The Neoproterozoic Fiq glaciation and its aftermath, Huqf supergroup of Oman   总被引：4，自引：0，他引：4  

Philip A. Allen  Jonathan Leather†  Martin D. Brasier‡ 《Basin Research》2004,16(4):507-534

The <1.5‐km thick Fiq Member of the Ghadir Manqil Formation, Huqf Supergroup, Oman, contains a succession of Marinoan‐age glacially and non‐glacially influenced deposits overlain by a transgressive, ¹³C‐depleted, deep‐water dolostone (Hadash Formation) that deepens up into the marine shales and siltstones of the Masirah Bay Formation. The Fiq Member and Hadash–Masirah Bay Formations are well exposed in the core of the Jebel Akhdar of northern Oman and provide a valuable insight into the processes operating during a Neoproterozoic glacial epoch and its aftermath. The Fiq Member comprises seven stratigraphic units (F1–F7) of proximal and distal glacimarine, non‐glacial sediment gravity flow, and non‐glacial shallow marine facies associations. These units can be correlated over almost the entire Neoproterozoic outcrop belt (ca. 80 km) of the Jebel Akhdar. Four units contain glacimarine rainout diamictites, commonly at the top of cycles beneath strong lithofacies dislocations suggesting flooding. The units are thought to have been generated by combined glacio‐isostatic and glacio‐eustatic forcing caused by changing volumes of terrestrial glacier ice. The lateral persistence and thickness of massive diamictite units increase upwards in the stratigraphy, the youngest (F7) diamictite being abruptly overlain by the Hadash Formation. Correlation of lithofacies associations across the rift basin and palaeocurrents indicate that siliciclastic sediment and glacially entrained debris were derived from both basin margins. Open‐water conditions existed during interglacials, attested to by the presence of wave‐rippled sandstones in the western part of the basin. The Hadash carbonate also exhibits variations between east and west, showing that despite an overall deep‐water depositional setting, rift margin and intrabasinal structure continued to exert a control on facies development during the post‐glacial aftermath. Onlap of basin margins continued through the deposition of the Masirah Bay Formation. The sedimentology and stratigraphy of the Fiq Member and Hadash–Masirah Bay Formations have a number of implications for the Snowball Earth hypothesis. The overall stratigraphic evolution of the Fiq Member suggests a dynamic, temperate/polythermal style of glaciation, perhaps nucleated on uplifted continental or rift margin topography, with marine‐terminating glaciers. Some transgressions coupled to deglaciations within the Fiq glacial epoch were accompanied by minor deposition of carbonate. However, final deglaciation triggered the deposition of a <8‐m thick, deep‐water dolomite contaminated with siliciclastics, with a lithofacies assemblage still reflecting the underlying bathymetric template, followed by relatively deep marine shales and siltstones. The preservation of relatively deep marine Masirah Bay sediments above the Fiq basin margin suggests either tectonic collapse of the rift shoulder or, more likely, rapid eustatic rise accompanying deglaciation.  相似文献   

