Palaeomagnetism and K-Ar Ages of Neogene Rocks of Northern Taiwan: Tectonics of the Arc Junction of Ryukyu and Luzon Arcs     

Masako Miki  Masahide Furukawa  Yo-Ichiro Otofuji  Shuhjong Tsao  Tunyow Huang 《Geophysical Journal International》1993,114(2):225-235

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Temporal Change of Dissolved Inorganic Carbon in the Subsurface Water at Station KNOT (44°N, 155°E) in the Western North Pacific Subpolar Region     

Masahide?WakitaEmail author  Shuichi?Watanabe  Yutaka?W.?Watanabe  Tsuneo?Ono  Nobuo?Tsurushima  Shizuo?Tsunogai 《Journal of Oceanography》2005,61(1):129-139

The dissolved inorganic carbon (DIC) and related chemical species have been measured from 1992 to 2001 at Station KNOT (44°N, 155°E) in the western North Pacific subpolar region. DIC (1.3∼2.3 µ mol/kg/yr) and apparent oxygen utilization (AOU, 0.7∼1.8 µmol/kg/yr) have increased while total alkalinity remained constant in the intermediate water (26.9∼27.3σ_θ). The increases of DIC in the upper intermediate water (26.9∼27.1σ_θ) were higher than those in the lower one (27.2∼ 27.3σ_θ). The temporal change of DIC would be controlled by the increase of anthropogenic CO₂, the decomposition of organic matter and the non-anthropogenic CO₂ absorbed at the region of intermediate water formation. We estimated the increase of anthropogenic CO₂ to be only 0.5∼0.7 µmol/kg/yr under equilibrium with the atmospheric CO₂ content. The effect of decomposition was estimated to be 0.8 ± 0.7 µmol/kg/yr from AOU increase. The remainder of non-anthropogenic CO₂ had increased by 0.6 ± 1.1 µmol/kg/yr. We suggest that the non-anthropogenic CO₂ increase is controlled by the accumulation of CO₂ liberated back to atmosphere at the region of intermediate water formation due to the decrease of difference between DIC in the winter mixed layer and DIC under equilibrium with the atmospheric CO₂ content, and the reduction of diapycnal vertical water exchange between mixed layer and pycnocline waters. In future, more accurate and longer time series data will be required to confirm our results.  相似文献   

Formation of intermediate-mass black holes as primordial black holes in the inflationary cosmology with running spectral index     

Toshihiro Kawaguchi  Masahiro Kawasaki    Tsutomu Takayama  Masahide Yamaguchi  Jun'ichi Yokoyama 《Monthly notices of the Royal Astronomical Society》2008,388(3):1426-1432

Formation of primordial black holes (PBHs) on astrophysical mass scales is a natural consequence of inflationary cosmology, if the primordial perturbation spectrum has a large and negative running of the spectral index as observationally suggested today because double inflation is required to explain it and fluctuations on some astrophysical scales are enhanced in the field-oscillation regime in between. It is argued that PBHs thus produced can serve as intermediate-mass black holes (IMBHs), which act as the observed ultraluminous X-ray sources (ULXs) by choosing appropriate values of the model parameters in their natural ranges. Our scenario can be observationally tested in near future because the mass of PBHs is uniquely determined once we specify the values of the amplitude of the curvature perturbation, spectral index and its running on large scales.  相似文献   

Dichothermal layer deepening in relation with halocline depth change associated with northward shrinkage of North Pacific western subarctic gyre in early 2000s     

Akira Nagano  Masahide Wakita  Shuichi Watanabe 《Ocean Dynamics》2016,66(2):163-172

In the western subarctic North Pacific, a wind-driven cyclonic circulation, called the western subarctic gyre (WSAG), exists. We examined year-to-year changes of the gyre and hydrographic structures, applying the altimetry-based gravest empirical mode (AGEM) method to hydrographic and altimetric sea surface height (SSH) data, and relation to the in situ variation of the temperature minimum layer, i.e., the dichothermal layer, depth at station K2 (47^° N, 160^° E). The AGEM-based geostrophic volume transport and the streamfunction of the WSAG in the top 1000-dbar layer show that the gyre changes substantially. From the late 1990s to the mid-2000s, the gyre shrunk northward. Due to the shrinkage, the halocline bottom, which is equivalent to the top of the main pycnocline, deepens at K2 outside the central part of the gyre. The downward displacement of the dichothermal layer at K2 was found to be significantly related to that of the underlying halocline due to the northward shrinkage of the WSAG.  相似文献   

