Inorganic cobalt species in seawater     

B. Ćosović  D. Degobbis  H. Bilinski  M. Branica 《Geochimica et cosmochimica acta》1982,46(2):151-158

Polarographic and precipitation methods were used for Co speciation in seawater taking into account only the major inorganic anionic components of seawater, such as chloride, sulphate, carbonate, hydroxide and bicarbonate. The corresponding constants were experimentally determined at the seawater ionic strength from the shift of the irreversible half-wave potential and solubility limits. The value for the carbonato-complex was obtained for the first time, while the hydroxo- and sulphato-complex values are in a fairly good agreement with the data already published. The value for the chlorocomplex was determined at $\text{I = 2.0}$ and 3.5 mol 1^?1 and extrapolated to the seawater ionic strength.The distribution of dissolved inorganic Co species in seawater was evaluated; free Co ion (hydrated) is the predominant species (about 45%) and CoSo₄⁰ and CoCl⁺ are found in approximately equal amounts (about 22%), while the fractions of CoOH⁺, Co(OH)₂⁰ and CoCO₃⁰ are between 1% and 5%.  相似文献   

Investigating Propagation of Short-Period Ocean Waves Into the Periphery of Arctic Pack Ice Using High-Resolution Upward-Looking Sonar     

Matthew G. Asplin  John Marko  David B. Fissel  Keath Borg 《大气与海洋》2018,56(3):152-161

Springtime fetch in the Cape Bathurst Polynya System may present opportunities for winds to generate waves capable of propagating into the thick pack ice formed over the winter. A waves-in-ice event at a study site located on the Canadian Shelf in the southern Beaufort Sea that occurred 22–23 May 2011 is presented and analyzed for wave energy attenuation and dissipation characteristics. The event was monitored near the ice edge and, therefore, presents information on attenuation of waves from the ice edge into the pack. Waves of T?=?5?s, λ?=?37.5?m were observed up to approximately 143?m and approximately 77?m away from the ice edge during two separate observation periods of ice edge wave propagation. We estimated reflection coefficients of 53% and 52% and wave attenuation coefficients of α?=?2.4?×?10^?2?m^?1 and α?=?5.4?×?10^?2?m^?1, respectively, for the two periods. Estimated attenuation rates are an order of magnitude greater than in comparable studies and are inconsistent with previous findings of a “rollover” effect in attenuation rates for short-period waves.  相似文献   

A transition from CMIP3 to CMIP5 for climate information providers: the case of surface temperature over eastern North America     

Marko Markovic  Ramón de Elía  Anne Frigon  H. Damon Matthews 《Climatic change》2013,120(1-2):197-210

The release of new data constituting the Coupled Model Intercomparison Project—Phase 5 (CMIP5) database is an important event in both climate science and climate services issues. Although users’ eagerness for a fast transition from CMIP3 to CMIP5 is expected, this change implies some challenges for climate information providers. The main reason is that the two sets of experiments were performed in different ways regarding radiative forcing and hence continuity between both datasets is partially lost. The objective of this research is to evaluate a metric that is independent of the amount and the evolution of radiative forcing, hence facilitating comparison between the two sets for surface temperature over eastern North America. The link between CMIP3 and CMIP5 data sets is explored spatially and locally (using the ratio of local to global temperatures) through the use of regional warming patterns, a relationship between the grid-box and the global mean temperature change for a certain time frame. Here, we show that local to global ratios are effective tools in making climate change information between the two sets comparable. As a response to the global mean temperature change, both CMIP experiments show very similar warming patterns, trends, and climate change uncertainty for both winter and summer. Sensitivity of the models to radiative forcing is not assessed. Real inter-model differences remain the largest source of uncertainty when calculating warming patterns as well as spatially-based patterns for the pattern scaling approach. This relationship between the datasets, which may escape users when they are provided with a single radiative forcing pathway, needs to be stressed by climate information providers.  相似文献