarization of the Cosmic Microwave Background (CMB) in clusters of galaxies, induced by the Thomson scattering of an anisotropic radiation. A local anisotropy of the CMB is produced by some scattering and gravitational effects, as, for instance, the Sunyaev Zel‘dovich effect, the Doppler shift due to the cluster motion and the gravitational lensing. The resulting anisotropy ΔI/I depends on the physical properties of the clusters, in particular on their emissivity in the X band on their size, on their gravitational potential and on the peculiar conditions characterizing the gas they contain. By solving the Boltzmann radiative transfer equation in presence of such anisotropies I calculate the average polarization at the centre of some clusters, namelyA2218, A576 and A2163, whose properties are quite well known. I prove that the gravitational effects due to the contraction or to the expansion have some importance, particularly for high density structures; moreover, the peculiar motion of the cluster, considered as a gravitational lens, influences the propagation of the CMB photons by introducing a particular angular dependence in the gravitational anisotropy and in the scattering integrals. Thus, the gravitational and the scattering effects overally produce an appreciable local average polarization of the CMB, may be observable through a careful polarization measurements towards the centres of the galaxy clusters. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
83.
Any progress in our understanding of low-temperature mineral assemblages and of quantitative physico-chemical modeling of stability conditions of mineral phases, especially those containing toxic elements like selenium, strongly depends on the knowledge of structural and thermodynamic properties of coexisting mineral phases. Interrelation of crystal chemistry/structure and thermodynamic properties of selenium-containing minerals is not systematically studied so far and thus any essential generalization might be difficult, inaccurate or even impossible and erroneous. Disagreement even exists regarding the crystal chemistry of some natural and synthetic selenium-containing phases. Hence, a systematic study was performed by synthesizing ferric selenite hydrates and subsequent thermal analysis to examine the thermal stability of synthetic analogues of the natural hydrous ferric selenite mandarinoite and its dehydration and dissociation to unravel controversial issues regarding the crystal chemistry. Dehydration of synthesized analogues of mandarinoite starts at 56–87?°C and ends at 226–237?°C. The dehydration happens in two stages and two possible schemes of dehydration exist: (a) mandarinoite loses three molecules of water in the first stage of the dehydration (up to 180?°C) and the remaining two molecules of water will be lost in the second stage (>180?°C) or (b) four molecules of water will be lost in the first stage up to 180?°C and the last molecule of water will be lost at a temperature above 180?°C. Based on XRD measurements and thermal analyses we were able to deduce Fe2(SeO3)3·(6-x)H2O (x?=?0.0–1.0) as formula of the hydrous ferric selenite mandarinoite. The total amount of water apparently affects the crystallinity, and possibly the stability of crystals: the less the x value, the higher crystallinity could be expected.  相似文献   
84.
The article dwells on the problems associated with the development of oil and gas Arctic region of Russia. It also suggests possibilities of their solution based on sociological studies conducted by the authors of representative samples in 2005, 2010 and 2015. Stressing the role and significance of sociological research in the general problem of the circumpolar regions by scientific study, the authors show the need for a sociological diagnosis in the context of different social groups. By doing so, characteristics of social problems inherent to the arctic region and requirements for scientific support of possible technologies is identified.  相似文献   
85.
A three-dimensional model is presented and used to reproduce the laboratory hydraulic fracturing test performed on a thick-walled hollow cylinder limestone sample. This work aims to investigate the implications of the fluid flow on the behaviour of the micro-structure of the rock sample, including the material strength, its elastic constants and the initialisation and propagation of fractures. The replication of the laboratory test conditions has been performed based on the coupled Discrete Element Method (DEM) and Computational Fluid Dynamics scheme. The numerical results are in good agreement with the experimental data, both qualitatively and quantitatively. The developed model closely validates the overall behaviour of the laboratory sample, providing a realistic overview of the cracking propagation towards total collapse as well as complying with Lame’s theory for thick-walled cylinders. This research aims to provide some insight into designing an accurate DEM model of a fracturing rock that can be used to predict its geo-mechanical behaviour during Enhanced Oil Recovery applications.  相似文献   
86.
正All the lakes are accumulative systems for the various chemical elements.However,the ratios of the elements in different lake types are very different.It is generally accepted that the composition of lake water determined by  相似文献   
87.
We have conducted hydration–dehydration experiments on terrestrial olivine to investigate the behavior of oxygen isotopic fractionation to test the hypothesis that multiple cycles of aqueous and thermal processing on a parent asteroid comprise a genetic relationship between CM2s and metamorphosed carbonaceous chondrites (MCCs). Two experiments were undertaken. In the first experiment, serpentine was obtained by hydrating terrestrial olivine (Fo90.9) in the laboratory. During this experiment, olivine was reacted with isotopically heavy water (δ18O 21.5‰) at T = 300 °C,  = 300 bar, for 100 days. The oxygen isotopic composition of the experimental serpentine was enriched in 18O (by 10 ‰ in δ18O) due to exchange of oxygen isotopes between olivine and the 18O‐rich water. Dehydrated serpentine was then produced during laboratory heating experiment in vacuum, at T = 930 °C, for 1 h. The oxygen isotopic composition of the dehydrated serpentine was enriched in 18O by a further 7 ‰. The net result of the hydration–dehydration process was an enrichment of 18O in the final material by approximately 17‰. The new experimental results suggest that the oxygen isotopic compositions of MCCs of the Belgica‐like group, including Dhofar 225 and Dhofar 725, could be derived from those of typical CM2 chondrites via several cycles of hydration–dehydration caused by aqueous alteration and subsequent thermal metamorphism within their parent asteroids.  相似文献   
88.
