Microfossils of Polynesian cultigens in lake sediment cores from Rano Kau, Easter Island     

M. Horrocks  W. T. Baisden  M. K. Nieuwoudt  J. Flenley  D. Feek  L. González Nualart  S. Haoa-Cardinali  T. Edmunds Gorman 《Journal of Paleolimnology》2012,47(2):185-204

Previous wetland vegetation records from Easter Island showing deforestation and Polynesian agriculture are limited to cores that rely on pollen, with a single cultigen pollen type identified: Urticaceae/Moraceae, possibly Broussonetia payrifera (paper mulberry). Here we redress this by also using phytolith and starch analyses on four lake sediment cores on a ~350-m transect along the southwest edge of Rano Kau, focusing on in-washed basal clayey layers. We also use a new method, Fourier transform infrared spectroscopy, to positively identify degraded starch collected from sedimentary deposits. The cores are the first samples recovered from an area in the lake that (a) lies below the relict village of Orongo, (b) is near a section of the crater believed to be most accessible from the Pacific coast, and (c) is far from the northern crater rim and receives high solar radiation, a likely benefit for crops of tropical origin. Pollen and phytoliths are abundant in the clayey layers and sparse in overlying layers of organic lake detritus and living rhizomes. Mixing of core deposits as a result of human activity has disordered the radiocarbon sequence, precluding development of an reliable chronology. Containing microfossils of several introduced cultigens, the clayey layers represent gardened terraces that have slumped into the lake. The data indicate large-scale deforestation and a mixed-crop production system including Broussonetia papyrifera, Colocasia esculenta (taro), Dioscorea alata (greater yam), Ipomoea batatas (sweet potato), Lagenaria siceraria (bottle gourd) and Musa (banana) sp. The data show (a) the potential for using the combined analyses to provide direct evidence of Polynesian horticulture on Easter Island and (b) that the island’s wetlands potentially hold extensive horticultural records. The study highlights the concept of ‘transported landscapes,’ whereby colonising people replace indigenous forests with artificial, imported agricultural landscapes.  相似文献   

North Atlantic atmospheric circulation and surface wind in the Northeast of the Iberian Peninsula: uncertainty and long term downscaled variability   总被引：1，自引：0，他引：1  

E. García-Bustamante  J. F. González-Rouco  J. Navarro  E. Xoplaki  P. A. Jiménez  J. P. Montávez 《Climate Dynamics》2012,38(1-2):141-160

The variability and predictability of the surface wind field at the regional scale is explored over a complex terrain region in the northeastern Iberian Peninsula by means of a downscaling technique based on Canonical Correlation Analysis. More than a decade of observations (1992–2005) allows for calibrating and validating a statistical method that elicits the main associations between the large scale atmospheric circulation over the North Atlantic and Mediterranean areas and the regional wind field. In an initial step the downscaling model is designed by selecting parameter values from practise. To a large extent, the variability of the wind at monthly timescales is found to be governed by the large scale circulation modulated by the particular orographic features of the area. The sensitivity of the downscaling methodology to the selection of the model parameter values is explored, in a second step, by performing a systematic sampling of the parameters space, avoiding a heuristic selection. This provides a metric for the uncertainty associated with the various possible model configurations. The uncertainties associated with the model configuration are considerably dependent on the spatial variability of the wind. While the sampling of the parameters space in the model set up moderately impact estimations during the calibration period, the regional wind variability is very sensitive to the parameters selection at longer timescales. This fact illustrates that downscaling exercises based on a single configuration of parameters should be interpreted with extreme caution. The downscaling model is used to extend the estimations several centuries to the past using long datasets of sea level pressure, thereby illustrating the large temporal variability of the regional wind field from interannual to multicentennial timescales. The analysis does not evidence long term trends throughout the twentieth century, however anomalous episodes of high/low wind speeds are identified.  相似文献   

Spatial trends in heavy metals and nitrogen deposition in Navarra (Northern Spain) based on moss analysis     

L. González-Miqueo  D. Elustondo  E. Lasheras  R. Bermejo  J. M. Santamaría 《Journal of Atmospheric Chemistry》2009,62(1):59-72

A biomonitoring survey using the moss species Hypnum cupressiforme Hedw. was performed in the North of Navarra (Spain) in 2006. The levels of V, Cr, Mn, Ni, Cu, Zn, As, Zr, Cd, Hg and Pb, and the total nitrogen content were determined in the samples by means of ICP-MS, CV-AA, and the Kjeldahl method. PCA analysis showed a differentiation between lithogenic (V, Cr, Mn, Ni, As and Zr) and anthropogenic elements (Mn, Cu, Zn, Cd, Hg and Pb). Spatial distribution maps were drawn using the kriging method, in order to identify the most affected areas and the main pollution sources. A similar spatial distribution was observed for the elements belonging to each group separated by the PCA, showing an important contribution from metal industries located in the Basque Country, as well as influence of long-range transboundary pollution processes. Background levels were also determined for the study area, along with the contamination factor for the different elements analysed. Mosses seemed to be good biomonitors of N deposition in areas of accumulation.  相似文献   