辽宁古元古代地体中富电气石岩石的成因：蒸发岩硼源的证据          下载免费PDF全文

许虹  彭齐鸣  Martin  R.  Palmer 《中国地质》2004,31(3):240-253

辽宁东部古元古界底部地层(南辽河群)中赋存着大型的硼酸盐矿床，含矿层位中广泛分布含电气石的变粒岩和电英岩。空间上这些含电气石的岩石与硼酸盐有着密切的联系，电气石可以作为区域硼矿找矿的标志。已有研究结果表明，该地区的硼酸盐矿床是变质蒸发岩成因。本研究对该区不同产状的电气石和硼酸盐的地质特征，全岩和矿物成分、硼同位素组成进行了分析。本区的电气石包括层状和脉状两大类，而电气石的富集与硼酸盐关系密切，电英岩往往分布在硼酸盐矿体的上盘。而矿体的下盘一般不产出富电气石的岩石。当长英质脉体穿过硼酸盐矿体时，脉体中往往会富集电气石。含电气石岩石的全岩地球化学分析表明，它们的REE及其他微量元素特征以及相关性关系与周围不含电气石的同类岩石十分相似，反映出一种成因上的联系。本区电气石主要属于镁电气石一铁电气石系列，靠近硼矿体的电气石比远离硼矿体的电气石更加富镁，有着更高的Mg／Fe比值。电气石和硼酸盐的硼同位素成分分析显示出二者在同位素组成上的相似性，前者比后者的δ^11B稍低，这可能是由于热液活动过程中同位素分馏的结果。电气石的硼同位素组成在空间上显示出变化规律：远离硼酸盐矿体的电气石的δ^11B值(-5．2‰- 3．6‰)比矿体附近的电气石低(平均 10．5‰)。以上空间和成分上的关系表明硼酸盐可能是形成电气石主要的硼来源，电气石是在热液过程中通过淋滤下伏含硼蒸发岩中的硼形成含硼热液，在与上覆沉积物交代过程中形成含电气石岩石。电气石的条带是热液顺层选择交代的结果。本区电气石与硼酸盐的关系表明，层状电气石可以通过含硼热液交代的方式形成。变质地体中的层状电气石岩石的出现可能与变质蒸发岩有关。这一认识对区域硼矿勘查工作和变质地体的沉积环境分析有借鉴意义。  相似文献   

Divergent evolution in fluviokarst landscapes of central Kentucky     

Jonathan D. Phillips  Linda L. Martin  Viva G. Nordberg  William A. Andrews 《地球表面变化过程与地形》2004,29(7):799-819

Central Kentucky is characterized by a mixture of karst and ?uvial features, typically manifested as mosaic of karst‐rich/channel‐poor (KRCP) and channel‐rich/karst‐poor (CRKP) environments. At the regional scale the location and distribution of KRCP and CRKP areas are not always systematically related to structural, lithological, topographic, or other controls. This study examines the relationship of KRCP and CRKP zones along the Kentucky River gorge area, where rapid incision in the last 1·5 million years has lowered local base levels and modi?ed slopes on the edge of the inner bluegrass plateau. At the scale of detailed ?eld mapping on foot within a 4 km² area, the development of karst and ?uvial features is controlled by highly localized structural and topographic constraints, and can be related to slope changes associated with retreat of the Kentucky River gorge escarpment. A conceptual model of karst/?uvial transitions is presented, which suggests that minor, localized variations are suf?cient to trigger a karst–?uvial or ?uvial–karst switch when critical slope thresholds are crossed. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Mechanisms of weathering of meteorites recovered from hot and cold deserts and the formation of phyllosilicates     

Martin R. Lee  Philip A. Bland 《Geochimica et cosmochimica acta》2004,68(4):893-916

Petrographic, mineralogical and chemical analysis of naturally weathered equilibrated ordinary chondrites collected from ‘ hot’ deserts and Antarctica has revealed striking similarities and also pronounced differences in weathering between the two environments. Terrestrial weathering in all meteorites studied is dominated by oxidation and hydration of Fe,Ni metal, producing Fe-oxides and oxyhydroxides that have partially replaced the metal grains and have also occluded primary intergranular pores to form veins. Troilite weathers readily in ‘ hot’ desert environments but undergoes very little alteration under Antarctic conditions. Most of the primary porosity of ordinary chondrites has been occluded by the time that ∼ 15 to 25% of the initial Fe⁰ and Fe²⁺ has been oxidised to Fe³⁺ in both environments. Results from modelling the volume changes upon alteration of primary minerals to a range of weathering products demonstrates that the primary porosity of most meteorites is sufficient to accommodate weathering products. Dilation of primary pores and brecciation, which has been observed in parts of some meteorites, will only occur if the meteorite is especially metal-rich, or has a low primary porosity. These weathering products are absent from recent falls but have formed in a fall after ∼ 100 yr of museum storage.Cl-bearing akaganéite and hibbingite are common weathering products in Antarctic finds but occur in abundance in only one ‘ hot’ desert meteorite, Daraj 014. The majority of Fe-rich weathering products in meteorites from both environments contain low, but variable concentrations of Si, Mg and Ca. In most meteorites a proportion of these elements are inferred to be present as a very finely crystalline mineral with a ∼ 1.0-nm lattice fringe spacing; where seen within intragranular fractures this mineral has a topotactic relationship with olivine and orthopyroxene. In the heavily-weathered Antarctic finds ALHA 78045 and 77002, Si is concentrated in cronstedtite, a Fe-rich phyllosilicate. An unidentified hydrous Si-Fe-Ni-Mg mineral or gel has also partially replaced taenite in ALHA 78045. In addition to Fe-rich weathering products, ‘ hot’ desert meteorites contain sulphates, Ca-carbonate and silica, whereas such minerals are largely absent from Antarctic finds. The abundance of silicate weathering products in Antarctic meteorites is unexpected and indicates that olivine and pyroxene undergo significant chemical weathering in these environments. As preterrestrial cronstedtite is abundant in CM2 carbonaceous chondrites, the Antarctic environment may be a powerful analog for aqueous alteration in the asteroidal parent bodies of primitive meteorites.  相似文献   