Distribution of Fe among octahedral sites and its effect on the crystal structure of pumpellyite     

Mariko Nagashima  Takahiro Ishida  Masahide Akasaka 《Physics and Chemistry of Minerals》2006,33(3):178-191

Two pumpellyites with the general formula W ₈ X ₄ Y ₈ Z ₁₂O_56-n (OH) _n were studied using ⁵⁷Fe Mössbauer spectroscopic and X-ray Rietveld methods to investigate the relationship between the crystal chemical behavior of iron and structural change. The samples are ferrian pumpellyite-(Al) collected from Mitsu and Kouragahana, Shimane Peninsula, Japan. Rietveld refinements gave Fe(X):Fe(Y) ratios (%) of 41.5(4):58.5(4) for the Mitsu pumpellyite and 46(1):54(1) for the Kouragahana pumpellyite, where Fe(X) and Fe(Y) represent Fe content at the X and Y sites, respectively. The Mössbauer spectra consisted of two Fe²⁺ and two Fe³⁺ doublets for the Mitsu pumpellyite, and one Fe²⁺ and two Fe³⁺ doublets for the Kouragahana pumpellyite. In terms of the area ratios of the Mössbauer doublets and the Fe(X):Fe(Y) ratios determined by the Rietveld refinements, Fe²⁺(X):Fe³⁺(X):Fe³⁺(Y) ratios are determined to be 22:14:64 for the Mitsu pumpellyite and 27:8:65 for the Kouragahana pumpellyite. By applying the Fe²⁺:Fe³⁺-ratio determined by the Mössbauer analysis and the site occupancies of Fe at the X and Y sites given by the Rietveld method together with chemical analysis, the resulting formula of the Mitsu and Kouragahana pumpellyites are established as Ca₈(Fe _0.88 ²⁺ Mg_0.68Fe _0.77 ³⁺ Al_1.66)_Σ3.99(Al_5.67Fe _2.34 ³⁺ )_Σ8.01Si₁₂O_42.41(OH)_13.59 and Ca₈(Mg_1.24Fe _0.65 ²⁺ Fe _0.46 ³⁺ Al_1.66)_Σ4.01(Al_6.71Fe _1.29 ³⁺ )_Σ8.00Si₁₂O_42.14(OH)_13.86, respectively. Mean Y–O distances and volumes of the YO₆ octahedra increase with increasing mean ionic radii, i.e., the Fe³⁺→Al substitution at the Y site. However, change of the sizes of XO₆ octahedra against the mean ionic radii at the X site is not distinct, and tends to depend on the volume change of the YO₆ octahedra. Thus, the geometrical change of the YO₆ octahedra with Fe³⁺→Al substitution at the Y site is essential for the structural changes of pumpellyite. The expansion of the YO₆ octahedra by the ionic substitution of Fe³⁺ for Al causes gradual change of the octahedra to more symmetrical and regular forms.  相似文献   

An overview of decadal climate predictability in a multi-model ensemble by climate model MIROC   总被引：1，自引：1，他引：0  

Yoshimitsu Chikamoto  Masahide Kimoto  Masayoshi Ishii  Takashi Mochizuki  Takashi T. Sakamoto  Hiroaki Tatebe  Yoshiki Komuro  Masahiro Watanabe  Toru Nozawa  Hideo Shiogama  Masato Mori  Sayaka Yasunaka  Yukiko Imada 《Climate Dynamics》2013,40(5-6):1201-1222

Decadal climate predictability is examined in hindcast experiments by a multi-model ensemble using three versions of the coupled atmosphere-ocean model MIROC. In these hindcast experiments, initial conditions are obtained from an anomaly assimilation procedure using the observed oceanic temperature and salinity with prescribed natural and anthropogenic forcings on the basis of the historical data and future emission scenarios in the Intergovernmental Panel of Climate Change. Results of the multi-model ensemble in our hindcast experiments show that predictability of surface air temperature (SAT) anomalies on decadal timescales mostly originates from externally forced variability. Although the predictable component of internally generated variability has considerably smaller SAT variance than that of externally forced variability, ocean subsurface temperature variability has predictive skills over almost a decade, particularly in the North Pacific and the North Atlantic where dominant signals associated with Pacific decadal oscillation (PDO) and the Atlantic multidecadal oscillation (AMO) are observed. Initialization enhances the predictive skills of AMO and PDO indices and slightly improves those of global mean temperature anomalies. Improvement of these predictive skills in the multi-model ensemble is higher than that in a single-model ensemble.  相似文献   

Structural variation of babingtonite depending on cation distribution at the octahedral sites     