Gas kinematics in the halo of the warm ULIRG PKS1345+12     

Javier Rodríguez Zaurín  Joanna Holt  Clive N. Tadhunter  Rosa M. González Delgado 《Astrophysics and Space Science》2009,324(2-4):225-229

We use long-slit spectra taken with the William Herschel Telescope on La Palma and high-resolution Hubble Space Telescope imaging to study the gas kinematic in the halo of the ultraluminous infrared/radio galaxy PKS1345+12 (z=0.122). Our long-slit spectra show line splitting at the locations of massive star clusters ( $10^{6}<M_{\mathrm{SSC}}^{\mathrm{YSP}}<10^{7}$ M_⊙), indicating that they are moving at up to 450 km?s^?1 with respect to the local ambient gas. Given their kinematics, it is plausible that these super star clusters have been formed either in fast-moving gas streams or tidal tails that are falling back into the nuclear regions as part of the merger process, or as a consequence of jet-induced star formation linked to the extended, diffuse radio emission detected in the halo of the galaxy.  相似文献   

Preface     

Enrique Pérez  Richard de Grijs  Rosa M. González Delgado 《Astrophysics and Space Science》2009,324(2-4):79-81

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Structural features of humic acids from a sedimentary sequence in the Guadiana estuary (Portugal–Spain border)     

O. Polvillo  J.A. González-Pérez  T. Boski  F.J. González-Vila 《Organic Geochemistry》2009,40(1):20-28

The structural characteristics of humic acids (HAs) from two different depths of a sedimentary sequence representing the last 13 kyr in the valley of Guadiana river estuary (SW Portugal/Spain border) have been approached using a combination of spectroscopic techniques, wet chemical degradation methods (sequential oxidation with sodium persulfate followed by KMnO₄, and oxidation with RuO₄) and analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) in the presence and absence of tetramethylammonium hydroxyde (TMAH). The aim was to obtain complementary information on the sources and alteration of the organic matter (OM) provided by a previous study on the vertical distribution of terrestrial and phytoplankton biogeochemical markers in the sequence. Both the FT-IR (Fourier transformed infrared) and ¹³C NMR (nuclear magnetic resonance) spectra showed a close similarity with the structural characteristics of the HA samples. NMR signals in the alkyl region (0–45 ppm) as well as FT-IR band patterns typical for methoxyl-substituted aromatic rings pointed to the presence of an important aliphatic domain, as well as to lignin-derived compounds. This finding was confirmed using analytical pyrolysis. In addition, the main TMAH thermochemolysis products were typical lignin-derived methoxyphenols with both guaicyl and syringyl nuclei. The detection of methoxyphenol units with three to six carbon atom (C₃–C₆) side chains suggests that lignin and possibly suberin were only partially degraded. Compounds arising from proteins and polysaccharides were also detected, although in lesser and varying amount. The major products from persulfate oxidation were series of n-alkanes (C₁₆–C₃₃ with clear odd/even predominance) and n-fatty acids, both saturated (C₁₀–C₂₆ with strong even/odd predominance) and unsaturated, which may arise from the above aliphatic biomacromolecules. The major products from permanganate oxidation of the persulfate residue were α,ω-diacids (C₆–C₁₁) originating from oxidation of the ether bonds linking the building blocks constituting the core of the HA structure. Aromatic compounds (phenols, methoxy-dimethoxybenzene carboxylic acid and benzene di-, tri-, tetra- and pentacarboxylic acids), most probably derived from the aromatic backbone of the HAs, that may also include lignin moieties as well as other polyphenols (flavonoids and tannins) were also detected. The RuO₄ oxidation also released series of n-alkanes (C₁₆–C₃₃), linear saturated fatty acids (C₁₀–C₂₈) and α,ω-diacids (C₇–C₂₅), as well as traces of benzene polycarboxylic acids. Regarding the usefulness of the various techniques used, they provide complementary information. Indeed, spectroscopic techniques and analytical pyrolysis provide information on the backbone of the HAs, and on their origin, whereas the oxidative degradations provide different information on the structural features of the HA, particularly the nature of the linking between the building blocks. In general, the data support the idea that the HAs still contain information about the signature of aliphatic and aromatic biomacromolecules contributing to the OM deposited. The presence of lignin-derived residues suggests a large input from terrestrial carbon throughout the core.  相似文献   

Regional stratigraphy and distribution of epigenetic stratabound celestine, fluorite, barite and Pb–Zn deposits in the MVT province of northeastern Mexico     