New constraints on the sources and behavior of neodymium and hafnium in seawater from Pacific Ocean ferromanganese crusts     

Tina van de Flierdt  Martin Frank  Alex N. Halliday  James R. Hein 《Geochimica et cosmochimica acta》2004,68(19):3827-3843

The behavior of dissolved Hf in the marine environment is not well understood due to the lack of direct seawater measurements of Hf isotopes and the limited number of Hf isotope time-series obtained from ferromanganese crusts. In order to place better constraints on input sources and develop further applications, a combined Nd-Hf isotope time-series study of five Pacific ferromanganese crusts was carried out. The samples cover the past 38 Myr and their locations range from sites at the margin of the ocean to remote areas, sites from previously unstudied North and South Pacific areas, and water depths corresponding to deep and bottom waters.For most of the samples a broad coupling of Nd and Hf isotopes is observed. In the Equatorial Pacific ε_Nd and ε_Hf both decrease with water depth. Similarly, ε_Nd and ε_Hf both increase from the South to the North Pacific. These data indicate that the Hf isotopic composition is, in general terms, a suitable tracer for ocean circulation, since inflow and progressive admixture of bottom water is clearly identifiable.The time-series data indicate that inputs and outputs have been balanced throughout much of the late Cenozoic. A simple box model can constrain the relative importance of potential input sources to the North Pacific. Assuming steady state, the model implies significant contributions of radiogenic Nd and Hf from young circum-Pacific arcs and a subordinate role of dust inputs from the Asian continent for the dissolved Nd and Hf budget of the North Pacific.Some changes in ocean circulation that are clearly recognizable in Nd isotopes do not appear to be reflected by Hf isotopic compositions. At two locations within the Pacific Ocean a decoupling of Nd and Hf isotopes is found, indicating limited potential for Hf isotopes as a stand-alone oceanographic tracer and providing evidence of additional local processes that govern the Hf isotopic composition of deep water masses. In the case of the Southwest Pacific there is evidence that decoupling may have been the result of changes in weathering style related to the buildup of Antarctic glaciation.  相似文献   

Socioeconomic GeoComputation and E-Social Science     

David Martin 《Transactions in GIS》2005,9(1):1-3

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Uptake and depuration of PAHs and chlorinated pesticides by semi-permeable membrane devices (SPMDs) and green-lipped mussels (Perna viridis)     

Bruce J. Richardson  Edmund S.-C. Tse  Sharon B. De Luca-Abbott  Michael Martin  Paul K.S. Lam 《Marine pollution bulletin》2005,51(8-12):975