We report radar, photometric, and spectroscopic observations of near-Earth Asteroid (136617) 1994 CC. The radar measurements were obtained at Goldstone (8560 MHz, 3.5 cm) and Arecibo (2380 MHz, 12.6 cm) on 9 days following the asteroid’s approach within 0.0168 AU on June 10, 2009. 1994 CC was also observed with the Panchromatic Robotic Optical Monitoring and Polarimetry Telescopes (PROMPT) on May 21 and June 1-3. Visible-wavelength spectroscopy was obtained with the 5-m Hale telescope at Palomar on August 25. Delay-Doppler radar images reveal that 1994 CC is a triple system; along with (153591) 2001 SN263, this is only the second confirmed triple in the near-Earth population. Photometry obtained with PROMPT yields a rotation period for the primary P = 2.38860 ± 0.00009 h and a lightcurve amplitude of ∼0.1 mag suggesting a shape with low elongation. Hale telescope spectroscopy indicates that 1994 CC is an Sq-class object. Delay-Doppler radar images and shape modeling reveal that the primary has an effective diameter of 0.62 ± 0.06 km, low pole-on elongation, few obvious surface features, and a prominent equatorial ridge and sloped hemispheres that closely resemble those seen on the primary of binary near-Earth Asteroid (66391) 1999 KW4. Detailed orbit fitting reported separately by Fang et al. (Fang, J., Margot, J.-L., Brozovic, M., Nolan, M.C., Benner, L.A.M., Taylor, P.A. [2011]. Astron. J. 141, 154-168) gives a mass of the primary of 2.6 × 1011 kg that, coupled with the effective diameter, yields a bulk density of 2.1 ± 0.6 g cm−3. The images constrain the diameters of the inner and outer satellites to be 113 ± 30 m and 80 ± 30 m, respectively. The inner satellite has a semimajor axis of ∼1.7 km (∼5.5 primary radii), an orbital period of ∼30 h, and its Doppler dispersion suggests relatively slow rotation, 26 ± 12 h, consistent with spin-orbit lock. The outer satellite has an orbital period of ∼9 days and a rotation period of 14 ± 7 h, establishing that the rotation is not spin-orbit locked. Among all binary and triple systems observed by radar, at least 25% (7/28) have a satellite that rotates more rapidly than its orbital period. This suggests that asynchronous configurations with Protation < Porbital are relatively common among multiple systems in the near-Earth population. 1994 CC’s outer satellite has an observed maximum separation from the primary of ∼5.7 km (∼18.4 primary radii) that is the largest separation relative to primary radius seen to date among all 36 known binary and triple NEA systems. 1994 CC, (153591) 2001 SN263, and 1998 ST27 are the only triple and binary systems known with satellite separations >10 primary radii, suggesting either a detection bias, or that such widely-separated satellites are relatively uncommon in NEA multiple systems.  相似文献   
89.
Working with a magnetic field periodic along Oz and decaying in time, we deal with the Dirac-type equation characterizing the fermions evolving in magnetar’s crust. For ultra-relativistic particles, one can employ the perturbative approach, to compute the conserved current density components. If the magnetic field is frozen and the magnetar is treated as a stationary object, the fermion’s wave function is expressed in terms of the Heun’s Confluent functions. Finally, we are extending some previous investigations on the linearly independent fermionic modes solutions to the Mathieu’s equation and we discuss the energy spectrum and the Mathieu Characteristic Exponent.  相似文献   
90.
This paper gathered available flow and transport solutions and used them for two composite liners, consisting of geomembrane (GM) overlying either a compacted clay liner (CCL) or a geosynthetic clay liner (GCL). Its aim is to provide a guiding framework for the possible choices of (a) approaches to bottom liner design, (b) respective analytical solutions to flow and transport equations, as well as (c) parameters required for each type of solution. On the basis of the obtained results, the following recommendations are made. When the goal of analysis is to determine material equivalency, leachate flow rate is an adequate key parameter for GM-CCL composite liners. For GM-GCL composite liners, it is necessary to compute contaminant concentration or mass flux, considering (a) transport through defects for inorganic contaminants and (b) diffusion and the contribution of any available attenuation layer for organic contaminants. When the goal of analysis is to assess impact to groundwater, it is advised to calculate both discharge rate and contaminant mass flux regardless of liner type. The critical parameter for the transport calculations is the retardation factor of the contaminant, for the case of CCLs, while the results for GCLs are much less sensitive to this parameter.  相似文献   
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