Francisco González-Sánchez  Antoni Camprubí  Eduardo González-Partida  Rafael Puente-Solís  Carles Canet  Elena Centeno-García  Viorel Atudorei 《Mineralium Deposita》2009,44(3):343-361

Northeastern Mexico hosts numerous epigenetic stratabound carbonate-hosted low-temperature hydrothermal deposits of celestine, fluorite, barite and zinc-lead, which formed by replacement of Mesozoic evaporites or carbonate rocks. Such deposits can be permissively catalogued as Mississippi Valley-type (MVT) deposits. The deposits studied in the state of Coahuila are associated with granitic and metasedimentary basement highs (horsts) marginal or central to the Mesozoic Sabinas Basin. These horsts controlled the stratigraphy of the Mesozoic basins and subsequently influenced the Laramide structural pattern. The Sabinas Basin consists of ~6,000-m-thick Jurassic to Cretaceous siliciclastic, carbonate and evaporitic series. The MVT deposits are mostly in Barremian and in Aptian-Albian to Cenomanian formations and likely formed from basinal brines that were mobilized during the Laramide orogeny, although earlier diagenetic replacement of evaporite layers (barite and celestine deposits) and lining of paleokarstic cavities in reef carbonates (Zn–Pb deposits) is observed. Fluid inclusion microthermometry and isotopic studies suggest ore formation due to mixing of basinal brines and meteoric water. Homogenization temperatures of fluid inclusions range from 45°C to 210°C; salinities range from 0 to 26 wt.% NaCl equiv., and some inclusions contain hydrocarbons or bitumen. Sulfur isotope data suggest that most of the sulfur in barite and celestine is derived from Barremian to Cenomanian evaporites. Regional geology and a compilation of metallogenic features define the new MVT province of northeastern Mexico, which comprises most of the state of Coahuila and portions of the neighboring states of Nuevo León, Durango and, perhaps extends into Zacatecas and southern Texas. This province exhibits a regional metal zonation, with celestine deposits to the south, fluorite deposits to the north and barite and Zn–Pb deposits mostly in the central part.  相似文献   

Origin of fault domains and fault-domain boundaries (transfer zones and accommodation zones) in extensional provinces: Result of random nucleation and self-organized fault growth     

Roy W. Schlische  Martha Oliver Withjack   《Journal of Structural Geology》2009,31(9):910

In many extensional provinces, large normal faults dip in the same direction forming fault domains. Features variously named transfer faults, transfer zones, and accommodation zones (hereafter non-genetically referred to as fault-domain boundaries) separate adjacent fault domains. Experimental modeling of distributed extension provides insights on the origin, geometry, and evolution of these fault domains and fault-domain boundaries. In our scaled models, a homogeneous layer of wet clay or dry sand overlies a latex sheet that is stretched orthogonally or obliquely between two rigid sheets. Fault domains and fault-domain boundaries develop in all models in both map view and cross-section. The number, size, and arrangement of fault domains as well as the number and orientation of fault-domain boundaries are variable, even for models with identical boundary conditions. The fault-domain boundaries in our models differ profoundly from those in many published conceptual models of transfer/accommodation zones. In our models, fault-domain boundaries are broad zones of deformation (not discrete strike-slip or oblique-slip faults), their orientations are not systematically related to the extension direction, and they can form spontaneously without any prescribed pre-existing zones of weakness. We propose that fault domains develop because early-formed faults perturb the stress field, causing new nearby faults to dip in the same direction (self-organized growth). As extension continues, faults from adjacent fault domains propagate toward each another. Because opposite-dipping faults interfere with one another in the zone of overlap, the faults stop propagating. In this case, the geometry of the domain boundaries depends on the spatial arrangement of the earliest formed faults, a result of the random distribution of the largest flaws at which the faults nucleate.  相似文献   

Generation and performance of automated jarosite mineral detectors for visible/near-infrared spectrometers at Mars   总被引：1，自引：0，他引：1  

Martha S. Gilmore  Benjamin Bornstein  Rebecca Castaño 《Icarus》2008,195(1):169-183

We have developed two automated detectors that can recognize the sulfate mineral jarosite in unknown visible to near-infrared spectra (350-2500 nm). The two detectors are optimized for use within the terrestrial and martian atmospheres. The detectors are built from Support Vector Machines trained using a generative model to create linear mixtures of library mineral spectra. Both detectors performed with an average ∼90% accuracy on laboratory spectra of single minerals and the laboratory and field spectra of rocks collected in a hydrothermal environment. This type of algorithm will contribute to the efficiency of onboard data analysis of landed and orbital visible/near-infrared spectrometers at Mars.  相似文献   

GPS differential code biases determination: methodology and analysis   总被引：1，自引：1，他引：0  

Jaume Sanz  J. Miguel Juan  Adrià Rovira-Garcia  Guillermo González-Casado 《GPS Solutions》2017,21(4):1549-1561

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