Semi-batch seawater experiments were conducted to follow the uptake and release of selected PAHs (anthracene, fluorathene, pyrene and B[a]P) and organochlorine pesticides (α-HCH, aldrin, dieldrin, p,p′-DDT) in semi-permeable membrane devices (SPMDs) and green-lipped mussels (Perna viridis). Mathematical models were applied to describe the uptake and elimination curves of the contaminants for SPMDs, and kinetic parameters, such as uptake rate constants, and equilibrium triolein/water partitioning coefficients were calculated. SPMD data showed a good fit to estimate rate constant and partition coefficient equations, but only those contaminants which partitioned mainly in the dissolved phase (α-HCH and dieldrin) were well explained for mussels. Poor conformity of the other contaminants indicated mussels uptake by routes other than diffusion, such as ingestion of algae. An apparent equilibrium state was only noted for α-HCH in mussels. Aldrin was not detected in mussels in the first few days of exposure, indicating potential metabolism of this compound. B[a]P was not detected in the triolein of SPMDs, which suggests that the membrane may act as a reservoir. Loss of spiked B[a]P from the triolein was evident in a depuration experiment, which may indicate transfer to the membrane. Rate constants for mussels were higher than those for SPMDs, but the reverse was true for partition coefficients. Overall, mussels and SPMDs had similar uptake rates for all compounds in this study, excluding p,p′-DDT and dieldrin. Contaminant elimination took place more rapidly in mussels, implying that SPMDs are better candidates for detecting episodic discharge of organic contaminants.  相似文献   

Centrifuge modeling of load-deformation behavior of rocking shallow foundations   总被引：4，自引：0，他引：4  

Sivapalan Gajan  Bruce L. Kutter  Justin D. Phalen  Tara C. Hutchinson  Geoff R. Martin 《Soil Dynamics and Earthquake Engineering》2005,25(7-10):773-783

Shallow foundations supporting building structures might be loaded well into their nonlinear range during intense earthquake loading. The nonlinearity of the soil may act as an energy dissipation mechanism, potentially reducing shaking demands exerted on the building. This nonlinearity, however, may result in permanent deformations that also cause damage to the building. Five series of tests on a large centrifuge, including 40 models of shear wall footings, were performed to study the nonlinear load-deformation characteristics during cyclic and earthquake loading. Footing dimensions, depth of embedment, wall weight, initial static vertical factor of safety, soil density, and soil type (dry sand and saturated clay) were systematically varied. The moment capacity was not observed to degrade with cycling, but due to the deformed shape of the footing–soil interface and uplift associated with large rotations, stiffness degradation was observed. Permanent deformations beneath the footing continue to accumulate with the number of cycles of loading, though the rate of accumulation of settlement decreases as the footing embeds itself.  相似文献   

Gene Expression Analysis for Exposure to Estrogenic Substances     

Martin Alberti  Ulf Kausch  Stefanie Haindl  Martin Seifert 《洁净——土壤、空气、水》2005,33(1):38-44

Zebrafish (Danio rerio) were exposed with 17β‐estradiol (E2) and nonylphenol (NP) in different concentrations. Gene expression analysis was carried out by two different approaches. First, RT‐PCR experiments were performed for the examination of expression levels of the two marker genes vitellogenin and aromatase. This approach showed a significant increase in the expression of the vitellogenin gene in exposed male fish (500 ng/L 17β‐estradiol and 250 μg/L nonylphenol). This egg yolk protein is usually not synthesized in male vertebrates. A slight decrease of expression of the aromatase gene was observed in exposed female zebrafish. Aromatase is known to catalyze the conversion of androgens to estrogens. Second, DNA microarray experiments were carried out, which allow the simultaneous examination of the expression levels of a great number of marker genes. The microarray experiments resulted in an up‐regulation of vitellogenin up to 850‐fold. In addition, several other genes were identified to be up‐regulated by estrogens, for example the high mobility group box protein ssrp1 (78‐fold) or the chaperonin containing t‐complex polypeptide 1, beta subunit cctb (22‐fold).  相似文献   

The significance of European high mountain lakes in critical load distributions at the EMEP grid scale     

Chris J. Curtis  Max Posch  Pilar Casals-Carrasco  Jordi Catalan  Mike Hughes  Martin Kernan  Marc Ventura 《Aquatic Sciences - Research Across Boundaries》2005,67(3):252-262

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