Mariko Nagashima  Keiko Mitani  Masahide Akasaka 《Mineralogy and Petrology》2014,108(2):287-301

Babingtonite, Ca₂Fe²⁺Fe³⁺[Si₅O₁₄(OH)] (Z?=?2, space group $ P\overline{1} $ ) from Yakuki mine (Japan), Grönsjöberget (Sweden), Kandivali Quarry (India), Baveno Quarry (Italy), Bråstad Mine (Norway), and Kouragahana (Japan), and manganbabingtonite, Ca₂(Mn²⁺, Fe²⁺)Fe³⁺[Si₅O₁₄(OH)], from Iron Cap mine (USA) were studied using electron-microprobe analysis (EMPA), ⁵⁷Fe Mössbauer analysis and single-crystal X-ray diffraction methods to determine the cation distribution at M1 and M2 and to analyze its effect on the crystal structure of babingtonite. Although all studied babingtonite crystals are relatively homogeneous, chemical zonation due to mainly Fe ? Mn substitution is observed in manganbabingtonite. Mössbauer spectra consist of two doublets with isomer shift (I.S.)?=?1.16–1.22 mm/s and quadrupole splitting (Q.S.)?=?2.33–2.50 mm/s and with I.S.?=?0.38–0.42 mm/s and Q.S.?=?0.82–0.90 mm/s, assigned to Fe²⁺ and Fe³⁺ at the M1 and M2 octahedral sites, respectively. The determined ratio of Fe²⁺/total Fe in manganbabingtonite (0.26) was smaller than that in the others (0.35–0.44) because of high Mn²⁺ content instead of Fe²⁺. The unit-cell parameters of babingtonite are a?=?7.466–7.478, b?=?11.624–11.642, c?=?6.681–6.690 Å, α?=?91.53–91.59, β?=?93.86–93.94, γ?=?104.20–104.34º, and V?=?560.2–562.3 Å³, and those of manganbabingtonite are a?=?7.4967(3), b?=?11.6632(4), c?=?6.7014(2) Å, α?=?91.602(2), β?=?93.989(2), γ?=?104.574(3)º, and V =565.09(5) ų. Structural refinements converged to R ₁ values of 1.64–3.16 %. The <M1-O> distance was lengthened due to the substitution of large octahedral cations such as Mn²⁺ for Fe²⁺. The increase of the M1-O8, M1-O8’ and M1-O13 lengths with mean ionic radii is slightly more pronounced than of the other M1-Oi lengths. The lengthened M1-O13 distance leads the positive correlation between Si5-O15-Si1 angle and M1-O13 distance. The increase of Si2-O3-Si1 and Si5-O12-Si4 angles due to the increase of mean ionic radius of M2 is also observed.  相似文献   

Comparison of carbon cycle between the western Pacific subarctic and subtropical time-series stations: highlights of the K2S1 project     

Makio C. Honda  Masahide Wakita  Kazuhiko Matsumoto  Tetsuichi Fujiki  Eko Siswanto  Kosei Sasaoka  Hajime Kawakami  Yoshihisa Mino  Chiho Sukigara  Minoru Kitamura  Yoshikazu Sasai  Sherwood L. Smith  Taketo Hashioka  Chisato Yoshikawa  Katsunori Kimoto  Shuichi Watanabe  Toru Kobari  Toshi Nagata  Koji Hamasaki  Ryo Kaneko  Mario Uchimiya  Hideki Fukuda  Osamu Abe  Toshiro Saino 《Journal of Oceanography》2017,73(5):647-667

A comparative study of ecosystems and biogeochemistry at time-series stations in the subarctic gyre (K2) and subtropical region (S1) of the western North Pacific Ocean (K2S1 project) was conducted between 2010 and 2013 to collect essential data about the ecosystem and biological pump in each area and to provide a baseline of information for predicting changes in biologically mediated material cycles in the future. From seasonal chemical and biological observations, general oceanographic settings were verified and annual carbon budgets at both stations were determined. Annual mean of phytoplankton biomass and primary productivity at the oligotrophic station S1 were comparable to that at the eutrophic station K2. Based on chemical/physical observations and numerical simulations, the likely “missing nutrient source” was suggested to include regeneration, meso-scale eddy driven upwelling, meteorological events, and eolian inputs in addition to winter vertical mixing. Time-series observation of carbonate chemistry revealed that ocean acidification (OA) was ongoing at both stations, and that the rate of OA was faster at S1 than at K2 although OA at K2 is more critical for calcifying organisms.  相似文献